CN107952203A - A kind of preparation method of fire-extinguishing composite for liquid fire - Google Patents

A kind of preparation method of fire-extinguishing composite for liquid fire Download PDF

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Publication number
CN107952203A
CN107952203A CN201711250275.0A CN201711250275A CN107952203A CN 107952203 A CN107952203 A CN 107952203A CN 201711250275 A CN201711250275 A CN 201711250275A CN 107952203 A CN107952203 A CN 107952203A
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China
Prior art keywords
fire
solid particle
mixture
hydrophobic solid
parts
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CN201711250275.0A
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Chinese (zh)
Inventor
李会玲
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Chengdu Jun Hetiancheng Science And Technology Ltd
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Chengdu Jun Hetiancheng Science And Technology Ltd
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Priority to CN201711250275.0A priority Critical patent/CN107952203A/en
Publication of CN107952203A publication Critical patent/CN107952203A/en
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    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0028Liquid extinguishing substances
    • A62D1/0035Aqueous solutions
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0071Foams
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0071Foams
    • A62D1/0078Foams containing proteins or protein derivatives

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Fire-Extinguishing Compositions (AREA)

Abstract

The invention discloses a kind of preparation method of the fire-extinguishing composite for liquid fire, including hydrophobic solid particle is put into the step fully air-dried in apparatus for drying;Hydrophobic solid particle is put into the step of ball mill carries out ball milling;Foaming agent, stabilizer, hydrophobic solid particle are put into the step of being mixed in blender, and solute is put into clear water and is mixed, the mixture for forming the foaming agent, stabilizer and hydrophobic solid particle that aqueous solution is added in step 3 forms extinguishing chemical;The step of extinguishing chemical of acquisition is contained in compression resistanted container and applies 1.8 2.3 atmospheric pressure storages.The present invention is by adding the ball milling step of hydrophobic solid particle, the element diameter of hydrophobic solid particle is substantially diminished, the body surface that catches fire can be more uniformly adhered to, the foam that foaming agent produces is coordinated rapidly to form the film of one layer of isolation, quick extinguishing in the environment of high temperature sintering.

Description

A kind of preparation method of fire-extinguishing composite for liquid fire
Technical field
The present invention relates to fire-fighting quipment field, the extinguishing chemical field more particularly, to put out a fire, is a kind of use specifically In the preparation method of the fire-extinguishing composite of liquid fire.
Background technology
Fire extinguisher is a kind of portable Fire extinguisher.Chemical substance is placed in fire extinguisher, to rescue fire extinguishing calamity.Fire extinguisher is One of common fireproofing installation, is stored in public place or the place of fire may occur, filling in different types of fire extinguisher Component it is different, be to aim at different fire alarms and set.It must be noted that during use in order to avoid producing minus effect and causing danger.
Existing extinguishing chemical mainly has two kinds of a foam and dry powder, and two kinds of extinguishing chemicals respectively have a quality, going out in dry powder extinguisher Perlate salt is filled in fiery agent to be used to put out a fire dry and be easy to flow attritive powder by tool fire extinguishing effectiveness machine salt a small amount of additive Extensively using extinguishing chemical and it is mainly used for fire extinguisher except metal of putting out a fire to save life and property through drying, crushing, the fire-fighting of mixing micro-solid powder group kind BC dry powder fire extinguishing agents (sodium acid carbonate) ABC dry powder (perlate salt) as the outer dry powder fire extinguishing agent of the special dry powdered extinguishing chemical of fire Two classes produce free radical with burning journey fuel by dry powder machine salt volatility solution thing or property group hairization suppresses negative catalyst and makes combustion Chain reaction is burnt to break fire extinguishing;Two fall the outgoingization reaction of combustion things surface and the glassy coating isolation of high temperature action shape layer by dry powder powder Oxygen plays certain cooling effect into the another external dilution oxygen of fire smothering.Fire foam is a kind of small volume, and surface is by liquid The bubble population that body surrounds, proportion is between 0.001~0.5.Since the proportion of foam is far smaller than the proportion of general flammable liquid, The surface of liquid can be thus floated on, forms a foam blanket.Meanwhile foam has certain viscosity again, can glue Invest the surface of general flammable solid.The foam blanket that fire foam is formed on comburant surface, can make comburant surface with Air insulated.
Different due to occurring the condition of a disaster of fire in actual life, the fire that different materials occurs not only wants specific aim Selection fire-extinguishing apparatus, more it is noted that selection extinguishing chemical, so could more preferably, faster, safer stamps out a fire.Therefore, carry Prepare that above-mentioned fire-fighting safety is reliable for one kind, the method meaning of efficient extinguishing chemical is extremely important.
The content of the invention
It is an object of the invention to provide a kind of preparation method of the fire-extinguishing composite for liquid fire, existing skill is solved The problem of dry powder extinguisher in art is not easy to put out oiliness fire and relatively low fire foam fire-fighting efficiency.
The present invention is achieved through the following technical solutions:
A kind of preparation method of fire-extinguishing composite for liquid fire, including following preparation process:
Step 1:Hydrophobic solid particle is put into apparatus for drying and is fully air-dried, and is spaced 30 minutes and hydrophobicity is consolidated Body particle carries out processing of weighing, when air-dry before and air-dry after quality difference be less than 2% when, stop air-dry, and will air-dry after dredge Aqueous solid particle pours out, and contains.
Step 2:It is small that the hydrophobic solid particle air-dried by step 1 is put into ball mill progress ball mill grinding 48-80 When, then the hydrophobic solid particle by the complete refinement of ball milling is toppled over, and is saved backup.
Step 3:Take the foaming agent of 6-8 mass parts, the stabilizer of 4-7 mass parts, the hydrophobic solid of 30-40 mass parts Particle is put into blender and is mixed.
Step 4:It is sylvite dry powder by solute, calcium carbonate particle, the mixture of sodium bicarbonate powder, dipotassium hydrogen phosphate, phosphorus One or more mixtures in sour disodium hydrogen, potassium dihydrogen phosphate, which are put into clear water, to be mixed, and is formed aqueous solution and is added step 3 In the foaming agent, the mixture of stabilizer and hydrophobic solid particle form extinguishing chemical.
Step 5:The extinguishing chemical obtained in step 4 is contained in compression resistanted container and applies 1.8-2.3 atmospheric pressure storage Hide spare.
Preferably, the hydrophobic solid particle in the step 1 is talc particles, aluminium oxide particles, aluminum hydroxide particles Middle one or more mixture.
Preferably, the constituent mass content of talc particles is respectively 20%-25% in the hydrophobic solid particle, aluminium oxide The constituent content of particle is respectively 35%-42%, remaining is aluminum hydroxide particles.
Preferably, foaming agent is plant protein hydrolysate or benzene sulfonyl hydrazide in the step 3;The stabilizer is polymerization chlorine Change aluminium.
Preferably, aqueous solution is made of the water of 60%-65% mass and the solute of 35%-40% in the step 4, and described A constituent mass percentage composition is respectively in solute:Sylvite dry powder, calcium carbonate particle, the mixture of sodium bicarbonate powder are 18%-25%, dipotassium hydrogen phosphate 30%-45%, disodium hydrogen phosphate 5%-8%, remaining is potassium dihydrogen phosphate.
Preferably, the mass parts of the foaming agent are 7 parts, and the mass parts of stabilizer are 6 parts, the matter of hydrophobic solid particle It is 40 parts to measure part, remaining is the mixture of aqueous solution, and the solute of the aqueous solution is sylvite dry powder, calcium carbonate particle, bicarbonate The mixture and dipotassium hydrogen phosphate of sodium dry powder are with 1:The mixture of 1 ratio mixing.
Preferably, the mass parts of the foaming agent are 6 parts, and the mass parts of stabilizer are 5 parts, the matter of hydrophobic solid particle It is 35 parts to measure part, remaining is the mixture of aqueous solution, and the solute of the aqueous solution is sylvite dry powder, calcium carbonate particle, bicarbonate The mixture and potassium dihydrogen phosphate of sodium dry powder are with 2:The mixture of 1 ratio mixing.
According to the method described above, the present invention provides the preferred solution of extinguishing chemical component and content.
It is a kind of be used to put out the extinguishing chemical of liquid oily matter fire, by the foaming agent of 6-8 mass parts, 4-7 mass parts The hydrophobic solid particle of stabilizer, 30-40 mass parts, remaining is the mixture of aqueous solution composition, and the foaming agent is plant Protein hydrolysate or benzene sulfonyl hydrazide;The stabilizer is aluminium polychloride, and the hydrophobic solid particle is talc particles, aluminium oxide One or more mixture in particle, aluminum hydroxide particles;The solvent of the aqueous solution is water, and solute is sylvite dry powder, carbon One or more in sour calcium particle, the mixture of sodium bicarbonate powder, dipotassium hydrogen phosphate, disodium hydrogen phosphate, potassium dihydrogen phosphate Mixture, the mass parts of the foaming agent are 7 parts, and the mass parts of stabilizer are 6 parts, and the mass parts of hydrophobic solid particle are 40 parts, remaining is the mixture of aqueous solution, and the solute of the aqueous solution is sylvite dry powder, calcium carbonate particle, sodium bicarbonate powder Mixture and dipotassium hydrogen phosphate with 1:The mixture of 1 ratio mixing;The mass parts of the foaming agent are 6 parts, stabilizer Mass parts are 5 parts, and the mass parts of hydrophobic solid particle are 35 parts, remaining is the mixture of aqueous solution, the aqueous solution it is molten Matter is sylvite dry powder, calcium carbonate particle, the mixture of sodium bicarbonate powder and potassium dihydrogen phosphate with 2:The mixing of 1 ratio mixing Thing.
Yet further, the mass parts of the foaming agent are 5 parts, and the mass parts of stabilizer are 4 parts, hydrophobic solid particle Mass parts be 32 parts, remaining is the mixture of aqueous solution, and the solute of the aqueous solution is sylvite dry powder, calcium carbonate particle, carbon The mixture and dipotassium hydrogen phosphate of sour hydrogen sodium dry powder are with 1:The mixture of 3 ratio mixing.
It is further preferred that the mass parts of the foaming agent are 8 parts, the mass parts of stabilizer are 7 parts, hydrophobic solid grain The mass parts of son are 38 parts, remaining is the mixture of aqueous solution, the solute of the aqueous solution is sylvite dry powder, calcium carbonate particle, The mixture and potassium dihydrogen phosphate of sodium bicarbonate powder are with 5:The mixture of 2 ratio mixing.
Compared with prior art, the present invention haing the following advantages and beneficial effect:
(1)The present invention is by adding the ball milling step of hydrophobic solid particle, by the element diameter of hydrophobic solid particle Substantially diminish, can more be uniformly adhered to the body surface that catches fire, coordinate the foam that foaming agent produces in the ring of high temperature sintering The film of one layer of isolation can be rapidly formed under border, achievees the purpose that quick extinguishing.
(2)Since the present invention is by the way of aqueous solution is mixed with hydrophobic particle thing, and it is applied with least 1.8 air Pressure, the impact force produced in fire extinguishing procedure and the effective fire-fighting area produced in the unit interval substantially increase relative to the prior art By force, so under the injection of fire extinguisher or other fire extinguishing jet devices, combustible surface can be more uniformly adhered to, more Add and effectively realize that large area is put out a fire.
Embodiment
The present invention is described in further detail with reference to embodiment, but the implementation of the present invention is not limited to this.
Preferred embodiment:
A kind of extinguishing chemical for being used to put out liquid oily matter fire, by the foaming agent of 6-8 mass parts, the stabilization of 4-7 mass parts Agent, the hydrophobic solid particle of 30-40 mass parts, remaining is the mixture of aqueous solution composition, and the foaming agent is plant hydrolyzed Albumen or benzene sulfonyl hydrazide;The stabilizer is aluminium polychloride, and the hydrophobic solid particle is talc particles, oxidation aluminum shot One or more mixture in son, aluminum hydroxide particles;The solvent of the aqueous solution is water, and solute is sylvite dry powder, carbonic acid It is one or more in calcium particle, the mixture of sodium bicarbonate powder, dipotassium hydrogen phosphate, disodium hydrogen phosphate, potassium dihydrogen phosphate Mixture, the mass parts of the foaming agent are 7 parts, and the mass parts of stabilizer are 6 parts, and the mass parts of hydrophobic solid particle are 40 Part, remaining is the mixture of aqueous solution, and the solute of the aqueous solution is sylvite dry powder, calcium carbonate particle, sodium bicarbonate powder Mixture and dipotassium hydrogen phosphate are with 1:The mixture of 1 ratio mixing;The mass parts of the foaming agent are 6 parts, the matter of stabilizer It is 5 parts to measure part, and the mass parts of hydrophobic solid particle are 35 parts, remaining is the mixture of aqueous solution, the solute of the aqueous solution It is sylvite dry powder, calcium carbonate particle, the mixture of sodium bicarbonate powder and potassium dihydrogen phosphate with 2:The mixing of 1 ratio mixing Thing.
Yet further, the mass parts of the foaming agent are 5 parts, and the mass parts of stabilizer are 4 parts, hydrophobic solid particle Mass parts be 32 parts, remaining is the mixture of aqueous solution, and the solute of the aqueous solution is sylvite dry powder, calcium carbonate particle, carbon The mixture and dipotassium hydrogen phosphate of sour hydrogen sodium dry powder are with 1:The mixture of 3 ratio mixing.
It is further preferred that the mass parts of the foaming agent are 8 parts, the mass parts of stabilizer are 7 parts, hydrophobic solid grain The mass parts of son are 38 parts, remaining is the mixture of aqueous solution, the solute of the aqueous solution is sylvite dry powder, calcium carbonate particle, The mixture and potassium dihydrogen phosphate of sodium bicarbonate powder are with 5:The mixture of 2 ratio mixing.
The above, is only presently preferred embodiments of the present invention, not does limitation in any form to the present invention, it is every according to Any simply modification, the equivalent variations made according to the technical spirit of the present invention to above example, each fall within the protection of the present invention Within the scope of.

Claims (7)

1. the preparation method of a kind of fire-extinguishing composite for liquid fire, it is characterised in that including following preparation process:
Step 1:Hydrophobic solid particle is put into apparatus for drying and is fully air-dried, and is spaced 30 minutes and hydrophobicity is consolidated Body particle carries out processing of weighing, when air-dry before and air-dry after quality difference be less than 2% when, stop air-dry, and will air-dry after dredge Aqueous solid particle pours out, and contains;
Step 2:By the hydrophobic solid particle air-dried by step 1 be put into ball mill carry out ball mill grinding 48-80 it is small when, so The hydrophobic solid particle by the complete refinement of ball milling is toppled over afterwards, is saved backup;
Step 3:Take the foaming agent of 6-8 mass parts, the stabilizer of 4-7 mass parts, the hydrophobic solid particle of 30-40 mass parts It is put into blender and is mixed;
Step 4:It is sylvite dry powder by solute, calcium carbonate particle, the mixture of sodium bicarbonate powder, dipotassium hydrogen phosphate, phosphoric acid hydrogen One or more mixtures in disodium, potassium dihydrogen phosphate, which are put into clear water, to be mixed, and is formed aqueous solution and is added in step 3 The mixture of the foaming agent, stabilizer and hydrophobic solid particle forms extinguishing chemical;
Step 5:The extinguishing chemical obtained in step 4 is contained in compression resistanted container and to apply 1.8-2.3 atmospheric pressure storage standby With.
A kind of 2. preparation method of fire-extinguishing composite for liquid fire according to claim 1, it is characterised in that institute It is one or more in talc particles, aluminium oxide particles, aluminum hydroxide particles mix to state the hydrophobic solid particle in step 1 Compound.
A kind of 3. preparation method of fire-extinguishing composite for liquid fire according to claim 2, it is characterised in that institute The constituent mass content for stating talc particles in hydrophobic solid particle is respectively 20%-25%, and the constituent content of aluminium oxide particles divides Not Wei 35%-42%, remaining is aluminum hydroxide particles.
A kind of 4. preparation method of fire-extinguishing composite for liquid fire according to claim 1, it is characterised in that institute It is plant protein hydrolysate or benzene sulfonyl hydrazide to state foaming agent in step 3;The stabilizer is aluminium polychloride.
A kind of 5. preparation method of fire-extinguishing composite for liquid fire according to claim 1, it is characterised in that institute State aqueous solution in step 4 to be made of the water of 60%-65% mass and the solute of 35%-40%, and a constituent mass contains in the solute Measuring percentage is respectively:Sylvite dry powder, calcium carbonate particle, the mixture of sodium bicarbonate powder are 18%-25%, dipotassium hydrogen phosphate is 30%-45%, disodium hydrogen phosphate 5%-8%, remaining is potassium dihydrogen phosphate.
A kind of 6. preparation method of fire-extinguishing composite for liquid fire according to claim 1, it is characterised in that institute The mass parts for stating foaming agent are 7 parts, and the mass parts of stabilizer are 6 parts, and the mass parts of hydrophobic solid particle are 40 parts, remaining is The mixture of aqueous solution, the solute of the aqueous solution is sylvite dry powder, calcium carbonate particle, the mixture and phosphorus of sodium bicarbonate powder Sour hydrogen dipotassium is with 1:The mixture of 1 ratio mixing.
A kind of 7. preparation method of fire-extinguishing composite for liquid fire according to claim 1, it is characterised in that institute The mass parts for stating foaming agent are 6 parts, and the mass parts of stabilizer are 5 parts, and the mass parts of hydrophobic solid particle are 35 parts, remaining is The mixture of aqueous solution, the solute of the aqueous solution is sylvite dry powder, calcium carbonate particle, the mixture and phosphorus of sodium bicarbonate powder Acid dihydride potassium is with 2:The mixture of 1 ratio mixing.
CN201711250275.0A 2017-12-01 2017-12-01 A kind of preparation method of fire-extinguishing composite for liquid fire Pending CN107952203A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711250275.0A CN107952203A (en) 2017-12-01 2017-12-01 A kind of preparation method of fire-extinguishing composite for liquid fire

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711250275.0A CN107952203A (en) 2017-12-01 2017-12-01 A kind of preparation method of fire-extinguishing composite for liquid fire

Publications (1)

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CN107952203A true CN107952203A (en) 2018-04-24

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