CN107880385A - A kind of PP plates weather-resistance flame-retardant Masterbatch and preparation method thereof - Google Patents
A kind of PP plates weather-resistance flame-retardant Masterbatch and preparation method thereof Download PDFInfo
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- CN107880385A CN107880385A CN201711116171.0A CN201711116171A CN107880385A CN 107880385 A CN107880385 A CN 107880385A CN 201711116171 A CN201711116171 A CN 201711116171A CN 107880385 A CN107880385 A CN 107880385A
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- weather
- plates
- retardant
- resistance flame
- retardant masterbatch
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/10—Homopolymers or copolymers of propene
- C08J2423/12—Polypropene
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a kind of PP plates weather-resistance flame-retardant Masterbatch and preparation method thereof, the Masterbatch is made up of PP carriers, toner, fire-retardant stabilizer, weather resisting agent and dispersant.The Masterbatch has good compatibility to polypropylene articles, has excellent properties in terms of weather-proof, fire retardant coloring.Bright in luster, glossiness is high, and the outdoor application time limit is non-discolouring up to 25 years, and fire-retardant rank can reach the V0 ranks of UL94 standards, while have excellent ultraviolet-resistent property and antioxidant, and the outdoor application time limit was up to not efflorescence in 5 years.
Description
Technical field
The present invention relates to field of polymer technology, more particularly to a kind of PP plates weather-resistance flame-retardant Masterbatch and preparation method.
Background technology
As country is for the increasing of environmental requirement, the craving that people pursue blue sea blue sky is more and more stronger, all kinds of manufactures
Type enterprise requires have waste gas, waste water etc. caused by itself to carry out necessary processing according to respective.Polypropylene environmental protection equipment
Demand it is increasingly vigorous, requirement for polypropylene (PP) sheet material also more and more higher.
The production of traditional polypropylene board is exactly by highly enriched color masterbatch purchased in market, is added to polypropylene tree according to a certain percentage
In fat, then carry out being extruded and processed into sheet material.
Although there is the Masterbatch for developing a variety of colors in color masterbatch manufacturer of China, also there are various single function sexuparas
Grain, but for there is the polypropylene board of particular/special requirement, such as, open air is using the sheet material for having high-weatherability, with flame retardant rating
It is required that sheet material, existing market there is no the Masterbatch for being fused into one multi-functional.
At present, the existing fire-retardant master granule in market or flame-retardant color master batch, it is fine in polyethylene product effect, but it is implemented at family
In the outer high-weatherability polypropylene board used, it can lose or significantly weaken its flame retardant effect, not reach desired resistance to
Time property and anti-flammability.
The content of the invention
The present invention provides a kind of PP plates weather-resistance flame-retardant Masterbatch to solve deficiency of the prior art, is added into
The PP sheet materials produced have excellent properties in terms of weather-proof, fire retardant coloring.
To reach above-mentioned purpose, the technical solution adopted by the present invention is：
A kind of PP plates weather-resistance flame-retardant Masterbatch, is made up of following percentage by weight：
Wherein, described fire-retardant stabilizer pills XP are a kind of special fire-retardant stabilizer, and its decomposition temperature is more than 230
℃.Weather resisting agent Tinuvin is a kind of excellent weathering stabilizers.
A kind of preferred scheme as PP plates of the present invention with weather-resistance flame-retardant Masterbatch, by following percentage by weight group
Into：
Further, described toner is the inorganic toner of weatherability, it is preferable that described toner is titanium white, titanium yellow, zinc
One or more during iron oxide yellow, ultramarine, ferromanganese are black.
A kind of preferred scheme as PP plates of the present invention with weather-resistance flame-retardant Masterbatch, described toner are weatherability
Organic toner, it is preferable that described toner is that blue or green mouth is yellow, diamine is yellow, low barium C is red, the one or more in low barium rhodo.
A kind of preferred scheme as PP plates of the present invention with weather-resistance flame-retardant Masterbatch, described dispersant are ethylene
Double stearic amides.
The present invention discloses a kind of PP plates preparation method of weather-resistance flame-retardant Masterbatch, comprise the following steps：
(1) in homogenizer, PP carriers is first added, then sequentially add remaining each composition of said ratio,
Under 1000RPM-4000RPM rotating speeds, 1-20 minutes are stirred；
(2) after 2-5 minutes are stood, after entire mixture is poured out from exit in mixer, mixer is rejoined.
Repeat step (1)；
(3) by stirrer for mixing thing, parallel dual-screw extruding machine (draw ratio 38 is poured into：1-48:1) head tank, open
Extruder, rate of feeding 200-550RPM, driving screw speed 200-550RPM, each area's temperature is set as 155-210 DEG C, through water
Packed after cold, air-cooled, pelletizing, screening.
Beneficial effect：
(1) the PP plates weather-resistance flame-retardant Masterbatch that technical solution of the present invention provides, has excellent for polypropylene board
Compatibility and tinting strength, tinting power.Bright in luster, glossiness is high, and the outdoor application time limit is non-discolouring up to 25 years.
(2) the PP plates weather-resistance flame-retardant Masterbatch that technical solution of the present invention provides, has good flame retardant effect, flame retardant grade
The V0 ranks of UL94 standards can not reached.
(3) the PP plates weather-resistance flame-retardant Masterbatch that technical solution of the present invention provides, has excellent ultraviolet-resistent property and antioxygen
Property, the outdoor application time limit was up to not efflorescence in 5 years.
Embodiment
Embodiment
A collection of PP plates weather-resistance flame-retardant Masterbatch, it is made up of the composition of each percentage by weight in table 1.
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| PP carriers | 43% | 40% | 45% | 51% |
| Titanium white | 2% | 2% | 2.5% | 1.5% |
| Titanium yellow | 1.5% | 0 | 0 | 0.5% |
| Zinc-iron is yellow | 0 | 1% | 2% | 0 |
| Ultramarine | 0.5% | 0 | 0.5% | 0 |
| Fire-retardant stabilizer | 28% | 25% | 32% | 35% |
| Weather resisting agent | 10% | 12% | 8% | 6% |
| Ethylene bis stearic acid amide | 15% | 20% | 10% | 6% |
Table 1
A kind of preferably PP plates weather-resistance flame-retardant Masterbatch preparation method, comprises the following steps
(1) in homogenizer, PP carriers is first added, then sequentially add remaining each composition of said ratio,
Under 1000RPM-4000RPM rotating speeds, 1-20 minutes are stirred；
(2) after 2-5 minutes are stood, after entire mixture is poured out from exit in mixer, mixer is rejoined.
Repeat step (1)；
(3) by stirrer for mixing thing, parallel dual-screw extruding machine (draw ratio 38 is poured into：1-48:1) head tank, open
Extruder, rate of feeding 200-550RPM, driving screw speed 200-550RPM, each area's temperature is set as 155-210 DEG C, through water
Packed after cold, air-cooled, pelletizing, screening.
The parameter of specific embodiment is as follows：
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| Homogenizer rotating speed (RPM) | 1800 | 1500 | 2000 | 2200 |
| Mixing time (minute) | 12 | 15 | 10 | 8 |
| Time of repose (minute) | 4 | 3 | 5 | 4 |
| Extruder draw ratio | 48:1 | 48:1 | 48:1 | 48:1 |
| Rate of feeding (RPM) | 370 | 350 | 370 | 360 |
| Driving screw speed (RPM) | 480 | 450 | 475 | 465 |
| Each warm area minimum temperature (DEG C) | 160 | 165 | 160 | 170 |
| Each warm area maximum temperature (DEG C) | 198 | 195 | 190 | 200 |
Table 2
The product that above-described embodiment is prepared is according to 1:12.5 ratio is used for true qualities polypropylene (homopolymerization：Copolymerization=1：
1) sampling implements flame retardant test after being re-packed after, being well mixed.
Remaining mixture carries out extrusion processing, produces grab sample progress weatherability test after sheet material.
Visually test coloring effect, compatibility and uniformity are carried out to product, weatherability and resistance are carried out respectively using equipment
The test of combustion property.
Wherein weather-proof test equipment is Q-LAB LU8051 types, and testing standard is SAE J 1885/2412.Flame retardant test is set
It is standby to be：PX-03-011 type flame retardant test instrument, testing standard UL94.
Test result shows that above-described embodiment 1-4 Masterbatch can reach following result：
(1) Masterbatch and true qualities acrylic resin compatibility are fine, strong coloring force, aberration<0.1.
(2) polypropylene board good weatherability made of the weather-resistance flame-retardant Masterbatch, the test of high-intensity ultraviolet irradiation cycle
After 400 hours, aberration<0.8.
(3) polypropylene board good weatherability made of the weather-resistance flame-retardant Masterbatch, after circulating weather-proof test 400 hours, nothing
Obvious efflorescence.
(4) the weather-resistance flame-retardant Masterbatch and polypropylene miser, it is fire-retardant after standard laboratory re-packs progress flame retardant test
Grade reaches V0.
Although embodiments of the present invention are illustrated in specification, these embodiments are intended only as prompting,
It should not limit protection scope of the present invention.It is equal that various omission, substitution, and alteration are carried out without departing from the spirit and scope of the present invention
It should include within the scope of the present invention.
Claims (8)
1. a kind of PP plates weather-resistance flame-retardant Masterbatch, it is characterised in that be made up of following percentage by weight：
Wherein, described fire-retardant stabilizer is pills XP, weather resisting agent Tinuvin.
2. PP plates weather-resistance flame-retardant Masterbatch according to claim 1, it is characterised in that by following percentage by weight group
Into：
3. PP plates weather-resistance flame-retardant Masterbatch according to claim 1, it is characterised in that described toner be weatherability without
Machine toner.
4. PP plates weather-resistance flame-retardant Masterbatch according to claim 3, it is characterised in that described toner is titanium white, titanium
One or more during nickel yellow, zinc-iron are yellow, ultramarine ferromanganese is black.
5. PP plates weather-resistance flame-retardant Masterbatch according to claim 1, it is characterised in that described toner has for weatherability
Machine toner.
6. PP plates weather-resistance flame-retardant Masterbatch according to claim 5, it is characterised in that described toner be blue or green mouth it is yellow,
Diamine is yellow, low barium C is red, the one or more in low barium rhodo.
7. PP plates weather-resistance flame-retardant Masterbatch according to claim 1, it is characterised in that described dispersant is that ethylene is double
Stearic amide.
A kind of 8. method for preparing any one above-mentioned PP plate weather-resistance flame-retardant Masterbatch, it is characterised in that comprise the following steps：
(1) in homogenizer, PP carriers is first added, then sequentially add remaining each composition of said ratio,
Under 1000RPM-4000RPM rotating speeds, 1-20 minutes are stirred；
(2) after 2-5 minutes are stood, after entire mixture is poured out from exit in mixer, mixer is rejoined.Repeat
Step 1；
(3) by stirrer for mixing thing, parallel dual-screw extruding machine head tank is poured into, opens extruder, rate of feeding 200-
550RPM, driving screw speed 200-550RPM, each area's temperature are set as 155-210 DEG C, wrapped after water cooled, air-cooled, pelletizing, screening
Dress.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711116171.0A CN107880385A (en) | 2017-11-13 | 2017-11-13 | A kind of PP plates weather-resistance flame-retardant Masterbatch and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711116171.0A CN107880385A (en) | 2017-11-13 | 2017-11-13 | A kind of PP plates weather-resistance flame-retardant Masterbatch and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
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Family
ID=61776750
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|---|---|---|---|
| CN201711116171.0A Pending CN107880385A (en) | 2017-11-13 | 2017-11-13 | A kind of PP plates weather-resistance flame-retardant Masterbatch and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108587019A (en) * | 2018-04-10 | 2018-09-28 | 山东建筑大学 | A kind of plastic master batch, preparation method and plastic products being made from it that paint slag is modified |
| CN110358196A (en) * | 2019-06-27 | 2019-10-22 | 武汉金发科技有限公司 | A kind of fire retardant and a kind of PP composite material |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0892433A (en) * | 1994-08-26 | 1996-04-09 | Albright & Wilson Ltd | Flame-retardant material |
| KR20080097871A (en) * | 2007-05-03 | 2008-11-06 | 엘에스전선 주식회사 | Color masterbatch composition for flame retardant polypropylene insulation material and polypropylene insulator using it |
| CN102604228A (en) * | 2012-03-20 | 2012-07-25 | 广州市聚赛龙工程塑料有限公司 | Multi-functional plastic masterbatch and preparation method thereof |
| CN104387666A (en) * | 2014-11-13 | 2015-03-04 | 东莞市金彩色母有限公司 | Ultraviolet-resistant oxidation-resistant color master batch and preparation method thereof |
| KR20170013788A (en) * | 2015-07-28 | 2017-02-07 | 신동석 | flame retardant net and webbing manufacturing methods |
| CN106467636A (en) * | 2016-09-22 | 2017-03-01 | 南宁市日建塑料包装有限责任公司 | A kind of plastic color master grain and preparation method thereof |
| CN106589591A (en) * | 2016-12-08 | 2017-04-26 | 滁州麦迪尔塑胶有限公司 | Flame-retardant toughening color master batch and preparation method thereof |
| CN107043492A (en) * | 2017-06-27 | 2017-08-15 | 天津毅兴彩科技有限公司 | A kind of environmentally friendly yellow bottle cap color masterbatch |
| CN107189221A (en) * | 2017-07-06 | 2017-09-22 | 盐城瑞泽色母粒有限公司 | A kind of environment friendly halogen-free fireproof polypropylene Masterbatch and preparation method thereof |
| CN107286466A (en) * | 2017-07-06 | 2017-10-24 | 盐城瑞泽色母粒有限公司 | A kind of polypropylene color masterbatch of the toner containing nanometer and preparation method thereof |
-
2017
- 2017-11-13 CN CN201711116171.0A patent/CN107880385A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0892433A (en) * | 1994-08-26 | 1996-04-09 | Albright & Wilson Ltd | Flame-retardant material |
| KR20080097871A (en) * | 2007-05-03 | 2008-11-06 | 엘에스전선 주식회사 | Color masterbatch composition for flame retardant polypropylene insulation material and polypropylene insulator using it |
| CN102604228A (en) * | 2012-03-20 | 2012-07-25 | 广州市聚赛龙工程塑料有限公司 | Multi-functional plastic masterbatch and preparation method thereof |
| CN104387666A (en) * | 2014-11-13 | 2015-03-04 | 东莞市金彩色母有限公司 | Ultraviolet-resistant oxidation-resistant color master batch and preparation method thereof |
| KR20170013788A (en) * | 2015-07-28 | 2017-02-07 | 신동석 | flame retardant net and webbing manufacturing methods |
| CN106467636A (en) * | 2016-09-22 | 2017-03-01 | 南宁市日建塑料包装有限责任公司 | A kind of plastic color master grain and preparation method thereof |
| CN106589591A (en) * | 2016-12-08 | 2017-04-26 | 滁州麦迪尔塑胶有限公司 | Flame-retardant toughening color master batch and preparation method thereof |
| CN107043492A (en) * | 2017-06-27 | 2017-08-15 | 天津毅兴彩科技有限公司 | A kind of environmentally friendly yellow bottle cap color masterbatch |
| CN107189221A (en) * | 2017-07-06 | 2017-09-22 | 盐城瑞泽色母粒有限公司 | A kind of environment friendly halogen-free fireproof polypropylene Masterbatch and preparation method thereof |
| CN107286466A (en) * | 2017-07-06 | 2017-10-24 | 盐城瑞泽色母粒有限公司 | A kind of polypropylene color masterbatch of the toner containing nanometer and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108587019A (en) * | 2018-04-10 | 2018-09-28 | 山东建筑大学 | A kind of plastic master batch, preparation method and plastic products being made from it that paint slag is modified |
| CN108587019B (en) * | 2018-04-10 | 2021-04-13 | 山东建筑大学 | Paint waste residue modified plastic master batch, preparation method and plastic product prepared from paint waste residue modified plastic master batch |
| CN110358196A (en) * | 2019-06-27 | 2019-10-22 | 武汉金发科技有限公司 | A kind of fire retardant and a kind of PP composite material |
| CN110358196B (en) * | 2019-06-27 | 2022-02-18 | 武汉金发科技有限公司 | Flame retardant and polypropylene composite material |
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Application publication date: 20180406 |
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