CN107868737A - A kind of preparation method of new amino acid Aloe care skin soap - Google Patents

A kind of preparation method of new amino acid Aloe care skin soap Download PDF

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Publication number
CN107868737A
CN107868737A CN201610844396.7A CN201610844396A CN107868737A CN 107868737 A CN107868737 A CN 107868737A CN 201610844396 A CN201610844396 A CN 201610844396A CN 107868737 A CN107868737 A CN 107868737A
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parts
solution
aloe
amino acid
soap
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金凯
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D13/00Making of soap or soap solutions in general; Apparatus therefor
    • C11D13/14Shaping
    • C11D13/16Shaping in moulds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • C11D1/10Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

The present invention relates to daily cleaning chemical products production field, in particular to a kind of amino acid aloe soap and preparation method thereof.Prepared jointly by following raw material:The propane diols 6 8% of lauroyl glutamate 30 35%, 1,2, glycerine 13 17%, water 14 18%, triethanolamine 23 28%, ethanol 1 3%, aloe extract 8 10%.Its preparation method is:Weigh propane diols, glycerine dissolves by heating to 85 DEG C and obtains solution a; lauroyl glutamate is slowly added into solution a; under conditions of at the uniform velocity stirring; insulation dissolving 30min, obtains solution b, the mixed solution of triethanolamine and water is added into b solution; mixing speed is 30 40 r/min; ethanol defoaming is sprayed after reacting 20min, 60 DEG C is cooled to, obtains solution c.Moulding after aloe extract stirs is added into solution c, is amino acid Aloe care skin soap after 5 7h of cooling.The invention enough improves user's skin quality, and sense is washed in prevention scaly dry skin, enhancing skin care, the effect of with acne-removing beauty.

Description

A kind of preparation method of new amino acid Aloe care skin soap
Technical field
The present invention relates to daily cleaning chemical products production field, in particular to a kind of amino acid Aloe care skin soap and its Preparation method.
Background technology
Soap is indispensable cleaning chemical products in a kind of life, with the raising that people are required quality of the life, soap Demand diversified trend is also presented.Soap has been not limited only to wash spot, it is often more important that adapts to the need of people's skin care Ask.China's production and application soap is since the eighties, but due to the limitation of technique etc., traditional soap lacks in alkalescence The shortcomings that to functions such as skin nursings, and soap production person can often add some oil recovery for the consideration to production cost, Long-term use can cause certain infringement to skin.
Amino acid surfactant is a kind of gentle degradable anion surfactant, and it is by with foaming decontamination energy The amino acid composition of the oreodaphene of power.Using the soap of its preparationPHIt is worth in the range of 5.5-6 and human skinPHIt is similar, and And amino acid, as the base substance for forming protein, nontoxic to skin, non-stimulated, therefore, sensitive skin crowd can also put The heart uses.
Aloe is Eremurus chinensis section herbaceos perennial, and main component has Anthraquinones synthesis, carbohydrate, amino acid, micro Element, organic acid etc..It is to integrate edible, medicinal, beauty plant nova, can not only sterilize, anti-inflammatory, it is immune, Removing toxic substances, also with certain beautifying skin-protection function.Vitamin in aloe can help the synthesis and reparation of epithelial tissue, prevention Cellular oxidation and aging, enhance metabolism and cell growth, the activity of internal enzyme are improved, so as to play certain beauty anti-acne Effect.
Application publication number is that CN104312747A application for a patent for invention discloses a kind of amino acid surfactant matrix Transparent solid soap, its match for amino acid surfactant 55-75 parts, pure water 3-13 parts, castor oil polyoxyethylene ether (15- 40EO) 3-10 parts, glycerine 3-8 parts, glucose 3-10 parts, ethanol 2-8 parts, PH poising agent 0.1-3 parts, essence 0.2-0.5 parts. The soap pH value that it is prepared is similar or close with human body, the skin sense after washing is improved completely.
Application publication number is that CN105106082A application for a patent for invention discloses a kind of aloetic anti-acne handmade soap, former Material of the material containing following weight proportion forms:Coconut oil 10-20 parts, palm oil 10-20 parts, spaonin powder 5-10 parts, glycerine 10-20 parts, higher fatty acids 10-15 parts, deionized water 50-100 parts, Oil suction powder 10-20 parts, fresh aloe juice 80-90 parts, plant Thing flower extract 5-10 parts, Salvia root P.E 5-10 parts, licorice 5-10 parts, sugar Thallus Laminariae (Thallus Eckloniae) extract 1-5 parts, allantoin 4- 10 parts.It the use of the handmade soap can be that skin establishes diaphragm, reach oil-water balance, have to improving neutral and Oily problem Preferably effect, thorough Peppermint Extract grease, careful foam take away excess oil, can reach anti-acne face cleaning and disposably complete, Prevention whelk can also be used as to use, positive effect.
Application publication number is that CN105647702A application for a patent for invention discloses a kind of preparation method of Aloe care skin soap, Raw material contains the material composition of following weight proportion:The extract solution from aloe of 10-30 parts, is placed in water-bath, and temperature range is 55~ 70℃;After oil phase, extraction liquid phase have all reached same temperature, first extract solution is poured into oil phase, stirs 1-2 minutes, 0.2-1.5 part sodium hydroxides are added under stirring, continue to stir, in the presence of saponification, originally insoluble two-phase is opened Beginning changes, and gradually becomes milky emulsion, reacts complete after 8-15 minutes, stops stirring, gained soap lye is poured into Mould, room temperature are placed, and produce Aloe care skin soap.
Although the Related product on aloe and aloe extract etc. is a lot of, played a part of also different;And In daily necessities field, the document that aloe extract is applied in soap is also had been reported that, but aloe is applied into amino acid soap In, destruction of the alkaline environment of traditional soap to active ingredient in aloe is avoided, improves dry skin, enhancing skin care is washed sense, subtracted It is few that skin damage, this amino acid aloe soap and its excellent performance are had not been reported.
In view of this, it is special to propose the present invention.
The content of the invention
The first object of the present invention is to provide a kind of amino acid soap containing aloe extract, described aloe amino acid soap User's skin quality can be improved, prevent scaly dry skin, enhancing skin care washes sense, has acne-removing beauty effect.
The second object of the present invention is to provide a kind of preparation method of the amino acid soap containing aloe extract, this method behaviour It is preferable to make simple and easy and obtained aloe amino acid soap appearance transparent fineness, using effect.
In order to realize the above-mentioned purpose of the present invention, using following technical scheme:A kind of amino acid aloe soap, by weight percentage Than being prepared jointly by following raw material:Lauroyl glutamate 30-35%, 1,2-PD 6-8%, glycerine 13-17%, water 14-18%, triethanolamine 23-28%, ethanol 1-3%, aloe extract 1-10%.
In above-mentioned amino acid aloe soap, 1,2-PD, water is as solvent, and as NMF, ethanol is used as to disappear glycerine Infusion, the PH of solution is adjusted with triethanolamine, aloe extract is as skin conditioning agent.
Present invention also offers the preparation method of amino acid aloe soap, comprise the following steps that:
(1)1,2- propane diols accurately will be weighed, glycerine dissolves by heating to 85 DEG C and obtains solution a
(2)Lauroyl glutamate is slowly added into solution a, insulation dissolving 30min, obtains solution b
(3)The mixed solution of triethanolamine and water is added into b solution, mixing speed is 30-40 r/min, after reacting 20min Ethanol defoaming is sprayed, 60 DEG C is cooled to, obtains solution c.
(4)Moulding after aloe extract stirs is added into c, cooling 5-7h is amino acid aloe soap.
Compared with prior art, more beneficial effect of the invention has:
(1)Aloe is applied in amino acid soap, avoids destruction of the alkaline environment of traditional soap to active ingredient in aloe,.
(2)Amino acid aloe soap of the present invention is prepared using lauroyl glutamate, aloe extract etc. as raw material, gas It is lightly seasoned refined pure and fresh, the skin quality of user can be improved, skin whitening, anti-inflammatory anti-acne, solve the problems such as dry skin, coarse.
(3)Amino acid aloe soap of the present invention make use of the beauty functions of aloe skin care, anti-acne etc., using in amino acid soap Without strong alkaline substance, the characteristics of waiting non-stimulated to skin, this effect is given full play to.
Embodiment
The solution of the present invention is described in detail with reference to practical embodiments, the following example is merely to illustrate this hair It is bright, it is not construed as limiting the scope of the present invention, the modification and adjustment of some non-intrinsically safes that other people make according to the present invention are still Belong to protection scope of the present invention.
Amino acid aloe soap raw material of the present invention with lower part by being formed, by weight percentage:Lauroyl glutamate 30-35%, 1,2-PD 6-8%, glycerine 13-17%, water 14-18%, triethanolamine 23-28%, ethanol 1-3%, aloe carry Take thing 1-10%.
The preparation method of amino acid aloe soap of the present invention, comprises the following steps:
(1)Accurately weigh 1,2- propane diols, glycerine dissolves by heating to 85 DEG C and obtains solution a.
(2)Lauroyl glutamate is slowly added into solution a, under conditions of at the uniform velocity stirring, insulation dissolving 30min, is obtained To solution b.
(3)The mixed solution of triethanolamine and water is added into b solution, mixing speed is 30-40 r/min, reaction Ethanol defoaming is sprayed after 20min, 60 DEG C is cooled to, obtains solution c.
(4)Moulding after aloe extract stirs is added into solution c, is amino acid aloe soap after cooling 5h.
Step(1)The heating rate slow heating heating that middle Elevated Temperature Conditions are 6 DEG C/min.Stirred with 20-30r/min speed Mixing prevents hot-spot and makes solution transparent and homogeneous.
Step(2)Middle addition lauroyl glutamate will be slowly added to by amount, and stir speed (S.S.) should be stablized in 30-40r/min, Otherwise a large amount of bubbles can be produced, influence the attractive in appearance of amino acid soap.
Step(3)Middle amino acid should maintain 85 DEG C with triethanolamine reaction temperature, and sprinkling ethanol disappears after reacting 20min Bubble.
Step(4)The middle temperature for adding aloe extract is 60 DEG C, to prevent that active ingredient is at relatively high temperatures in aloe It is ineffective.
Above-mentioned amino acid aloe soap preparation technology can be such that the active ingredient in amino acid and aloe extract more fills That divides is absorbed by user.
Embodiment 1
Take following raw material:35 parts of lauroyl glutamate, 15 parts of glycerine, 8 parts of 1,2-PD, 16 parts of water, triethanolamine 25 parts, 2 parts of ethanol, 10 parts of aloe extract
Prepared according to the following steps:
(1)First by glycerine, 1,2-PD equal solvent is slowly heated to 85 DEG C, and stirring is homogeneous, obtains the solution of clear a。
(2)35 parts of lauroyl glutamates are slowly added into solution a, insulation dissolving 30min obtains solution b.
(3)The mixed solution of triethanolamine and water is added into solution b, mixing speed is 30-40 r/min, reaction Ethanol is sprayed after 20min, is cooled to 60 DEG C, obtains solution c.
(4)Moulding after aloe extract stirs is added into solution c, is amino acid aloe soap after cooling 5h.
(5)The amino acid aloe soap of shaping is stripped, taken out, packaging and storage.
Embodiment 2
Take following raw material:30 parts of lauroyl glutamate, 13 parts of glycerine, 6 parts of 1,2-PD, 15 parts of water, triethanolamine 23 parts, 1.8 parts of ethanol, 9 parts of aloe extract.
Prepared according to the following steps:
(1)First by glycerine, 1,2-PD equal solvent is slowly heated to 85 DEG C, and stirring is homogeneous, obtains the solution of clear a。
(2)Corresponding amino acid is slowly added into solution a, insulation dissolving 30min obtains solution b.
(3)The mixed solution of triethanolamine and water is added into solution b, mixing speed is 30-40 r/min, reaction Ethanol is sprayed after 20min, is cooled to 60 DEG C, obtains solution c.
(4)Moulding after aloe extract stirs is added into solution c, is amino acid aloe soap after cooling 5h.
(5)The amino acid aloe soap of shaping is stripped, taken out, packaging and storage.
Embodiment 3
Take following raw material:32 parts of lauroyl glutamate, 17 parts of glycerine, 7 parts of 1,2-PD, 17 parts of water, triethanolamine 22.5 parts, 3 parts of ethanol, 8 parts of aloe extract.
Prepared according to the following steps:
(1)First by glycerine, 1,2-PD equal solvent is slowly heated to 85 DEG C, and stirring is homogeneous, obtains the solution of clear a。
(2)Lauroyl glutamate is slowly added into solution a, insulation dissolving 30min obtains solution b.
(3)The mixed solution of triethanolamine and water is added into solution b, mixing speed is 30-40 r/min, reaction Ethanol is sprayed after 20min, is cooled to 60 DEG C, obtains solution c.
(4)Moulding after aloe extract stirs is added into solution c, is amino acid aloe soap after cooling 5h.
(5)The amino acid aloe soap of shaping is stripped, taken out, packaging and storage.
Embodiment 4
Take following raw material:31 parts of lauroyl glutamate, 15 parts of glycerine, 8 parts of 1,2-PD, 16 parts of water, triethanolamine 25 parts, 2 parts of ethanol, 10 parts of aloe extract.
Prepared according to the following steps:
(1)First by glycerine, 1,2-PD equal solvent is slowly heated to 85 DEG C, and stirring is homogeneous, obtains the solution of clear a。
(2)Lauroyl glutamate is slowly added into solution a, insulation dissolving 30min obtains solution b.
(3)The mixed solution of triethanolamine and water is added into solution b, mixing speed is 30-40 r/min, reaction Ethanol is sprayed after 20min, is cooled to 60 DEG C, obtains solution c.
(4)Moulding after aloe extract stirs is added into solution c, is amino acid aloe soap after cooling 5h.
(5)The amino acid aloe soap of shaping is stripped, taken out, packaging and storage.
Comparative example 1
Take following raw material:31 parts of lauroyl glutamate, 16 parts of glycerine, 7 parts of 1,2-PD, 17 parts of water, triethanolamine 22.5 parts, 3 parts of ethanol, 1 part of aloe extract.
Prepared according to the following steps:
(1)First by glycerine, 1,2-PD equal solvent is slowly heated to 85 DEG C, and stirring is homogeneous, obtains the solution of clear a。
(2)The amino acid of respective amount is slowly added into solution a, insulation dissolving 30min obtains solution b.
(3)The mixed solution of triethanolamine and water is added into solution b, mixing speed is 30-40 r/min, reaction Ethanol is sprayed after 20min, is cooled to 60 DEG C, obtains solution c.
(4)Moulding after extract solution from aloe stirs is added into solution c, is amino acid aloe soap after cooling 5h.
(5)The amino acid aloe soap of shaping is stripped, taken out, packaging and storage.
Comparative example 2
Take following raw material:35 parts of lauroyl glutamate, 16 parts of glycerine, 7 parts of 1,2-PD, 17 parts of water, triethanolamine 22.5 parts, 3 parts of ethanol, 3 parts of aloe extract.
Prepared according to the following steps:
(1)First by glycerine, 1,2-PD equal solvent is slowly heated to 85 DEG C, and stirring is homogeneous, obtains the solution of clear a。
(2)The amino acid of respective amount is slowly added into solution a, insulation dissolving 30min obtains solution b.
(3)The mixed solution of triethanolamine and water is added into solution b, mixing speed is 30-40 r/min, reaction Ethanol is sprayed after 20min, is cooled to 60 DEG C, obtains solution c.
(4)Moulding after extract solution from aloe stirs is added into solution c, is amino acid aloe soap after cooling 5h.
(5)The amino acid aloe soap of shaping is stripped, taken out, packaging and storage.
Comparative example 3
Take following raw material:30 parts of lauroyl glutamate, 15 parts of glycerine, 6 parts of 1,2-PD, 18 parts of water, triethanolamine 23 parts, 3 parts of ethanol, 2 parts of aloe extract.
Prepared according to the following steps:
(1)First by glycerine, 1,2-PD equal solvent is slowly heated to 85 DEG C, and stirring is homogeneous, obtains the solution of clear a。
(2)The amino acid of respective amount is slowly added into solution a, insulation dissolving 30min obtains solution b.
(3)The mixed solution of triethanolamine and water is added into solution b, mixing speed is 30-40 r/min, reaction Ethanol is sprayed after 20min, is cooled to 60 DEG C, obtains solution c.
(4)Moulding after extract solution from aloe stirs is added into solution c, is amino acid aloe soap after cooling 5h.
(5)The amino acid aloe soap of shaping is stripped, taken out, packaging and storage.
Comparative example 4
Take following raw material:20 parts of lauroyl glutamate, 18 parts of glycerine, 8 parts of 1,2-PD, 16 parts of water, triethanolamine 25 parts, 3 parts of ethanol, 10 parts of aloe extract.
Prepared according to the following steps:
(1)First by glycerine, 1,2-PD equal solvent is slowly heated to 85 DEG C, and stirring is homogeneous, obtains the solution of clear a。
(2)The amino acid of respective amount is slowly added into solution a, insulation dissolving 30min obtains solution b.
(3)The mixed solution of triethanolamine and water is added into solution b, mixing speed is 30-40 r/min, reaction Ethanol is sprayed after 20min, is cooled to 60 DEG C, obtains solution c.
(4)Moulding after extract solution from aloe stirs is added into solution c, is amino acid aloe soap after cooling 5h.
(5)The amino acid aloe soap of shaping is stripped, taken out, packaging and storage.
From result above:
Embodiment 1 to 4 and comparative example 1 to 3 can obtain the amino acid aloe soap of the high grade of transparency.
Comparative example 4 is softer into soap, is difficult to shaping and demoulding after placing 5h.
Embodiment 1 is compared with comparative example 1:The smell of embodiment 1 is simple more and elegant on smell washes sense more preferably than comparative example 1, It is not tight that salubrious and skin is moistened after washing.
Volunteer is recruited, skin is chosen and relatively dries, the more person of acne print is tested, with embodiment 1-4 and comparative example 1-3 systems Amino acid aloe soap is obtained as sample, common soap is as reference substance.Experimenter(10 people/group, totally 8 groups)Daily using sample with And reference substance carries out bathing, once in the morning and once at night, a cycle, the feedback feelings that statistics user is improved with rear skin quality are used as within 14 days Condition.
As a result as shown above, shown in embodiment 1-4 skin improve obvious number be significantly higher than comparative example with it is common Soap.Skin improver is significantly more than common soap number in comparative example.
Aloe extract addition is considerably less than comparative example 1-4, from the point of view of user's feedback situation, reed in comparative example 1-3 The addition situation of luxuriant growth extract determines the improvement to skin quality and anti-acne effect.
Comparative example 4 because amino acid addition not enough causes soap body relatively viscous softer, can not stripping forming, be unfavorable for producing.
Illustrate the present invention although with specific example, but be not the limitation to technical solution of the present invention, without departing substantially from Many modifications can be still made in the case of the scope of the invention.It is, therefore, intended that include belonging to this in the following claims All changes and modification in invention scope are regarded as falling into the protection domain of patent of the present invention.

Claims (9)

1. a kind of new amino acid Aloe care skin soap, it is characterised in that raw material is calculated by weight:Lauroyl glutamate 30- 35 parts, 1,2-PD 6-8 parts, glycerine 13-17 parts, water 14-18 parts, triethanolamine 18-28 parts, ethanol 1-5 parts, aloe Extract 1-10 parts.
2. amino acid aloe soap as claimed in claim 1, it is characterised in that calculate by weight, mainly by following raw material:Bay Acyl glutamic acid 31-34 parts, 1,2-PD 5-7 parts, glycerine 12-15 parts, triethanolamine 22-27 parts, ethanol 1-3 parts, aloe Extract 8-10 parts.
3. the preparation method of any one of the claim 1-2 amino acid aloe soaps, it is characterised in that comprise the following steps:
(1)Accurately weigh propane diols, glycerine dissolves by heating to 85 DEG C and obtains solution a.
4.(2)Lauroyl glutamate is slowly added into solution a, under conditions of at the uniform velocity stirring, insulation dissolving 30min, is obtained Solution b.
5.(3)The mixed solution of triethanolamine and water is added into b solution, mixing speed is 30-40 r/min, reacts 20min Ethanol defoaming is sprayed afterwards, is cooled to 60 DEG C, is obtained solution c.
6.(4)Moulding after aloe extract stirs is added into solution c, is amino acid aloe soap after cooling 5h.
7. preparation method as claimed in claim 3, step(2)Middle addition lauroyl glutamate will add by amount, stirring speed Rate should be stablized in 30-40r/min.
8. preparation method as claimed in claim 3, step(3)Middle amino acid should maintain 85 with triethanolamine reaction temperature DEG C, 20min is reacted, foam is eliminated using ethanol.
9. preparation method as claimed in claim 3, step(4)The middle temperature for adding aloe extract is 60 DEG C.
CN201610844396.7A 2016-09-23 2016-09-23 A kind of preparation method of new amino acid Aloe care skin soap Withdrawn CN107868737A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109971569A (en) * 2019-03-29 2019-07-05 电子科技大学中山学院 Nano-silver transparent amino acid handmade soap and preparation method thereof
CN111925872A (en) * 2020-09-16 2020-11-13 广州美果生物科技有限公司 Amino acid Q bomb handmade soap and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102978048A (en) * 2012-11-16 2013-03-20 广州伊凡生物科技有限公司 Weakly acidic transparent soap and preparation method thereof
CN105647702A (en) * 2016-01-15 2016-06-08 南京科技职业学院 Preparation method of aloe soap achieving skin beautifying
CN105769730A (en) * 2016-03-16 2016-07-20 广州市香事文化传播有限公司 Agilawood pearl amino acid soap and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102978048A (en) * 2012-11-16 2013-03-20 广州伊凡生物科技有限公司 Weakly acidic transparent soap and preparation method thereof
CN105647702A (en) * 2016-01-15 2016-06-08 南京科技职业学院 Preparation method of aloe soap achieving skin beautifying
CN105769730A (en) * 2016-03-16 2016-07-20 广州市香事文化传播有限公司 Agilawood pearl amino acid soap and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109971569A (en) * 2019-03-29 2019-07-05 电子科技大学中山学院 Nano-silver transparent amino acid handmade soap and preparation method thereof
CN111925872A (en) * 2020-09-16 2020-11-13 广州美果生物科技有限公司 Amino acid Q bomb handmade soap and preparation method thereof
CN111925872B (en) * 2020-09-16 2021-11-12 广州美果生物科技有限公司 Amino acid Q bomb handmade soap and preparation method thereof

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Application publication date: 20180403