CN107936536A - A kind of automobile using inside gadget elastomeric material - Google Patents
A kind of automobile using inside gadget elastomeric material Download PDFInfo
- Publication number
- CN107936536A CN107936536A CN201711403616.3A CN201711403616A CN107936536A CN 107936536 A CN107936536 A CN 107936536A CN 201711403616 A CN201711403616 A CN 201711403616A CN 107936536 A CN107936536 A CN 107936536A
- Authority
- CN
- China
- Prior art keywords
- parts
- automobile
- elastomeric material
- inside gadget
- filler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of automobile using inside gadget elastomeric material, including following raw material：Polyurethane rubber, ethylene propylene diene rubber, polyvinyl alcohol, compounding filler, plasticizer, bobbin oil, Triallyl isocyanurate, sodium potassium silicate, dibasic lead phosphite, antioxidant, sulphur, vulcanizing agent PDM.The automobile using inside gadget elastomeric material of the present invention and existing rubber phase ratio, after rubber compounding, compounding filler, plasticizer, crosslinking agent etc. are added again, it is closely knit to be allowed to structure, pliability is good, and security performance is preferable, easy processing, while it is also equipped with the performance such as high-low temperature resistant, protecting against shock, wear-resisting, oil resistant.
Description
Technical field
The present invention relates to field of rubber technology, and in particular to a kind of automobile using inside gadget elastomeric material.
Background technology
Rubber industry is one of important foundation industry of national economy, is not only provided for the people indispensable in daily life
Daily, the medical light work(rubber product of hydrogen, and to digging, traffic, building, mechano-electronic heavy industry and new industry provide each
Kind rubber system production equipment or rubber components.Based on industry material, application is quite varied.It is many in automobile production field
Rubber needs heat-resisting, cold-resistant, antidetonation, wear-resisting and durable, and this requires rubber has preferable high and low temperature resistance and machine
Tool intensity is to meet condition.Therefore, a kind of obtained high-low temperature resistant damping performance is excellent and the rubber of holding good mechanical properties is
Urgent problem to be solved of the present invention.The present invention provides a kind of automobile using inside gadget elastomeric material so that the rubber being prepared
With good high and low temperature resistance, damping and anti ageing property.
The content of the invention
In view of the above, the present invention provides a kind of automobile using inside gadget elastomeric material so that the rubber being prepared
With good high and low temperature resistance, damping and anti ageing property.
To achieve these goals, the technical solution adopted by the present invention is：A kind of automobile using inside gadget elastomeric material, by with
The raw material composition of lower parts by weight：
70-90 parts of polyurethane rubber, 25-30 parts of ethylene propylene diene rubber, 5-8 parts of polyvinyl alcohol, compounding filler 20-30
Part, 3-5 parts of plasticizer, 5-8 parts of bobbin oil, 0.5-1.5 parts of Triallyl isocyanurate, 1.5-3 parts of sodium potassium silicate, dibasic
0.5-1 parts of lead phosphite, 2-5 parts of antioxidant, 1-2 parts of sulphur, 0.5-1 parts of vulcanizing agent PDM；Wherein, the preparation of filler is compounded
Step is as follows：
Count in parts by weight, weigh 6-8 parts of high impact polystyrenes, 2-3 parts of nano zine oxides, 10-15 parts of gas phase hard charcoals
Black, 3-5 parts of zinc dimethacrylate, 5-8 parts of end hydroxy butadienes and 4-7 parts of perfluoropolyether, are placed in grinder and grind 3-
Taken out after 5h, then the mixture of taking-up is placed in vacuum drying chamber at 55-70 DEG C dry 6-8h, obtain compounding filler.
The plasticizer is plasticizer NB-4 and the compound of paraffin oil；Wherein, the weight of plasticizer NB-4 and paraffin oil
Part is than being 1：(1-1.5).
The antioxidant is the compound of anti-aging agent RD/TMQ and antioxidant ODA；Wherein, anti-aging agent RD/TMQ and antioxidant
The weight part ratio of ODA is 1：(0.8-1.2).
The compounding filler of the present invention is compounded using inorganic toughness reinforcing filler and organic damping high-low temperature resistant filler, then using friendship
Join agent end hydroxy butadiene and perfluoropolyether so that the bond properties and compatibility of inorganic filler and organic filler improve, knot
Structure is closely knit, so as to greatly improve integral strength and performance after inorganic filler and organic filler compounding.
Beneficial effects of the present invention：The automobile using inside gadget elastomeric material of the present invention and existing rubber phase ratio, rubber are multiple
After matching somebody with somebody, then compounding filler, plasticizer, crosslinking agent etc. are added, be allowed to that structure is closely knit, and pliability is good, and security performance is preferable,
Easy processing, while it is also equipped with the performance such as high-low temperature resistant, protecting against shock, wear-resisting, oil resistant.
Embodiment
The embodiment of the present invention is described in detail below.It is it should be appreciated that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to limit the invention.In embodiment, various raw materials are all Marko's ripple
Net product.
Embodiment 1
A kind of automobile using inside gadget elastomeric material, is made of the raw material of following parts by weight：
85 parts of polyurethane rubber, 28 parts of ethylene propylene diene rubber, 6 parts of polyvinyl alcohol, 26 parts of filler of compounding, plasticizer NB-4
2 parts, 3 parts of paraffin oil, 6 parts of bobbin oil, 1 part of Triallyl isocyanurate, 2 parts of sodium potassium silicate, dibasic lead phosphite 0.5
Part, 2 parts of anti-aging agent RD, 2 parts of antioxidant ODA, 1.5 parts of sulphur, 0.8 part of vulcanizing agent PDM；Wherein, the preparation of filler is compounded
Step is as follows：
Count in parts by weight, weigh 7 parts of high impact polystyrenes, 3 parts of nano zine oxides, 13 parts of gas-phase silicas, 4 part two
Zinc methacrylate, 6 parts of end hydroxy butadienes and 5 parts of perfluoropolyether, are placed in grinder after grinding 4h and take out, then will take out
Mixture be placed in vacuum drying chamber at 60 DEG C dry 7h, obtain compounding filler.
Embodiment 2
A kind of automobile using inside gadget elastomeric material, is made of the raw material of following parts by weight：
90 parts of polyurethane rubber, 30 parts of ethylene propylene diene rubber, 8 parts of polyvinyl alcohol, 28 parts of filler of compounding, plasticizer NB-4
2.5 parts, 2.5 parts of paraffin oil, 7 parts of bobbin oil, 1.5 parts of Triallyl isocyanurate, 2.5 parts of sodium potassium silicate, dibasic phosphorous
0.8 part of lead plumbate, 2.5 parts of antioxidant TMQ, 2 parts of antioxidant ODA, 2 parts of sulphur, 1 part of vulcanizing agent PDM；Wherein, filler is compounded
Preparation process it is as follows：
Count in parts by weight, weigh 8 parts of high impact polystyrenes, 3 parts of nano zine oxides, 15 parts of gas-phase silicas, 4 part two
Zinc methacrylate, 7 parts of end hydroxy butadienes and 6 parts of perfluoropolyether, are placed in grinder after grinding 5h and take out, then will take out
Mixture be placed in vacuum drying chamber at 60 DEG C dry 7h, obtain compounding filler.
Test example
Air oven aging test is carried out to automobile using inside gadget elastomeric material produced by the present invention, according to GB/T3512-
2001 standard testings, aging condition：175℃,96h；Tensile strength test, test side are carried out to automobile using inside gadget elastomeric material
Method is according to GB/T528-1998 standard testings；Akron abrasion test, test method are carried out to automobile using inside gadget elastomeric material
According to GB/T1689-1998 standard testings；To automobile using inside gadget elastomeric material carry out impact strength test, test method according to
GB/T1697-2001 standard testings；Its portion of techniques parameter is as follows：
Claims (3)
1. a kind of automobile using inside gadget elastomeric material, it is characterised in that be made of the raw material of following parts by weight：
70-90 parts of polyurethane rubber, 25-30 parts of ethylene propylene diene rubber, 5-8 parts of polyvinyl alcohol, 20-30 parts of filler of compounding, increasing
Mould 3-5 parts of agent, 5-8 parts of bobbin oil, 0.5-1.5 parts of Triallyl isocyanurate, 1.5-3 parts of sodium potassium silicate, dibasic phosphorous
0.5-1 parts of lead plumbate, 2-5 parts of antioxidant, 1-2 parts of sulphur, 0.5-1 parts of vulcanizing agent PDM；Wherein, the preparation process of filler is compounded
It is as follows：
Count in parts by weight, weigh 6-8 parts of high impact polystyrenes, 2-3 parts of nano zine oxides, 10-15 parts of gas-phase silicas, 3-
5 parts of zinc dimethacrylates, 5-8 parts of end hydroxy butadienes and 4-7 parts of perfluoropolyether, are placed in grinder after grinding 3-5h and take
Go out, then the mixture of taking-up is placed in vacuum drying chamber at 55-70 DEG C dry 6-8h, obtain compounding filler.
A kind of 2. automobile using inside gadget elastomeric material according to claim 1, it is characterised in that：The plasticizer is plasticising
The compound of agent NB-4 and paraffin oil；Wherein, the weight part ratio of plasticizer NB-4 and paraffin oil is 1：(1-1.5).
A kind of 3. automobile using inside gadget elastomeric material according to claim 1, it is characterised in that：The antioxidant is anti-old
The compound of agent RD/TMQ and antioxidant ODA；Wherein, the weight part ratio of anti-aging agent RD/TMQ and antioxidant ODA are 1：(0.8-
1.2)。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711403616.3A CN107936536A (en) | 2017-12-22 | 2017-12-22 | A kind of automobile using inside gadget elastomeric material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711403616.3A CN107936536A (en) | 2017-12-22 | 2017-12-22 | A kind of automobile using inside gadget elastomeric material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107936536A true CN107936536A (en) | 2018-04-20 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711403616.3A Pending CN107936536A (en) | 2017-12-22 | 2017-12-22 | A kind of automobile using inside gadget elastomeric material |
Country Status (1)
| Country | Link |
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| CN (1) | CN107936536A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109082101A (en) * | 2018-07-03 | 2018-12-25 | 阜南县创发工艺品有限公司 | A kind of high-intensitive Artificial board for braiding |
Citations (6)
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|---|---|---|---|---|
| WO2001010950A1 (en) * | 1999-08-09 | 2001-02-15 | Huntsman International Llc | Thermoplastic vulcanizates from dynamically vulcanized tpu/apolar rubber blends |
| CN102250422B (en) * | 2011-05-24 | 2013-06-05 | 上海众力汽车部件有限公司 | Low-hardness and high temperature resistant rubber material with excellent tensile and fatigue performance |
| CN104119670A (en) * | 2014-07-17 | 2014-10-29 | 桐城市永锦建筑工程有限公司 | High-wear-resistance tear-resistant polyurethane rubber |
| CN104292418A (en) * | 2014-09-26 | 2015-01-21 | 苏州博利迈新材料科技有限公司 | Automobile mattress and preparation method thereof |
| CN105524357A (en) * | 2014-09-29 | 2016-04-27 | 中国石油化工股份有限公司 | Thermoplastic vulcanizate and preparation method thereof |
| CN107325532A (en) * | 2017-08-24 | 2017-11-07 | 芜湖凯奥尔环保科技有限公司 | A kind of wear-resisting high-impact compounded rubber and preparation method thereof |
-
2017
- 2017-12-22 CN CN201711403616.3A patent/CN107936536A/en active Pending
Patent Citations (6)
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|---|---|---|---|---|
| WO2001010950A1 (en) * | 1999-08-09 | 2001-02-15 | Huntsman International Llc | Thermoplastic vulcanizates from dynamically vulcanized tpu/apolar rubber blends |
| CN102250422B (en) * | 2011-05-24 | 2013-06-05 | 上海众力汽车部件有限公司 | Low-hardness and high temperature resistant rubber material with excellent tensile and fatigue performance |
| CN104119670A (en) * | 2014-07-17 | 2014-10-29 | 桐城市永锦建筑工程有限公司 | High-wear-resistance tear-resistant polyurethane rubber |
| CN104292418A (en) * | 2014-09-26 | 2015-01-21 | 苏州博利迈新材料科技有限公司 | Automobile mattress and preparation method thereof |
| CN105524357A (en) * | 2014-09-29 | 2016-04-27 | 中国石油化工股份有限公司 | Thermoplastic vulcanizate and preparation method thereof |
| CN107325532A (en) * | 2017-08-24 | 2017-11-07 | 芜湖凯奥尔环保科技有限公司 | A kind of wear-resisting high-impact compounded rubber and preparation method thereof |
Non-Patent Citations (5)
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| 严莲荷，等: "《水处理药剂及配方手册》", 31 January 2004, 中国石化出版社 * |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109082101A (en) * | 2018-07-03 | 2018-12-25 | 阜南县创发工艺品有限公司 | A kind of high-intensitive Artificial board for braiding |
| CN109082101B (en) * | 2018-07-03 | 2020-11-27 | 阜南县创发工艺品有限公司 | High-strength artificial wood board for weaving and preparation method thereof |
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| SE01 | Entry into force of request for substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180420 |
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| RJ01 | Rejection of invention patent application after publication |