CN107902885A - A kind of pro-skin type fire prevention rock wool blanket and preparation method thereof - Google Patents

A kind of pro-skin type fire prevention rock wool blanket and preparation method thereof Download PDF

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Publication number
CN107902885A
CN107902885A CN201711171944.5A CN201711171944A CN107902885A CN 107902885 A CN107902885 A CN 107902885A CN 201711171944 A CN201711171944 A CN 201711171944A CN 107902885 A CN107902885 A CN 107902885A
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CN
China
Prior art keywords
rock wool
wool blanket
pro
fire prevention
skin type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711171944.5A
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Chinese (zh)
Inventor
汪丽婷
孙鑫
赵艳娟
王滌非
许建华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Tong Tian Rock Wool Co Ltd
Original Assignee
Nanjing Tong Tian Rock Wool Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Tong Tian Rock Wool Co Ltd filed Critical Nanjing Tong Tian Rock Wool Co Ltd
Priority to CN201711171944.5A priority Critical patent/CN107902885A/en
Publication of CN107902885A publication Critical patent/CN107902885A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/005Manufacture of flakes
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/04Manufacture of glass fibres or filaments by using centrifugal force, e.g. spinning through radial orifices; Construction of the spinner cups therefor
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00Fibre or filament compositions
    • C03C13/06Mineral fibres, e.g. slag wool, mineral wool, rock wool
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10Coating
    • C03C25/12General methods of coating; Devices therefor
    • C03C25/14Spraying
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10Coating
    • C03C25/48Coating with two or more coatings having different compositions
    • C03C25/50Coatings containing organic materials only

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Building Environments (AREA)
  • Glass Compositions (AREA)

Abstract

The present invention discloses a kind of pro-skin type fire prevention rock wool blanket and preparation method thereof, and pro-skin type fire prevention rock wool blanket is melted by following components by weight percentage to be formed:Each raw material accounting is as follows in raw material material side:Black Warrior stone 47.5 50.2%;Dolomite 15.8 17.6%;Iron ore 12.3 14.1%;Slag 4.4 6.2%;Coke 15.0 15.7%;Binding agent accounts for 0.8% 1.2% in rock wool blanket.The present invention is by rock wool fibers modification and improves curing process, and obtained rock wool blanket has fire prevention and flexibility concurrently, greatly facilitates construction operability, is widely used in steel building fireproof heat-insulation system, strengthens the market competitiveness, reduces production cost.

Description

A kind of pro-skin type fire prevention rock wool blanket and preparation method thereof
Technical field
The present invention relates to construction material technical field, and in particular to a kind of pro-skin type fire prevention rock wool blanket and its preparation side Method.
Background technology
Rock wool is for puffy short glass fibre made of raw material with natural rock and mineral etc..Existing rock wool manufacturing process Being will be using basalt as main raw material(s), the inorganic fiberboard that is process through high-temperature fusion.Common asbestos product have it is light, It is non-ignitable, mothproof, thermal conductivity is low, heatproof up to 300-400 DEG C, corrosion-resistant, chemical stability is strong, sound absorbing capabilities are good the advantages that.
When as construction material, current asbestos product is but liable to stick on skin, there are certain irritation, is connect Touching the people of asbestos product has minority difficult to handle or skin allergy phenomenon occur;The steel building of Multiple Shape needs more unfolding Rock wool product, there is bigger application advantage for fireproof durable, more preferable flexible rock wool blanket.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of pro-skin type fire prevention rock wool blanket and its preparation side Method
A kind of pro-skin type fire prevention rock wool blanket, the raw material of the rock wool blanket by forming as follows:
A kind of preparation method of pro-skin type fire prevention rock wool blanket, includes the following steps:
A, raw material is weighed according to the parts by weight of claim 1
B, raw material is added to melting furnace high temperature by different feed bins and melted, melting furnace combustion air amount 5500- 6000m3/h, combustion-supporting 500-600 DEG C of air temperature, oxygen-enriched ratio 0.023-0.024, Jiao's material compare 0.185-0.2.
C, melted melt is flowed on centrifuge roller head by siphon port, by centrifugal force into silk, binding agent along The heart wind that blows off is sprayed onto on fiber, binding agent discharge rate 0.8-1%, one roller linear velocity 95-105m/s of centrifuge;Two roller linear velocity 110- 120m/s, blow off wind wind speed 90-95m/s;Three roller linear velocity 120-130m/s, blow off wind wind speed 110-120m/s;Four-roller linear speed 125-130m/s is spent, blow off wind wind speed 110-120m/s.
D, the fiber that centrifugation produces is piled into cotton into " z " repeatedly under pendulum effect, is sent into by web plate collection cotton into a felt Curing oven cures, and three sections are heating and curing as area drying, the drying of 2nd area and the drying of 3rd area, and the temperature of area drying is 140- 160 DEG C, the temperature of the 2nd areas drying is 170-190 DEG C, and the temperature of the 3rd areas drying is 220-240 DEG C, curing oven hydrofuge Degree 40%.
E, rock wool blanket is suppressed through pressure roller, cuts fixed specification is made, and the unit weight of rock wool blanket is 70-90kg/m3, and thickness is 25-100mm。
With above-mentioned pro-skin type fire prevention rock wool blanket, the binding agent by forming as follows:
The present invention is by rock wool fibers modification and improves curing process, and obtained rock wool blanket fiber is finer and closely woven, neat, face Color uniformly, slag ball it is few, it is soft, do not prick the hand, can directly contact skin, nonirritant and allergic reaction, have concurrently fire prevention and Flexibility, greatly facilitates construction operability, is widely used in steel building fireproof heat-insulation system, strengthens market competition Power, reduces production cost.
Embodiment
Technical scheme is described in further detail with reference to specific embodiment, but protection scope of the present invention is not It is confined to as described below.
The present invention proposes that a kind of pro-skin type prevents fires rock wool blanket preparation method, it is necessary to use following raw material:Black Warrior stone, white clouds Stone, iron ore, slag, coke, binding agent.
Wherein, basalt granularity 80-120mm, Size of Dolomite 40-60mm, slag granularity 60-80mm, coke size 80- 150mm。
Embodiment raw material is raw material given above, the content (%) by weight percentage in following embodiments.
Embodiment 1
Raw material is weighed according to the following ratio:Black Warrior stone 48%;Dolomite 17%;Iron ore 14%;Slag 6%;Coke 15%;
Raw material is premixed, hybrid technique is:It is divided to two storehouses to feed intake in Black Warrior stone, coke, raw material uniformly puts into melted through batch charger In stove;Melting furnace combustion air amount 5500-6000m3/h, combustion-supporting 500-600 DEG C of air temperature, oxygen-enriched ratio 0.023-0.024 are burnt Material compares 0.185-0.2;
Melt is sprayed through centrifuge closes 1% binding agent, one roller linear velocity 95-105m/s of centrifuge;Two roller linear velocities 110-120m/s, blow off wind wind speed 90-95m/s;Three roller linear velocity 120-130m/s, blow off wind wind speed 110-120m/s;Four-roller Linear velocity 125-130m/s, blow off wind wind speed 110-120m/s;
Through collecting cotton, curing, compacting and cutting, the be heating and curing temperature of area drying of three sections of curing oven is 140-160 DEG C, two The temperature of area's drying is 170-190 DEG C, and the temperature of 3rd area drying is 220-240 DEG C, curing oven hydrofuge degree 40%.
Embodiment 2
Raw material is weighed according to the following ratio:Black Warrior stone 50%;Dolomite 16%;Iron ore 13%;Slag 6%;Coke 15%;
Preparation process is the same as embodiment 1.
Embodiment 3
Raw material is weighed according to the following ratio:Black Warrior stone 52%;Dolomite 15%;Iron ore 12%;Slag 6%;Coke 15%;
Preparation process is the same as embodiment 1.
Embodiment 4
Raw material is weighed according to the following ratio:Black Warrior stone 54%;Dolomite 14%;Iron ore 11%;Slag 6%;Coke 15%;
Preparation process is the same as embodiment 1.
Embodiment 5
Raw material is weighed according to the following ratio:Black Warrior stone 56%;Dolomite 14%;Iron ore 9%;Slag 6%;Coke 15%;
Preparation process is the same as embodiment 1.
The performance test of example 1-5 is shown in Table 1
Embodiment 1 has good a pro-skin performance and fire protecting performance it can be seen from embodiment experimental data, dolomite and Iron ore has rock wool blanket pliability and fire resistance period a considerable influence, and iron ore is reduced with dolomite content, during rock wool blanket fire resisting Between reduce, felt face it is coarse prick the hand.
The above is only the preferred embodiment of the present invention, it should be understood that the present invention is not limited to described herein Form, is not to be taken as the exclusion to other embodiment, and can be used for various other combinations, modification and environment, and can be at this In the text contemplated scope, it is modified by the technology or knowledge of above-mentioned teaching or association area.And those skilled in the art institute into Capable modifications and changes do not depart from the spirit and scope of the present invention, then all should be in the protection domain of appended claims of the present invention It is interior.

Claims (7)

  1. The rock wool blanket 1. a kind of pro-skin type is prevented fires, it is characterised in that the raw material of the rock wool blanket by forming as follows:
    Black Warrior stone 47.5-50.2%;
    Dolomite 15.8-17.6%;
    Iron ore 12.3-14.1%;
    Slag 4.4-6.2%;
    Coke 15.0-15.7%.
  2. 2. the preparation method of a kind of pro-skin type fire prevention rock wool blanket described in claim 1, it is characterised in that include the following steps:
    A. according to Black Warrior stone 47.5-50.2%, dolomite 15.8-17.6%, iron ore 12.3-14.1%, slag 4.4-6.2% and Jiao The weight ratio of charcoal 15.0-15.7% weighs raw material;
    B, raw material is added to melting furnace high temperature by different feed bins and melted;
    C, melted melt is flowed on centrifuge roller head by siphon port, and by centrifugal force into silk, binding agent is along blowing off Heart wind is sprayed onto on fiber, binding agent discharge rate 0.8-1%;
    D, the fiber that centrifugation produces is piled into cotton into " z " repeatedly under pendulum effect, is sent into and cures by web plate collection cotton into a felt Stove cures, and three sections are heating and curing as area drying, the drying of 2nd area and the drying of 3rd area;
    E, rock wool blanket is suppressed through pressure roller, cuts the unit weight and thickness that fixed specification is made.
  3. A kind of 3. preparation method of pro-skin type fire prevention rock wool blanket according to claim 2, it is characterised in that the b The combustion air amount 5500-6000m3/h of melting furnace, combustion-supporting 500-600 DEG C of air temperature, oxygen-enriched ratio 0.023- in step 0.024, Jiao's material compares 0.185-0.2.
  4. A kind of 4. preparation method of pro-skin type fire prevention rock wool blanket according to claim 2, it is characterised in that the step c Middle binding agent by forming as follows:
    Phenolic resin(40% concentration)400 parts by weight;
    Dust laying oil (50% concentration) 30-35 parts by weight;
    Silane(KH550)4-6 parts by weight;
    Hydrophober(40-50% concentration)15-20 parts by weight;
    Water 3000-3500 parts by weight.
  5. A kind of 5. preparation method of pro-skin type fire prevention rock wool blanket according to claim 2, it is characterised in that the step c Middle one roller linear velocity 95-105m/s of centrifuge;Two roller linear velocity 110-120m/s, blow off wind wind speed 90-95m/s;Three roller linear speeds 120-130m/s is spent, blow off wind wind speed 110-120m/s;Four-roller linear velocity 125-130m/s, blow off wind wind speed 110-120m/s.
  6. A kind of 6. preparation method of pro-skin type fire prevention rock wool blanket according to claim 2, it is characterised in that the Step d The temperature of Zhong-1 block drying is 140-160 DEG C, and the temperature of 2nd area drying is 170-190 DEG C, and the temperature of 3rd area drying is 220-240 ℃;The curing oven hydrofuge degree 40%.
  7. A kind of 7. preparation method of pro-skin type fire prevention rock wool blanket according to claim 2, it is characterised in that the step e Middle unit weight is 70-90kg/m3, and thickness is 25-100mm.
CN201711171944.5A 2017-11-22 2017-11-22 A kind of pro-skin type fire prevention rock wool blanket and preparation method thereof Pending CN107902885A (en)

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111331995A (en) * 2020-03-02 2020-06-26 南京彤天岩棉有限公司 Preparation method of formaldehyde-free rock wool
CN111410432A (en) * 2020-04-29 2020-07-14 河北三楷深发科技股份有限公司 Graphite modified rock wool product and preparation method thereof
CN111847891A (en) * 2020-07-27 2020-10-30 湖南恒盛新材料有限公司 Rock wool and method for producing and manufacturing rock wool
CN113955944A (en) * 2021-10-26 2022-01-21 天长市康美达新型绝热材料有限公司 Fireproof rock wool board

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CN102873738A (en) * 2012-07-09 2013-01-16 江苏富星新材料科技有限公司 Production method of fly ash insulation boards
CN104478208A (en) * 2014-12-15 2015-04-01 山东鲁阳股份有限公司 Preparation method of black rock wool
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111331995A (en) * 2020-03-02 2020-06-26 南京彤天岩棉有限公司 Preparation method of formaldehyde-free rock wool
CN111410432A (en) * 2020-04-29 2020-07-14 河北三楷深发科技股份有限公司 Graphite modified rock wool product and preparation method thereof
CN111847891A (en) * 2020-07-27 2020-10-30 湖南恒盛新材料有限公司 Rock wool and method for producing and manufacturing rock wool
CN113955944A (en) * 2021-10-26 2022-01-21 天长市康美达新型绝热材料有限公司 Fireproof rock wool board

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Application publication date: 20180413