CN107880452A - A kind of high-performance environment-friendly plastics and its preparation method and application - Google Patents
A kind of high-performance environment-friendly plastics and its preparation method and application Download PDFInfo
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- CN107880452A CN107880452A CN201711410901.8A CN201711410901A CN107880452A CN 107880452 A CN107880452 A CN 107880452A CN 201711410901 A CN201711410901 A CN 201711410901A CN 107880452 A CN107880452 A CN 107880452A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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Abstract
The invention discloses a kind of high-performance environment-friendly plastics and its preparation method and application.The high-performance environment-friendly plastics include the raw material of following parts by weight：80 130 parts of polyvinyl chloride, 25 34 parts of carvacrol, 20 30 parts of tannic acid, 10 18 parts of left-handed theanine, 10 15 parts of ethylmaltol, 10 30 parts of pearl white, 7 15 parts of L asparagus amino-acid calciums.The high-performance environment-friendly plastics of the present invention have the advantages of resistance to elevated temperatures is good, mechanical performance is high, can be widely used for the fields such as electric, building, automobile, office equipment, mechanical field；Preparation technology is simple, is advantageous to marketing.
Description
Technical field
The present invention relates to a kind of plastics, specifically a kind of high-performance environment-friendly plastics and its preparation method and application.
Background technology
Plastics are as a kind of general material that has many uses, and while people's life is facilitated significantly, its is nondecomposable
Characteristic also result in serious environmental problem.Therefore study and production degredation plastic product causes height weight in the world
Depending on.People start to utilize to having carried out substantial amounts of research and development using the production degradation plastic such as starch and vegetable protein.But
It is the shortcomings that existing plastics still have heat resistance difference and bad mechanical property.Therefore, the present invention provides a kind of high-performance ring
Protect plastics and its preparation method and application.
The content of the invention
It is an object of the invention to provide a kind of high-performance environment-friendly plastics and its preparation method and application, to solve the above-mentioned back of the body
The problem of being proposed in scape technology.
To achieve the above object, the present invention provides following technical scheme：
A kind of high-performance environment-friendly plastics, include the raw material of following parts by weight：Polyvinyl chloride 80-130 parts, carvacrol 25-
34 parts, tannic acid 20-30 parts, left-handed theanine 10-18 parts, ethylmaltol 10-15 parts, pearl white 10-30 parts, L- lucid asparagus
Propylhomoserin calcium 7-15 parts.
As the further scheme of the present invention：Include the raw material of following parts by weight：Polyvinyl chloride 90-125 parts, carvacrol
26-30 parts, tannic acid 22-28 parts, left-handed theanine 14-17 parts, ethylmaltol 12-14 parts, pearl white 13-26 parts, L- days
C8H12CaN2O8 8-13 parts.
As the further scheme of the present invention：Include the raw material of following parts by weight：120 parts of polyvinyl chloride, carvacrol 28
Part, 25 parts of tannic acid, 16 parts of left-handed theanine, 13 parts of ethylmaltol, 20 parts of pearl white, 11 parts of ASPARTIC ACID calcium.
A kind of preparation method of high-performance environment-friendly plastics, preparation process are：
(1) carvacrol and tannic acid are mixed, add in 40-60 parts 50-75% ethanol solution, be uniformly mixed,
Obtain mixture A；
(2) ethylmaltol, ASPARTIC ACID calcium and left-handed theanine are mixed, added in 50-75 part deionized waters,
It is uniformly mixed, obtains mixture B；
(3) mixture A is well mixed at 80-105 DEG C with mixture B, obtains mixture C；
(4) polyvinyl chloride and pearl white are mixed, adds mixture C, 20-35min is mixed at 165-185 DEG C；
(5) upper step gains are extruded by extruder, produced.
As the further scheme of the present invention：Step (1) mixing speed is 300-500r/min；Step (2) mixing speed
For 100-200r/min；Step (3) mixing speed is 500-700r/min；Step (4) mixing speed is 100-300r/min.
A kind of application of high-performance environment-friendly plastics, the high-performance environment-friendly plastics are used for electric, building, automobile, done
Postulate standby or mechanical field.
Compared with prior art, the beneficial effects of the invention are as follows：
The high-performance environment-friendly plastics of the present invention have the advantages of resistance to elevated temperatures is good, mechanical performance is high, available for electronics electricity
The fields such as gas, building, automobile, office equipment, mechanical field；It is more environmentally-friendly meanwhile plastic degradation rate of the invention is high；And make
Standby technique is simple, is advantageous to marketing.
Embodiment
The technical scheme of this patent is described in more detail with reference to embodiment.
Embodiment 1
A kind of high-performance environment-friendly plastics, include the raw material of following parts by weight：80 parts of polyvinyl chloride, 25 parts of carvacrol, pellet
Peaceful 20 parts of acid, 10 parts of left-handed theanine, 10 parts of ethylmaltol, 10 parts of pearl white, 7 parts of ASPARTIC ACID calcium.
A kind of preparation method of high-performance environment-friendly plastics, preparation process are：(1) carvacrol and tannic acid are mixed, added
In 40 part 50% of ethanol solution, it is uniformly mixed, obtains mixture A；Mixing speed is 300r/min；(2) by ethyl wheat
Bud phenol, ASPARTIC ACID calcium and the mixing of left-handed theanine, add in 50 parts of deionized waters, are uniformly mixed, are mixed
Thing B；Mixing speed is 100r/min；(3) mixture A is well mixed at 80 DEG C with mixture B, obtains mixture C；Stirring
Speed is 500r/min；(4) polyvinyl chloride and pearl white are mixed, adds mixture C, 20min is mixed at 165 DEG C；
Mixing speed is 100r/min；(5) upper step gains are extruded by extruder, produced.The high-performance environment-friendly plastics can use
In fields such as electric, building, automobile, office equipment, machineries.
Embodiment 2
A kind of high-performance environment-friendly plastics, include the raw material of following parts by weight：130 parts of polyvinyl chloride, 34 parts of carvacrol, pellet
Peaceful 30 parts of acid, 18 parts of left-handed theanine, 15 parts of ethylmaltol, 30 parts of pearl white, 15 parts of ASPARTIC ACID calcium.
A kind of preparation method of high-performance environment-friendly plastics, preparation process are：(1) carvacrol and tannic acid are mixed, added
In 60 part 75% of ethanol solution, it is uniformly mixed, obtains mixture A；Mixing speed is 500r/min；(2) by ethyl wheat
Bud phenol, ASPARTIC ACID calcium and the mixing of left-handed theanine, add in 75 parts of deionized waters, are uniformly mixed, are mixed
Thing B；Mixing speed is 200r/min；(3) mixture A is well mixed at 105 DEG C with mixture B, obtains mixture C；Stir
It is 700r/min to mix speed；(4) polyvinyl chloride and pearl white are mixed, adds mixture C, mixed at 185 DEG C
35min；Mixing speed is 300r/min；(5) upper step gains are extruded by extruder, produced.The high-performance environment-friendly modeling
Material can be used for the fields such as electric, building, automobile, office equipment, machinery.
Embodiment 3
A kind of high-performance environment-friendly plastics, include the raw material of following parts by weight：120 parts of polyvinyl chloride, 28 parts of carvacrol, pellet
Peaceful 25 parts of acid, 16 parts of left-handed theanine, 13 parts of ethylmaltol, 20 parts of pearl white, 11 parts of ASPARTIC ACID calcium.
A kind of preparation method of high-performance environment-friendly plastics, preparation process are：(1) carvacrol and tannic acid are mixed, added
In 50 part 65% of ethanol solution, it is uniformly mixed, obtains mixture A；Mixing speed is 400r/min；(2) by ethyl wheat
Bud phenol, ASPARTIC ACID calcium and the mixing of left-handed theanine, add in 65 parts of deionized waters, are uniformly mixed, are mixed
Thing B；Mixing speed is 180r/min；(3) mixture A is well mixed at 95 DEG C with mixture B, obtains mixture C；Stirring
Speed is 600r/min；(4) polyvinyl chloride and pearl white are mixed, adds mixture C, 30min is mixed at 175 DEG C；
Mixing speed is 200r/min；(5) upper step gains are extruded by extruder, produced.The high-performance environment-friendly plastics can use
In fields such as electric, building, automobile, office equipment, machineries.
Embodiment 4
A kind of high-performance environment-friendly plastics, include the raw material of following parts by weight：90 parts of polyvinyl chloride, 26 parts of carvacrol, pellet
Peaceful 22 parts of acid, 14 parts of left-handed theanine, 12 parts of ethylmaltol, 13 parts of pearl white, 8 parts of ASPARTIC ACID calcium.
A kind of preparation method of high-performance environment-friendly plastics, preparation process are：(1) carvacrol and tannic acid are mixed, added
In 45 part 55% of ethanol solution, it is uniformly mixed, obtains mixture A；Mixing speed is 350r/min；(2) by ethyl wheat
Bud phenol, ASPARTIC ACID calcium and the mixing of left-handed theanine, add in 55 parts of deionized waters, are uniformly mixed, are mixed
Thing B；Mixing speed is 120r/min；(3) mixture A is well mixed at 89 DEG C with mixture B, obtains mixture C；Stirring
Speed is 570r/min；(4) polyvinyl chloride and pearl white are mixed, adds mixture C, 25min is mixed at 174 DEG C；
Mixing speed is 130r/min；(5) upper step gains are extruded by extruder, produced.The high-performance environment-friendly plastics can use
In fields such as electric, building, automobile, office equipment, machineries.
Embodiment 5
A kind of high-performance environment-friendly plastics, include the raw material of following parts by weight：125 parts of polyvinyl chloride, 30 parts of carvacrol, pellet
Peaceful 28 parts of acid, 17 parts of left-handed theanine, 14 parts of ethylmaltol, 26 parts of pearl white, 13 parts of ASPARTIC ACID calcium.
A kind of preparation method of high-performance environment-friendly plastics, preparation process are：(1) carvacrol and tannic acid are mixed, added
In 58 part 71% of ethanol solution, it is uniformly mixed, obtains mixture A；Mixing speed is 470r/min；(2) by ethyl wheat
Bud phenol, ASPARTIC ACID calcium and the mixing of left-handed theanine, add in 72 parts of deionized waters, are uniformly mixed, are mixed
Thing B；Mixing speed is 185r/min；(3) mixture A is well mixed at 98 DEG C with mixture B, obtains mixture C；Stirring
Speed is 685r/min；(4) polyvinyl chloride and pearl white are mixed, adds mixture C, 32min is mixed at 182 DEG C；
Mixing speed is 274r/min；(5) upper step gains are extruded by extruder, produced.The high-performance environment-friendly plastics can use
In fields such as electric, building, automobile, office equipment, machineries.
Comparative example 1
A kind of high-performance environment-friendly plastics, include the raw material of following parts by weight：120 parts of polyvinyl chloride, 25 parts of tannic acid, a left side
Revolve 16 parts of theanine, 13 parts of ethylmaltol, 20 parts of pearl white, 11 parts of ASPARTIC ACID calcium.
A kind of preparation method of high-performance environment-friendly plastics, preparation process are：(1) tannic acid is added to 50 part 65% of ethanol
In solution, it is uniformly mixed, obtains mixture A；Mixing speed is 400r/min；(2) by ethylmaltol, L- asparagines
Sour calcium and the mixing of left-handed theanine, add in 65 parts of deionized waters, are uniformly mixed, obtain mixture B；Mixing speed is
180r/min；(3) mixture A is well mixed at 95 DEG C with mixture B, obtains mixture C；Mixing speed is 600r/
min；(4) polyvinyl chloride and pearl white are mixed, adds mixture C, 30min is mixed at 175 DEG C；Mixing speed is
200r/min；(5) upper step gains are extruded by extruder, produced.
Comparative example 2
A kind of high-performance environment-friendly plastics, include the raw material of following parts by weight：120 parts of polyvinyl chloride, 28 parts of carvacrol, pellet
Peaceful 25 parts of acid, 13 parts of ethylmaltol, 20 parts of pearl white, 11 parts of ASPARTIC ACID calcium.
A kind of preparation method of high-performance environment-friendly plastics, preparation process are：(1) carvacrol and tannic acid are mixed, added
In 50 part 65% of ethanol solution, it is uniformly mixed, obtains mixture A；Mixing speed is 400r/min；(2) by ethyl wheat
Bud phenol and the mixing of ASPARTIC ACID calcium, add in 65 parts of deionized waters, are uniformly mixed, obtain mixture B；Mixing speed
For 180r/min；(3) mixture A is well mixed at 95 DEG C with mixture B, obtains mixture C；Mixing speed is 600r/
min；(4) polyvinyl chloride and pearl white are mixed, adds mixture C, 30min is mixed at 175 DEG C；Mixing speed is
200r/min；(5) upper step gains are extruded by extruder, produced.
Comparative example 3
A kind of high-performance environment-friendly plastics, include the raw material of following parts by weight：120 parts of polyvinyl chloride, 25 parts of tannic acid, second
13 parts of base maltol, 20 parts of pearl white, 11 parts of ASPARTIC ACID calcium.
A kind of preparation method of high-performance environment-friendly plastics, preparation process are：(1) tannic acid is added to 50 part 65% of ethanol
In solution, it is uniformly mixed, obtains mixture A；Mixing speed is 400r/min；(2) by ethylmaltol and L- lucid asparagus
Propylhomoserin calcium mixes, and adds in 65 parts of deionized waters, is uniformly mixed, obtains mixture B；Mixing speed is 180r/min；(3)
Mixture A is well mixed at 95 DEG C with mixture B, obtains mixture C；Mixing speed is 600r/min；(4) by polychlorostyrene second
Alkene and pearl white mixing, add mixture C, 30min are mixed at 175 DEG C；Mixing speed is 200r/min；(5) will be upper
Step gains are extruded by extruder, are produced.
Experimental example 1
Performance detection is carried out to high-performance environment-friendly plastics prepared by embodiment 1-3 and comparative example 1-3.Structure is shown in Table 1.
The performance test results of table 1
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, can also be on the premise of this patent objective not be departed from one skilled in the relevant art's possessed knowledge
Make a variety of changes.
Claims (6)
1. a kind of high-performance environment-friendly plastics, it is characterised in that include the raw material of following parts by weight：Polyvinyl chloride 80-130 parts,
Carvacrol 25-34 parts, tannic acid 20-30 parts, left-handed theanine 10-18 parts, ethylmaltol 10-15 parts, pearl white 10-30
Part, ASPARTIC ACID calcium 7-15 parts.
2. high-performance environment-friendly plastics according to claim 1, it is characterised in that include the raw material of following parts by weight：It is poly-
Vinyl chloride 90-125 parts, carvacrol 26-30 parts, tannic acid 22-28 parts, left-handed theanine 14-17 parts, ethylmaltol 12-14
Part, pearl white 13-26 parts, ASPARTIC ACID calcium 8-13 parts.
3. high-performance environment-friendly plastics according to claim 1, it is characterised in that include the raw material of following parts by weight：It is poly-
120 parts of vinyl chloride, 28 parts of carvacrol, 25 parts of tannic acid, 16 parts of left-handed theanine, 13 parts of ethylmaltol, 20 parts of pearl white, L-
11 parts of asparagus amino-acid calcium.
A kind of 4. preparation method of high-performance environment-friendly plastics as described in claim 1-3 is any, it is characterised in that preparation process
For：
（1）Carvacrol and tannic acid are mixed, is added in 40-60 parts 50-75% ethanol solution, is uniformly mixed, is mixed
Compound A；
（2）Ethylmaltol, ASPARTIC ACID calcium and left-handed theanine are mixed, added in 50-75 part deionized waters, stirring
It is well mixed, obtain mixture B；
（3）Mixture A is well mixed at 80-105 DEG C with mixture B, obtains mixture C；
（4）Polyvinyl chloride and pearl white are mixed, mixture C is added, 20-35min is mixed at 165-185 DEG C；
（5）Upper step gains are extruded by extruder, produced.
5. the preparation method of high-performance environment-friendly plastics according to claim 4, it is characterised in that step（1）Mixing speed
For 300-500r/min；Step（2）Mixing speed is 100-200r/min；Step（3）Mixing speed is 500-700r/min；Step
Suddenly（4）Mixing speed is 100-300r/min.
A kind of 6. application of high-performance environment-friendly plastics as described in claim 1-3 is any, it is characterised in that the high-performance ring
Protect plastics and be used for electric, building, automobile, office equipment or mechanical field.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711410901.8A CN107880452A (en) | 2017-12-23 | 2017-12-23 | A kind of high-performance environment-friendly plastics and its preparation method and application |
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| CN201711410901.8A CN107880452A (en) | 2017-12-23 | 2017-12-23 | A kind of high-performance environment-friendly plastics and its preparation method and application |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111718589A (en) * | 2020-07-16 | 2020-09-29 | 长沙理工大学 | Asphalt modification method using fish scales as modifier and modified asphalt |
| CN113773594A (en) * | 2021-10-30 | 2021-12-10 | 芜湖新磊塑胶科技有限公司 | Environment-friendly PVC (polyvinyl chloride) plastic pipe and preparation process thereof |
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| CN1709957A (en) * | 2005-06-17 | 2005-12-21 | 华南农业大学 | Preparation for fly-repellent plastic-bottle cap and use in seasoning package product thereof |
| CN105482292A (en) * | 2015-12-10 | 2016-04-13 | 南京大学 | Antibacterial anti-oxidation aeration hose and preparation method thereof |
| CN105885287A (en) * | 2016-05-03 | 2016-08-24 | 安徽九华金润铜业有限公司 | High-wear-resistance magnetoresistive PVC (polyvinyl chloride) cable material |
-
2017
- 2017-12-23 CN CN201711410901.8A patent/CN107880452A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3907958A (en) * | 1972-04-10 | 1975-09-23 | Kohjin Co | Highly flame-retardant shaped articles and method for preparing the same |
| CN1709957A (en) * | 2005-06-17 | 2005-12-21 | 华南农业大学 | Preparation for fly-repellent plastic-bottle cap and use in seasoning package product thereof |
| CN105482292A (en) * | 2015-12-10 | 2016-04-13 | 南京大学 | Antibacterial anti-oxidation aeration hose and preparation method thereof |
| CN105885287A (en) * | 2016-05-03 | 2016-08-24 | 安徽九华金润铜业有限公司 | High-wear-resistance magnetoresistive PVC (polyvinyl chloride) cable material |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111718589A (en) * | 2020-07-16 | 2020-09-29 | 长沙理工大学 | Asphalt modification method using fish scales as modifier and modified asphalt |
| CN111718589B (en) * | 2020-07-16 | 2021-10-26 | 长沙理工大学 | Asphalt modification method using fish scales as modifier and modified asphalt |
| CN113773594A (en) * | 2021-10-30 | 2021-12-10 | 芜湖新磊塑胶科技有限公司 | Environment-friendly PVC (polyvinyl chloride) plastic pipe and preparation process thereof |
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