CN107934912A - A kind of micro-nano driver of bionical paramecium - Google Patents

A kind of micro-nano driver of bionical paramecium Download PDF

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Publication number
CN107934912A
CN107934912A CN201711288359.3A CN201711288359A CN107934912A CN 107934912 A CN107934912 A CN 107934912A CN 201711288359 A CN201711288359 A CN 201711288359A CN 107934912 A CN107934912 A CN 107934912A
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CN
China
Prior art keywords
cobalt
micro
paramecium
nano
ptfe
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CN201711288359.3A
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Chinese (zh)
Inventor
邹强
苏奇
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Tianjin University
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Tianjin University
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Application filed by Tianjin University filed Critical Tianjin University
Priority to CN201711288359.3A priority Critical patent/CN107934912A/en
Publication of CN107934912A publication Critical patent/CN107934912A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00349Creating layers of material on a substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B2201/00Specific applications of microelectromechanical systems
    • B81B2201/03Microengines and actuators
    • B81B2201/038Microengines and actuators not provided for in B81B2201/031 - B81B2201/037

Abstract

The present invention relates to a kind of micro-nano driver of bionical paramecium, including positioned at middle polytetrafluoroethylene (PTFE) substrate, on the two sides of polytetrafluoroethylene (PTFE) substrate, cobalt-based bottom is connected with by conductive silver paste respectively, on the surface at two cobalt-based bottoms, is distributed with cobalt nanowire array.

Description

A kind of micro-nano driver of bionical paramecium
Technical field
The invention is related to micro-nano robot field, more particularly to the bionical micro-nano field of drivers of field drives.
Background technology
Micro-nano robot refers to small scale robot of the scale in micro-nano rank (several nanometers to hundreds of microns), in life There is a very important potential application in the field such as thing medicine and environmental protection, such as available for micro-wound surgical operation, targeted therapy, thin Born of the same parents' operation, heavy metal analysis, contaminant degradation etc., therefore it is subject to the extensive concern of domestic and international researcher, quickly grow in recent years.
Compared to traditional heavy-duty machines people, the working environment of micro-nano robot is located at the very low environment of Reynolds number In, object can be regarded as to move in a very viscous, small and slow environment, and viscous force accounts for leading role, inertia force Then it can be neglected.Under these conditions, if wanting to drive micro-nano robot, it is necessary to continuously provide power for it.But Due to its small size, power source such as battery, engine are difficult to be loaded in micro-nano robot, therefore, various Micro-nano robotically-driven mode be suggested, it is including self-driven (from electrophoresis driving, self-diffusion swimming driving, from thermophoresis driving, gas The modes such as bubble driving) and outfield driving (magnetic field, sound field and optical drive).Since field drives mode magnetic field intensity is relatively low, and Low frequency magnetic field can penetrate biological tissue and harmless to organism, become the most promising driving of micro-nano robot field One of mode.Therefore, how to prepare under relatively low Reynolds number environment, be easy to the driving of micro-nano robot being driven and controlled Device becomes the emphasis of research.
The content of the invention
It can be easy to be driven and controlled by external magnetic field under low Reynolds number environment the object of the present invention is to provide one kind Micro-nano driver.The present invention is prepared similar with paramecium ciliary structures and motion mode according to the motion principle of paramecium Nanowire array structure, as micro-nano driver.Technical solution is as follows:
A kind of micro-nano driver of bionical paramecium, including positioned at middle polytetrafluoroethylene (PTFE) substrate, in polytetrafluoroethylene (PTFE) The two sides of substrate, is connected with cobalt-based bottom by conductive silver paste respectively, on the surface at two cobalt-based bottoms, is distributed with cobalt nanowire battle array Row.
Compared with prior art, which is easy to be driven and controlled by external electromagnetic field under low Reynolds number environment System, has expanded micro-nano driver in biomedical and field of environment protection application range.
Brief description of the drawings
In order to make the content of the present invention more clearly understood, the specific embodiment below according to the present invention and combination Attached drawing, the present invention is described in further detail, wherein:
Fig. 1 is the structure diagram of the present invention;
Fig. 2 is unicellular organism paramecium cilium schematic diagram.
Reference numeral:101- cobalt-baseds bottom;102- conductive silver pastes;103- polytetrafluoroethylene (PTFE) substrates;104- cobalt nanowires;201- Paramecium cilium;202- paramecium bodies.
Embodiment
The solution of the present invention thinking source is the research to unicellular organism paramecium motion principle.The body table of paramecium Face covers a large amount of diameters in nano level cilium, and paramecium relies on the swing of these ciliums to advance, while these ciliums also may be used To help paramecium to avoid the adhesion of pollutant in environment.
The present invention provides one kind can be under low Reynolds number environment, and the micro-nano for being easy to be driven and controlled by external magnetic field drives Dynamic device and preparation method thereof, including step:
(1) cleaning of polytetrafluoroethylene (PTFE) substrate and copper sheet substrate:Need to use 200mL deionizations successively before use Water, 100mL acetone, 100mL absolute ethyl alcohols and 200mL deionized waters are to polytetrafluoroethylene (PTFE) substrate (length of side 20mm) and red copper chip base (length of side 20mm) is cleaned at bottom, spare in 30 DEG C of low temperature dryings afterwards.
(2) preparation of working electrode:Suitable martial virtue alloy (70 DEG C of fusing point) is placed on copper sheet, is put into baking oven jointly In be heated to its fusing point (70 DEG C), continue under this temperature environment, it is using quartz glass edge that martial virtue alloy-coated is uniform, so Porous polycarbonate template (circular, aperture 200nm, diameter 19mm) is overlying on martial virtue alloy upper surface afterwards, while described in guarantee Porous polycarbonate template has good contact with the martial virtue alloy, and the lower surface of porous polycarbonate template can be by the martial virtue Alloy all covers.Take a fine copper wire (diameter 0.8mm), one end connection copper sheet back side, other end connection electrode folder.Utilize Epoxide-resin glue coats the copper sheet back side and side, ensures that cobalt ions can only deposit in porous polycarbonate form plate hole.
(3) the hole wetting of porous polycarbonate template:Working electrode is placed in the electrolyte of the quartzy electrolytic cell, 3min is stirred to electrolyte using magnetic agitation instrument, the cobalt ions in the electrolyte is entered porous polycarbonate template Among hole.
(4) preparation at cobalt nanowire 104 and cobalt-based bottom 101:The composition of electrolyte is:The CoSO of 0.63M/L4 7H2O with The H of 0.65M/L3BO3, while adjust pH value of solution=3 using H2SO4.Two electrode systems are to put platinized platinum to electrode and working electrode In quartzy cell bath, two electrodes are connected to power supply, and power supply can provide " simple alternating current+constant voltage DC biasing ", " perseverance The output mode such as straightening stream " and " pulse direct current ".Using digital multimeter to monitor the situation of change of deposition current, when cobalt nanometer After the completion of line deposits in hole, it may proceed to deposit in the porous polycarbonate template upper surface, deposition current can go out at this time Now rise to.Therefore the deposition of nano wire can be learnt from the situation of change of deposition current.When cobalt nanowire 104 has overflowed After the porous polycarbonate form plate hole starts to deposit, and connection forms the cobalt-based bottom 101 between each other, it is straight to continue deposition Stop deposition after reaching 5 microns to 101 thickness of cobalt-based bottom.
(5) transfer at nano wire 104 and cobalt-based bottom 101:By the cobalt nanowire 104 after the completion of deposition and cobalt-based bottom 101 from Taken out in electrolyte, after low temperature drying, 101 side of cobalt-based bottom is coated into a small amount of conductive silver paste, by the ptfe substrate Be placed in above conductive silver paste, place at normal temperatures 12 it is small when after cobalt-based bottom 101 be connected firmly with ptfe substrate, in acquisition Between combining structure.
(6) remove copper sheet and remove porous polycarbonate template:Above-mentioned intermediate combination structure is put into equipped with 300mL water Beaker in, 70 DEG C of water-bath heating is carried out to middle combining structure, until the copper sheet for being covered with martial virtue alloy comes off, is obtained final Combining structure.The final combining structure is placed in 100mL dichloromethane, washout porous polycarbonate template, described in acquisition The integrative-structure that cobalt nanowire, the cobalt-based bottom, the conductive silver paste and the ptfe substrate are linked as, forms side Ptfe substrate and cobalt nanowire array.
(7) combined with polytetrafluoroethylene (PTFE) substrate 103:Forming the ptfe substrate and cobalt nanowire array of side Afterwards, the preparation method of opposite side is identical, forms the two-sided cobalt nanowire array based on ptfe substrate.
(8) by laser cutting, two-sided cobalt nanowire array is cut into the rectangle of 800um × 200um, it is final to obtain Multiple magnetism micro-nano drivers.

Claims (1)

1. a kind of micro-nano driver of bionical paramecium, including positioned at middle polytetrafluoroethylene (PTFE) substrate, in PTFE base The two sides at bottom, is connected with cobalt-based bottom by conductive silver paste respectively.On the surface at two cobalt-based bottoms, cobalt nanowire battle array is distributed with Row.
CN201711288359.3A 2017-12-07 2017-12-07 A kind of micro-nano driver of bionical paramecium Pending CN107934912A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711288359.3A CN107934912A (en) 2017-12-07 2017-12-07 A kind of micro-nano driver of bionical paramecium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711288359.3A CN107934912A (en) 2017-12-07 2017-12-07 A kind of micro-nano driver of bionical paramecium

Publications (1)

Publication Number Publication Date
CN107934912A true CN107934912A (en) 2018-04-20

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CN (1) CN107934912A (en)

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102646745A (en) * 2012-04-01 2012-08-22 北京大学深圳研究生院 Photovoltaic device and solar battery
EP2506325A1 (en) * 2011-04-01 2012-10-03 Bayer Material Science AG Electromechanical converter, method for manufacture and use of same
CN103098263A (en) * 2010-09-09 2013-05-08 加州理工学院 Electrochemical energy storage systems and methods
CN103245990A (en) * 2012-02-08 2013-08-14 苏州锦富新材料股份有限公司 Novel high-permeable and high-haze easy-to-clean diffusion plate and preparation method thereof
KR20140062365A (en) * 2012-11-14 2014-05-23 한국과학기술연구원 Nanowires thin film, nanowire, and method of fabricating nanowires thin film by physical vapor deposition
CN105881492A (en) * 2016-06-01 2016-08-24 苏州大学 Magnetic force micro robot with multiple cilia, and manufacturing method and control system of magnetic force micro robot
US9610580B2 (en) * 2013-06-03 2017-04-04 Massachusetts Institute Of Technology Magnetically tunable microstructured surfaces
ES2609600A1 (en) * 2017-01-10 2017-04-21 Fundación Imdea Materiales Multifunctional composite material (Machine-translation by Google Translate, not legally binding)
KR20170083012A (en) * 2017-07-07 2017-07-17 서울대학교산학협력단 Actuator and method for manufacturing same, and robot
US20170336272A1 (en) * 2014-10-31 2017-11-23 King Abdullah University Of Science And Technology Magnetic nanocomposite sensor

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103098263A (en) * 2010-09-09 2013-05-08 加州理工学院 Electrochemical energy storage systems and methods
EP2506325A1 (en) * 2011-04-01 2012-10-03 Bayer Material Science AG Electromechanical converter, method for manufacture and use of same
CN103245990A (en) * 2012-02-08 2013-08-14 苏州锦富新材料股份有限公司 Novel high-permeable and high-haze easy-to-clean diffusion plate and preparation method thereof
CN102646745A (en) * 2012-04-01 2012-08-22 北京大学深圳研究生院 Photovoltaic device and solar battery
KR20140062365A (en) * 2012-11-14 2014-05-23 한국과학기술연구원 Nanowires thin film, nanowire, and method of fabricating nanowires thin film by physical vapor deposition
US9610580B2 (en) * 2013-06-03 2017-04-04 Massachusetts Institute Of Technology Magnetically tunable microstructured surfaces
US20170336272A1 (en) * 2014-10-31 2017-11-23 King Abdullah University Of Science And Technology Magnetic nanocomposite sensor
CN105881492A (en) * 2016-06-01 2016-08-24 苏州大学 Magnetic force micro robot with multiple cilia, and manufacturing method and control system of magnetic force micro robot
ES2609600A1 (en) * 2017-01-10 2017-04-21 Fundación Imdea Materiales Multifunctional composite material (Machine-translation by Google Translate, not legally binding)
KR20170083012A (en) * 2017-07-07 2017-07-17 서울대학교산학협력단 Actuator and method for manufacturing same, and robot

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