CN107930421A - One kind improves the deliquescent method of powder additives - Google Patents
One kind improves the deliquescent method of powder additives Download PDFInfo
- Publication number
- CN107930421A CN107930421A CN201711308494.XA CN201711308494A CN107930421A CN 107930421 A CN107930421 A CN 107930421A CN 201711308494 A CN201711308494 A CN 201711308494A CN 107930421 A CN107930421 A CN 107930421A
- Authority
- CN
- China
- Prior art keywords
- acid
- salt
- agent
- powder additives
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000654 additive Substances 0.000 title claims abstract description 83
- 239000000843 powder Substances 0.000 title claims abstract description 83
- 238000000034 method Methods 0.000 title claims abstract description 37
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 45
- 239000003595 mist Substances 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims abstract description 30
- 239000003381 stabilizer Substances 0.000 claims abstract description 22
- 239000004094 surface-active agent Substances 0.000 claims abstract description 22
- 230000000996 additive effect Effects 0.000 claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 238000013329 compounding Methods 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 14
- 239000000126 substance Substances 0.000 claims abstract description 14
- 239000000839 emulsion Substances 0.000 claims description 31
- 239000007864 aqueous solution Substances 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 27
- 239000000725 suspension Substances 0.000 claims description 27
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 26
- 239000008213 purified water Substances 0.000 claims description 25
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 24
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 20
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 20
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 20
- 239000000344 soap Substances 0.000 claims description 18
- -1 citrulling Natural products 0.000 claims description 16
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 15
- 239000001095 magnesium carbonate Substances 0.000 claims description 15
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 15
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 14
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical group CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 14
- 239000005711 Benzoic acid Substances 0.000 claims description 13
- 235000010233 benzoic acid Nutrition 0.000 claims description 13
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 12
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 claims description 12
- 239000001530 fumaric acid Substances 0.000 claims description 12
- 239000000174 gluconic acid Substances 0.000 claims description 12
- 235000012208 gluconic acid Nutrition 0.000 claims description 12
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 12
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 12
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 12
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 11
- 229920002545 silicone oil Polymers 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- 235000015165 citric acid Nutrition 0.000 claims description 9
- 235000011087 fumaric acid Nutrition 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 8
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 8
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 8
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 235000015424 sodium Nutrition 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 239000000811 xylitol Substances 0.000 claims description 8
- 235000010447 xylitol Nutrition 0.000 claims description 8
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 8
- 229960002675 xylitol Drugs 0.000 claims description 8
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 claims description 7
- AYFVYJQAPQTCCC-UHFFFAOYSA-N Threonine Natural products CC(O)C(N)C(O)=O AYFVYJQAPQTCCC-UHFFFAOYSA-N 0.000 claims description 7
- 239000004473 Threonine Substances 0.000 claims description 7
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 6
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 6
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 claims description 6
- LEVWYRKDKASIDU-IMJSIDKUSA-N L-cystine Chemical compound [O-]C(=O)[C@@H]([NH3+])CSSC[C@H]([NH3+])C([O-])=O LEVWYRKDKASIDU-IMJSIDKUSA-N 0.000 claims description 6
- ROHFNLRQFUQHCH-YFKPBYRVSA-N L-leucine Chemical compound CC(C)C[C@H](N)C(O)=O ROHFNLRQFUQHCH-YFKPBYRVSA-N 0.000 claims description 6
- COLNVLDHVKWLRT-QMMMGPOBSA-N L-phenylalanine Chemical compound OC(=O)[C@@H](N)CC1=CC=CC=C1 COLNVLDHVKWLRT-QMMMGPOBSA-N 0.000 claims description 6
- ROHFNLRQFUQHCH-UHFFFAOYSA-N Leucine Natural products CC(C)CC(N)C(O)=O ROHFNLRQFUQHCH-UHFFFAOYSA-N 0.000 claims description 6
- 239000004472 Lysine Substances 0.000 claims description 6
- 229910002651 NO3 Inorganic materials 0.000 claims description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 235000004279 alanine Nutrition 0.000 claims description 6
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 6
- 235000001014 amino acid Nutrition 0.000 claims description 6
- 150000001413 amino acids Chemical group 0.000 claims description 6
- 150000003863 ammonium salts Chemical class 0.000 claims description 6
- 159000000007 calcium salts Chemical class 0.000 claims description 6
- 150000001868 cobalt Chemical class 0.000 claims description 6
- 229960003067 cystine Drugs 0.000 claims description 6
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 6
- 239000004310 lactic acid Substances 0.000 claims description 6
- 235000014655 lactic acid Nutrition 0.000 claims description 6
- 159000000003 magnesium salts Chemical class 0.000 claims description 6
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 6
- 239000001630 malic acid Substances 0.000 claims description 6
- 235000011090 malic acid Nutrition 0.000 claims description 6
- 150000002696 manganese Chemical class 0.000 claims description 6
- 150000007524 organic acids Chemical class 0.000 claims description 6
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 claims description 6
- 239000001103 potassium chloride Substances 0.000 claims description 6
- 235000011164 potassium chloride Nutrition 0.000 claims description 6
- 125000003748 selenium group Chemical class *[Se]* 0.000 claims description 6
- 159000000000 sodium salts Chemical class 0.000 claims description 6
- 239000013076 target substance Substances 0.000 claims description 6
- 150000003751 zinc Chemical class 0.000 claims description 6
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 5
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 5
- KPGXRSRHYNQIFN-UHFFFAOYSA-N 2-oxoglutaric acid Chemical compound OC(=O)CCC(=O)C(O)=O KPGXRSRHYNQIFN-UHFFFAOYSA-N 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 5
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 claims description 5
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- 235000010323 ascorbic acid Nutrition 0.000 claims description 5
- 239000011668 ascorbic acid Substances 0.000 claims description 5
- 229960005070 ascorbic acid Drugs 0.000 claims description 5
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 5
- 239000001506 calcium phosphate Substances 0.000 claims description 5
- 235000012241 calcium silicate Nutrition 0.000 claims description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000787 lecithin Substances 0.000 claims description 5
- 229940067606 lecithin Drugs 0.000 claims description 5
- 235000010445 lecithin Nutrition 0.000 claims description 5
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 claims description 5
- 239000004137 magnesium phosphate Substances 0.000 claims description 5
- 229960002261 magnesium phosphate Drugs 0.000 claims description 5
- 229910000157 magnesium phosphate Inorganic materials 0.000 claims description 5
- 235000010994 magnesium phosphates Nutrition 0.000 claims description 5
- 239000002480 mineral oil Substances 0.000 claims description 5
- 235000010446 mineral oil Nutrition 0.000 claims description 5
- 150000002815 nickel Chemical class 0.000 claims description 5
- 235000010241 potassium sorbate Nutrition 0.000 claims description 5
- 239000004302 potassium sorbate Substances 0.000 claims description 5
- 229940069338 potassium sorbate Drugs 0.000 claims description 5
- GHBFNMLVSPCDGN-UHFFFAOYSA-N rac-1-monooctanoylglycerol Chemical compound CCCCCCCC(=O)OCC(O)CO GHBFNMLVSPCDGN-UHFFFAOYSA-N 0.000 claims description 5
- 235000010352 sodium erythorbate Nutrition 0.000 claims description 5
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 5
- 229940078499 tricalcium phosphate Drugs 0.000 claims description 5
- 229910000391 tricalcium phosphate Inorganic materials 0.000 claims description 5
- 235000019731 tricalcium phosphate Nutrition 0.000 claims description 5
- CODAYFPFZXWNLD-UHFFFAOYSA-N 2-hydroxypropanoyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(=O)C(C)O CODAYFPFZXWNLD-UHFFFAOYSA-N 0.000 claims description 4
- 239000004255 Butylated hydroxyanisole Substances 0.000 claims description 4
- AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 4
- 235000019282 butylated hydroxyanisole Nutrition 0.000 claims description 4
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 claims description 4
- 229940043253 butylated hydroxyanisole Drugs 0.000 claims description 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 4
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical group O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- LDCRTTXIJACKKU-ONEGZZNKSA-N dimethyl fumarate Chemical compound COC(=O)\C=C\C(=O)OC LDCRTTXIJACKKU-ONEGZZNKSA-N 0.000 claims description 4
- 229960004419 dimethyl fumarate Drugs 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- 235000012245 magnesium oxide Nutrition 0.000 claims description 4
- 108700019599 monomethylolglycine Proteins 0.000 claims description 4
- 229920000136 polysorbate Polymers 0.000 claims description 4
- 239000000473 propyl gallate Substances 0.000 claims description 4
- 235000010388 propyl gallate Nutrition 0.000 claims description 4
- 229940075579 propyl gallate Drugs 0.000 claims description 4
- 229940101011 sodium hydroxymethylglycinate Drugs 0.000 claims description 4
- CITBNDNUEPMTFC-UHFFFAOYSA-M sodium;2-(hydroxymethylamino)acetate Chemical compound [Na+].OCNCC([O-])=O CITBNDNUEPMTFC-UHFFFAOYSA-M 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 4
- 239000008158 vegetable oil Substances 0.000 claims description 4
- 239000004475 Arginine Substances 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- 239000004471 Glycine Substances 0.000 claims description 3
- AHLPHDHHMVZTML-BYPYZUCNSA-N L-Ornithine Chemical compound NCCC[C@H](N)C(O)=O AHLPHDHHMVZTML-BYPYZUCNSA-N 0.000 claims description 3
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 claims description 3
- KZSNJWFQEVHDMF-BYPYZUCNSA-N L-valine Chemical compound CC(C)[C@H](N)C(O)=O KZSNJWFQEVHDMF-BYPYZUCNSA-N 0.000 claims description 3
- AHLPHDHHMVZTML-UHFFFAOYSA-N Orn-delta-NH2 Natural products NCCCC(N)C(O)=O AHLPHDHHMVZTML-UHFFFAOYSA-N 0.000 claims description 3
- UTJLXEIPEHZYQJ-UHFFFAOYSA-N Ornithine Natural products OC(=O)C(C)CCCN UTJLXEIPEHZYQJ-UHFFFAOYSA-N 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- KZSNJWFQEVHDMF-UHFFFAOYSA-N Valine Natural products CC(C)C(N)C(O)=O KZSNJWFQEVHDMF-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 239000011363 dried mixture Substances 0.000 claims description 3
- 125000005456 glyceride group Chemical group 0.000 claims description 3
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000391 magnesium silicate Substances 0.000 claims description 3
- 235000019792 magnesium silicate Nutrition 0.000 claims description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 3
- 235000019359 magnesium stearate Nutrition 0.000 claims description 3
- 229930182817 methionine Natural products 0.000 claims description 3
- 229960003104 ornithine Drugs 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 239000004474 valine Substances 0.000 claims description 3
- DWNBOPVKNPVNQG-LURJTMIESA-N (2s)-4-hydroxy-2-(propylamino)butanoic acid Chemical compound CCCN[C@H](C(O)=O)CCO DWNBOPVKNPVNQG-LURJTMIESA-N 0.000 claims description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 claims description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 2
- QIVBCDIJIAJPQS-VIFPVBQESA-N L-tryptophane Chemical compound C1=CC=C2C(C[C@H](N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-VIFPVBQESA-N 0.000 claims description 2
- QIVBCDIJIAJPQS-UHFFFAOYSA-N Tryptophan Natural products C1=CC=C2C(CC(N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-UHFFFAOYSA-N 0.000 claims description 2
- 229940095259 butylated hydroxytoluene Drugs 0.000 claims description 2
- 230000006641 stabilisation Effects 0.000 claims description 2
- 238000011105 stabilization Methods 0.000 claims description 2
- 239000000375 suspending agent Substances 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- 125000000637 arginyl group Chemical group N[C@@H](CCCNC(N)=N)C(=O)* 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 239000000052 vinegar Substances 0.000 claims 1
- 235000021419 vinegar Nutrition 0.000 claims 1
- 238000001035 drying Methods 0.000 abstract description 8
- 238000004090 dissolution Methods 0.000 abstract description 6
- 239000012752 auxiliary agent Substances 0.000 abstract description 3
- 239000006185 dispersion Substances 0.000 abstract description 3
- 238000001291 vacuum drying Methods 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 53
- 235000019483 Peanut oil Nutrition 0.000 description 13
- 239000000312 peanut oil Substances 0.000 description 13
- 229940083542 sodium Drugs 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 5
- 239000001433 sodium tartrate Substances 0.000 description 5
- 229960002167 sodium tartrate Drugs 0.000 description 5
- 235000011004 sodium tartrates Nutrition 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 229940024606 amino acid Drugs 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- TYQCGQRIZGCHNB-JLAZNSOCSA-N l-ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(O)=C(O)C1=O TYQCGQRIZGCHNB-JLAZNSOCSA-N 0.000 description 4
- 239000008108 microcrystalline cellulose Substances 0.000 description 4
- 229940016286 microcrystalline cellulose Drugs 0.000 description 4
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 235000019484 Rapeseed oil Nutrition 0.000 description 3
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 3
- 229920000053 polysorbate 80 Polymers 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 229960003975 potassium Drugs 0.000 description 3
- 235000012424 soybean oil Nutrition 0.000 description 3
- 239000003549 soybean oil Substances 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 2
- AGPKZVBTJJNPAG-WHFBIAKZSA-N L-isoleucine Chemical compound CC[C@H](C)[C@H](N)C(O)=O AGPKZVBTJJNPAG-WHFBIAKZSA-N 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 235000001465 calcium Nutrition 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229960000310 isoleucine Drugs 0.000 description 2
- AGPKZVBTJJNPAG-UHFFFAOYSA-N isoleucine Natural products CCC(C)C(N)C(O)=O AGPKZVBTJJNPAG-UHFFFAOYSA-N 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- XIVNZHXRIPJOIZ-UHFFFAOYSA-N octadecanoic acid;zinc Chemical group [Zn].CCCCCCCCCCCCCCCCCC(O)=O XIVNZHXRIPJOIZ-UHFFFAOYSA-N 0.000 description 2
- 229940072033 potash Drugs 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- YODUIMCJDQUOPA-QRPNPIFTSA-M sodium;(2s)-2-amino-3-(4-hydroxyphenyl)propanoate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CC1=CC=C(O)C=C1 YODUIMCJDQUOPA-QRPNPIFTSA-M 0.000 description 2
- 235000002374 tyrosine Nutrition 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- GDSOZVZXVXTJMI-SNAWJCMRSA-N (e)-1-methylbut-1-ene-1,2,4-tricarboxylic acid Chemical compound OC(=O)C(/C)=C(C(O)=O)\CCC(O)=O GDSOZVZXVXTJMI-SNAWJCMRSA-N 0.000 description 1
- ZJGSVSYBKAZJGP-KVVVOXFISA-N (z)-octadec-9-enoic acid;zinc Chemical compound [Zn].CCCCCCCC\C=C/CCCCCCCC(O)=O ZJGSVSYBKAZJGP-KVVVOXFISA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 240000006927 Foeniculum vulgare Species 0.000 description 1
- 235000004204 Foeniculum vulgare Nutrition 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- HIAAVKYLDRCDFQ-UHFFFAOYSA-L calcium;dodecanoate Chemical compound [Ca+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O HIAAVKYLDRCDFQ-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- HIHIPCDUFKZOSL-UHFFFAOYSA-N ethenyl(methyl)silicon Chemical compound C[Si]C=C HIHIPCDUFKZOSL-UHFFFAOYSA-N 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000004247 glycine and its sodium salt Substances 0.000 description 1
- 235000013905 glycine and its sodium salt Nutrition 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000002502 liposome Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 235000001055 magnesium Nutrition 0.000 description 1
- NCWQJOGVLLNWEO-UHFFFAOYSA-N methylsilicon Chemical compound [Si]C NCWQJOGVLLNWEO-UHFFFAOYSA-N 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229940029258 sodium glycinate Drugs 0.000 description 1
- WUWHFEHKUQVYLF-UHFFFAOYSA-M sodium;2-aminoacetate Chemical compound [Na+].NCC([O-])=O WUWHFEHKUQVYLF-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000008521 threonine Nutrition 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F21/00—Dissolving
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F21/00—Dissolving
- B01F21/40—Dissolving characterised by the state of the material being dissolved
- B01F21/402—Dissolving characterised by the state of the material being dissolved characterised by the configuration, form or shape of the solid material, e.g. in the form of tablets or blocks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
Abstract
The invention discloses one kind to improve the deliquescent method of powder additives, comprises the following steps：A) powder additives raw material is crushed to 40~300 targeted fine powders or micro mist；B) to the micro mist that step a) is obtained and surfactant, defomaing agent, stabilizer, fully mix, obtain mixture；C) compounding substances for obtaining step a) are spray-dried, and dried material is mixed with wandering agent, obtain the powder additives product that dissolubility is improved after mixing；The present invention is using surfactant, defomaing agent, stabilizer, wandering agent as improvement powder additives class product dissolubility auxiliary agent；By the ratio for controlling above-mentioned raw materials so that the rate of dissolution of additive product is high, and dispersion performance is good；And product drying is carried out by vacuum drying mode, one side temperature is low, the time is fast, can not only improve rate of drying, on the other hand can also effectively keep the function and special property of various additives.
Description
Technical field
It is especially a kind of to improve the deliquescent side of powder additives the present invention relates to the application characteristic field of additive product
Method.
Background technology
How to accelerate or increase the solubility and dissolution velocity of slightly solubility powder additives, be always application field research
Hot spot.In powder additives screening, many powder additives with good physiological function and characteristic add for slightly solubility powder
Add agent, to be made suitable solution, or using when need to be dissolved in water, it is necessary to try to increase its solubility and dissolving speed
Degree.Solubility and the dissolving of powder additives can be improved using the classical way such as mixed solvent or addition solubilizer, cosolvent
Speed.In addition, liposome technology, inclusion compound technology and block copolymer innovation technology can also be effectively increased powder
Body additives solubility and dissolution velocity, and apply to more and more in the dissolving sex work for improving product.But these
For method all there is its production procedure process is more, step is complicated, the defect problem such as human cost height.
The content of the invention
In view of this, the object of the present invention is to provide one kind to improve the deliquescent method of powder additives, can solve to give birth to
It is more to produce flow process, human cost is high, the low technical problem of processing efficiency.
To achieve these goals, the present invention provides following technical solution：
One kind improves the deliquescent method of powder additives, comprises the following steps：
A) additive raw material is broken to 40~300 targeted fine powders or micro mist；
B) to the obtained fine powders of step a) or micro mist and surfactant, defomaing agent, stabilizer, fully mix, mixed
Compound；
C) compounding substances for obtaining step a) are dried, and abundant to the wandering agent of dried mixture addition
Mixing, the powder additives product improved up to dissolubility；
The additive is amino acid and/or organic acid；
In the powder additives by mass percentage, including following component：
The surfactant：0.1%~2.5%；The defomaing agent：0.01%~1%, the stabilizer：0.01%
~0.7%, the wandering agent：0.01%~7.0%, surplus is additive raw material.
Preferably, step b) includes：
B1) the obtained fine powders of step a) or micro mist are dissolved or dispersed in purified water, form aqueous solution, emulsion or outstanding
Turbid；
B2) to step b1) surface-active is sequentially added in the obtained aqueous solution, the emulsion or the suspension
Agent, defomaing agent and stabilizer, fully mix, obtain mixture.
3rd, according to the method described in claim 2, it is characterized in that, step c) is specially：
C1) by step b2) obtained mixture carries out spray solidification, obtain target substance；
C2) by step c2) obtained target substance carries out redrying, and wandering agent is added into dried material,
It is fully mixed, obtain the powder additives product that dissolubility is improved.
Preferably, step b) includes：
B1`) surfactant, defomaing agent and stabilizer are dissolved or dispersed in purified water, form aqueous solution, emulsion
Or suspension；
B2`) to step b1`) the obtained aqueous solution, the emulsion or the suspension be atomized backward step a)
To fine powder or micro mist surface uniformly spray, adhere to or be embedded in fine powder or micro mist surface, obtain mixture.
Preferably, the surfactant for nonylphenol polyoxyethylene ether, octyl phenol polyoxyethylene ether, fatty acid soaps salt,
Alkylphenol polyoxyethylene ether, tween, stearoyl lactate, this disk, glyceride, lecithin or the ester of xylitol.
Preferably, the defomaing agent is higher aliphatic, silicone oil, mineral oil or vegetable oil.
Preferably, the stabilizer for benzoic acid, butylated hydroxy anisole, dibutyl hydroxy toluene, propylgallate,
Dehydroactic acid sodium, arabo-ascorbic acid, xylitol, potassium sorbate, Capmul MCM C8, sodium hydroxy methyl glycinate or fumaric acid diformazan
Ester.
Preferably, the wandering agent is sodium silicoaluminate, tricalcium phosphate, microcrystalline cellulose, silica, alumina silicate, sial
Sour calcium, calcium silicates, calcium stearate, magnesium carbonate, magnesia, magnesium stearate, magnesium phosphate, magnesium silicate, kaolin or talcum powder.
Preferably, the amino acid is selected from cystine, leucine, tyrosine, arginine, lysine, tryptophan, Soviet Union's ammonia
Acid, citrulling, methionine, glycine, phenylalanine, ornithine, alanine, isoleucine, valine and its ammonium salt, sodium salt,
Sylvite, calcium salt, magnesium salts, zinc salt, molysite, ferrous iron, mantoquita, manganese salt, chromic salts, selenium salt, nickel salt, cobalt salt, hydrochloride, carbonate, sulphur
One or more in hydrochlorate, nitrate and acetate.
Preferably, the organic acid is selected from citric acid, malic acid, fumaric acid, ascorbic acid, fumaric acid, tartaric acid, ketone
Glutaric acid, gluconic acid, lactic acid and its ammonium salt, sodium salt, sylvite, calcium salt, magnesium salts, zinc salt, molysite, ferrous iron, mantoquita, manganese salt, chromium
One or more in salt, selenium salt, nickel salt, cobalt salt, hydrochloride, carbonate, sulfate, nitrate and acetate.
A kind of improvement deliquescent method of powder additives provided by the invention, using surfactant, defomaing agent, stabilization
Agent, wandering agent are as improvement powder additives class product dissolubility auxiliary agent；By the ratio for controlling above-mentioned raw materials so that additive
The rate of dissolution of product is high, and dispersion performance is good；And product drying is carried out by vacuum drying mode, one side temperature is low, when
Between it is fast, rate of drying can not only be improved, on the other hand can also effectively keep the function and special property of various additives.Separately
Outside, method technique provided by the invention is simple, high in machining efficiency, is easy to industrialized production, and obtained is changed through dissolubility
Kind powder additives product cut size is homogeneous, solubility property is good, and stable type is high.
Embodiment
A kind of improvement deliquescent method of powder additives provided by the invention, comprises the following steps：
A) additive raw material is broken to 40~300 targeted fine powders or micro mist；
B) to the obtained fine powders of step a) or micro mist and surfactant, defomaing agent, stabilizer, fully mix, mixed
Compound；
C) compounding substances for obtaining step a) are dried, and abundant to the wandering agent of dried mixture addition
Mixing, the powder additives product improved up to dissolubility；
The additive is amino acid and/or organic acid；
In the powder additives by mass percentage, including following component：
The surfactant：0.1%~2.5%；The defomaing agent：0.01%~1%, the stabilizer：0.01%
~0.7%, the wandering agent：0.01%~7.0%, surplus is additive raw material.
In above-mentioned technical proposal, the present invention is using surfactant, defomaing agent, stabilizer, wandering agent as improvement powder
Additive kind product dissolubility auxiliary agent；By the ratio for controlling above-mentioned raw materials so that the rate of dissolution of additive product is high, disperses
Performance is good；And product drying is carried out by vacuum drying mode, one side temperature is low, the time is fast, can not only improve drying
Speed, on the other hand can also effectively keep the function and special property of various additives.In addition, method work provided by the invention
Skill is simple, high in machining efficiency, is easy to industrialized production, and the powder additives product cut size that obtained dissolubility is improved is equal
First, solubility property is good, and stability is high.
In an embodiment of the present invention, in order to enable additive：Surfactant, defomaing agent, stabilizer, wandering agent are abundant
Ground is dispersed in additive raw material, and additive raw material and surfactant, defomaing agent, there are two kinds of hybrid modes for stabilizer.
The first is：Fine powder or micro mist are dissolved or dispersed in purified water, form aqueous solution, emulsion or suspension；
Surfactant, defomaing agent and stabilizer are sequentially added into aqueous solution, emulsion or suspension, fully mixes, is mixed
Thing.
Said mixture is subjected to spray solidification, obtains target substance；Target substance is subjected to redrying, and to drying
Wandering agent is added in material afterwards, it is fully mixed, obtains the powder additives product that dissolubility is improved.
It is for second：Surfactant, defomaing agent and stabilizer are dissolved or dispersed in purified water, formation aqueous solution,
Emulsion or suspension；Backward fine powder is atomized to aqueous solution, emulsion or suspension or micro mist surface is uniformly sprayed, adheres to or wrapped
Fine powder or micro mist surface are embedded in, obtains mixture.
The addition of purified water, stabilizer, surfactant can improve the rate of dissolution of powder additives.The present invention's
In embodiment, surfactant is nonylphenol polyoxyethylene ether, octyl phenol polyoxyethylene ether, fatty acid soaps salt, alkyl phenol polyoxy
Vinethene, tween, stearoyl lactate, this disk, glyceride, lecithin or the ester of xylitol.
It should be noted that fatty acid soaps salt is stearic acid zinc soap, oleic acid zinc soap, laurate zinc soap, stearic acid calcium soap, oil
Sour calcium soap, laurate calcium soap, stearic acid soda soap, stearic acid potash soap, sodium oleate soap or oleic acid potash soap.
It should be noted that tween is Tween 80.
The addition of defoamer contributes to the dissolving of additive.In an embodiment of the present invention, defomaing agent for higher aliphatic,
Silicone oil, mineral oil or vegetable oil.
Wherein it should be noted that higher aliphatic is eight alcohol, lauryl alcohol, hexadecanol or octadecyl alcolol；Silicone oil is methyl silicon
Oil, MethylethoxylsiliconFluid Fluid, methyl trifluoro propyl silicone oil, methyl vinyl silicon oil or methylhydroxy silicone oil；Vegetable oil is peanut
Oil, soybean oil, rapeseed oil or olive oil.
Stabilizer is used for the activity for keeping additive raw material, prevents in drying process, additive raw material goes bad.In the present invention
Embodiment in, stabilizer for benzoic acid, butylated hydroxy anisole, dibutyl hydroxy toluene, propylgallate, dehydroactic acid
Sodium, arabo-ascorbic acid, xylitol, potassium sorbate, Capmul MCM C8, sodium hydroxy methyl glycinate or dimethyl fumarate.
Wandering agent can improve anti-caking performance and dispersion performance.In an embodiment of the present invention, agent of scattering is aluminosilicate
Sodium, tricalcium phosphate, microcrystalline cellulose, silica, alumina silicate, ca aluminosilicate, calcium silicates, calcium stearate, magnesium carbonate, oxidation
Magnesium, magnesium stearate, magnesium phosphate, magnesium silicate, kaolin or talcum powder.
In an embodiment of the present invention, amino acid is selected from cystine, leucine, tyrosine, arginine, lysine, color ammonia
Acid, threonine, citrulling, methionine, glycine, phenylalanine, ornithine, alanine, isoleucine, valine and its ammonium
Salt, sodium salt, sylvite, calcium salt, magnesium salts, zinc salt, molysite, ferrous iron, mantoquita, manganese salt, chromic salts, selenium salt, nickel salt, cobalt salt, hydrochloride, carbon
One or more in hydrochlorate, sulfate, nitrate and acetate.
In an embodiment of the present invention, organic acid be selected from citric acid, malic acid, fumaric acid, ascorbic acid, fumaric acid,
Tartaric acid, ketoglutaric acid, gluconic acid, lactic acid and its ammonium salt, sodium salt, sylvite, calcium salt, magnesium salts, zinc salt, molysite, ferrous iron, copper
Salt, manganese salt, chromic salts, selenium salt, nickel salt, cobalt salt, hydrochloride, carbonate, sulfate, nitrate and one kind or more in acetate
Kind.
It is molten to a kind of improvement powder additives provided by the invention with reference to embodiment in order to further illustrate the present invention
The method of solution property is described in detail, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
Improve the deliquescent method of powder additives, comprise the following steps：
Cystine, leucine are broken to the micro mist of 200 mesh；Micro mist is dissolved or dispersed in purified water, formation aqueous solution,
Emulsion or suspension；Nonylphenol polyoxyethylene ether, peanut oil, benzene first are sequentially added into aqueous solution, emulsion or suspension
Acid, fully mixes, obtains mixture；Compounding substances are spray-dried, obtain target product；It is and target product is secondary dry
It is dry, and dried material is uniformly mixed with magnesium carbonate, that is, obtain the powder additives product that dissolubility is improved；Purifying
The quality of water is 3 times of nonylphenol polyoxyethylene ether, peanut oil, benzoic acid, magnesium carbonate, cystine and leucine gross mass.
In the powder additives product that dissolubility is improved by mass percentage, including following component：
Nonylphenol polyoxyethylene ether：1.8%, peanut oil：0.05%, benzoic acid：0.05%, magnesium carbonate：2%, cystine：
50%, surplus is leucine.
Embodiment 2
Improve the deliquescent method of powder additives, comprise the following steps：
Citric acid, malic acid are broken to the micro mist of 300 mesh；By Tween 80, MethylethoxylsiliconFluid Fluid and butylhydroxy fennel
Ether is dissolved or dispersed in purified water, forms aqueous solution, emulsion or suspension；Into aqueous solution, emulsion or suspension
It is even to be sprayed at micro mist surface, fully mix, obtain mixture；Compounding substances are spray-dried, and by dried material
Mixed with magnesium phosphate, obtain the powder additives product that dissolubility is improved after mixing；The quality of purified water is nonyl
Base phenol polyethenoxy ether, peanut oil, benzoic acid, magnesium carbonate, citric acid, 4 times of malic acid gross mass.
In the powder additives product that dissolubility is improved by mass percentage, including following component：
Tween 80：0.1%, MethylethoxylsiliconFluid Fluid：1%, butylated hydroxy anisole：0.01%, magnesium phosphate：0.01%,
Citric acid：40%, surplus is malic acid.
Embodiment 3
Improve the deliquescent method of powder additives, comprise the following steps：
Gluconic acid, tyrosine are broken to the micro mist of 100 mesh；Micro mist is dissolved or dispersed in purified water, is formed water-soluble
Liquid, emulsion or suspension；Alkylphenol polyoxyethylene ether, eight alcohol and two are sequentially added into aqueous solution, emulsion or suspension
Butylated hydroxytoluene, fully mixes, obtains mixture；Compounding substances are spray-dried, obtain target product；And by target
Product carries out redrying, and dried material is uniformly mixed with calcium silicates, that is, obtains the powder that dissolubility is improved
Additive product；The quality of purified water is nonylphenol polyoxyethylene ether, peanut oil, benzoic acid, magnesium carbonate, gluconic acid, junket ammonia
3 times of sour gross mass.
In the powder additives product that dissolubility is improved by mass percentage, including following component：
Alkylphenol polyoxyethylene ether：0.8%, eight alcohol：0.4%, dibutyl hydroxy toluene：0.35%, calcium silicates：0.5%,
Gluconic acid：40%, surplus is tyrosine.
Embodiment 4
Improve the deliquescent method of powder additives, comprise the following steps：
Tyrosine, fumaric acid, lysine, ketoglutaric acid raw material are broken to 40 targeted fine powders；By octylphenol polyethylene ethylene oxide
Ether, hexadecanol, propylgallate are dissolved or dispersed in purified water, form aqueous solution, emulsion or suspension；To water-soluble
Micro mist surface is uniformly sprayed in liquid, emulsion or suspension, fully mixes, obtains mixture；Compounding substances are sprayed
It is dry, obtain target product；And target product is subjected to redrying, and dried material is mixed with ca aluminosilicate, mix
The powder additives product that dissolubility is improved is obtained after closing uniformly；The quality of purified water be nonylphenol polyoxyethylene ether,
Peanut oil, benzoic acid, magnesium carbonate, tyrosine, fumaric acid, 3 times of lysine and ketoglutaric acid gross mass.
In the powder additives product that dissolubility is improved by mass percentage, including following component：
Surfactant：1.2%, defomaing agent：0.7%, stabilizer：0.6%, agent of scattering：3.5%, tyrosine：15%,
Fumaric acid 10%, lysine 20%, surplus are ketoglutaric acid.
Embodiment 5
Improve the deliquescent method of powder additives, comprise the following steps：
Threonine, citrulling are broken to the micro mist of 100~300 mesh；Micro mist is dissolved or dispersed in purified water, forms water
Solution, emulsion or suspension；Stearoyl lactate, rapeseed oil are sequentially added into aqueous solution, emulsion or suspension with taking off
Hydroacetic acid sodium, fully mixes, obtains mixture；Compounding substances are spray-dried, obtain target product；And by target product
Redrying is carried out, and dried material is uniformly mixed with talcum powder, that is, obtains the powder addition that dissolubility is improved
Agent product；The quality of purified water is nonylphenol polyoxyethylene ether, peanut oil, benzoic acid, magnesium carbonate, threonine and the total matter of citrulling
3 times of amount.
In the powder additives product that dissolubility is improved by mass percentage, including following component：
Stearoyl lactate：0.3%, rapeseed oil：0.2%, dehydroactic acid sodium：0.3%, talcum powder：5.0%, 35% Soviet Union
Propylhomoserin, surplus are citrulling.
Embodiment 6
Improve the deliquescent method of powder additives, comprise the following steps：
Sodium L-tyrosinate, lactic acid, alanine zinc raw material are broken to the micro mist of 250 mesh；By this disk, mineral oil and arabo-ascorbic acid
It is dissolved or dispersed in purified water, forms aqueous solution, emulsion or suspension；Into aqueous solution, emulsion or suspension uniformly
Micro mist surface is embedded in, fully mixes, obtains mixture；Compounding substances are spray-dried, obtain target product；And by mesh
Mark product and carry out redrying, and dried material is mixed with kaolin, obtaining dissolubility after mixing is changed
Kind powder additives product；The quality of purified water is nonylphenol polyoxyethylene ether, peanut oil, benzoic acid, magnesium carbonate, tyrosine
2 times of sodium, lactic acid and alanine zinc gross mass.
In the powder additives product that dissolubility is improved by mass percentage, including following component：
This disk：1.5%, mineral oil：0.1%, arabo-ascorbic acid：0.3%, kaolin：2%, Sodium L-tyrosinate 25%, lactic acid
25%, surplus is alanine zinc.
Embodiment 7
Improve the deliquescent method of powder additives, comprise the following steps：
Fumaric acid, ascorbic acid, gluconic acid are broken to the micro mist of 100~300 mesh；Micro mist is dissolved or dispersed in purifying
In water, aqueous solution, emulsion or suspension are formed；Stearic acid zinc soap, first are sequentially added into aqueous solution, emulsion or suspension
Base silicone oil and potassium sorbate, fully mix, obtain mixture；Compounding substances are spray-dried, obtain target product；And will
Target product carries out redrying, and dried material is uniformly mixed with magnesia, that is, obtains what dissolubility was improved
Powder additives product；The quality of purified water is nonylphenol polyoxyethylene ether, peanut oil, benzoic acid, magnesium carbonate, fumaric acid, anti-
3 times of bad hematic acid, gluconic acid gross mass.
In the powder additives product that dissolubility is improved by mass percentage, including following component：
Stearic acid zinc soap：1%, methyl-silicone oil：0.05%, potassium sorbate：0.1%, magnesia：1%, fumaric acid：15%th,
Ascorbic acid：15%, surplus is gluconic acid.
Embodiment 8
Improve the deliquescent method of powder additives, comprise the following steps：
Sodium tartrate and threonine potassium are broken to the micro mist of 200 mesh；Sodium oleate soap, soybean oil and Capmul MCM C8 is molten
Solve or be scattered in purified water, form aqueous solution, emulsion or suspension；It is uniformly attached into aqueous solution, emulsion or suspension
On micro mist surface, fully mix, obtain mixture；Compounding substances are spray-dried, obtain target product；And by target
Product carries out redrying, and dried material is mixed with microcrystalline cellulose, and obtaining dissolubility after mixing obtains
Improved powder additives product；The quality of purified water is nonylphenol polyoxyethylene ether, peanut oil, benzoic acid, magnesium carbonate, winestone
3 times of sour sodium and threonine potassium gross mass.
In the powder additives product that dissolubility is improved by mass percentage, including following component：
Sodium oleate soap：2%, soybean oil：0.5%, Capmul MCM C8：0.5%, microcrystalline cellulose：4%, sodium tartrate：
35%, surplus is threonine potassium.
Embodiment 9
Improve the deliquescent method of powder additives, comprise the following steps：
Gluconic acid is broken to the micro mist of 200 mesh；Micro mist is dissolved or dispersed in purified water, forms aqueous solution, milkiness
Liquid or suspension；The ester of xylitol, methyl trifluoro propyl silicone oil and methylol are sequentially added into aqueous solution, emulsion or suspension
Sodium Glycinate, fully mixes, obtains mixture；Compounding substances are spray-dried, obtain target product；And by target product
Redrying is carried out, and dried material is uniformly mixed with tricalcium phosphate, that is, the powder that obtaining dissolubility is improved adds
Add agent product；The quality of purified water is nonylphenol polyoxyethylene ether, peanut oil, benzoic acid, magnesium carbonate and gluconic acid gross mass
4 times.
In the powder additives product that dissolubility is improved by mass percentage, including following component：
The ester of xylitol：2.5%, methyl trifluoro propyl silicone oil 1%, sodium hydroxy methyl glycinate：0.7%, tricalcium phosphate：
7.0%, surplus is gluconic acid.
Embodiment 10
Improve the deliquescent method of powder additives, comprise the following steps：
Tyrosine iron, citric acid, phenylalanine and sodium tartrate are broken to the micro mist of 200 mesh；By lecithin, lauryl alcohol with
Dimethyl fumarate is dissolved or dispersed in purified water, forms aqueous solution, emulsion or suspension；To aqueous solution, emulsion or
Micro mist surface is uniformly sprayed in suspension, fully mixes, obtains mixture；Compounding substances are spray-dried, obtain mesh
Mark product；And target product is subjected to redrying, and dried material is mixed with sodium silicoaluminate, after mixing to obtain the final product
The powder additives product improved to dissolubility；The quality of purified water is nonylphenol polyoxyethylene ether, peanut oil, benzene first
Acid, magnesium carbonate, tyrosine iron, citric acid, 3 times of phenylalanine and sodium tartrate gross mass.
In the powder additives product that dissolubility is improved by mass percentage, including following component：
Lecithin：1.2%, lauryl alcohol：0.5%, dimethyl fumarate：0.35%, sodium silicoaluminate：3.5%, tyrosine
Iron：10%, citric acid：15%, phenylalanine：30%, surplus is sodium tartrate.
The jitter time of the powder additives product improved to dissolubility made from embodiment 1~10, dissolving clarification
Time and solution light transmittance are tested, and the results are shown in Table 1：
The experimental result of 1 embodiment 1~10 of table
The foregoing description of the disclosed embodiments, enables professional and technical personnel in the field to realize or using this to institute's public affairs
The described above for the embodiment opened, enables professional and technical personnel in the field to realize or use the present invention.To these embodiments
A variety of modifications will be apparent for those skilled in the art, and the general principles defined herein can be
In the case of not departing from the spirit or scope of the present invention, realize in other embodiments.Therefore, the present invention is not intended to be limited to
The embodiments shown herein, and it is to fit to the most wide model consistent with principles disclosed herein and novel features
Enclose.
Claims (10)
1. one kind improves the deliquescent method of powder additives, it is characterised in that comprises the following steps：
A) powder additives raw material is crushed to 40~300 targeted fine powders or micro mist；
B) to the obtained fine powders of step a) or micro mist and surfactant, defomaing agent, stabilizer, fully mix, obtain mixture；
C) the obtained compounding substances of step b) are dried, and add wandering agent to dried mixture and be sufficiently mixed, i.e.,
Obtain the powder additives product that dissolubility is improved；
The additive is amino acid and/or organic acid；
In the powder additives product that the dissolubility is improved by mass percentage, including following component：
The surfactant：0.1%~2.5%；The defomaing agent：0.01%~1%, the stabilizer：0.01%~
0.7%, the wandering agent：0.01%~7.0%, surplus is powder additives raw material.
2. according to the method described in claim 1, it is characterized in that, step b) includes：
B1) by the obtained fine powders of step a) or micro mist, it is dissolved or dispersed in purified water, forms aqueous solution, emulsion or suspended
Liquid；
B2) to step b1) surfactant, defomaing agent and stabilization are sequentially added in obtained aqueous solution, emulsion or suspension
Agent, fully mixes, obtains mixture.
3. according to the method described in claim 2, it is characterized in that, step c) is specially：
C1) by step b2) obtained mixture carries out spray solidification, obtain target substance；
C2) by step c1) obtained target substance carries out redrying, and wandering agent is added into dried material, make it
Fully mix, obtain the powder additives product that dissolubility is improved.
4. according to the method described in claim 1, it is characterized in that, step b) includes：
B1`) surfactant, defomaing agent and stabilizer are dissolved or dispersed in purified water, form aqueous solution, emulsion or outstanding
Turbid；
B2`) to step b1`) the obtained aqueous solution, the emulsion or the suspension be atomized what backward step a) was obtained
Fine powder or micro mist surface are uniformly sprayed, adhere to or are embedded in fine powder or micro mist surface, obtains mixture.
5. according to the method described in claim 1, it is characterized in that, the surfactant is nonylphenol polyoxyethylene ether, pungent
Base phenol polyethenoxy ether, fatty acid soaps salt, alkylphenol polyoxyethylene ether, tween, stearoyl lactate, this disk, glyceride, lecithin
Fat or the ester of xylitol.
6. according to the method described in claim 1, it is characterized in that, the defomaing agent for higher aliphatic, silicone oil, mineral oil or
Vegetable oil.
7. according to the method described in claim 1, it is characterized in that, the stabilizer is benzoic acid, butylated hydroxy anisole, two
Butylated hydroxytoluene, propylgallate, dehydroactic acid sodium, arabo-ascorbic acid, xylitol, potassium sorbate, Capmul MCM C8,
Sodium hydroxy methyl glycinate or dimethyl fumarate.
8. according to the method described in claim 1, it is characterized in that, the wandering agent is sodium silicoaluminate, tricalcium phosphate, crystallite fibre
Tie up element, silica, alumina silicate, ca aluminosilicate, calcium silicates, calcium stearate, magnesium carbonate, magnesia, magnesium stearate, magnesium phosphate,
Magnesium silicate, kaolin or talcum powder.
9. according to the method described in claim 1, it is characterized in that, the amino acid be selected from cystine, leucine, tyrosine,
It is arginine, lysine, tryptophan, threonine, citrulling, methionine, glycine, phenylalanine, ornithine, alanine, different bright
Propylhomoserin, valine and its ammonium salt, sodium salt, sylvite, calcium salt, magnesium salts, zinc salt, molysite, ferrous iron, mantoquita, manganese salt, chromic salts, selenium salt, nickel
One or more in salt, cobalt salt, hydrochloride, carbonate, sulfate, nitrate and acetate.
10. according to the method described in claim 1, it is characterized in that, the organic acid be selected from citric acid, malic acid, fumaric acid,
Ascorbic acid, fumaric acid, tartaric acid, ketoglutaric acid, gluconic acid, lactic acid and its ammonium salt, sodium salt, sylvite, calcium salt, magnesium salts,
Zinc salt, molysite, ferrous iron, mantoquita, manganese salt, chromic salts, selenium salt, nickel salt, cobalt salt, hydrochloride, carbonate, sulfate, nitrate and vinegar
One or more in hydrochlorate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711308494.XA CN107930421A (en) | 2017-12-11 | 2017-12-11 | One kind improves the deliquescent method of powder additives |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711308494.XA CN107930421A (en) | 2017-12-11 | 2017-12-11 | One kind improves the deliquescent method of powder additives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107930421A true CN107930421A (en) | 2018-04-20 |
Family
ID=61946469
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711308494.XA Pending CN107930421A (en) | 2017-12-11 | 2017-12-11 | One kind improves the deliquescent method of powder additives |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107930421A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113749205A (en) * | 2021-09-09 | 2021-12-07 | 山东凯翔生物科技股份有限公司 | Preparation method of calcium gluconate-gluconic acid composite powder |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1964624A (en) * | 2004-05-24 | 2007-05-16 | 瓦伦特生物科学公司 | Stable and water-soluble plant growth regulator liquid compositions and methods for use of same |
| KR100935217B1 (en) * | 2009-02-11 | 2010-01-06 | 오진범 | Manufacturing apparatus for dissolute gas in water |
| CN103039631A (en) * | 2013-01-09 | 2013-04-17 | 无锡超科食品有限公司 | Whipped cream powder, preparation method and application |
-
2017
- 2017-12-11 CN CN201711308494.XA patent/CN107930421A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1964624A (en) * | 2004-05-24 | 2007-05-16 | 瓦伦特生物科学公司 | Stable and water-soluble plant growth regulator liquid compositions and methods for use of same |
| KR100935217B1 (en) * | 2009-02-11 | 2010-01-06 | 오진범 | Manufacturing apparatus for dissolute gas in water |
| CN103039631A (en) * | 2013-01-09 | 2013-04-17 | 无锡超科食品有限公司 | Whipped cream powder, preparation method and application |
Non-Patent Citations (3)
| Title |
|---|
| 朱晓薇等: "《中药药剂学》", 31 May 2015, 中国农业大学出版社 * |
| 沈晋良: "《农药加工与管理》", 30 June 2002, 中国农业出版社 * |
| 高振川等: "《饲料添加剂应用技术问答》", 28 February 1993, 农业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113749205A (en) * | 2021-09-09 | 2021-12-07 | 山东凯翔生物科技股份有限公司 | Preparation method of calcium gluconate-gluconic acid composite powder |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP3191431B1 (en) | Micronutrient fertilizer | |
| CN104858422A (en) | Stainless steel composite powder for 3D printing and preparation method of stainless steel composite powder for 3D printing | |
| CN106317421B (en) | A kind of high-performance cationic rosin size and preparation method thereof | |
| CN103881498A (en) | Walling paint and preparation method thereof | |
| RU2014141616A (en) | POWDER COMPOSITIONS OF COMPLEX ACID COMPOUND WITH METAL AND METHOD FOR PRODUCING THEM | |
| CN107056423A (en) | A kind of sun-proof blade face fluid fertilizer and preparation method thereof | |
| CN107930421A (en) | One kind improves the deliquescent method of powder additives | |
| CN103771427A (en) | Method for preparing sphere-like mesoporous silica | |
| CN105495272A (en) | Preparation method of oil-soluble water-soluble type rosemary antioxidant | |
| CN101787237B (en) | Powder emulsion paint for interior wall | |
| JP2018168032A (en) | Anhydrous calcium hydrogen phosphate, and method for producing the same | |
| KR101896424B1 (en) | Porous Mineral Manufacturing Method and Solubilized Porous Mineral Composition Manufacturing Method Using It | |
| CN103506225B (en) | A kind of Zinc oxide minerals beneficiation collecting agent and preparation method thereof | |
| CN104961148B (en) | The mixing crystal formation nano-calcium carbonate synthetic method that a kind of content is controlled | |
| CN107321052A (en) | A kind of air conditioning for automobiles antibacterial filter core material and preparation method | |
| CN105503019B (en) | The preparation method of concrete water evaporation inhibitor | |
| CN108264412B (en) | Special anti-caking agent for ammonium sulfate and preparation method and application thereof | |
| CN103788929A (en) | Biodegradation type raised dust inhibitor and preparation method thereof | |
| CN107572564A (en) | A kind of wheat head shape porous magnesia and preparation method thereof | |
| CN106179764A (en) | The preparation method of vegetable fatty acid soap tartaric acid hydrocarbyl carbonate Compositional type phosphorite flotation collector | |
| JP5052062B2 (en) | Method for producing high concentration Bordeaux liquid composition | |
| KR101152688B1 (en) | Method for nutralization and stabilization of food additive calcium carbonate and the composition using said method | |
| CN105621462B (en) | Method for preparing aluminium oxide material | |
| JP4318906B2 (en) | Plant vital agent granule | |
| CN102241548A (en) | Novel chemical fertilizer and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180420 |
|
| RJ01 | Rejection of invention patent application after publication |