CN107936310A - A kind of degradable vest shopping bag and its production technology - Google Patents

A kind of degradable vest shopping bag and its production technology Download PDF

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Publication number
CN107936310A
CN107936310A CN201711391280.3A CN201711391280A CN107936310A CN 107936310 A CN107936310 A CN 107936310A CN 201711391280 A CN201711391280 A CN 201711391280A CN 107936310 A CN107936310 A CN 107936310A
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CN
China
Prior art keywords
parts
degradable
vest
shopping bag
plant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711391280.3A
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Chinese (zh)
Inventor
缪磊
孙建军
邱丰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Star Fire Plentiful Environmental Packaging Co Ltd
Original Assignee
Suzhou Star Fire Plentiful Environmental Packaging Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Star Fire Plentiful Environmental Packaging Co Ltd filed Critical Suzhou Star Fire Plentiful Environmental Packaging Co Ltd
Priority to CN201711391280.3A priority Critical patent/CN107936310A/en
Publication of CN107936310A publication Critical patent/CN107936310A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02Starch; Degradation products thereof, e.g. dextrin
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45CPURSES; LUGGAGE; HAND CARRIED BAGS
    • A45C3/00Flexible luggage; Handbags
    • A45C3/04Shopping bags; Shopping nets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Abstract

The present invention is packaging material field, more particularly to a kind of degradable vest shopping bag, it is made of 0.8 part of 20 parts of 22 parts of 25 parts of plant amylum, plant fiber, the polyhydroxyalkanoate of parts by weight meter, 20 parts of polylactic acid, 12 parts of polyadipate butylene terephthalate, 6 parts of pentaerythrite, 1 part of nano-titanium dioxide, 0.6 part of plant paraffin, 0.8 part of plasticizer and stabilizer.The present invention has the advantages that tough and tensile, firm and degradation rate is fast.

Description

A kind of degradable vest shopping bag and its production technology
Technical field
The present invention is packaging material field, and in particular to a kind of degradable vest shopping bag and its production technology.
Technical background
Shopping bag is the essential items that people go out shopping.Available shopping bag mainly has currently on the market:Plastics are done shopping Bag, non-woven fabric shopping bag, stationery shopping bag, linen-cotton shopping bag etc..Wherein plastics package is the most commonly used, but its transition Dependent on fossil resources, the pollution to environment is maximum.Therefore, degredation plastic is vigorously promoted the use, this is to solve " white dirt The effective way of dye " problem.
There is the manufacturing technology of several degradable materials such as light degradation, thermal degradation, biodegradation at present.From the point of view of degradation pathway, Biodegradable feasibility is higher, is the hot spot studied at present.The problem of taking into account of biological degradability and mechanical property is existing skill Art common problem.
The content of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, there is provided a kind of degradable vest shopping bag and its life Production. art.
To achieve the object of the present invention, the technical solution adopted by the present invention is:
A kind of degradable vest shopping bag, by 22 parts of 25 parts of plant amylum, plant fiber, the poly- hydroxy aliphatic of parts by weight meter 20 parts of acid esters, 20 parts of polylactic acid, 12 parts of polyadipate-butylene terephthalate, 6 parts of pentaerythrite, nano-titanium dioxide 1 Part, 0.6 part of plant paraffin, 0.8 part of plasticizer and 0.8 part of stabilizer are made.
Preferably, the plant amylum is selected from the one or more of wheaten starch, cornstarch and rice starch.
Preferably, the particle diameter of the nano-titanium dioxide is 300~400nm.
Preferably, the plasticizer is selected from the one or more of ethylene glycol, sorbierite and dibutyl phthalate.
Preferably, one or more of the stabilizer in stearic acid sodium, potassium stearate and epoxy resin.
Preferably, one or more of the plant fiber in maize straw, sawdust and Cotton Stalk.
A kind of production technology of degradable vest shopping bag, includes the following steps:
(1) by 25 parts of plant amylum, 22 parts of plant fiber, 20 parts of polyhydroxyalkanoate, 20 parts of polylactic acid, gather oneself two 12 parts of acid-butylene terephthalate, 6 parts of pentaerythrite, 1 part of nano-titanium dioxide, 0.6 part of plant paraffin, 0.8 part of plasticizer Added with stabilizer in reactor for 0.8 part, purpose particle is melted into molten condition, and extrusion molding system under conditions of stirring Obtain film;
(2) start wrap-up, first press and open making button, then press Scroll compression cylinder button, receive air heave type Spool is close to winding roller completely, presses traction lockage button afterwards, and the set-point for adjusting traction frequency convertor is 7M/MIN;Press again Lower inching button, makes extrusion machine trolley be moved to the surface of Compound cooling roller, presses lower compression roller and closes button, makes Compound cooling roller And silica gel roller, counter-pressure cylinder are close to, it is 5 kg/cms to adjust its atmospheric pressure;
(3) corresponding impression cylinder is selected according to product requirement, after embossing machine is embossed, the pattern that sets out on request, Print on plastic film, by winding, cut, flanging, pack after heat-sealing, up to degradable vest shopping bag through color press.
Preferably, the temperature control of step (1) is at 170~180 DEG C.
Relative to the prior art, the application achieves following beneficial effect:
Package 0.015~0.020mm of thickness prepared by the present invention, consumption material is few, and comprehensive use cost is relatively low;Consuming On the basis of material is less, excellent mechanical property is achieved;
Package made from raw material proportioning according to the present invention is tough and tensile, firm, has good biodegradability and drop It is very fast to solve speed, and is produced during burning disposal without poisonous and harmful substance, environmental-protecting performance is excellent.
Shopping bag prepared by the present invention can effectively reduce white pollution, improve City Landscape Environment.
Embodiment
Embodiment 1
A kind of degradable vest shopping bag, by 22 parts of 25 parts of plant amylum, plant fiber, the poly- hydroxy aliphatic of parts by weight meter 20 parts of acid esters, 20 parts of polylactic acid, 12 parts of polyadipate-butylene terephthalate, 6 parts of pentaerythrite, nano-titanium dioxide 1 Part, 0.6 part of plant paraffin, 0.8 part of plasticizer and 0.8 part of stabilizer are made.
The plant amylum is selected from the one or more of wheaten starch, cornstarch and rice starch.
The particle diameter of the nano-titanium dioxide is 300~400nm.
The plasticizer is selected from the one or more of ethylene glycol, sorbierite and dibutyl phthalate.
One or more of the stabilizer in stearic acid sodium, potassium stearate and epoxy resin.
One or more of the plant fiber in maize straw, sawdust and Cotton Stalk.
Present invention also offers a kind of production technology of degradable vest shopping bag, which includes:
(1) by 25 parts of plant amylum, 22 parts of plant fiber, 20 parts of polyhydroxyalkanoate, 20 parts of polylactic acid, gather oneself two 12 parts of acid-butylene terephthalate, 6 parts of pentaerythrite, 1 part of nano-titanium dioxide, 0.6 part of plant paraffin, 0.8 part of plasticizer Added with stabilizer in reactor for 0.8 part, purpose particle is melted into molten condition, and extrusion molding system under conditions of stirring Obtain film;
(2) start wrap-up, first press and open making button, then press Scroll compression cylinder button, receive air heave type Spool is close to winding roller completely, presses traction lockage button afterwards, and the set-point for adjusting traction frequency convertor is 7M/MIN;Press again Lower inching button, makes extrusion machine trolley be moved to the surface of Compound cooling roller, presses lower compression roller and closes button, makes Compound cooling roller And silica gel roller, counter-pressure cylinder are close to, it is 5 kg/cms to adjust its atmospheric pressure;
(3) corresponding impression cylinder is selected according to product requirement, after embossing machine is embossed, the pattern that sets out on request, Print on plastic film, by winding, cut, flanging, pack after heat-sealing, up to degradable vest shopping bag through color press.
The temperature control of step (1) is at 170~180 DEG C.
The thickness of gained shopping bag is 0.015~0.018mm;Nominal load-bearing is not less than 15kg, and sealing strength is not less than 15.0N/15mm。
Embodiment 2
The different package of 10 groups of components, and the vest of stochastic buying market sale are made using component as described in Table 1 Bag is used as the 11st group, measures three groups of light degradation number of days, biodegradable number of days and absorption of UV, the statistical result such as institute of table 2 Show.Wherein the light degradation time measures according to country mark QB/T 2461-1999, and Biodegradation Times are according to standard GB/T/T 20197-2006 is measured, and absorption of UV parameter is carried out according to standard GB/T/T 9344-88.
Table 1
Table 2
From Tables 1 and 2, degradable vest shopping bag provided by the invention has preferable light degradation and biodegradation Performance, and the anti-ultraviolet function and tensile property having had.Demonstrate the synergistic effect between the raw material components of different proportion So that the degradable paper and plastics compound bag both has excellent light degradation and biodegradability.

Claims (8)

  1. A kind of 1. degradable vest shopping bag, it is characterised in that by 22 parts of 25 parts of plant amylum, the plant fiber of parts by weight meter, 20 parts of polyhydroxyalkanoate, 20 parts of polylactic acid, 12 parts of polyadipate-butylene terephthalate, pentaerythrite 6 part, nanometer 0.8 part of 1 part of titanium dioxide, 0.6 part of plant paraffin, 0.8 part of plasticizer and stabilizer are made.
  2. 2. degradable vest shopping bag according to claim 1, it is characterised in that the plant amylum forms sediment selected from wheat The one or more of powder, cornstarch and rice starch.
  3. 3. degradable vest shopping bag according to claim 1, it is characterised in that the particle diameter of the nano-titanium dioxide is 300~400nm.
  4. 4. degradable vest shopping bag according to claim 1, it is characterised in that the plasticizer is selected from ethylene glycol, mountain The one or more of pears alcohol and dibutyl phthalate.
  5. 5. degradable vest shopping bag according to claim 1, it is characterised in that the stabilizer be selected from stearic acid sodium, One or more in potassium stearate and epoxy resin.
  6. 6. degradable vest shopping bag according to claim 1, it is characterised in that the plant fiber is selected from corn stalk One or more in stalk, sawdust and Cotton Stalk.
  7. 7. the production technology of degradable vest shopping bag according to claim 1, it is characterised in that include the following steps:
    (1) by 25 parts of plant amylum, 22 parts of plant fiber, 20 parts of polyhydroxyalkanoate, 20 parts of polylactic acid, polyadipate-right 12 parts of terephtha-late, 6 parts of pentaerythrite, 1 part of nano-titanium dioxide, 0.6 part of plant paraffin, 0.8 part of plasticizer and steady Determine 0.8 part of agent to add in reactor, purpose particle is melted into molten condition under conditions of stirring, and extrusion molding is made thin Film;
    (2) start wrap-up, first press and open making button, then press Scroll compression cylinder button, make air heave type Scroll Winding roller is close to completely, presses traction lockage button afterwards, and the set-point for adjusting traction frequency convertor is 7M/MIN;Press again a little Dynamic button, makes extrusion machine trolley be moved to the surface of Compound cooling roller, presses lower compression roller and closes button, makes Compound cooling roller and silicon Rubber roller, counter-pressure cylinder are close to, and it is 5 kg/cms to adjust its atmospheric pressure;
    (3) corresponding impression cylinder is selected according to product requirement, after embossing machine is embossed, the pattern that sets out on request, through coloured silk Print machine is printed on plastic film, by winding, cut, flanging, is packed after heat-sealing, up to degradable vest shopping bag.
  8. 8. the production technology of degradable vest shopping bag according to claim 7, it is characterised in that the temperature of step (1) Control is at 170~180 DEG C.
CN201711391280.3A 2017-12-21 2017-12-21 A kind of degradable vest shopping bag and its production technology Pending CN107936310A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711391280.3A CN107936310A (en) 2017-12-21 2017-12-21 A kind of degradable vest shopping bag and its production technology

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711391280.3A CN107936310A (en) 2017-12-21 2017-12-21 A kind of degradable vest shopping bag and its production technology

Publications (1)

Publication Number Publication Date
CN107936310A true CN107936310A (en) 2018-04-20

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111748129A (en) * 2019-03-28 2020-10-09 安庆市康明纳包装有限公司 Biodegradable packaging bag

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194289A (en) * 2014-08-25 2014-12-10 浙江渤海卫生用品有限公司 Bio-based biodegradable plastic bag material
CN104960744A (en) * 2015-05-26 2015-10-07 铜陵方正塑业科技有限公司 Degradable paper plastic composite bag and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194289A (en) * 2014-08-25 2014-12-10 浙江渤海卫生用品有限公司 Bio-based biodegradable plastic bag material
CN104960744A (en) * 2015-05-26 2015-10-07 铜陵方正塑业科技有限公司 Degradable paper plastic composite bag and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111748129A (en) * 2019-03-28 2020-10-09 安庆市康明纳包装有限公司 Biodegradable packaging bag

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Application publication date: 20180420