CN107903024A - 一种抗氧化陶瓷金属复合材料 - Google Patents

一种抗氧化陶瓷金属复合材料 Download PDF

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CN107903024A
CN107903024A CN201711188516.3A CN201711188516A CN107903024A CN 107903024 A CN107903024 A CN 107903024A CN 201711188516 A CN201711188516 A CN 201711188516A CN 107903024 A CN107903024 A CN 107903024A
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weight
parts
oxidation
resistant ceramic
titanium
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王云荣
关剑轩
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Guilin Yanshan District Youth Activity Center
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Abstract

一种抗氧化陶瓷金属复合材料，包括重量份的原料：粘土70‑90重量份、重晶石10‑15重量份、氧化钛13‑18重量份、三氧化二铝8‑17重量份、锆英石35‑55重量份、纳米碳化硅24‑26重量份、磷酸钠1‑3重量份、铜2.5‑3.6重量份、钴0.9‑2.7重量份、钛8‑11重量份。本发明的有益效果是,在现有技术的基础上，提供一种抗氧化陶瓷金属复合材料。

Description

一种抗氧化陶瓷金属复合材料
技术领域
本发明涉及材料领域，具体的说，涉及一种抗氧化陶瓷金属复合材料。
背景技术
陶瓷是由粘土、石英砂以及其他无机非金属原料，经配料、球磨、制粉、成型、烧结等工艺生产的板状或块状制品，广泛应用于装饰与保护建筑物、构筑物的墙面和地面。随着房地产业的迅速发展，使得瓷砖的生产和消费都获得了较大的发展，同时对陶瓷的性能要求也越来越高。然而目前市场上的陶瓷大多强度低，不够坚硬，易碎，使用性差，无法满足市场需求。
由此，如何得到一种抗氧化陶瓷金属复合材料是目前陶瓷产业急需解决的问题。
发明内容
本发明所要解决的技术问题是提供一种抗氧化陶瓷金属复合材料。
本发明解决上述技术问题的技术方案如下：
一种抗氧化陶瓷金属复合材料，包括重量份的原料：粘土70-90重量份、重晶石10-15重量份、氧化钛13-18重量份、三氧化二铝8-17重量份、锆英石35-55重量份、纳米碳化硅24-26重量份、磷酸钠1-3重量份、铜2.5-3.6重量份、钴0.9-2.7重量份、钛8-11重量份。
本发明的有益效果是：在现有技术的基础上，提供一种抗氧化陶瓷金属复合材料。
在上述技术方案的基础上，本发明还可以做如下改进:
进一步，其包括重量份的原料：粘土70重量份、重晶石10重量份、氧化钛13重量份、三氧化二铝8重量份、锆英石35重量份、纳米碳化硅24重量份、磷酸钠1重量份、铜2.5重量份、钴0.9重量份、钛8重量份。
进一步，其包括重量份的原料：粘土90重量份、重晶石15重量份、氧化钛18重量份、三氧化二铝17重量份、锆英石55重量份、纳米碳化硅26重量份、磷酸钠3重量份、铜3.6重量份、钴2.7重量份、钛11重量份。
进一步，其包括重量份的原料：粘土80重量份、重晶石12重量份、氧化钛15重量份、三氧化二铝13重量份、锆英石42重量份、纳米碳化硅25重量份、磷酸钠2.3重量份、铜3.2重量份、钴1.9重量份、钛9重量份。
进一步，其制作方法包括：
(1)按质量比称取原料，混合均匀，粉碎，湿法球磨5-10h，烘干后过150-200目筛，待用；
(2)将上述步骤(1)制得的粉料中加入质量为混合料重量2-4％的水玻璃混合20-30min，静置10-15h，所述水玻璃的固含量为35％；
(3)将步骤(2)混合均匀的粉料送到成型机在60-80MPa下压制成型，然后将压制好的砖坯送至干燥窑中干燥至含水量为3-5％的干坯；
(4)将干坯以5-10℃/min的速率升温至1160-1220℃，保温2-3h，再以10-15℃/min的速率降温至750-850℃，保温0.5-1h，冷却至常温，经磨边、包装即得成品。
具体实施方式
以下结合实施例对本发明的原理和特征进行描述，所举实例只用于解释本发明，并非用于限定本发明的范围。
实施例1
一种抗氧化陶瓷金属复合材料，包括重量份的原料：粘土70重量份、重晶石10重量份、氧化钛13重量份、三氧化二铝8重量份、锆英石35重量份、纳米碳化硅24重量份、磷酸钠1重量份、铜2.5重量份、钴0.9重量份、钛8重量份。
其制作方法包括：
(1)按质量比称取原料，混合均匀，粉碎，湿法球磨5h，烘干后过150目筛，待用；
(2)将上述步骤(1)制得的粉料中加入质量为混合料重量2％的水玻璃混合20min，静置10h，所述水玻璃的固含量为35％；
(3)将步骤(2)混合均匀的粉料送到成型机在60MPa下压制成型，然后将压制好的砖坯送至干燥窑中干燥至含水量为3％的干坯；
(4)将干坯以5℃/min的速率升温至1160℃，保温3h，再以10℃/min的速率降温至750℃，保温0.5h，冷却至常温，经磨边、包装即得成品。
实施例2
一种抗氧化陶瓷金属复合材料，包括重量份的原料：粘土90重量份、重晶石15重量份、氧化钛18重量份、三氧化二铝17重量份、锆英石55重量份、纳米碳化硅26重量份、磷酸钠3重量份、铜3.6重量份、钴2.7重量份、钛11重量份。
其制作方法包括：
(1)按质量比称取原料，混合均匀，粉碎，湿法球磨10h，烘干后过200目筛，待用；
(2)将上述步骤(1)制得的粉料中加入质量为混合料重量4％的水玻璃混合30min，静置15h，所述水玻璃的固含量为35％；
(3)将步骤(2)混合均匀的粉料送到成型机在80MPa下压制成型，然后将压制好的砖坯送至干燥窑中干燥至含水量为5％的干坯；
(4)将干坯以10℃/min的速率升温至1220℃，保温3h，再以15℃/min的速率降温至850℃，保温1h，冷却至常温，经磨边、包装即得成品。
实施例3
一种抗氧化陶瓷金属复合材料，包括重量份的原料：粘土80重量份、重晶石12重量份、氧化钛15重量份、三氧化二铝13重量份、锆英石42重量份、纳米碳化硅25重量份、磷酸钠2.3重量份、铜3.2重量份、钴1.9重量份、钛9重量份。
其制作方法包括：
(1)按质量比称取原料，混合均匀，粉碎，湿法球磨10h，烘干后过200目筛，待用；
(2)将上述步骤(1)制得的粉料中加入质量为混合料重量4％的水玻璃混合30min，静置15h，所述水玻璃的固含量为35％；
(3)将步骤(2)混合均匀的粉料送到成型机在80MPa下压制成型，然后将压制好的砖坯送至干燥窑中干燥至含水量为5％的干坯；
(4)将干坯以10℃/min的速率升温至1220℃，保温3h，再以15℃/min的速率降温至850℃，保温1h，冷却至常温，经磨边、包装即得成品。
对比例1
市售普通陶瓷材料。
分别将实施例1-3中得到的样品1-3和对比例中的对比样品1进行性能的测试，测试其破坏强度、断裂模数和耐高温性能，结果如下表所示。
破坏强度/N 断裂模数/MPa 耐高温性能
实施例1 3155 45 优秀
实施例2 3158 45 优秀
实施例3 3157 43 优秀
对比例1 857 29 一般
以上所述仅为本发明的较佳实施例，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (5)

1.一种抗氧化陶瓷金属复合材料，其特征在于，包括重量份的原料：粘土70-90重量份、重晶石10-15重量份、氧化钛13-18重量份、三氧化二铝8-17重量份、锆英石35-55重量份、纳米碳化硅24-26重量份、磷酸钠1-3重量份、铜2.5-3.6重量份、钴0.9-2.7重量份、钛8-11重量份。
2.根据权利要求1所述一种抗氧化陶瓷金属复合材料，其特征在于，包括重量份的原料：粘土70重量份、重晶石10重量份、氧化钛13重量份、三氧化二铝8重量份、锆英石35重量份、纳米碳化硅24重量份、磷酸钠1重量份、铜2.5重量份、钴0.9重量份、钛8重量份。
3.根据权利要求1所述一种抗氧化陶瓷金属复合材料，其特征在于，包括重量份的原料：粘土90重量份、重晶石15重量份、氧化钛18重量份、三氧化二铝17重量份、锆英石55重量份、纳米碳化硅26重量份、磷酸钠3重量份、铜3.6重量份、钴2.7重量份、钛11重量份。
4.根据权利要求1所述一种抗氧化陶瓷金属复合材料，其特征在于，包括重量份的原料：粘土80重量份、重晶石12重量份、氧化钛15重量份、三氧化二铝13重量份、锆英石42重量份、纳米碳化硅25重量份、磷酸钠2.3重量份、铜3.2重量份、钴1.9重量份、钛9重量份。
5.根据权利要求1-4任一所述一种抗氧化陶瓷金属复合材料，其特征在于，其制作方法包括：
(1)按质量比称取原料，混合均匀，粉碎，湿法球磨5-10h，烘干后过150-200目筛，待用；
(2)将上述步骤(1)制得的粉料中加入质量为混合料重量2-4％的水玻璃混合20-30min，静置10-15h，所述水玻璃的固含量为35％；
(3)将步骤(2)混合均匀的粉料送到成型机在60-80MPa下压制成型，然后将压制好的砖坯送至干燥窑中干燥至含水量为3-5％的干坯；
(4)将干坯以5-10℃/min的速率升温至1160-1220℃，保温2-3h，再以10-15℃/min的速率降温至750-850℃，保温0.5-1h，冷却至常温，经磨边、包装即得成品。
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Publication number Priority date Publication date Assignee Title
CN108793967A (zh) * 2018-07-03 2018-11-13 合肥连森裕腾新材料科技开发有限公司 一种抗氧化陶瓷基复合材料及其制备方法

Citations (1)

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CN104803658A (zh) * 2015-04-27 2015-07-29 苏州统明机械有限公司 一种耐腐蚀性强的陶瓷及其制备方法

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* Cited by examiner, † Cited by third party
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CN104803658A (zh) * 2015-04-27 2015-07-29 苏州统明机械有限公司 一种耐腐蚀性强的陶瓷及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108793967A (zh) * 2018-07-03 2018-11-13 合肥连森裕腾新材料科技开发有限公司 一种抗氧化陶瓷基复合材料及其制备方法

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