CN107903950A - A kind of raw coke oven gas waste heat is used for the hot water cyclesystem of vacuum potassium carbonate desulfurization - Google Patents

A kind of raw coke oven gas waste heat is used for the hot water cyclesystem of vacuum potassium carbonate desulfurization Download PDF

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Publication number
CN107903950A
CN107903950A CN201711401876.7A CN201711401876A CN107903950A CN 107903950 A CN107903950 A CN 107903950A CN 201711401876 A CN201711401876 A CN 201711401876A CN 107903950 A CN107903950 A CN 107903950A
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China
Prior art keywords
hot water
pipeline
water
nitrogen
doctor solution
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Pending
Application number
CN201711401876.7A
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Chinese (zh)
Inventor
陈魁
刘开源
王嵩林
张素利
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Acre Coking and Refractory Engineering Consulting Corp MCC
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Acre Coking and Refractory Engineering Consulting Corp MCC
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Priority to CN201711401876.7A priority Critical patent/CN107903950A/en
Publication of CN107903950A publication Critical patent/CN107903950A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/12Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors
    • C10K1/122Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors containing only carbonates, bicarbonates, hydroxides or oxides of alkali-metals (including Mg)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/002Removal of contaminants
    • C10K1/003Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C10K1/004Sulfur containing contaminants, e.g. hydrogen sulfide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D19/00Details
    • F24D19/10Arrangement or mounting of control or safety devices
    • F24D19/1006Arrangement or mounting of control or safety devices for water heating systems
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D3/00Hot-water central heating systems
    • F24D3/10Feed-line arrangements, e.g. providing for heat-accumulator tanks, expansion tanks ; Hydraulic components of a central heating system
    • F24D3/1008Feed-line arrangements, e.g. providing for heat-accumulator tanks, expansion tanks ; Hydraulic components of a central heating system expansion tanks
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D3/00Hot-water central heating systems
    • F24D3/10Feed-line arrangements, e.g. providing for heat-accumulator tanks, expansion tanks ; Hydraulic components of a central heating system
    • F24D3/1058Feed-line arrangements, e.g. providing for heat-accumulator tanks, expansion tanks ; Hydraulic components of a central heating system disposition of pipes and pipe connections
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D2200/00Heat sources or energy sources
    • F24D2200/16Waste heat
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to the hot water cyclesystem that a kind of raw coke oven gas waste heat is used for vacuum potassium carbonate desulfurization, including the closed circulation system being made of primary cooler, hot water feeding pipe road, doctor solution reboiler, hot water backwater's pipeline;Hot water circulating pump is set on hot water backwater's pipeline;Expansion tank is additionally provided with hot water backwater's pipeline, relief valve is set at the top of expansion tank, top sets compressed nitrogen entrance, and compressed nitrogen entrance connects external compression Nitrogen source gases by nitrogen pipeline, nitrogen pressure regulator valve is set on nitrogen pipeline;Expansion tank is additionally provided with liquid level gauge one.The present invention uses closed circulation system, it can avoid circulation water loss and losses of potential energy caused by the circulation of primary cooler epimere high-temperature-hot-water open type, at the same time by setting automatic water supplement pipeline and being passed through the expansion tank of compressed gas, the problem of avoiding water loss and pressure instability common during closed cycle, realizes efficient and energy conservation object during waste heat recovery.

Description

A kind of raw coke oven gas waste heat is used for the hot water cyclesystem of vacuum potassium carbonate desulfurization
Technical field
The present invention relates to coking industry technical field of energy saving and environmental protection, more particularly to a kind of raw coke oven gas waste heat to be used for vacuum carbonic acid The hot water cyclesystem of potassium desulfurization.
Background technology
During reclaiming clean coke-oven gas, about 80~84 DEG C of the raw coke oven gas from gas collecting tube must be in primary cooler It is cooled to 20~22 DEG C.Primary cooler generally uses the indirect primary cooler of transverse tube, with industrial circulating water and water at low temperature to raw coke oven gas into Row sub-sectional cooling.The user of high-temperature-hot-water or heating if needed, primary cooler can use epimere, stage casing, hypomere three-stage structure, on Section circulating hot water goes out primary cooler temperature up to 75~78 DEG C.
Vacuum potassium carbonate desulfurization regeneration bottom of towe temperature needs to be maintained at 60 DEG C or so, the high temperature produced using primary cooler epimere Hot water, there is provided the heat needed for the regeneration of vacuum potassium carbonate sulfur removing pregnant solution, can not only recycle the waste heat of raw coke oven gas, save de- Quantity of steam needed for the regeneration of sulphur rich solution, while the industrial cycle water needed for raw coke oven gas cooling can be reduced, it is coking industry coal gas One important energy conservation and environmental protection measure in Recovery Purifying field.Coking industry primary cooler epimere high-temperature-hot-water is used for vacuum carbonic acid at present The circulation of potassium desulfurization, is generally designed using open circuit, high-temperature-hot-water after reboiler and the heat exchange of regenerator bottom desulphurization circulating liquid, Before returning to primary cooler epimere, intercycle groove is introduced into, then is pumped to primary cooler epimere and exchanges heat with raw coke oven gas.Hot water circuit mistake Hot water potential energy is not fully used in journey, and hot water has with air directly to be contacted, and there are hot water volatilization loss and oxygen to enter The problem of hot-water heating system etching apparatus and pipeline.
It " is desorption heat source directly using raw coke oven gas waste heat that the Chinese patent of Patent No. CN101016485A, which discloses a kind of, Vacuum carbonate method coal gas desulfurization technique and its equipment ", its using the open circulation with circulation desulfurization liquid bath, and It is the waste heat that doctor solution is sent directly into primary cooler epimere absorption raw coke oven gas, but since doctor solution has stronger corrosivity, after The maintenance cost of phase and influence to production can not be ignored, and there are the shortcomings that losses of potential energy and waste of energy for open circulation.Specially Profit number discloses a kind of " coke-oven plant's primary cooler heating water waste heat recovery device " for the Chinese patent of CN205842824U, its Circulated using the open type with heating pond, shortcoming is the recirculated water that primary cooler epimere high-temperature-hot-water will enter the formula that plows open Pond, and need powerful water pump that recirculated water is fed again into primary cooler epimere, the volatilization of recirculated water is had during this Loss, and need to consume a large amount of electric energy to make the potential energy that recirculated water obtains nearly 40 meters again.
Patent No. CN104787825A proposes a kind of " coal gas primary cooler waste heat ammonia steaming device and waste heat ammonia still process method ", It is sent using the negative pressure ammonia distillation process using raw coke oven gas waste heat as heat source, distilled ammonia wastewater from ammonia still bottom by distilled ammonia wastewater pumping To primary cooler epimere, after exchanging heat with raw coke oven gas, ammonia still flash distillation is returned to provide the heat of ammonia still process.It is this using distilled ammonia wastewater as be situated between The open circulation technique of matter, the corrosion to equipment and pipeline is stronger, and there are the shortcomings that losses of potential energy and waste of energy.
The content of the invention
The present invention provides the hot water cyclesystem that a kind of raw coke oven gas waste heat is used for vacuum potassium carbonate desulfurization, followed using enclosed Loop system, can avoid circulation water loss and losses of potential energy caused by the circulation of primary cooler epimere high-temperature-hot-water open type, at the same time By setting automatic water supplement pipeline and being passed through the expansion tank of compressed gas, common water loss during closed cycle is avoided And the problem of pressure instability, realize efficient and energy conservation object during waste heat recovery.
In order to achieve the above object, the present invention is realized using following technical scheme:
A kind of raw coke oven gas waste heat is used for the hot water cyclesystem of vacuum potassium carbonate desulfurization, including is supplied water by primary cooler, hot water Pipeline, doctor solution reboiler, the closed circulation system of hot water backwater's pipeline composition;The epimere high-temperature-hot-water outlet of the primary cooler The heat transferring medium entrance of doctor solution reboiler is connected by hot water feeding pipe road, the heat transferring medium outlet of doctor solution reboiler passes through The epimere low-temperature water heating outlet of hot water backwater's pipeline connection primary cooler;The doctor solution entrance and doctor solution of the doctor solution reboiler The doctor solution outlet on regenerator top is connected, the doctor solution outlet of doctor solution reboiler and the doctor solution of desulfurization regeneration tower bottom Entrance is connected;Hot water circulating pump is set on hot water backwater's pipeline;Expansion tank, the top of expansion tank are additionally provided with hot water backwater's pipeline Portion sets relief valve, and top sets compressed nitrogen entrance, and compressed nitrogen entrance connects external compression Nitrogen source gases, nitrogen by nitrogen pipeline Nitrogen pressure regulator valve is set in feed channel;Expansion tank is additionally provided with liquid level gauge one.
One end of hot water backwater's pipeline connection moisturizing pipeline between the hot water circulating pump and expansion tank, moisturizing pipeline The other end set soft water entrance, be equipped with stop valve, water supply tank and small pump successively in the moisturizing pipeline in soft water entrance downstream;Its In, small pump and one interlocked control of liquid level gauge on expansion tank;Liquid level gauge two is set on water supply tank, liquid level gauge two joins with stop valve Lock control.
Compared with prior art, the beneficial effects of the invention are as follows:
1) a kind of proper closed circulation system is employed, is compared with existing open-cycle system:It can avoid Water caused by open environment (such as intercycle groove, cooling tower, circulating water pool) is lost;Oxygen is avoided to enter hot-water heating system to equipment With the corrosion of pipeline;Reduce the mechanical power loss of water, as long as the power of hot water circulating pump can overcome the pipeline in cyclic process Resistance, has saved substantial amounts of electric energy;
2) expansion tank is set on heating water return pipeline, volumetric expansion caused by after being heated for absorption cycle water, keeps away Exempt from that circulating water line is caused to impact;Pressure in expansion tank is maintained using compressed nitrogen, avoids expansion tank from being placed in Circulation line top and caused by it is inconvenient.
Brief description of the drawings
Fig. 1 is that the structure for the hot water cyclesystem that a kind of raw coke oven gas waste heat of the present invention is used for vacuum potassium carbonate desulfurization is shown It is intended to.
In figure:1. 5. relief valve of primary cooler 2. desulfurization regeneration tower, 3. hot water circulating pump, 4. expansion tank, 6. nitrogen 10. hot water feeding pipe road of pressure regulator valve 7. small pump, 8. water supply tank, 9. stop valve, 11. hot water backwater's pipeline, 12. moisturizing pipeline 13. 14. liquid level gauge of doctor solution reboiler, one 15. liquid level gauge two
Embodiment
The embodiment of the present invention is described further below in conjunction with the accompanying drawings:
As shown in Figure 1, a kind of raw coke oven gas waste heat of the present invention is used for the hot water cyclesystem of vacuum potassium carbonate desulfurization, bag Include the closed circulation system being made of primary cooler 1, hot water feeding pipe road 10, doctor solution reboiler 13, hot water backwater's pipeline 11;Institute The epimere high-temperature-hot-water outlet for stating primary cooler 2 is entered by the heat transferring medium of the connection doctor solution reboiler of hot water feeding pipe road 10 13 Mouthful, the heat transferring medium outlet of doctor solution reboiler 13 is gone out by the epimere low-temperature water heating of the connection primary cooler 2 of hot water backwater's pipeline 11 Mouthful;The doctor solution entrance of the doctor solution reboiler 13 is connected with the doctor solution outlet on 2 top of desulfurization regeneration tower, and doctor solution is again The doctor solution outlet of boiling device 13 is connected with the doctor solution entrance of 2 bottom of desulfurization regeneration tower;Hot water is set on hot water backwater's pipeline 11 Circulating pump 3;Expansion tank 4 is additionally provided with hot water backwater's pipeline 11, the top of expansion tank 4 sets relief valve 5, and top sets compressed nitrogen Gas entrance, compressed nitrogen entrance connect external compression Nitrogen source gases by nitrogen pipeline, nitrogen pressure regulator valve 6 are set on nitrogen pipeline; Expansion tank 4 is additionally provided with liquid level gauge 1.
One end of hot water backwater's pipeline connection moisturizing pipeline 12 between the hot water circulating pump 3 and expansion tank 4, moisturizing The other end of pipeline 12 sets soft water entrance, and stop valve 9,8 and of water supply tank are equipped with successively in the moisturizing pipeline 12 in soft water entrance downstream Small pump 7;Wherein, small pump 7 and one 14 interlocked control of liquid level gauge on expansion tank 4;Liquid level gauge 2 15 is set on water supply tank 8, Liquid level gauge 2 15 and 9 interlocked control of stop valve.
A kind of raw coke oven gas waste heat of the present invention is used in the hot water cyclesystem of vacuum potassium carbonate desulfurization, and high-temperature-hot-water exists By primary cooler 1 and doctor solution reboiler 13 and connect both hot water feeding pipe road 10 and hot water backwater's pipeline 11 formed Closed circulation system internal circulation flow, will not pressure release without unlimited environment.
Hot water circulating pump 3 is provided with hot water backwater's pipeline 11, it is used for for the high-temperature-hot-water in closed circulation system Energy is provided to overcome pipe resistance, due to there is no pressure release in closed circulation system high temperature hot water, it is not necessary to repeat constantly Potential energy is obtained, so can be met the requirements using the hot water circulating pump 3 of smaller power, electric energy can be saved.
Expansion tank 4 is provided with hot water backwater's pipeline 11, for absorption cycle water be heated caused by volumetric expansion, Protect whole circulation line.
The compressed nitrogen being passed through on expansion tank 4 after the adjustment of nitrogen pressure regulator valve 6, keeps having in closed circulation system Stablize suitable pressure.Relief valve 5 is set on expansion tank 4, for protecting closed cycle system when nitrogen pressure regulator valve 6 fails Pressure is unlikely to excessive in system.
Pressure is maintained due to being passed through compressed nitrogen on expansion tank 4, expansion tank 4 can be installed on easy to operation Lower, rather than the peak of whole closed circulation system.
Liquid level gauge 1 is provided with expansion tank 4, for monitoring simultaneously interlocked control small pump 7, when whole enclosed is followed Loop system can interlock due to leakage or other reasons and during water shortage and open small pump 7, by moisturizing pipeline 12 to closed cycle Supplement soft water in system.
The entrance of small pump 7 is connected by pipeline with water supply tank 8, and water supply tank 8 is provided with liquid level gauge 2 15, for monitoring simultaneously Interlocked control stop valve 9, when water level is too low in water supply tank 8, can interlock and open the water filling into water supply tank 8 of stop valve 9, until Water level returns to setting value.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (2)

1. a kind of raw coke oven gas waste heat be used for vacuum potassium carbonate desulfurization hot water cyclesystem, it is characterised in that including by primary cooler, Hot water feeding pipe road, doctor solution reboiler, the closed circulation system of hot water backwater's pipeline composition;The epimere high temperature of the primary cooler Hot water outlet connects the heat transferring medium entrance of doctor solution reboiler, the heat transferring medium of doctor solution reboiler by hot water feeding pipe road The epimere low-temperature water heating that outlet connects primary cooler by hot water backwater's pipeline exports;The doctor solution entrance of the doctor solution reboiler It is connected with the doctor solution outlet on desulfurization regeneration tower top, doctor solution outlet and the desulfurization regeneration tower bottom of doctor solution reboiler Doctor solution entrance be connected;Hot water circulating pump is set on hot water backwater's pipeline;Expansion tank is additionally provided with hot water backwater's pipeline, is expanded Relief valve is set at the top of water tank, top sets compressed nitrogen entrance, and compressed nitrogen entrance connects external compression nitrogen by nitrogen pipeline Gas source of the gas, sets nitrogen pressure regulator valve on nitrogen pipeline;Expansion tank is additionally provided with liquid level gauge one.
2. a kind of raw coke oven gas waste heat according to claim 1 is used for the hot water cyclesystem of vacuum potassium carbonate desulfurization, it is special Sign is that hot water backwater's pipeline between the hot water circulating pump and expansion tank connects one end of moisturizing pipeline, moisturizing pipeline The other end set soft water entrance, be equipped with stop valve, water supply tank and small pump successively in the moisturizing pipeline in soft water entrance downstream;Its In, small pump and one interlocked control of liquid level gauge on expansion tank;Liquid level gauge two is set on water supply tank, liquid level gauge two joins with stop valve Lock control.
CN201711401876.7A 2017-12-22 2017-12-22 A kind of raw coke oven gas waste heat is used for the hot water cyclesystem of vacuum potassium carbonate desulfurization Pending CN107903950A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110295066A (en) * 2018-12-07 2019-10-01 西安诺普电气工程技术有限公司 Solve the transverse pipe initial cooler and its method of exhaust valve water spray

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101016485A (en) * 2007-03-13 2007-08-15 中冶焦耐工程技术有限公司 Vacuum carbonate method coal gas desulfurization processes and apparatus thereof directly utilizing deserted coal gas residual heat as desorption heat source
CN207738712U (en) * 2017-12-22 2018-08-17 中冶焦耐(大连)工程技术有限公司 A kind of raw coke oven gas waste heat is used for the hot water cyclesystem of vacuum potassium carbonate desulfurization

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101016485A (en) * 2007-03-13 2007-08-15 中冶焦耐工程技术有限公司 Vacuum carbonate method coal gas desulfurization processes and apparatus thereof directly utilizing deserted coal gas residual heat as desorption heat source
CN207738712U (en) * 2017-12-22 2018-08-17 中冶焦耐(大连)工程技术有限公司 A kind of raw coke oven gas waste heat is used for the hot water cyclesystem of vacuum potassium carbonate desulfurization

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110295066A (en) * 2018-12-07 2019-10-01 西安诺普电气工程技术有限公司 Solve the transverse pipe initial cooler and its method of exhaust valve water spray

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