CN107899363A - A kind of method of water spray absorption emergency disposal liquid ammonia storage tank leakage ammonia - Google Patents
A kind of method of water spray absorption emergency disposal liquid ammonia storage tank leakage ammonia Download PDFInfo
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- CN107899363A CN107899363A CN201711406146.6A CN201711406146A CN107899363A CN 107899363 A CN107899363 A CN 107899363A CN 201711406146 A CN201711406146 A CN 201711406146A CN 107899363 A CN107899363 A CN 107899363A
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- water spray
- liquid ammonia
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims abstract description 253
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 211
- 239000007921 spray Substances 0.000 title claims abstract description 99
- 229910021529 ammonia Inorganic materials 0.000 title claims abstract description 87
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 17
- 238000005253 cladding Methods 0.000 claims description 42
- 238000005507 spraying Methods 0.000 claims description 33
- 239000003595 mist Substances 0.000 claims description 12
- 239000012774 insulation material Substances 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 230000004044 response Effects 0.000 abstract description 4
- 230000006872 improvement Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000008901 benefit Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/406—Ammonia
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
A kind of method of water spray absorption emergency disposal liquid ammonia storage tank leakage ammonia, it is included in the emergency system that liquid ammonia storage tank surrounding sets water spray to adsorb disposal liquid ammonia storage tank leakage ammonia, the emergency system of water spray absorption disposal liquid ammonia storage tank leakage ammonia includes water spray water supply pump, the water inlet of water spray water supply pump is communicated by hydraulic pipeline of intaking with water source, the water outlet of water spray water supply pump is communicated with the water inlet of water spray water-supply-pipe, filter and water delivery motor-driven valve have been sequentially connected in series on water spray water-supply-pipe from inlet end to water outlet end, discharge outlet is equipped with water spray water-supply-pipe from inlet end to the pipeline section between filter.It is high the purpose is to provide a kind of reliability height, fast response time, disposal efficiency, can be fast linked when detecting NH_3 leakage, to realize the method for effectively disposing and ensuring that a kind of water spray of personnel safety adsorbs emergency disposal liquid ammonia storage tank leakage ammonia.
Description
Technical field
The present invention relates to a kind of method of water spray absorption emergency disposal liquid ammonia storage tank leakage ammonia.
Background technology
Ammonia as cooling medium, possess be easily obtained, be cheap, specific refrigerating effect is big, exothermic coefficient is high, flow resistance
It is small, with the simple advantage of circuits, extensive popularization and application have been obtained in the refrigeration process of many industries, has generally been respectively provided with
There is storage tank to store liquefied ammonia, but ammonia has stronger toxicity and inflammable and explosive property at the same time, and once because of NH_3 leakage, there occurs Shanghai father-in-law's board
Refrigerate the great NH_3 leakage accident of Industrial Co., Ltd. " 8.31 ", Changchun City Bao Yuanfengqin industry Co., Ltd " 63 " especially
Fire disaster explosion accident etc., causes serious casualties, huge property loss and severe social influence.Current reply liquid
The emergency disposal measure of ammonia storage tank NH_3 leakage is that shower water is set above liquid ammonia storage tank, can not quickly and efficiently dispose ammonia comprehensively
Leakage, there are larger risk hidden danger.Because ammonia has extremely strong water solubility, tool should be formed around it when liquid ammonia storage tank leaks
The covering property water mist of standby elevated pressures, carries out efficient emergency disposal of meeting an urgent need, it is ensured that people's life and property safety, avoid at the same time
Generation environmental pollution accident.
The content of the invention
The object of the present invention is to provide a kind of reliability height, fast response time, disposal efficiency height, can be let out detecting ammonia
It is fast linked during leakage, effectively dispose and ensure that the water spray of personnel safety adsorbs emergency disposal liquid ammonia storage tank and leaks ammonia to realize
Method.
A kind of method of water spray absorption emergency disposal liquid ammonia storage tank leakage ammonia of the present invention, it comprises the following steps：
A, water spray is set to adsorb the emergency system that disposal liquid ammonia storage tank leaks ammonia, water spray absorption in liquid ammonia storage tank surrounding
The emergency system of disposal liquid ammonia storage tank leakage ammonia includes water spray water supply pump, and the water inlet of water spray water supply pump passes through water inlet
Hydraulic pipeline is communicated with water source, and the water outlet of water spray water supply pump is communicated with the water inlet of water spray water-supply-pipe, and water spray is defeated
Filter and water delivery motor-driven valve are sequentially connected in series on water pipe from inlet end to water outlet end, from water inlet on water spray water-supply-pipe
End is equipped with discharge outlet to the pipeline section between filter, and discharge outlet is communicated with the water inlet of drainpipe, the middle part series connection of drainpipe
There is draining motor-driven valve, the water outlet of drainpipe is communicated with the external world；
The water outlet of the water spray water-supply-pipe is communicated with the water inlet of distributive pipe, and distributive pipe is vertically set, point
Water pipe is equipped with the water outlet of more than 3 from top to bottom, each water outlet of distributive pipe respectively with a space spraying cladding system
Water inlet communicate, the bottom of distributive pipe is equipped with dewatering outlet, and the motor-driven valve that discharges water is equipped with the dewatering outlet of distributive pipe；
Each space spraying cladding system includes preceding jet pipe, left jet pipe, rear jet and right jet pipe, preceding jet pipe edge respectively
Left and right horizontal direction is set, and the left end of preceding jet pipe is communicated with the front end of left jet pipe, and left jet pipe is set along anterior-posterior horizontal direction, left spray
The rear end of pipe is communicated with the left end of rear jet, and rear jet is set along left and right horizontal direction, after the right end of rear jet and right jet pipe
End communicates, and right jet pipe is set along anterior-posterior horizontal direction, and the front end of right jet pipe communicates with the right end of preceding jet pipe, preceding jet pipe, left jet pipe,
The side of rear jet and right jet pipe inwardly is respectively equipped with multiple nozzles, the preceding jet pipe of each space spraying cladding system, a left side
Jet pipe, rear jet and right jet pipe, which enclose, forms a rectangle frame, and preceding jet pipe, left jet pipe, rear jet and right jet pipe enclose the rectangle frame of structure
Middle part be equipped with liquid ammonia storage tank, the space spraying cladding system at top is at top 0.5m -1.2m at the top of liquid ammonia storage tank, liquid
The ammonia detector of detectable ammonia leakage is provided with above ammonia storage tank；
Multiple nozzles can spray the water mist to form cladding liquid ammonia storage tank to liquid ammonia storage tank；
The water delivery motor-driven valve, water spray water supply pump, draining motor-driven valve, discharge water motor-driven valve and ammonia detector with electrically
Control system is connected；
Intake hydraulic pipeline, water spray water-supply-pipe, water delivery motor-driven valve, filter, distributive pipe, drainpipe, draining motor-driven valve,
Each preceding jet pipe, be each enclosed with thermal insulation material on the lateral wall of left jet pipe, each rear jet and each right jet pipe；
B, when ammonia detector detects the alarm linkage concentration and alarm linkage concentration for leaking ammonia concentration and reaching setting
Time more than 1.0 seconds, electric control system linkage open water spray water supply electrically operated valve make water spray water-supply-pipe connect, afterwards
Electric control system starts water spray water supply pump, and water spray water supply pump send water to each space by water spray water-supply-pipe
All nozzles, nozzle spray to form cladding to liquid ammonia storage tank surrounding on spraying cladding system and each space spraying cladding system
The water mist of liquid ammonia storage tank, to absorb the ammonia of liquefied ammonia tank leak；
C, the leak site of liquid ammonia storage tank is handled, after being disposed, first closes water spray water supply pump, turn off
Water spray water supply electrically operated valve, then open draining motor-driven valve and the motor-driven valve 5-10 minutes of discharging water, then turn off draining motor-driven valve
With the motor-driven valve that discharges water.
Further, the ammonia detector is located above liquid ammonia storage tank at 0.9m -1.8m, the suction of ammonia detector
Mouth vertically liquid ammonia storage tank, the spacing on the same space spraying cladding system between adjacent nozzle is 0.3m -0.8m, on
Under spacing between adjacent space spraying cladding system be 0.8m -1.5m, preceding jet pipe, left jet pipe, rear jet and right jet pipe exist
Horizontal direction and the spacing of liquid ammonia storage tank are 0.5m -1.2m.
Further, the ammonia detector is located above liquid ammonia storage tank at 1.1m -1.6m, the same space spraying covering
Spacing on device between adjacent nozzle is 0.4m -0.7m, and the spacing between neighbouring space spraying cladding system is
0.9m -1.3m, preceding jet pipe, left jet pipe, rear jet and right jet pipe in the horizontal direction with the spacing of liquid ammonia storage tank for 0.7m -
1.0m。
Further, the corner of multiple space spraying cladding systems is fixedly linked with stent respectively, the bottom of stent
Fixed on the ground by ring flange.
Further, the stent is made of stainless steel square pipe.
A kind of method of water spray absorption emergency disposal liquid ammonia storage tank leakage ammonia of the present invention：When ammonia detector detects
When leakage ammonia density exceedes alarming value, all nozzles can spray to form covering property water mist to liquid ammonia storage tank surrounding, make liquid ammonia storage tank
The water mists parcel being completely nebulised, improves the solute effect of leakage ammonia, realizes effective disposal of leakage ammonia.Therefore, it is of the invention
The method of water spray absorption emergency disposal liquid ammonia storage tank leakage ammonia a kind of there is reliability height, fast response time, disposal efficiency
Height, can be fast linked when detecting NH_3 leakage, the characteristics of realizing effectively disposal leakage ammonia and ensure personnel safety.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention,
And can be practiced according to the content of specification, described in detail below with presently preferred embodiments of the present invention as after.
With reference to embodiment, the embodiment of the present invention is described in further detail.Following embodiments are used for
Illustrate the present invention, but be not limited to the scope of the present invention.
Brief description of the drawings
Fig. 1 is the structure diagram that the water spray absorption disposal liquid ammonia storage tank of the present invention leaks the emergency system of ammonia.
Embodiment
A kind of method of water spray absorption emergency disposal liquid ammonia storage tank leakage ammonia of the present invention, it comprises the following steps：
A, water spray is set to adsorb the emergency system that disposal liquid ammonia storage tank leaks ammonia in liquid ammonia storage tank surrounding, as shown in Figure 1,
The emergency system of water spray absorption disposal liquid ammonia storage tank leakage ammonia includes water spray water supply pump 6, water spray water supply pump 6 into
The mouth of a river is communicated by hydraulic pipeline of intaking with water source, the water outlet of water spray water supply pump 6 and the water inlet of water spray water-supply-pipe 3
Communicate, be sequentially connected in series filter 5 and water delivery motor-driven valve 4, water spray on water spray water-supply-pipe 3 from inlet end to water outlet end
Discharge outlet, discharge outlet and the water inlet phase of drainpipe 8 are equipped with water-supply-pipe 3 from inlet end to the pipeline section between filter 5
Logical, the middle part of drainpipe 8 is in series with draining motor-driven valve 7, and the water outlet of drainpipe 8 is communicated with the external world；Drainpipe 8, which is used to discharge, answers
Remaining remaining water, prevents frost from blocking in anxious system.
The water outlet of the water spray water-supply-pipe 3 is communicated with the water inlet of distributive pipe 10, and distributive pipe 10 is vertically set
Put, distributive pipe 10 is equipped with the water outlet of more than 3 from top to bottom, and each water outlet of distributive pipe 10 is sprayed with a space respectively
The water inlet of cladding system 1 communicates, and the bottom of distributive pipe 10 is equipped with dewatering outlet, be equipped with the dewatering outlet of distributive pipe 10 discharge water it is electronic
Valve 12；The dewatering outlet of distributive pipe 10 is used to discharge remaining remaining water in emergency system, prevents frost from blocking.
Each space spraying cladding system 1 includes preceding jet pipe, left jet pipe, rear jet and right jet pipe, preceding jet pipe respectively
Set along left and right horizontal direction, the left end of preceding jet pipe is communicated with the front end of left jet pipe, and left jet pipe is set along anterior-posterior horizontal direction, left
The rear end of jet pipe is communicated with the left end of rear jet, and rear jet is set along left and right horizontal direction, the right end of rear jet and right jet pipe
Rear end communicates, and right jet pipe is set along anterior-posterior horizontal direction, and the front end of right jet pipe is communicated with the right end of preceding jet pipe, preceding jet pipe, left spray
Pipe, the side of rear jet and right jet pipe inwardly are respectively equipped with multiple nozzles 2, the preceding spray of each space spraying cladding system 1
Pipe, left jet pipe, rear jet and right jet pipe, which enclose, forms a rectangle frame, and preceding jet pipe, left jet pipe, rear jet and right jet pipe enclose the square of structure
The middle part of shape frame is equipped with liquid ammonia storage tank 13, the space spraying cladding system 1 at top the top of liquid ammonia storage tank 13 top 0.5m-
At 1.2m, the top of liquid ammonia storage tank 13 is provided with the ammonia detector 9 of detectable ammonia leakage；
Multiple nozzles 2 can spray the water mist for forming cladding liquid ammonia storage tank 13 to liquid ammonia storage tank 13；
The water delivery motor-driven valve 4, water spray water supply pump 6, draining motor-driven valve 7, discharge water motor-driven valve 12 and ammonia detector 9
It is connected with electric control system；
Water inlet hydraulic pipeline, water spray water-supply-pipe 3, water delivery motor-driven valve 4, filter 5, distributive pipe 10, drainpipe 8, draining
Motor-driven valve 7, each preceding jet pipe, be each enclosed with thermal insulation material on the lateral wall of left jet pipe, each rear jet and each right jet pipe；
Intake hydraulic pipeline, water spray water-supply-pipe 3, water delivery motor-driven valve 4, filter 5, distributive pipe 10, drainpipe 8, draining motor-driven valve 7,
Each preceding jet pipe, be each enclosed with thermal insulation material on the lateral wall of left jet pipe, each rear jet and each right jet pipe, and can prevent should
Anxious internal system freezes, it is ensured that emergency system remains to work normally in the winter time.
B, when ammonia detector 9 detect leakage ammonia concentration reach setting alarm linkage concentration and alarm linkage it is dense
The time of degree, water spray water supply electrically operated valve 4 is opened in electric control system linkage connected water spray water-supply-pipe 3 more than 1.0 seconds,
Electric control system starts water spray water supply pump 6 afterwards, water spray water supply pump 6 by water by water spray water-supply-pipe 3 send to
All nozzles 2 on each space spraying cladding system 1 and each space spraying cladding system 1, nozzle 2 is to liquid ammonia storage tank 13 4
Week injection forms the water mist of cladding liquid ammonia storage tank 13, to absorb the ammonia of the leakage of liquid ammonia storage tank 13；
C, the leak site of liquid ammonia storage tank 13 is handled, after being disposed, first closes water spray water supply pump 6, then
Water spray water supply electrically operated valve 4 is closed, then opens draining motor-driven valve 7 and the motor-driven valve 5 minutes -10 minutes of discharging water, is then turned off
Draining motor-driven valve 7 and the motor-driven valve 12 that discharges water.
As a further improvement on the present invention, above-mentioned ammonia detector 9 is located at 13 top 0.9m -1.8m of liquid ammonia storage tank,
The suction inlet of ammonia detector vertically liquid ammonia storage tank 9, on the same space spraying cladding system 1 between adjacent nozzle 2
Spacing is 0.3m -0.8m, and the spacing between neighbouring space spraying cladding system 1 is 0.8m -1.5m, preceding jet pipe, a left side
Jet pipe, rear jet and right jet pipe are in the horizontal direction 0.5m -1.2m with the spacing of liquid ammonia storage tank.
As a further improvement on the present invention, above-mentioned ammonia detector 9 is located at 13 top 1.1m -1.6m of liquid ammonia storage tank,
Spacing on the same space spraying cladding system 1 between adjacent nozzle 2 is 0.4m -0.7m, and the spraying of neighbouring space is covered
Spacing between lid arrangement 1 is 0.9m -1.3m, and preceding jet pipe, left jet pipe, rear jet and right jet pipe are stored up with liquefied ammonia in the horizontal direction
The spacing of tank is 0.7m -1.0m.
As a further improvement on the present invention, the corner of above-mentioned multiple space spraying cladding systems 1 is solid with stent 14 respectively
Fixed to be connected, the bottom of stent 14 is fixed on the ground by ring flange 11.
As a further improvement on the present invention, above-mentioned stent 14 is made of stainless steel square pipe.
When ammonia detector 9, which detects leakage ammonia density, exceedes alarming value, water delivery electricity is opened in electric control system linkage
Dynamic valve 4, starts water spray water supply pump 6, water spray water supply pump 6 send water to each sky by water spray water-supply-pipe 3 afterwards
Between spray cladding system 1 on all nozzles 2, nozzle 2 to 13 surrounding water spray of liquid ammonia storage tank formed covering property water mist, make liquefied ammonia
The water mists parcel that storage tank 13 is completely nebulised, improves the solute effect of leakage ammonia, realizes effective disposal of leakage ammonia.Therefore,
A kind of method of water spray absorption emergency disposal liquid ammonia storage tank leakage ammonia of the present invention has reliability height, fast response time, place
Put it is efficient, can be fast linked when detecting NH_3 leakage, realize effectively disposal leakage ammonia and the characteristics of ensure personnel safety.
The present invention by liquid ammonia storage tank surrounding gather nozzle formed the covering property water mist with pressure, high-efficiency dissolution leakage
Ammonia, prevent leakage the escaping of ammonia, diffusion.Because the boiling point of ammonia is extremely low, ammonia is quickly formed after leakage, there is stronger toxicity and inflammable
Explosion hazard, it is therefore necessary to distance between the distance of spray to space cladding system 1 and liquid ammonia storage tank 13, space spraying cladding system 1,
When distance, ammonia warning concentration, ammonia warning concentration are stablized between distance, ammonia detector 9 and liquid ammonia storage tank 13 between nozzle 2
Between carry out hard constraints, distance, each space spraying cladding system 1 spacing of the space spraying cladding system 1 with liquid ammonia storage tank 13
If excessive with a distance between, nozzle 2, complete covering property water mist can not be formed, the diffusion of leakage ammonia is easy to cause and escapes
Ease, if increasing unnecessary construction cost if too small and wasting great lot of water resources, if ammonia detector 9 is stored up with liquefied ammonia
Distance is excessive between tank 13, then can not accurately detect NH_3 leakage at the first time, system interlink starts overlong time, place of meeting an urgent need
Effect is put to have a greatly reduced quality, if if too small 9 effective reconnaissance range of ammonia detector it is too small, can not detect in zone of reasonableness
NH_3 leakage, if the excessive or stabilization time that ammonia warning concentration is set is long, cannot start emergency disposal in time, if report
Alert concentration setting too low or stabilization time is too short, then system can electrically drift about because of equipment, cause continually to malfunction.By a large amount of
Actual test, we have shown that gas detector is located at 1.1m -1.6m of the top of liquid ammonia storage tank 13, the spacing between nozzle
For 0.4m -0.7m, spacing is 0.7m -1.0m between every layer of water spray feed pipe, and ammonia reaches the stabilization time of warning concentration
More than 1.0 seconds, on this condition, liquid ammonia storage tank leakage ammonia can comprehensively, rapidly, be efficiently disposed, to ensure related work
Personnel safety, which is withdrawn, provides feasible operation scheme.
The above is only the preferred embodiment of the present invention, is not intended to limit the invention, it is noted that for this skill
For the those of ordinary skill in art field, without departing from the technical principles of the invention, can also make it is some improvement and
Modification, these improvements and modifications also should be regarded as protection scope of the present invention.
Claims (5)
- A kind of 1. method of water spray absorption emergency disposal liquid ammonia storage tank leakage ammonia, it is characterised in that comprise the following steps：A, water spray is set to adsorb the emergency system that disposal liquid ammonia storage tank leaks ammonia, water spray absorption disposal in liquid ammonia storage tank surrounding The emergency system of liquid ammonia storage tank leakage ammonia includes water spray water supply pump (6), the water inlet of water spray water supply pump (6) by into Water hydraulic pipeline is communicated with water source, and the water outlet of water spray water supply pump (6) is communicated with the water inlet of water spray water-supply-pipe (3), Filter (5) and water delivery motor-driven valve (4), water spray have been sequentially connected in series on water spray water-supply-pipe (3) from inlet end to water outlet end On mist water-supply-pipe (3) discharge outlet, discharge outlet and drainpipe (8) are equipped with from inlet end to the pipeline section between filter (5) Water inlet communicates, and draining motor-driven valve (7) is in series with the middle part of drainpipe (8), and the water outlet of drainpipe (8) is communicated with the external world；The water outlet of the water spray water-supply-pipe (3) is communicated with the water inlet of distributive pipe (10), and distributive pipe (10) is vertically Set, distributive pipe (10) is equipped with the water outlet of more than 3 from top to bottom, each water outlet of distributive pipe (10) respectively with a sky Between the spray water inlet of cladding system (1) communicate, the bottom of distributive pipe (10) is equipped with dewatering outlet, at the dewatering outlet of distributive pipe (10) Equipped with the motor-driven valve that discharges water (12)；Each space spraying cladding system (1) includes preceding jet pipe, left jet pipe, rear jet and right jet pipe, preceding jet pipe edge respectively Left and right horizontal direction is set, and the left end of preceding jet pipe is communicated with the front end of left jet pipe, and left jet pipe is set along anterior-posterior horizontal direction, left spray The rear end of pipe is communicated with the left end of rear jet, and rear jet is set along left and right horizontal direction, after the right end of rear jet and right jet pipe End communicates, and right jet pipe is set along anterior-posterior horizontal direction, and the front end of right jet pipe communicates with the right end of preceding jet pipe, preceding jet pipe, left jet pipe, The side of rear jet and right jet pipe inwardly is respectively equipped with multiple nozzles (2), the preceding spray of each space spraying cladding system (1) Pipe, left jet pipe, rear jet and right jet pipe, which enclose, forms a rectangle frame, and preceding jet pipe, left jet pipe, rear jet and right jet pipe enclose the square of structure The middle part of shape frame is equipped with liquid ammonia storage tank (13), the top of the space spraying cladding system (1) at top at the top of liquid ammonia storage tank (13) At 0.5m -1.2m, the ammonia detector (9) of detectable ammonia leakage is provided with above liquid ammonia storage tank (13)；Multiple nozzles (2) can spray the water mist for forming cladding liquid ammonia storage tank (13) to liquid ammonia storage tank (13)；The water delivery motor-driven valve (4), water spray water supply pump (6), draining motor-driven valve (7), the motor-driven valve that discharges water (12) and ammonia are visited Device (9) is surveyed with electric control system to be connected；Water inlet hydraulic pipeline, water spray water-supply-pipe (3), water delivery motor-driven valve (4), filter (5), distributive pipe (10), drainpipe (8), wrapped up on the lateral wall of draining motor-driven valve (7), each preceding jet pipe, each left jet pipe, each rear jet and each right jet pipe There is thermal insulation material；B, when ammonia detector (9) detects the alarm linkage concentration and alarm linkage concentration for leaking ammonia concentration and reaching setting Time more than 1.0 seconds, electric control system linkage open water spray water supply electrically operated valve (4) connect water spray water-supply-pipe (3) Logical, electric control system starts water spray water supply pump (6) afterwards, and water is passed through water spray water delivery by water spray water supply pump (6) Pipe (3) is sent to nozzle (2) all on each space spraying cladding system (1) and each space spraying cladding system (1), nozzle (2) water mist to form cladding liquid ammonia storage tank (13) is sprayed to liquid ammonia storage tank (13) surrounding, to absorb liquid ammonia storage tank (13) leakage Ammonia；C, the leak site of liquid ammonia storage tank (13) is handled, after being disposed, first closes water spray water supply pump (6), then Water spray water supply electrically operated valve (4) is closed, then opens draining motor-driven valve (7) and the motor-driven valve (12) 5-10 minutes of discharging water, Ran Houzai Close draining motor-driven valve (7) and the motor-driven valve that discharges water (12).
- 2. a kind of method of water spray absorption emergency disposal liquid ammonia storage tank leakage ammonia according to claim 1, its feature exist In：The ammonia detector (9) is located above liquid ammonia storage tank (13) at 0.9m -1.8m, the vertical court of suction inlet of ammonia detector To liquid ammonia storage tank (9), the spacing on the same space spraying cladding system (1) between adjacent nozzle (2) is 0.3m -0.8m, on Under spacing between adjacent space spraying cladding system (1) be 0.8m -1.5m, preceding jet pipe, left jet pipe, rear jet and right spray Pipe is in the horizontal direction 0.5m -1.2m with the spacing of liquid ammonia storage tank.
- 3. a kind of method of water spray absorption emergency disposal liquid ammonia storage tank leakage ammonia according to claim 2, its feature exist In：The ammonia detector (9) is located above liquid ammonia storage tank (13) at 1.1m -1.6m, the same space spraying cladding system (1) Spacing between upper adjacent nozzle (2) be 0.4m -0.7m, the spacing that neighbouring space is sprayed between cladding system (1) For 0.9m -1.3m, preceding jet pipe, left jet pipe, rear jet and right jet pipe in the horizontal direction with the spacing of liquid ammonia storage tank for 0.7m - 1.0m。
- 4. a kind of method of water spray absorption emergency disposal liquid ammonia storage tank leakage ammonia according to claim 1 or 2 or 3, its It is characterized in that：The corner of multiple space spraying cladding systems (1) is fixedly linked with stent (14) respectively, the bottom of stent (14) End is fixed on the ground by ring flange (11).
- 5. a kind of method of water spray absorption emergency disposal liquid ammonia storage tank leakage ammonia according to claim 4, its feature exist In：The stent (14) is made of stainless steel square pipe.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711406146.6A CN107899363B (en) | 2017-12-22 | 2017-12-22 | Method for emergency disposal of ammonia leaked from liquid ammonia storage tank through water spray adsorption |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711406146.6A CN107899363B (en) | 2017-12-22 | 2017-12-22 | Method for emergency disposal of ammonia leaked from liquid ammonia storage tank through water spray adsorption |
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| Publication Number | Publication Date |
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| CN107899363A true CN107899363A (en) | 2018-04-13 |
| CN107899363B CN107899363B (en) | 2020-01-03 |
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| CN201711406146.6A Expired - Fee Related CN107899363B (en) | 2017-12-22 | 2017-12-22 | Method for emergency disposal of ammonia leaked from liquid ammonia storage tank through water spray adsorption |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109539809A (en) * | 2018-12-18 | 2019-03-29 | 安徽海螺集团有限责任公司 | The safety system for preventing liquefied ammonia from spreading |
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| CN101101085A (en) * | 2007-07-30 | 2008-01-09 | 四川美丰化工股份有限公司 | Liquid ammonia storage tank remote control monitoring and automatic sprinkling system realization method |
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| CN206444785U (en) * | 2016-12-30 | 2017-08-29 | 中国安全生产科学研究院 | Synchronous spray isolation and spraying absorption disposal freezing plant leaks the emergency system of ammonia |
| CN107096672A (en) * | 2017-06-14 | 2017-08-29 | 大唐环境产业集团股份有限公司 | A kind of liquid ammonia storage tank fire-fighting water sprinkler system |
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| CN101101085A (en) * | 2007-07-30 | 2008-01-09 | 四川美丰化工股份有限公司 | Liquid ammonia storage tank remote control monitoring and automatic sprinkling system realization method |
| CN104100340A (en) * | 2013-04-09 | 2014-10-15 | 福特环球技术公司 | Enhanced real-time ammonia slip detection |
| CN203463940U (en) * | 2013-09-26 | 2014-03-05 | 山西大唐国际临汾热电有限责任公司 | Liquid ammonia leakage prevention device for denitration in thermal power plant |
| JP2015230053A (en) * | 2014-06-05 | 2015-12-21 | 株式会社Ihi | Ammonia storage facility |
| CN204933221U (en) * | 2015-07-28 | 2016-01-06 | 中国华电工程(集团)有限公司 | A kind of denitrating flue gas treatment system in conjunction with distributed system |
| CN204933229U (en) * | 2015-07-29 | 2016-01-06 | 南通天泽化工有限公司 | Ammonia storage tank overtemperature or leakage automatic spray cooling absorption system device |
| CN106824696A (en) * | 2016-12-30 | 2017-06-13 | 中国安全生产科学研究院 | The method that synchronous spray isolation and spraying absorption disposal freezing plant leak ammonia |
| CN206444785U (en) * | 2016-12-30 | 2017-08-29 | 中国安全生产科学研究院 | Synchronous spray isolation and spraying absorption disposal freezing plant leaks the emergency system of ammonia |
| CN107096672A (en) * | 2017-06-14 | 2017-08-29 | 大唐环境产业集团股份有限公司 | A kind of liquid ammonia storage tank fire-fighting water sprinkler system |
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| CN109539809A (en) * | 2018-12-18 | 2019-03-29 | 安徽海螺集团有限责任公司 | The safety system for preventing liquefied ammonia from spreading |
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| CN107899363B (en) | 2020-01-03 |
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