CN107903706A - A kind of environmental protection UV curable ink - Google Patents
A kind of environmental protection UV curable ink Download PDFInfo
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- CN107903706A CN107903706A CN201711193655.5A CN201711193655A CN107903706A CN 107903706 A CN107903706 A CN 107903706A CN 201711193655 A CN201711193655 A CN 201711193655A CN 107903706 A CN107903706 A CN 107903706A
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- curable ink
- environmental protection
- ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of environmentally friendly UV curable ink, it is related to technical field of environmental protection ink.The environmentally friendly UV curable ink of the present invention, includes the raw material of following parts by weight：65~80 parts of environment protection modification resin, 5~15 parts of ultraviolet initiator, 8~18 parts of Cu-Zn alloy powder, 3~10 parts of trimethylolpropane trimethacrylate, 2~8 parts of attapulgite, 1~5 part of organic silicon modified by polyether oxygen alkane, 0.5~3 part of silane coupling agent, 0.1~0.6 part of dimethicone, 1~3 part of photosensitizer, 0.2~0.8 part of thickener.The environmental protection of present component reasonable mixture ratio, has the advantages that quick solidifying, heat-resisting, wear-resistant, printing performance is good, reduces the penetrating odor of ink, environment protection health.
Description
Technical field：
The present invention relates to technical field of environmental protection ink, and in particular to a kind of environmental protection UV curable ink.
Background technology：
UV curable ink refers to that the binder under the ultraviolet light of certain wavelength in ink crosslinks reaction,
It is changed into solid-state from liquid and completes cured ink.As a kind of new environment-friendlyink ink UV curable ink have it is energy saving,
Solvent-free discharge, free from environmental pollution, production efficiency is high, low etc. excellent suitable for temperature sensitive substrate, printing excellent performance, equipment investment
Point, has extremely to be widely applied on the printing faces such as paper, plastic-metal, paint film and almost contains all existing printers
Skill, the occupation rate of ink in the market are also stepping up.
In the prior art, esters of acrylic acid small molecule monomer is contained mostly in the component of UV curable ink, in room temperature
Under saturated vapour pressure it is larger, it is readily volatilized, and this kind of reactive diluent mostly have compare strong impulse smell, because
This produces that UV printing ink may pollute production and the environment used and printing effect is poor.
The content of the invention：
The technical problems to be solved by the invention are to provide a kind of environmentally friendly UV curable ink, have quick solidifying, resistance to
Hot, wear-resistant, the advantages of printing performance is good, reduce the penetrating odor of ink, environment protection health.
The technical problems to be solved by the invention are realized using following technical solution：
The present invention provides a kind of environmentally friendly UV curable ink, include the raw material of following parts by weight：Environment protection modification resin
65~80 parts, it is 5~15 parts of ultraviolet initiator, 8~18 parts of Cu-Zn alloy powder, 3~10 parts of trimethylolpropane trimethacrylate, concavo-convex
2~8 parts of rod soil, 1~5 part of organic silicon modified by polyether oxygen alkane, 0.5~3 part of silane coupling agent, 0.1~0.6 part of dimethicone,
1~3 part of photosensitizer, 0.2~0.8 part of thickener.
The environment protection modification resin includes the raw material of following parts by weight：6~10 parts of waterborne acrylic paint, aminomethyl phenyl
2~6 parts of silicones, 1~3 part of tetrahydrophthalic anhydride, 0.8~1.2 part of acrylic acid.
Preferably, the raw material of following parts by weight is included：72 parts of environment protection modification resin, 9 parts of ultraviolet initiator, Cu-Zn alloy powder 12
Part, 7 parts of trimethylolpropane trimethacrylate, 5 parts of attapulgite, 2 parts of organic silicon modified by polyether oxygen alkane, 1 part of silane coupling agent,
0.5 part of dimethicone, 2 parts of photosensitizer, 0.6 part of thickener；
The environment protection modification resin includes the raw material of following parts by weight：8 parts of waterborne acrylic paint, aminomethyl phenyl silicon tree
3 parts of fat, 2 parts of tetrahydrophthalic anhydride, 0.8 part of acrylic acid.
Preferably, the photosensitizer for 2- ethyl hydrazine, styrax diethyl ether, 2- hydroxy-2-methyl -1- phenylacetones,
One or more combinations in 1- hydroxy cyclohexyl phenylketones.
Preferably, the thickener is alkali swelling type acrylate copolymer, polyurethanes, cellulose family water-based thickener
In one or more combinations.
Present invention also offers the preparation method of above-mentioned environmentally friendly UV curable ink, comprise the following steps：
1) mill base is prepared：Environment protection modification resin, Cu-Zn alloy powder are put into mill base special barrel according to parts by weight, 600~800r/
Stirred evenly under min rotating speeds, then put into three-roller and be ground to particle diameter less than 20 μm, obtain mill base；
2) ink formulation is premixed：Ultraviolet initiator, trimethylolpropane trimethacrylate, attapulgite, silane is even
Join in agent, dimethicone, photosensitizer input reaction kettle, stir evenly, then put into mill base, thickener, organic silicon modified by polyether
Oxygen alkane, is warming up to 40~60 DEG C, 40~60min of insulated and stirred, obtains premix ink；
3) grinding filtering：Premix ink is ground to particle diameter less than 10 μm using three-roller, 200~300 mesh sieves is crossed, obtains
The environmental protection UV curable ink.
The beneficial effects of the invention are as follows：1st, environmentally friendly UV curable ink of the invention, is main using environment protection modification resin
Component, by the reactive diluent trimethylolpropane trimethacrylate, loose more for adding colouring agent Cu-Zn alloy powder, good intermiscibility
Stick attapulgite, the defoaming lubricant organic silicon modified by polyether oxygen alkane in hole, compound a variety of conventional auxiliary agents, composition proportion is closed
Reason environmental protection, has the advantages that quick solidifying, heat-resisting, wear-resistant, printing performance is good, reduces the penetrating odor of ink, ring health care
Health.
2nd, environment protection modification resin of the invention, with cheap environmental protection, glossiness is good, the water of excellent pigment wetability and color developing
Property acrylate is principal resinous ingredients, by the methyl phenyl silicone resin, the curing agent tetrahydrochysene benzene that add high-temperature corrosion resistance
The fast vinyl monomer acrylic acid of acid anhydride, polymerization speed, is modified waterborne acrylic paint, has obtained high comprehensive performance
Environment protection modification resin.
Embodiment：
In order to make the technical means, the creative features, the aims and the efficiencies achieved by the present invention easy to understand, tie below
Specific embodiment is closed, the present invention is further explained.
Embodiment 1
A kind of environmental protection UV curable ink, includes the raw material of following parts by weight：72 parts of environment protection modification resin, ultraviolet light draw
Send out 9 parts of agent, 12 parts of Cu-Zn alloy powder, 7 parts of trimethylolpropane trimethacrylate, 5 parts of attapulgite, organic silicon modified by polyether oxygen alkane 2
Part, 1 part of silane coupling agent, 0.5 part of dimethicone, 2 parts of styrax diethyl ether, 0.6 part of alkali swelling type acrylate copolymer；
Environment protection modification resin includes the raw material of following parts by weight：8 parts of waterborne acrylic paint, 3 parts of methyl phenyl silicone resin, tetrahydrochysene benzene
2 parts of acid anhydride, 0.8 part of acrylic acid.
The preparation method of above-mentioned environmental protection UV curable ink, comprises the following steps：
1) mill base is prepared：Environment protection modification resin, Cu-Zn alloy powder are put into mill base special barrel according to parts by weight, 700r/min turns
Stirred evenly under speed, then put into three-roller and be ground to particle diameter less than 20 μm, obtain mill base；
2) ink formulation is premixed：Ultraviolet initiator, trimethylolpropane trimethacrylate, attapulgite, silane is even
Join in agent, dimethicone, photosensitizer input reaction kettle, stir evenly, then put into mill base, thickener, organic silicon modified by polyether
Oxygen alkane, is warming up to 60 DEG C, insulated and stirred 60min, obtains premix ink；
3) grinding filtering：Premix ink is ground to particle diameter less than 10 μm using three-roller, 200~300 mesh sieves is crossed, obtains
The environmental protection UV curable ink.
Embodiment 2
A kind of environmental protection UV curable ink, includes the raw material of following parts by weight：70 parts of environment protection modification resin, ultraviolet light draw
Send out 12 parts of agent, 14 parts of Cu-Zn alloy powder, 6 parts of trimethylolpropane trimethacrylate, 5 parts of attapulgite, organic silicon modified by polyether oxygen alkane 2
Part, 1.6 parts of silane coupling agent, 0.3 part of dimethicone, 1 part of 2- hydroxy-2-methyl -1- phenylacetones, polyurethanes thickener
0.5 part；Environment protection modification resin includes the raw material of following parts by weight：8 parts of waterborne acrylic paint, 4 parts of methyl phenyl silicone resin,
2 parts of tetrahydrophthalic anhydride, 1.0 parts of acrylic acid.
The preparation method of above-mentioned environmental protection UV curable ink, comprises the following steps：
1) mill base is prepared：Environment protection modification resin, Cu-Zn alloy powder are put into mill base special barrel according to parts by weight, 800r/min turns
Stirred evenly under speed, then put into three-roller and be ground to particle diameter less than 20 μm, obtain mill base；
2) ink formulation is premixed：Ultraviolet initiator, trimethylolpropane trimethacrylate, attapulgite, silane is even
Join in agent, dimethicone, photosensitizer input reaction kettle, stir evenly, then put into mill base, thickener, organic silicon modified by polyether
Oxygen alkane, is warming up to 55 DEG C, insulated and stirred 48min, obtains premix ink；
3) grinding filtering：Premix ink is ground to particle diameter less than 10 μm using three-roller, 200~300 mesh sieves is crossed, obtains
The environmental protection UV curable ink.
Embodiment 3
A kind of environmental protection UV curable ink, includes the raw material of following parts by weight：74 parts of environment protection modification resin, ultraviolet light draw
Send out 11 parts of agent, 9 parts of Cu-Zn alloy powder, 7 parts of trimethylolpropane trimethacrylate, 5 parts of attapulgite, organic silicon modified by polyether oxygen alkane 3
Part, 2.2 parts of silane coupling agent, 0.3 part of dimethicone, 2 parts of 1- hydroxy cyclohexyl phenylketones, cellulose family water-based thickener
0.4 part；Environment protection modification resin includes the raw material of following parts by weight：9 parts of waterborne acrylic paint, 4 parts of methyl phenyl silicone resin,
3 parts of tetrahydrophthalic anhydride, 1.2 parts of acrylic acid.
The preparation method of above-mentioned environmental protection UV curable ink, comprises the following steps：
1) mill base is prepared：Environment protection modification resin, Cu-Zn alloy powder are put into mill base special barrel according to parts by weight, 600~800r/
Stirred evenly under min rotating speeds, then put into three-roller and be ground to particle diameter less than 20 μm, obtain mill base；
2) ink formulation is premixed：Ultraviolet initiator, trimethylolpropane trimethacrylate, attapulgite, silane is even
Join in agent, dimethicone, photosensitizer input reaction kettle, stir evenly, then put into mill base, thickener, organic silicon modified by polyether
Oxygen alkane, is warming up to 45 DEG C, insulated and stirred 60min, obtains premix ink；
3) grinding filtering：Premix ink is ground to particle diameter less than 10 μm using three-roller, 200~300 mesh sieves is crossed, obtains
The environmental protection UV curable ink.
Embodiment 4
A kind of environmental protection UV curable ink, includes the raw material of following parts by weight：80 parts of environment protection modification resin, ultraviolet light draw
Send out 13 parts of agent, 16 parts of Cu-Zn alloy powder, 10 parts of trimethylolpropane trimethacrylate, 7 parts of attapulgite, organic silicon modified by polyether oxygen alkane
5 parts, 2.6 parts of silane coupling agent, 0.6 part of dimethicone, 3 parts of 2- ethyl hydrazine, alkali swelling type acrylate copolymer 0.8
Part；Environment protection modification resin includes the raw material of following parts by weight：10 parts of waterborne acrylic paint, 6 parts of methyl phenyl silicone resin, four
3 parts of hydrogen phthalic anhydride, 1.2 parts of acrylic acid.
The preparation method of above-mentioned environmental protection UV curable ink, comprises the following steps：
1) mill base is prepared：Environment protection modification resin, Cu-Zn alloy powder are put into mill base special barrel according to parts by weight, 800r/min turns
Stirred evenly under speed, then put into three-roller and be ground to particle diameter less than 20 μm, obtain mill base；
2) ink formulation is premixed：Ultraviolet initiator, trimethylolpropane trimethacrylate, attapulgite, silane is even
Join in agent, dimethicone, photosensitizer input reaction kettle, stir evenly, then put into mill base, thickener, organic silicon modified by polyether
Oxygen alkane, is warming up to 60 DEG C, insulated and stirred 50min, obtains premix ink；
3) grinding filtering：Premix ink is ground to particle diameter less than 10 μm using three-roller, 200~300 mesh sieves is crossed, obtains
The environmental protection UV curable ink.
Comparative example 1
A kind of environmental protection UV curable ink, includes the raw material of following parts by weight：It is 72 parts of waterborne acrylic paint, ultraviolet
9 parts of photoinitiator, 12 parts of Cu-Zn alloy powder, 7 parts of trimethylolpropane trimethacrylate, 5 parts of attapulgite, organic silicon modified by polyether oxygen
2 parts of alkane, 1 part of silane coupling agent, 0.5 part of dimethicone, 2 parts of styrax diethyl ether, alkali swelling type acrylate copolymer 0.6
Part.
The preparation method of above-mentioned environmental protection UV curable ink, comprises the following steps：
1) mill base is prepared：Waterborne acrylic paint, Cu-Zn alloy powder are put into mill base special barrel according to parts by weight, 700r/
Stirred evenly under min rotating speeds, then put into three-roller and be ground to particle diameter less than 20 μm, obtain mill base；
2) ink formulation is premixed：Ultraviolet initiator, trimethylolpropane trimethacrylate, attapulgite, silane is even
Join in agent, dimethicone, photosensitizer input reaction kettle, stir evenly, then put into mill base, thickener, organic silicon modified by polyether
Oxygen alkane, is warming up to 60 DEG C, insulated and stirred 60min, obtains premix ink；
3) grinding filtering：Premix ink is ground to particle diameter less than 10 μm using three-roller, 200~300 mesh sieves is crossed, obtains
The environmental protection UV curable ink.
Performance test：When the environmentally friendly UV curable ink prepared to above-described embodiment, comparative example has carried out average dry
Between, the test of hardness, heat resistance, concrete outcome is shown in Table 1.
The environmentally friendly UV curable ink the performance test results of table 1.
As can be seen from the above table, the environmentally friendly UV curable ink of embodiment of the present invention drying time that is averaged is short, after dry
Hardness is high, 300 DEG C, it is not blistering in 10s do not fall oil, there is quick solidifying, wear-resistant, heat safe.Comparative example 1 changes environmental protection
Property resin changed into routine waterborne acrylic paint, curings, hardness, Heat-tolerant index decline significantly.
The basic principles, main features and the advantages of the invention have been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (4)
1. a kind of environmental protection UV curable ink, it is characterised in that include the raw material of following parts by weight：Environment protection modification resin 65~
80 parts, 5~15 parts of ultraviolet initiator, 8~18 parts of Cu-Zn alloy powder, 3~10 parts of trimethylolpropane trimethacrylate, attapulgite
2~8 parts, it is 1~5 part of organic silicon modified by polyether oxygen alkane, 0.5~3 part of silane coupling agent, 0.1~0.6 part of dimethicone, photosensitive
1~3 part of agent, 0.2~0.8 part of thickener.
2. environmental protection UV curable ink according to claim 1, it is characterised in that include the raw material of following parts by weight：
72 parts of environment protection modification resin, 9 parts of ultraviolet initiator, 12 parts of Cu-Zn alloy powder, 7 parts of trimethylolpropane trimethacrylate, concave convex rod
5 parts of soil, 2 parts of organic silicon modified by polyether oxygen alkane, 1 part of silane coupling agent, 0.5 part of dimethicone, 2 parts of photosensitizer, thickener 0.6
Part.
3. environmental protection UV curable ink according to claim 1, it is characterised in that the photosensitizer is 2- ethyl anthracenes
One or more groups in quinone, styrax diethyl ether, 2- hydroxy-2-methyl -1- phenylacetones, 1- hydroxy cyclohexyl phenylketones
Close.
4. environmental protection UV curable ink according to claim 1, it is characterised in that the thickener is alkali swelling type third
One or more combinations in olefin(e) acid ester copolymer, polyurethanes, cellulose family water-based thickener.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711193655.5A CN107903706A (en) | 2017-11-24 | 2017-11-24 | A kind of environmental protection UV curable ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711193655.5A CN107903706A (en) | 2017-11-24 | 2017-11-24 | A kind of environmental protection UV curable ink |
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| Publication Number | Publication Date |
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| CN107903706A true CN107903706A (en) | 2018-04-13 |
Family
ID=61848007
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711193655.5A Pending CN107903706A (en) | 2017-11-24 | 2017-11-24 | A kind of environmental protection UV curable ink |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113307637A (en) * | 2020-02-27 | 2021-08-27 | 通用电气公司 | Ceramic slurry with photoreactive-photostable hybrid binder |
| CN113307636A (en) * | 2020-02-27 | 2021-08-27 | 通用电气公司 | Ceramic slurry with photoreactive-photostable hybrid binder |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805541A (en) * | 2010-04-09 | 2010-08-18 | 上海化工研究院 | Ultraviolet curing ink and production method thereof |
| CN101974267A (en) * | 2010-11-04 | 2011-02-16 | 中钞油墨有限公司 | Aqueous ultraviolet light curing pearlescent silk screen ink and preparation method thereof |
| CN102417758A (en) * | 2011-08-09 | 2012-04-18 | 江门市阪桥电子材料有限公司 | Liquid photoreceptive solder resist ink |
| CN102964922A (en) * | 2012-12-03 | 2013-03-13 | 恒昌涂料（惠阳）有限公司 | Super-weatherproof high-resolution liquid photosensitive solder-resisting tin printing ink and preparation method thereof |
| CN103396518A (en) * | 2013-08-26 | 2013-11-20 | 张家港康得新光电材料有限公司 | Organic silicon modified water-based acrylate resin and preparation method thereof |
| CN104046124A (en) * | 2014-06-18 | 2014-09-17 | 江门市阪桥电子材料有限公司 | Ultraviolet-curing solder resist ink and preparation method thereof |
| CN104046125A (en) * | 2014-06-18 | 2014-09-17 | 江门市阪桥电子材料有限公司 | Ultraviolet-curing marking ink and preparation method thereof |
| CN104311793A (en) * | 2014-09-29 | 2015-01-28 | 嘉兴市南开油墨有限公司 | Photochromic ink prepolymer and preparation method thereof as well as photochromic ink |
| CN106189491A (en) * | 2016-07-12 | 2016-12-07 | 桐城市凌志彩印包装有限责任公司 | A kind of antifalse ink |
| CN106349806A (en) * | 2016-08-31 | 2017-01-25 | 东莞市蓝邦电子五金材料有限公司 | Flexible liquid photosensitive white ink and application method thereof |
-
2017
- 2017-11-24 CN CN201711193655.5A patent/CN107903706A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805541A (en) * | 2010-04-09 | 2010-08-18 | 上海化工研究院 | Ultraviolet curing ink and production method thereof |
| CN101974267A (en) * | 2010-11-04 | 2011-02-16 | 中钞油墨有限公司 | Aqueous ultraviolet light curing pearlescent silk screen ink and preparation method thereof |
| CN102417758A (en) * | 2011-08-09 | 2012-04-18 | 江门市阪桥电子材料有限公司 | Liquid photoreceptive solder resist ink |
| CN102964922A (en) * | 2012-12-03 | 2013-03-13 | 恒昌涂料（惠阳）有限公司 | Super-weatherproof high-resolution liquid photosensitive solder-resisting tin printing ink and preparation method thereof |
| CN103396518A (en) * | 2013-08-26 | 2013-11-20 | 张家港康得新光电材料有限公司 | Organic silicon modified water-based acrylate resin and preparation method thereof |
| CN104046124A (en) * | 2014-06-18 | 2014-09-17 | 江门市阪桥电子材料有限公司 | Ultraviolet-curing solder resist ink and preparation method thereof |
| CN104046125A (en) * | 2014-06-18 | 2014-09-17 | 江门市阪桥电子材料有限公司 | Ultraviolet-curing marking ink and preparation method thereof |
| CN104311793A (en) * | 2014-09-29 | 2015-01-28 | 嘉兴市南开油墨有限公司 | Photochromic ink prepolymer and preparation method thereof as well as photochromic ink |
| CN106189491A (en) * | 2016-07-12 | 2016-12-07 | 桐城市凌志彩印包装有限责任公司 | A kind of antifalse ink |
| CN106349806A (en) * | 2016-08-31 | 2017-01-25 | 东莞市蓝邦电子五金材料有限公司 | Flexible liquid photosensitive white ink and application method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113307637A (en) * | 2020-02-27 | 2021-08-27 | 通用电气公司 | Ceramic slurry with photoreactive-photostable hybrid binder |
| CN113307636A (en) * | 2020-02-27 | 2021-08-27 | 通用电气公司 | Ceramic slurry with photoreactive-photostable hybrid binder |
| EP3872052A1 (en) * | 2020-02-27 | 2021-09-01 | General Electric Company | Ceramic slurries with photoreactive-photostable hybrid binders |
| EP3872051A1 (en) * | 2020-02-27 | 2021-09-01 | General Electric Company | Ceramic slurries with photoreactive-photostable hybrid binders |
| US11572313B2 (en) | 2020-02-27 | 2023-02-07 | General Electric Company | Ceramic slurries with photoreactive-photostable hybrid binders |
| US11578002B2 (en) | 2020-02-27 | 2023-02-14 | General Electric Company | Ceramic slurries with photoreactive-photostable hybrid binders |
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