CN107880981A - A kind of biological base grease for automated machine equipment and preparation method thereof - Google Patents
A kind of biological base grease for automated machine equipment and preparation method thereof Download PDFInfo
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- CN107880981A CN107880981A CN201711127638.1A CN201711127638A CN107880981A CN 107880981 A CN107880981 A CN 107880981A CN 201711127638 A CN201711127638 A CN 201711127638A CN 107880981 A CN107880981 A CN 107880981A
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- phytyl
- automated machine
- machine equipment
- thickening agent
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/105—Silica
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/046—Hydroxy ethers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/401—Fatty vegetable or animal oils used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/402—Castor oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/086—Imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/065—Organic compounds derived from inorganic acids or metal salts derived from Ti or Zr
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
Abstract
The invention discloses a kind of biological base grease for automated machine equipment, it is made up of the raw material of following parts by weight:60 ~ 90 parts of phytyl base oil, 8 ~ 15 parts of thickening agent, 1 ~ 3 part of titanate coupling agent, 1 ~ 3 part of graphite powder, 20 ~ 30 parts of pentaerythritol ester, 1 ~ 3 part of ricinoleic alkyl alcohol amide borate, 2 ~ 5 parts of two phthalimide of single polyisobutene fourth, 3 ~ 7 parts of aerosil, 3 ~ 6 parts of APG, 2 ~ 5 parts of hydroxymethyl cellulose, 1 ~ 2 part of other function additives.The present invention is using the good organism-based raw material of the feature of environmental protection, avoid the addition of mineral base base oil, with good lubricity and biodegradability, gained lubricating grease synthesis greasy property is good, with higher economic value and social value, it is adapted to industrialized production and large batch of automation equipment to use.
Description
Technical field
The present invention relates to lubricant grease technical field, moistens more particularly, to a kind of bio-based for automated machine equipment
Consistent lubricant and preparation method thereof.
Background technology
With the increasingly enhancing that the environmental crisis of people is realized, it is widely acknowledged that a large amount of lubrications that all trades and professions use
Grease in production, use and discharge process due to leak, permeate, overflow and deal with improperly and caused by problem of environmental pollution get over
Come more serious, from the point of view of the trend of social development, environment protection biological based lubricating oil fat and its additive will progressively substitute existing
Mineral based lubricating oil fat.
Environment protection biological base grease refers to that carbon dioxide and water can be decomposed into by active microorganism in the short period of time
Lubricating grease, it has not only good greasy property, and can be reduced environmental pollution by saving energy consumption;Product can be given birth to
Thing is degraded, and can be decomposed into simple CO2Absorbed and non-hazardous by environment with water;Product itself is on environment nonhazardous, influence
It is small.
The continuous development of science and technology has driven the continuous progress of automatic technology, and so far, automation equipment is widely used in workers and peasants
Industry, military affairs, scientific research, transportation, business, medical treatment, service and household electrical appliances etc..Automatic technology not only can be people
Freed from heavy manual labor, part mental labour and danger, severe working environment, while people can be extended
Organ dysfunction, be greatly enhanced labor productivity, strengthen the ability of the human cognitive world and reforming world.Automation equipment exists
Using in, running, the operating of many parts needs to use substantial amounts of grease lubrication, the existing profit for automation equipment
Consistent lubricant is mainly traditional mineral base grease, and the feature of environmental protection is poor, easily to environment and use environment in the case of a large amount of uses
Have undesirable effect.
The content of the invention
In view of the shortcomings of the prior art, the invention provides the good life of a kind of lubricity of automation equipment, the feature of environmental protection
Thing base grease and its preparation.
The present invention solve the technical scheme that uses of above-mentioned technical problem for:A kind of bio-based for automated machine equipment
Lubricating grease, it is made up of following raw material:Phytyl base oil, thickening agent, titanate coupling agent, graphite powder, pentaerythritol ester, castor-oil plant
Oily alkanolamide borate, single phthalimide of polyisobutene fourth two, aerosil, APG, hydroxymethyl cellulose, other
Function additive;
The parts by weight of described raw material are:60 ~ 90 parts of phytyl base oil, 8 ~ 15 parts of thickening agent, 1 ~ 3 part of titanate coupling agent,
1 ~ 3 part of graphite powder, 20 ~ 30 parts of pentaerythritol ester, 1 ~ 3 part of ricinoleic alkyl alcohol amide borate, the phthalimide 2 of single polyisobutene fourth two
~ 5 parts, 3 ~ 7 parts of aerosil, 3 ~ 6 parts of APG, 2 ~ 5 parts of hydroxymethyl cellulose, 1 ~ 2 part of other function additives.
Further, described phytyl base oil is palm oil, soybean oil and rilanit special, and its mass parts ratio is 3 ~ 5:
1~3:1。
Further, described thickening agent is lithium soap, calcium soap or lithium calcium compound soap thickening agent.
Further, other described function additives be antioxidant, defoamer, antirust agent, pour-point depressant it is compound.
A kind of described bio-based preparation of greases method for automated machine equipment, comprises the following steps:Will
Thickening agent, the phytyl base oil of 50 ~ 70% amounts are placed in saponification kettle after mixing, in 80 ~ 100 DEG C of 2 ~ 4h of saponification, are added remaining
Phytyl base oil continues 0.5 ~ 1h of insulation reaction, is warming up to 160 ~ 180 DEG C and is incubated after 10min to be transferred to and reconciles kettle and cool back
Stream, remaining raw material is added when being cooled to 70 ~ 80 DEG C, insulation homogenizing grinding, degassing process, obtains the present invention's after being cooled to normal temperature
Lubricating grease.
Compared with prior art, what the present invention possessed has the beneficial effect that:One kind provided by the invention is used for automated machine
The biological base grease of equipment and its preparation, using the good organism-based raw material of the feature of environmental protection, avoid mineral base basic grease
Addition, there is good lubricity and biodegradability, gained lubricating grease synthesis greasy property is good, has higher economy
Value and social value, it is adapted to industrialized production and large batch of automation equipment to use.
Embodiment
With reference to specific embodiment, the present invention is described further.
Embodiment 1:A kind of biological base grease for automated machine equipment, it is made up of following raw material:Phytyl base
Plinth oil, thickening agent, titanate coupling agent, graphite powder, pentaerythritol ester, ricinoleic alkyl alcohol amide borate, single polyisobutene fourth
Two phthalimides, aerosil, APG, hydroxymethyl cellulose, other function additives;
The parts by weight of described raw material are:75 parts of phytyl base oil, 12 parts of thickening agent, 2 parts of titanate coupling agent, graphite powder 2
Part, 25 parts of pentaerythritol ester, 2 parts of ricinoleic alkyl alcohol amide borate, 4 parts of two phthalimide of single polyisobutene fourth, gas phase titanium dioxide
5 parts of silicon, 5 parts of APG, 3 parts of hydroxymethyl cellulose, 1.5 parts of other function additives.
Further, described phytyl base oil is palm oil, soybean oil and rilanit special, and its mass parts ratio is 4:2:
1。
Further, described thickening agent is lithium soap thickening agent.
Further, other described function additives be antioxidant, defoamer, antirust agent, pour-point depressant it is compound.
A kind of described bio-based preparation of greases method for automated machine equipment, comprises the following steps:Will
Thickening agent, the phytyl base oil of 60% amount are placed in saponification kettle after mixing, in 90 DEG C of saponification 3h, add remaining phytyl basis
Oil continues insulation reaction 45min, is warming up to 170 DEG C and is transferred to mediation kettle cooling for reflux after being incubated 10min, when being cooled to 75 DEG C
Remaining raw material is added, insulation homogenizing grinding, degassing process, the lubricating grease of the present invention is obtained after being cooled to normal temperature.
Embodiment 2:A kind of biological base grease for automated machine equipment, its by following parts by weight raw material group
Into:60 ~ 90 parts of phytyl base oil, 8 parts of thickening agent, 1 part of titanate coupling agent, 1 part of graphite powder, 20 parts of pentaerythritol ester, castor-oil plant
Oily 1 part of alkanolamide borate, 2 parts of two phthalimide of single polyisobutene fourth, 3 parts of aerosil, 3 parts of APG, hydroxyl first
2 parts of base cellulose, 1 part of other function additives.
Further, described phytyl base oil is palm oil, soybean oil and rilanit special, and its mass parts ratio is 3:1:
1;Described thickening agent is calcium soap thickening agent;Other described function additives are antioxidant, defoamer, antirust agent, pour-point depressant
It is compound.
A kind of described bio-based preparation of greases method for automated machine equipment, comprises the following steps:Will
Thickening agent, the phytyl base oil of 50% amount are placed in saponification kettle after mixing, in 80 DEG C of saponification 2h, add remaining phytyl basis
Oil continues insulation reaction 0.5h, is warming up to 160 DEG C and is transferred to mediation kettle cooling for reflux after being incubated 10min, when being cooled to 70 DEG C
Remaining raw material is added, insulation homogenizing grinding, degassing process, the lubricating grease of the present invention is obtained after being cooled to normal temperature.
Embodiment 3:A kind of biological base grease for automated machine equipment, its by following parts by weight raw material group
Into:90 parts of phytyl base oil, 15 parts of thickening agent, 3 parts of titanate coupling agent, 3 parts of graphite powder, 30 parts of pentaerythritol ester, castor oil
3 parts of alkanolamide borate, 5 parts of two phthalimide of single polyisobutene fourth, 7 parts of aerosil, 6 parts of APG, methylol
5 parts of cellulose, 2 parts of other function additives.
Further, described phytyl base oil is palm oil, soybean oil and rilanit special, and its mass parts ratio is 5:
3:1;Described thickening agent is lithium calcium compound soap thickening agent;Other described function additives be antioxidant, defoamer, antirust agent,
Pour-point depressant it is compound.
A kind of described bio-based preparation of greases method for automated machine equipment, comprises the following steps:Will
Thickening agent, the phytyl base oil of 70% amount are placed in saponification kettle after mixing, in 100 DEG C of saponification 4h, add remaining phytyl basis
Oil continues insulation reaction 1h, is warming up to 180 DEG C and is transferred to mediation kettle cooling for reflux after being incubated 10min, adds when being cooled to 80 DEG C
Enter remaining raw material, insulation homogenizing grinding, degassing process, the lubricating grease of the present invention is obtained after being cooled to normal temperature.
Embodiment 4:A kind of biological base grease for automated machine equipment, its by following parts by weight raw material group
Into:60 parts of phytyl base oil, 15 parts of thickening agent, 3 parts of titanate coupling agent, 1 part of graphite powder, 30 parts of pentaerythritol ester, castor oil
1 part of alkanolamide borate, 5 parts of two phthalimide of single polyisobutene fourth, 3 parts of aerosil, 6 parts of APG, methylol
2 parts of cellulose, 2 parts of other function additives.
Further, described phytyl base oil is palm oil, soybean oil and rilanit special, and its mass parts ratio is 5:1:
1;Described thickening agent is lithium soap thickening agent;Other described function additives are antioxidant, defoamer, antirust agent, pour-point depressant
It is compound.
A kind of described bio-based preparation of greases method for automated machine equipment, comprises the following steps:Will
Thickening agent, the phytyl base oil of 55% amount are placed in saponification kettle after mixing, in 95 DEG C of saponification 2.5h, add remaining phytyl base
Plinth oil continues insulation reaction 50min, is warming up to 165 DEG C and is transferred to mediation kettle cooling for reflux after being incubated 10min, is cooled to 75 DEG C
When add remaining raw material, insulation homogenizing grinding, degassing process, the lubricating grease of the present invention is obtained after being cooled to normal temperature.
Embodiment 5:A kind of biological base grease for automated machine equipment, its by following parts by weight raw material group
Into:80 parts of phytyl base oil, 10 parts of thickening agent, 1.5 parts of titanate coupling agent, 2.5 parts of graphite powder, 26 parts of pentaerythritol ester, castor
2.5 parts of sesame oil alkanolamide borate, 4 parts of two phthalimide of single polyisobutene fourth, 6 parts of aerosil, 4 parts of APG,
4 parts of hydroxymethyl cellulose, 1.5 parts of other function additives.
Further, described phytyl base oil is palm oil, soybean oil and rilanit special, and its mass parts ratio is 9:4:
2;Described thickening agent is lithium soap thickening agent;Other described function additives are antioxidant, defoamer, antirust agent, pour-point depressant
It is compound.
A kind of described bio-based preparation of greases method for automated machine equipment, its specific steps is the same as implementation
Example 1.
The lubricating grease obtained to above-described embodiment 1-5 carries out standard testing, as a result shows, above-described embodiment 1-5 is obtained
The work cone penetration of lubricating grease(0.1mm)It is worth for 260 ~ 285, four ball method 0.44 ~ 0.53mm of abrasion resistance, 225 ~ 234 DEG C of dropping point,
Environmentally friendly level biological raw material is used completely simultaneously, and the feature of environmental protection is preferable, and preparation method is simple, is a kind of suitable industrialized production and large quantities of
The lubricating grease that amount automation equipment uses.
It should be pointed out that the content disclosed in above-described embodiment, only present pre-ferred embodiments is several, as long as this
The partial alteration of art personnel use, change, or the part of disclosed technology contents is modified, and come from this
The technological essence of invention and creative thinking is not added with to be familiar with the people of this skill is easy to deduce acquisition, all do not depart from this hair
Bright patent right category.
Claims (5)
1. a kind of biological base grease for automated machine equipment, it is characterised in that be made up of following raw material:Phytyl basis
Oil, titanate coupling agent, thickening agent, graphite powder, pentaerythritol ester, ricinoleic alkyl alcohol amide borate, single polyisobutene fourth two
Phthalimide, aerosil, APG, hydroxymethyl cellulose, other function additives;
The parts by weight of described raw material are:60 ~ 90 parts of phytyl base oil, 8 ~ 15 parts of thickening agent, 1 ~ 3 part of titanate coupling agent,
1 ~ 3 part of graphite powder, 20 ~ 30 parts of pentaerythritol ester, 1 ~ 3 part of ricinoleic alkyl alcohol amide borate, the phthalimide 2 of single polyisobutene fourth two
~ 5 parts, 3 ~ 7 parts of aerosil, 3 ~ 6 parts of APG, 2 ~ 5 parts of hydroxymethyl cellulose, 1 ~ 2 part of other function additives.
A kind of 2. biological base grease for automated machine equipment according to claim 1, it is characterised in that:It is described
Phytyl base oil be palm oil, soybean oil and rilanit special, its mass parts ratio is 3 ~ 5:1~3:1.
A kind of 3. biological base grease for automated machine equipment according to claim 1, it is characterised in that:It is described
Thickening agent be lithium soap, calcium soap or lithium calcium compound soap thickening agent.
A kind of 4. biological base grease for automated machine equipment according to claim 1, it is characterised in that:It is described
Other function additives for antioxidant, defoamer, antirust agent, pour-point depressant it is compound.
5. a kind of bio-based preparation of greases method for automated machine equipment described in claim any one of 1-4,
It is characterised in that it includes following steps:The phytyl base oil of thickening agent, 50 ~ 70% amounts is placed in saponification kettle after mixing, in 80 ~
100 DEG C of 2 ~ 4h of saponification, add remaining phytyl base oil and continue 0.5 ~ 1h of insulation reaction, be warming up to 160 ~ 180 DEG C and be incubated
Mediation kettle cooling for reflux is transferred to after 10min, remaining raw material is added when being cooled to 70 ~ 80 DEG C, insulation homogenizing is ground, at degassing
Reason, the lubricating grease of the present invention is obtained after being cooled to normal temperature.
Priority Applications (1)
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CN201711127638.1A CN107880981A (en) | 2017-11-15 | 2017-11-15 | A kind of biological base grease for automated machine equipment and preparation method thereof |
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CN201711127638.1A CN107880981A (en) | 2017-11-15 | 2017-11-15 | A kind of biological base grease for automated machine equipment and preparation method thereof |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102433195A (en) * | 2011-10-24 | 2012-05-02 | 中国石油化工股份有限公司 | Open gear lubricating grease composition |
CN103013627A (en) * | 2012-12-24 | 2013-04-03 | 武汉理工大学 | Degradable lubricating grease for locomotive wheel flange and preparation method |
CN103497812A (en) * | 2013-08-29 | 2014-01-08 | 中国石油化工股份有限公司 | Biodegradable bentonite lubricating grease composition and preparation method thereof |
CN105623813A (en) * | 2016-01-29 | 2016-06-01 | 安徽三环水泵有限责任公司 | Pump coupling grease |
CN106939099A (en) * | 2017-04-20 | 2017-07-11 | 贵州省材料产业技术研究院 | A kind of antistatic TPV composites of dynamic vulcanization and preparation method thereof |
-
2017
- 2017-11-15 CN CN201711127638.1A patent/CN107880981A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102433195A (en) * | 2011-10-24 | 2012-05-02 | 中国石油化工股份有限公司 | Open gear lubricating grease composition |
CN103013627A (en) * | 2012-12-24 | 2013-04-03 | 武汉理工大学 | Degradable lubricating grease for locomotive wheel flange and preparation method |
CN103497812A (en) * | 2013-08-29 | 2014-01-08 | 中国石油化工股份有限公司 | Biodegradable bentonite lubricating grease composition and preparation method thereof |
CN105623813A (en) * | 2016-01-29 | 2016-06-01 | 安徽三环水泵有限责任公司 | Pump coupling grease |
CN106939099A (en) * | 2017-04-20 | 2017-07-11 | 贵州省材料产业技术研究院 | A kind of antistatic TPV composites of dynamic vulcanization and preparation method thereof |
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