CN1079419C - Dry composite adhesive for high-temp. polyurethane bag and its preparing process - Google Patents
Dry composite adhesive for high-temp. polyurethane bag and its preparing process Download PDFInfo
- Publication number
- CN1079419C CN1079419C CN99114097A CN99114097A CN1079419C CN 1079419 C CN1079419 C CN 1079419C CN 99114097 A CN99114097 A CN 99114097A CN 99114097 A CN99114097 A CN 99114097A CN 1079419 C CN1079419 C CN 1079419C
- Authority
- CN
- China
- Prior art keywords
- sebacic acid
- percent
- propylene glycol
- high temperature
- glycol ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 11
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 11
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 10
- 239000004814 polyurethane Substances 0.000 title claims abstract description 10
- 239000002131 composite material Substances 0.000 title claims abstract description 9
- 238000000034 method Methods 0.000 title claims description 17
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims abstract description 22
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Substances CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 21
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 15
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920000728 polyester Polymers 0.000 claims abstract description 7
- 238000006068 polycondensation reaction Methods 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 239000002351 wastewater Substances 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000010792 warming Methods 0.000 claims description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract 6
- 229960004063 propylene glycol Drugs 0.000 abstract 2
- 235000013305 food Nutrition 0.000 description 8
- 239000002985 plastic film Substances 0.000 description 7
- 229920006255 plastic film Polymers 0.000 description 7
- 238000009835 boiling Methods 0.000 description 3
- 238000010025 steaming Methods 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
The dry composite adhesive for high temperature steamed polyurethane bag is prepared with the following components in weight percent:
13.64 to 18.6 percent of diethylene glycol
23.26 to 25.73 percent of sebacic acid
2.06-2.94% of 1.2-propylene glycol
6 to 5.43 percent of isophthalic acid
3.86 to 5.74 percent of diphenylmethane diisocyanate
Ethyl acetate 48.71-44.03%
The manufacturing method comprises the following steps:
firstly, mixing diethylene glycol and sebacic acid, then adding 1, 2-propylene glycol and isophthalic acid, then carrying out polycondensation, reducing pressure to 755 mm Hg to generate polyester, then adding diphenylmethane diisocyanate to generate main adhesive, and finally adding ethyl acetate to dilute, thus completing the invention.
Description
The present invention is a kind of polyurethane binder and manufacture method, in particular for the composite dry adhesive and the manufacture method thereof of high-temperature retort bag.
The food product pack industry is to directly more and more higher together with the requirement that food carries out high temperature steaming together with food pack in the world today, use high-temperature retort bag can be directly the food of production to be encapsulated in to heat in the bag after with seasoning matter and be processed into prepared food to carrying out boiling more than 121 ℃, simplify the production technique of food, guaranteed the health reliability of food.Because pressure pad is made up of the combination of plastic film and plastic film or plastic film/aluminium film/plastic film, the tackiness agent dry type Compound Machining by anti-boiling between plastic film and the plastic film or between plastic film or the aluminium film forms, and has good binding property.And present existing tackiness agent such as Chinese patent " ZL87104917 " nontoxic polyurethane adhesive by name and preparation thereof, the greatest problem of this tackiness agent is that resistance to elevated temperatures is poor, can not under the situation of high temperature steaming, keep high-strength binding property, therefore to high temperature steaming packing bag and inapplicable.
Purpose of the present invention just provides a kind of have moisture-proof, resistant to elevated temperatures composite dry adhesive for high temperature steamed polyurethane bag and manufacture method.
Composite dry adhesive for high temperature steamed polyurethane bag of the present invention component by weight percentage is:
Glycol ether 13.64～18.6%
Sebacic acid 23.26～25.73%
A 1.2 propylene glycol 2.06～2.94%
M-phthalic acid 6～5.43%
Diphenylmethanediisocyanate 3.86～5.74%
Vinyl acetic monomer 48.71～44.03%
The manufacture method of composite dry adhesive for high temperature steamed polyurethane bag of the present invention is:
1. mix: glycol ether and sebacic acid are mixed to heat under the effect of nitrogen and amines catalyst, continue 25 hours, add 1.2 1 propylene glycol and m-phthalic acid then and under 200 ℃ ± 2 ℃ condition, continue 12 hours to 220 ± 2 ℃.
2. polycondensation: former process is decompressed to 755 mmhg, generates intermediate raw material polyester and waste water, useless alcohol.
3. addition: the polyester adding diphenylmethanediisocyanate that former process is generated is cooled to 90～100 ℃ of main glue of generation.
4. dilution: the main glue that will generate adds vinyl acetic monomer, is warming up to 80～90 ℃ and makes tackiness agent.
The invention has the advantages that this tackiness agent has high temperature resistant, moisture-resistant, advantage that bonding strength is high, use the boiling after 30 minutes in 121 ℃ salt solution of high-temperature retort bag that this tackiness agent makes, the intensity of its compound sticking does not have considerable change, is the desirable tackiness agent of food product pack industry production high-temperature retort bag.
Embodiment of the present invention are:
Example 1: count by weight percentage: get
Glycol ether 16.17% is 198kg
Sebacic acid 24.49% is 300kg
1.2 a propylene glycol 2.61% is 32kg
M-phthalic acid 5.72% is 70kg
Diphenylmethanediisocyanate 4.64% is 56.8kg
Vinyl acetic monomer 46.37% is 568kg
Its operation steps is:
1. mix: earlier the glycol ether of 198kg and the sebacic acid of 300kg are mixed, heat to 220 ℃, under the effect of nitrogen and amines catalyst, kept 25 hours, add 32kg1.2 one propylene glycol and 70kg m-phthalic acid afterwards, under 200 ℃ condition, kept 12 hours.
2. polycondensation: former process is decompressed to 755 mmhg, generates intermediate raw material polyester 510kg, waste water 75.5kg, useless pure 14.5kg.
3. addition: the 510kg polyester that former process is produced adds the diphenylmethanediisocyanate of 56.8kg, generates main glue 566.8kg under 90 ℃～100 ℃ condition.
4. dilution: the main glue of 566.8kg is added the vinyl acetic monomer of 568kg, under 85 ℃ condition, vapor away the 1.2kg ethyl ester, generate tackiness agent 1133.6kg.
Example 2: count by weight percentage, get
Glycol ether 13.64%
Sebacic acid 25.73%
A 1.2 propylene glycol 2.06%
M-phthalic acid 6%
Diphenylmethanediisocyanate 3.86%
Vinyl acetic monomer 48.71%
Its operating process is with embodiment 1.
Example 3: count by weight percentage, get
Glycol ether 18.6%
Sebacic acid 23.26%
A 1.2 propylene glycol 2.94%
M-phthalic acid 5.43%
Diphenylmethanediisocyanate 5.74%
Vinyl acetic monomer 44.03%
Its operating process is with embodiment 1.
Just can realize the present invention according to the above.
Claims (2)
1. a composite dry adhesive for high temperature steamed polyurethane bag is made up of glycol ether, sebacic acid, m-phthalic acid, it is characterized in that this tackiness agent component by weight percentage is:
Glycol ether 13.64～18.6%
Sebacic acid 23.26～25.73%
1.2-propylene glycol 2.06～2.94%
M-phthalic acid 6～5.43%
Diphenylmethanediisocyanate 3.86～5.74%
Vinyl acetic monomer 48.71～44.03%.
2. the manufacture method of a composite dry adhesive for high temperature steamed polyurethane bag is characterized in that manufacture method is:
1. mix: glycol ether and sebacic acid are mixed to heat under the effect of nitrogen and amines catalyst, continue 25 hours, add 1.2 1 propylene glycol and m-phthalic acid then and under 200 ℃ ± 2 ℃ condition, continue 12 hours to 220 ± 2 ℃;
2. polycondensation: former process is decompressed to 755 mmhg, generates intermediate raw material polyester and waste water, useless alcohol;
3. addition: the polyester adding diphenylmethanediisocyanate that former process is generated is cooled to 90～100 ℃ of main glue of generation;
4. dilution: the main glue that will generate adds vinyl acetic monomer, is warming up to 80～90 ℃ and makes tackiness agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99114097A CN1079419C (en) | 1999-03-12 | 1999-03-12 | Dry composite adhesive for high-temp. polyurethane bag and its preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99114097A CN1079419C (en) | 1999-03-12 | 1999-03-12 | Dry composite adhesive for high-temp. polyurethane bag and its preparing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1232851A CN1232851A (en) | 1999-10-27 |
| CN1079419C true CN1079419C (en) | 2002-02-20 |
Family
ID=5277218
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99114097A Expired - Fee Related CN1079419C (en) | 1999-03-12 | 1999-03-12 | Dry composite adhesive for high-temp. polyurethane bag and its preparing process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1079419C (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0349838A1 (en) * | 1988-06-28 | 1990-01-10 | Takeda Chemical Industries, Ltd. | Polyurethane adhesive compositions |
| CN1008501B (en) * | 1985-08-08 | 1990-06-20 | 佳能株式会社 | Decoding device for image code |
| CN1087927A (en) * | 1993-11-15 | 1994-06-15 | 辽宁省印刷技术研究所 | The high-temperature boiling resistant tackiness agent of non-metallic ion |
| JPH07196764A (en) * | 1993-12-28 | 1995-08-01 | Sakata Corp | Polyurethane resin, aqueous laminating adhesive composition and method for lamination processing using the same |
| JPH08183829A (en) * | 1994-12-28 | 1996-07-16 | Takeda Chem Ind Ltd | Polyurethane adhesive composition |
| CN1161362A (en) * | 1997-02-21 | 1997-10-08 | 吉林省科技开发实业公司 | Method for preparing single component polyurethane adhesive/seal gum |
-
1999
- 1999-03-12 CN CN99114097A patent/CN1079419C/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1008501B (en) * | 1985-08-08 | 1990-06-20 | 佳能株式会社 | Decoding device for image code |
| EP0349838A1 (en) * | 1988-06-28 | 1990-01-10 | Takeda Chemical Industries, Ltd. | Polyurethane adhesive compositions |
| CN1087927A (en) * | 1993-11-15 | 1994-06-15 | 辽宁省印刷技术研究所 | The high-temperature boiling resistant tackiness agent of non-metallic ion |
| JPH07196764A (en) * | 1993-12-28 | 1995-08-01 | Sakata Corp | Polyurethane resin, aqueous laminating adhesive composition and method for lamination processing using the same |
| JPH08183829A (en) * | 1994-12-28 | 1996-07-16 | Takeda Chem Ind Ltd | Polyurethane adhesive composition |
| CN1161362A (en) * | 1997-02-21 | 1997-10-08 | 吉林省科技开发实业公司 | Method for preparing single component polyurethane adhesive/seal gum |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1232851A (en) | 1999-10-27 |
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| C10 | Entry into substantive examination | ||
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| C06 | Publication | ||
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: CAI BINGZHAO Free format text: FORMER OWNER: JINTAN CITY ADHESIVE FACTORY Effective date: 20110111 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 213200 104, XIMEN AVENUE, JINCHENG TOWN, JINTAN CITY, JIANGSU PROVINCE TO: 213200 NO. 4, YAOCHI VILLA, JINCHENG TOWN, JINTAN CITY, JIANGSU PROVINCE |
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| TR01 | Transfer of patent right |
Effective date of registration: 20110111 Address after: 213200 Jiangsu city of Jintan Province town pool villa No. 4 Patentee after: Cai Bingzhao Address before: 213200 Simon Street, Golden Town, Jiangsu, Jintan 104 Patentee before: Adhesive Factory, Jintan City |
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| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Jiangsu LiHe Adhesive Co., Ltd. Assignor: Cai Bingzhao Contract record no.: 2011320000120 Denomination of invention: Composite dry adhesive for high temperature steamed polyurethane bag and its production process Granted publication date: 20020220 License type: Exclusive License Open date: 19991027 Record date: 20110302 |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20020220 Termination date: 20150312 |
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| EXPY | Termination of patent right or utility model |