CN107915892A - A kind of Wear-resistant sole material and preparation method thereof - Google Patents
A kind of Wear-resistant sole material and preparation method thereof Download PDFInfo
- Publication number
- CN107915892A CN107915892A CN201711128966.3A CN201711128966A CN107915892A CN 107915892 A CN107915892 A CN 107915892A CN 201711128966 A CN201711128966 A CN 201711128966A CN 107915892 A CN107915892 A CN 107915892A
- Authority
- CN
- China
- Prior art keywords
- parts
- wear
- added
- kneading machine
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0095—Mixtures of at least two compounding ingredients belonging to different one-dot groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K11/00—Use of ingredients of unknown constitution, e.g. undefined reaction products
- C08K11/005—Waste materials, e.g. treated or untreated sewage sludge
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/08—Ingredients of unknown constitution and ingredients covered by the main groups C08K3/00 - C08K9/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1545—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2419/00—Characterised by the use of rubbers not provided for in groups C08J2407/00 - C08J2417/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention discloses a kind of Wear-resistant sole material, the Wear-resistant sole material includes the raw material of following parts by weight meter：65 115 parts of EVA plastic materials, 30 50 parts of waste rubber tyre powder, 5 15 parts of nano magnesia, 6 12 parts of sepiolite powder, 5 10 parts of plant ash, 58 parts of ferrous sulfate, 48 parts of disodium ethylene diamine tetraacetate, 13 parts of bacteriostatic agent, 10 18 parts of paper white sludge, 5 10 parts of vermiculite, 10 20 parts of filter mud of sugar refinery, 58 parts of nano aluminium oxide, 13 parts of age resister, 12 parts of sodium alginate, 12 parts of foaming agent.The wear-resisting sole of the present invention has preferable mechanical performance, and tensile strength, tearing strength are high, and wear-resisting property is good, and elongation percentage is high；And anti-static effect is good；There is preferable fungistatic effect at the same time；It is more environmentally-friendly and raw material is easy to get, small toxicity.
Description
Technical field
The present invention relates to footwear technical field, is specifically a kind of Wear-resistant sole material and preparation method thereof.
Background technology
The common characteristic of material for sole of shoe should possess wear-resisting, water-fast, and oil resistant, heat-resisting, pressure-resistant, impact resistance, elasticity are good, easily suitable
Fit after type, sizing not flexible type, insulation, easily absorb moisture etc., while more to coordinate midsole, there is brake work in the change of feet on foot
With being not to slip and the terms and conditions such as be easy to stop.The species of sole materials is very much, can be divided into natural class bottom material and synthesis class
Two kinds of bottom material.Natural class bottom material includes natural bottom leather, bamboo and wood material etc., and synthesis class bottom material includes rubber, plastics, rubber and plastic and shares material
Material, regenerated leather, elastic hardboard etc..As the improvement of people's living standards, requirement of the people for material for sole of shoe is also increasingly
Height, does not need only to have excellent wear-resisting property, antistatic performance, it is also necessary to there is certain fungistatic effect, while with people
Support for environmental protection cause, environment-friendly materials be favor increasingly be subject to people.Therefore, a kind of wear-resisting, antistatic, environmental protection
And the material for sole of shoe with fungistatic effect becomes the hot spot of research.
The content of the invention
It is an object of the invention to provide a kind of Wear-resistant sole material and preparation method thereof, to solve in above-mentioned background technology
The problem of proposition.
To achieve the above object, the present invention provides following technical solution：
A kind of Wear-resistant sole material, the Wear-resistant sole material include the raw material of following parts by weight meter：EVA plastic materials
65-115 parts, 30-50 parts of waste rubber tyre powder, 5-15 parts of nano magnesia, 6-12 parts of sepiolite powder, 5-10 parts of plant ash, sulfuric acid it is sub-
5-8 parts of iron, 4-8 parts of disodium ethylene diamine tetraacetate, 1-3 parts of bacteriostatic agent, 10-18 parts of paper white sludge, 5-10 parts of vermiculite, filter mud of sugar refinery
10-20 parts, 5-8 parts of nano aluminium oxide, 1-3 parts of age resister, 1-2 parts of sodium alginate, 1-2 parts of foaming agent；The bacteriostatic agent bag
Include the raw material of following parts by weight meter：2-5 parts of dihydromyricetin, 5-8 parts of gallic acid, 4-11 parts of barnacle, 1-2 parts of lime.
As the further scheme of the present invention：The Wear-resistant sole material includes the raw material of following parts by weight meter：EVA plastic cement
85 parts of raw material, 42 parts of waste rubber tyre powder, 10 parts of nano magnesia, 8 parts of sepiolite powder, 7 parts of plant ash, 6 parts of ferrous sulfate, ethylenediamine
5.5 parts of tetraacethyl disodium, 2.6 parts of bacteriostatic agent, 15 parts of paper white sludge, 8 parts of vermiculite, 16 parts of filter mud of sugar refinery, 7 parts of nano aluminium oxide,
2.3 parts of age resister, 1.4 parts of sodium alginate, 1.2 parts of foaming agent.
As the further scheme of the present invention：The bacteriostatic agent includes the raw material of following parts by weight meter：Dihydromyricetin
3.5 parts, 6.2 parts of gallic acid, 6 parts of barnacle, 1.5 parts of lime.
A kind of preparation method of wear resistant shoe ground, step include：(1) by EVA plastic materials, disodium ethylene diamine tetraacetate,
Ferrous sulfate, nano aluminium oxide and nano magnesia are added in high-speed kneading machine, at 200-250 DEG C, mediate 20-35min,
Obtain mixture A；(2) waste rubber tyre powder, sepiolite powder, plant ash and paper white sludge are added in high-speed kneading machine, in 100-120
At DEG C, 1-4min is mediated, continuously adds vermiculite, filter mud of sugar refinery, 15-20min is mediated, obtains mixture B；(3) by mixture A,
Mixture B is added in high-speed kneading machine, at 190-205 DEG C, is mediated 2-5min, is continuously added foaming agent, mediates 10-
20min, obtains mixture C；(4) mixture C, bacteriostatic agent, age resister, sodium alginate are added in high-speed kneading machine,
At 165-175 DEG C, 2-5min is mediated；(5) upper step gains are added to die for molding, after cooling, to obtain the final product.
As the further scheme of the present invention：Step (1) is sub- by EVA plastic materials, disodium ethylene diamine tetraacetate, sulfuric acid
Iron, nano aluminium oxide and nano magnesia are added in high-speed kneading machine, at 214 DEG C, are mediated 25min, are obtained mixture A.
As the further scheme of the present invention：Step (2) adds waste rubber tyre powder, sepiolite powder, plant ash and paper white sludge
Enter in high-speed kneading machine, at 110 DEG C, mediate 2min, continuously add vermiculite, filter mud of sugar refinery, mediate 18min, obtain mixture
B。
As the further scheme of the present invention：Mixture A, mixture B are added in high-speed kneading machine by step (3),
At 195 DEG C, 3min is mediated, continuously adds foaming agent, 15min is mediated, obtains mixture C.
As the further scheme of the present invention：Step (4) adds mixture C, bacteriostatic agent, age resister, sodium alginate
Into high-speed kneading machine, at 170 DEG C, 3min is mediated.
Compared with prior art, the beneficial effects of the invention are as follows：
The wear-resisting sole of the present invention has preferable mechanical performance, and tensile strength, tearing strength are high, and wear-resisting property is good, prolongs
Stretch rate height；And sole resistance value, between 0.1-45M Ω, anti-static effect is good；Large intestine bacteriostasis rate, staphylococcus aureus at the same time
Bacteriostasis rate is high, has preferable fungistatic effect；And raw material is easy to get, small toxicity, a variety of discarded objects are used as raw material, more ring
Protect.
Embodiment
The technical solution of this patent is described in more detail with reference to embodiment.
Embodiment 1
A kind of Wear-resistant sole material, the Wear-resistant sole material include the raw material of following parts by weight meter：EVA plastic materials 65
Part, 30 parts of waste rubber tyre powder, 5 parts of nano magnesia, 6 parts of sepiolite powder, 5 parts of plant ash, 5 parts of ferrous sulfate, ethylenediamine tetra-acetic acid
4 parts of disodium, 1 part of bacteriostatic agent, 10 parts of paper white sludge, 5 parts of vermiculite, 10 parts of filter mud of sugar refinery, 5 parts of nano aluminium oxide, age resister 1
Part, 1 part of sodium alginate, 1 part of foaming agent；The bacteriostatic agent includes the raw material of following parts by weight meter：2 parts of dihydromyricetin, do not have
5 parts of gallate-based, 4 parts of barnacle, 1 part of lime.
A kind of preparation method of wear resistant shoe ground, step include：(1) by EVA plastic materials, disodium ethylene diamine tetraacetate,
Ferrous sulfate, nano aluminium oxide and nano magnesia are added in high-speed kneading machine, at 200 DEG C, are mediated 20min, are mixed
Compound A；(2) waste rubber tyre powder, sepiolite powder, plant ash and paper white sludge are added in high-speed kneading machine, at 100 DEG C, mediated
1min, continuously adds vermiculite, filter mud of sugar refinery, mediates 15min, obtains mixture B；(3) mixture A, mixture B are added to height
In fast kneader, at 190 DEG C, 2min is mediated, continuously adds foaming agent, 10min is mediated, obtains mixture C；(4) will mixing
Thing C, bacteriostatic agent, age resister, sodium alginate are added in high-speed kneading machine, at 165 DEG C, mediate 2min；(5) by upper step institute
Obtain thing and be added to die for molding, after cooling, to obtain the final product.
Embodiment 2
A kind of Wear-resistant sole material, the Wear-resistant sole material include the raw material of following parts by weight meter：EVA plastic materials
115 parts, 50 parts of waste rubber tyre powder, 15 parts of nano magnesia, 12 parts of sepiolite powder, 10 parts of plant ash, 8 parts of ferrous sulfate, ethylenediamine
It is 8 parts of tetraacethyl disodium, 3 parts of bacteriostatic agent, 18 parts of paper white sludge, 10 parts of vermiculite, 20 parts of filter mud of sugar refinery, 8 parts of nano aluminium oxide, anti-ageing
3 parts of agent, 2 parts of sodium alginate, 2 parts of foaming agent；The bacteriostatic agent includes the raw material of following parts by weight meter：Dihydromyricetin 5
Part, 8 parts of gallic acid, 11 parts of barnacle, 2 parts of lime.
A kind of preparation method of wear resistant shoe ground, step include：(1) by EVA plastic materials, disodium ethylene diamine tetraacetate,
Ferrous sulfate, nano aluminium oxide and nano magnesia are added in high-speed kneading machine, at 250 DEG C, are mediated 35min, are mixed
Compound A；(2) waste rubber tyre powder, sepiolite powder, plant ash and paper white sludge are added in high-speed kneading machine, at 120 DEG C, mediated
4min, continuously adds vermiculite, filter mud of sugar refinery, mediates 20min, obtains mixture B；(3) mixture A, mixture B are added to height
In fast kneader, at 205 DEG C, 5min is mediated, continuously adds foaming agent, 20min is mediated, obtains mixture C；(4) will mixing
Thing C, bacteriostatic agent, age resister, sodium alginate are added in high-speed kneading machine, at 175 DEG C, mediate 5min；(5) by upper step institute
Obtain thing and be added to die for molding, after cooling, to obtain the final product.
Embodiment 3
A kind of Wear-resistant sole material, the Wear-resistant sole material include the raw material of following parts by weight meter：EVA plastic materials 85
Part, 42 parts of waste rubber tyre powder, 10 parts of nano magnesia, 8 parts of sepiolite powder, 7 parts of plant ash, 6 parts of ferrous sulfate, ethylenediamine tetra-acetic acid
It is 5.5 parts of disodium, 2.6 parts of bacteriostatic agent, 15 parts of paper white sludge, 8 parts of vermiculite, 16 parts of filter mud of sugar refinery, 7 parts of nano aluminium oxide, anti-aging
2.3 parts of agent, 1.4 parts of sodium alginate, 1.2 parts of foaming agent.The bacteriostatic agent includes the raw material of following parts by weight meter：Dihydromyricetin
3.5 parts of element, 6.2 parts of gallic acid, 6 parts of barnacle, 1.5 parts of lime.
A kind of preparation method of wear resistant shoe ground, step include：(1) by EVA plastic materials, disodium ethylene diamine tetraacetate,
Ferrous sulfate, nano aluminium oxide and nano magnesia are added in high-speed kneading machine, at 214 DEG C, are mediated 25min, are mixed
Compound A.(2) waste rubber tyre powder, sepiolite powder, plant ash and paper white sludge are added in high-speed kneading machine, at 110 DEG C, mediated
2min, continuously adds vermiculite, filter mud of sugar refinery, mediates 18min, obtains mixture B.(3) mixture A, mixture B are added to height
In fast kneader, at 195 DEG C, 3min is mediated, continuously adds foaming agent, 15min is mediated, obtains mixture C.Step (4) will
Mixture C, bacteriostatic agent, age resister, sodium alginate are added in high-speed kneading machine, at 170 DEG C, mediate 3min.(5) will be upper
Step gains are added to die for molding, after cooling, to obtain the final product.
1-3 of the embodiment of the present invention wear-resisting soles prepared are tested for the property below, test result is shown in Table 1：
Table 1
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Tensile strength/MPa | 4.8 | 5.1 | 5.5 |
| Tearing strength/Nmm-1 | 6.5 | 6.5 | 6.8 |
| Wear-resisting property/mm3 | 148 | 156 | 153 |
| Elongation percentage/% | 467 | 485 | 488 |
| Sole resistance value M Ω | 0.1-45 | 0.1-45 | 0.1-45 |
| Large intestine bacteriostasis rate/% | 95 | 97 | 99 |
| Staphylococcus aureus bacteriostasis rate/% | 98 | 96 | 99 |
As seen from the above table, wear-resisting sole of the invention has preferable mechanical performance, and tensile strength, tearing strength are high, resistance to
It is good to grind performance, elongation percentage is high；And sole resistance value, between 0.1-45M Ω, anti-static effect is good；Large intestine bacteriostasis rate, gold at the same time
Staphylococcus aureus bacteriostasis rate is high, has preferable fungistatic effect；And raw material is easy to get, small toxicity, use a variety of discarded objects for
Raw material, it is more environmentally-friendly.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, can also be on the premise of this patent objective not be departed from the knowledge that one skilled in the relevant art possesses
Make a variety of changes.
Claims (8)
1. a kind of Wear-resistant sole material, it is characterised in that the Wear-resistant sole material includes the raw material of following parts by weight meter：EVA
65-115 parts of plastic material, 30-50 parts of waste rubber tyre powder, 5-15 parts of nano magnesia, 6-12 parts of sepiolite powder, plant ash 5-10
Part, 5-8 parts of ferrous sulfate, 4-8 parts of disodium ethylene diamine tetraacetate, 1-3 parts of bacteriostatic agent, 10-18 parts of paper white sludge, vermiculite 5-10
Part, 10-20 parts of filter mud of sugar refinery, 5-8 parts of nano aluminium oxide, 1-3 parts of age resister, 1-2 parts of sodium alginate, 1-2 parts of foaming agent；Institute
Stating bacteriostatic agent includes the raw material of following parts by weight meter：2-5 parts of dihydromyricetin, 5-8 parts of gallic acid, 4-11 parts of barnacle, stone
It is 1-2 parts grey.
2. Wear-resistant sole material according to claim 1, it is characterised in that the Wear-resistant sole material includes following weight
The raw material of part meter：85 parts of EVA plastic materials, 42 parts of waste rubber tyre powder, 10 parts of nano magnesia, 8 parts of sepiolite powder, 7 parts of plant ash,
6 parts of ferrous sulfate, 5.5 parts of disodium ethylene diamine tetraacetate, 2.6 parts of bacteriostatic agent, 15 parts of paper white sludge, 8 parts of vermiculite, filter mud of sugar refinery 16
Part, 7 parts of nano aluminium oxide, 2.3 parts of age resister, 1.4 parts of sodium alginate, 1.2 parts of foaming agent.
3. Wear-resistant sole material according to claim 1 or 2, it is characterised in that the bacteriostatic agent includes following parts by weight
The raw material of number meter：3.5 parts of dihydromyricetin, 6.2 parts of gallic acid, 6 parts of barnacle, 1.5 parts of lime.
4. a kind of preparation method of wear resistant shoe ground as claimed in claim 3, it is characterised in that step includes：(1) by EVA
Plastic material, disodium ethylene diamine tetraacetate, ferrous sulfate, nano aluminium oxide and nano magnesia are added in high-speed kneading machine,
At 200-250 DEG C, 20-35min is mediated, obtains mixture A；(2) it is waste rubber tyre powder, sepiolite powder, plant ash and papermaking is white
Mud is added in high-speed kneading machine, at 100-120 DEG C, is mediated 1-4min, is continuously added vermiculite, filter mud of sugar refinery, mediates 15-
20min, obtains mixture B；(3) mixture A, mixture B are added in high-speed kneading machine, at 190-205 DEG C, mediate 2-
5min, continuously adds foaming agent, mediates 10-20min, obtains mixture C；(4) by mixture C, bacteriostatic agent, age resister, sea
Mosanom is added in high-speed kneading machine, at 165-175 DEG C, mediates 2-5min；(5) upper step gains are added in mould
Shaping, after cooling, to obtain the final product.
5. the preparation method of wear resistant shoe ground according to claim 4, it is characterised in that step (1) is former by EVA plastic cement
Material, disodium ethylene diamine tetraacetate, ferrous sulfate, nano aluminium oxide and nano magnesia are added in high-speed kneading machine, at 214 DEG C
Under, 25min is mediated, obtains mixture A.
6. the preparation method of wear resistant shoe ground according to claim 4, it is characterised in that step (2) is by waste rubber tyre powder, sea
Afrodite powder, plant ash and paper white sludge are added in high-speed kneading machine, at 110 DEG C, are mediated 2min, are continuously added vermiculite, sugar refinery
Filter mud, mediates 18min, obtains mixture B.
7. the preparation method of wear resistant shoe ground according to claim 4, it is characterised in that step (3) is by mixture A, mixed
Compound B is added in high-speed kneading machine, at 195 DEG C, is mediated 3min, is continuously added foaming agent, mediates 15min, mixed
Thing C.
8. the preparation method of wear resistant shoe ground according to claim 4, it is characterised in that step (4) by mixture C, suppression
Microbial inoculum, age resister, sodium alginate are added in high-speed kneading machine, at 170 DEG C, mediate 3min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711128966.3A CN107915892A (en) | 2017-11-15 | 2017-11-15 | A kind of Wear-resistant sole material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711128966.3A CN107915892A (en) | 2017-11-15 | 2017-11-15 | A kind of Wear-resistant sole material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107915892A true CN107915892A (en) | 2018-04-17 |
Family
ID=61896409
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711128966.3A Pending CN107915892A (en) | 2017-11-15 | 2017-11-15 | A kind of Wear-resistant sole material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107915892A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115011060A (en) * | 2022-05-06 | 2022-09-06 | 茂泰(福建)鞋材有限公司 | Semitransparent thermoplastic rubber sole, semitransparent thermoplastic elastomer composition for sole and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060249417A1 (en) * | 2005-04-21 | 2006-11-09 | Merrick Jones | Scented shoe and shoe packaging system |
| CN103951856A (en) * | 2014-05-23 | 2014-07-30 | 徐建先 | Shoemaking material, shoe soles and shoe pads prepared from material and preparation method of material |
| CN104861279A (en) * | 2015-04-24 | 2015-08-26 | 茂泰(福建)鞋材有限公司 | Bi-color antibacterial EVA footwear and preparation method thereof |
-
2017
- 2017-11-15 CN CN201711128966.3A patent/CN107915892A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060249417A1 (en) * | 2005-04-21 | 2006-11-09 | Merrick Jones | Scented shoe and shoe packaging system |
| CN103951856A (en) * | 2014-05-23 | 2014-07-30 | 徐建先 | Shoemaking material, shoe soles and shoe pads prepared from material and preparation method of material |
| CN104861279A (en) * | 2015-04-24 | 2015-08-26 | 茂泰(福建)鞋材有限公司 | Bi-color antibacterial EVA footwear and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115011060A (en) * | 2022-05-06 | 2022-09-06 | 茂泰(福建)鞋材有限公司 | Semitransparent thermoplastic rubber sole, semitransparent thermoplastic elastomer composition for sole and preparation method thereof |
| CN115011060B (en) * | 2022-05-06 | 2024-05-10 | 茂泰(福建)新材料科技有限公司 | Semitransparent thermoplastic rubber sole, semitransparent thermoplastic elastomer composition for sole and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107216504B (en) | A kind of high abrasion rare-earth rubber material for shoes and preparation method thereof | |
| CN101767362A (en) | Long-acting mould-proof wood plastic composite material and preparation method thereof | |
| CN103788439B (en) | Wide temperature range height shock-absorbing sport shoes sole rubber material and preparation method thereof | |
| CN105694149A (en) | Oil-resistant and low-temperature-resistant material for shoe sole and method for preparing oil-resistant and low-temperature-resistant material | |
| CN107418002A (en) | A kind of high-quality rubber seal | |
| CN105542251B (en) | One kind foaming compounded rubber material for sole of shoe and preparation method thereof | |
| CN107915892A (en) | A kind of Wear-resistant sole material and preparation method thereof | |
| CN101565517A (en) | Modified thermoplastic styrene butadiene rubber sole material and preparation method thereof | |
| CN101725046A (en) | Midsole material of leather shoes | |
| Li et al. | Development of a strong and multifunctional soy protein-based adhesive with excellent coating and prepressing in wet state by constructing a radical polymerization and organic-inorganic mineralization bionic structure | |
| CN108864615A (en) | A kind of wear-resisting resistance to migration high resiliency PVC bottom leather imitation material | |
| CN105647450A (en) | Environment-friendly water-based adhesive for shoes | |
| CN108192212A (en) | A kind of environment-friendly degradable PP plastics and preparation method thereof | |
| CN111548762A (en) | Hot melt adhesive for orthopedic shoe molding and manufacturing process thereof | |
| JP2018532021A (en) | A mixture containing plastic and organic fibers | |
| CN105086013A (en) | No-blooming wear-resistant rubber and preparing method thereof | |
| CN109370197A (en) | Sole macromolecule translucent rubber material and preparation method and shoes | |
| KR100894963B1 (en) | Rubber composition for shoes sole materials and a shoe sole having natural leather material-like feel prepared using the same | |
| CN107652480A (en) | Antistatic dust suction blocks water rubber shoes with cloth upper adhesive and preparation method thereof and application method | |
| CN108503997B (en) | Lignin-filled foamed slipper and preparation method thereof | |
| CN106867384A (en) | A kind of aqueous tear-proof auxiliary agent suitable for synthetic leather | |
| CN106916348A (en) | A kind of wear-resisting high-strength degree slipper sole and its production technology and application | |
| CN108707397A (en) | A kind of dust-proof coating on plastic plate | |
| CN105968555A (en) | Preparation method of high-resilience deodorant basketball shoe sole material | |
| CN103450523B (en) | Formula of a kind of environment-friendlyadhesive adhesive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180417 |