CN107863251A - Electricity-saving lamp alminium electrolytic condenser electrolyte - Google Patents

Electricity-saving lamp alminium electrolytic condenser electrolyte Download PDF

Info

Publication number
CN107863251A
CN107863251A CN201711004440.4A CN201711004440A CN107863251A CN 107863251 A CN107863251 A CN 107863251A CN 201711004440 A CN201711004440 A CN 201711004440A CN 107863251 A CN107863251 A CN 107863251A
Authority
CN
China
Prior art keywords
weight
parts
ammonium
electricity
saving lamp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711004440.4A
Other languages
Chinese (zh)
Inventor
周琼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201711004440.4A priority Critical patent/CN107863251A/en
Publication of CN107863251A publication Critical patent/CN107863251A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/004Details
    • H01G9/022Electrolytes; Absorbents
    • H01G9/035Liquid electrolytes, e.g. impregnating materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of electricity-saving lamp alminium electrolytic condenser electrolyte, including:Combination, binary organic carboxyl acid ammonium, hexahydroxylic alcohols, polyethylene glycol, waterproof mixture, the hydrogen agent that disappears, suppression leakage current and the lifting of ethylene glycol, ammonium adipate or adipic acid and its ammonium salt are melted into the components such as the additive of performance, ethylenediacetate.Technical scheme is by reasonably matching and the combination of each component has higher flash over voltage and more preferable heat endurance, and, hexyl adipic acid and its ammonium salt of the present invention have more preferable dissolubility in ethylene glycol, aluminium electrolutic capacitor containing the electrolyte has the advantages of proof voltage is high, and capacitor life-span is long.It is the mixed solvent system of main solvent and polyethylene glycol as secondary solvent to use using ethylene glycol, can reduce the vapour pressure of dicyandiamide solution, further improves the flash over voltage of Working electrolyte.

Description

Electricity-saving lamp alminium electrolytic condenser electrolyte
Technical field
The invention belongs to new energy and energy-conserving and environment-protective technical fiel, more particularly to a kind of electricity-saving lamp alminium electrolytic condenser to be electrolysed Liquid.
Background technology
In the electronics industry, developing rapidly with electronic technology, alminium electrolytic condenser are applied in the working environment of harshness More and more, Green Lighting Project is implemented in full, electronic energy-saving lamp and electric ballast, especially powerful electric energy-saving Lamp and electric ballast, to its q&r, higher and higher requirement is proposed, alminium electrolytic condenser is that wherein reliability is relative Relatively low component, and Working electrolyte is the real negative electrode of alminium electrolytic condenser, it can repair alminium electrolytic condenser anode at any time Oxide-film, leakage current, loss and service life of alminium electrolytic condenser etc. are decide, the energy-conserving and environment-protective performance of electricity-saving lamp is played very Big effect.
The content of the invention
In view of the problems of prior art, the present invention provides a kind of electricity-saving lamp alminium electrolytic condenser electrolysis of stability and high efficiency Liquid.
In order to solve the above technical problems, technical scheme proposed by the present invention is as follows:A kind of electricity-saving lamp alminium electrolytic condenser electrolysis Liquid, include the component of following parts by weight:The combination 8 of the parts by weight of ethylene glycol 60~90, ammonium adipate or adipic acid and its ammonium salt~ 10 parts by weight, the parts by weight of binary organic carboxyl acid ammonium 6~8, the parts by weight of hexahydroxylic alcohols 5~7, the parts by weight of polyethylene glycol 5~7, methanol The parts by weight of agent 2~2.5, the parts by weight of hydrogen agent 0.2~2 that disappear, the weight of additive 0.1~1 for suppressing leakage current and lifting chemical conversion performance Part, the parts by weight of ethylenediacetate 0.05~0.5.
According to electricity-saving lamp alminium electrolytic condenser electrolyte provided by the invention, by reasonably matching and the combination of each component With higher flash over voltage and more preferable heat endurance, moreover, hexyl adipic acid of the present invention and its ammonium salt are in second two There is more preferable dissolubility in alcohol, the aluminium electrolutic capacitor containing the electrolyte has the advantages of proof voltage is high, and capacitor life-span is long. And it is the mixed solvent system of main solvent and polyethylene glycol as secondary solvent to use using ethylene glycol, can reduce dicyandiamide solution Vapour pressure, further improve Working electrolyte flash over voltage;It is main solute from binary organic carboxyl acid ammonium, is aided with methanol It agent and the hydrogen additive that disappears, can effectively suppress anodic attack, increase electrical conductivity, increase the service life.
In addition, electricity-saving lamp alminium electrolytic condenser electrolyte according to the above embodiment of the present invention, can also have following additional Technical characteristic:
According to the example of the present invention, the ethylene glycol is 60 parts by weight, the ammonium adipate or adipic acid and its ammonium Salt be combined as 8 parts by weight, binary organic carboxyl acid ammonium is 6 parts by weight, the hexahydroxylic alcohols is 5 parts by weight, the polyethylene glycol is 5 Parts by weight, the waterproof mixture are 2 parts by weight, the hydrogen agent that disappears is 0.2 parts by weight, the suppression leakage current and lifting chemical conversion property The additive of energy is 0.1 parts by weight, the ethylenediacetate is 0.05 parts by weight.
According to the example of the present invention, the ethylene glycol is 75 parts by weight, the ammonium adipate or adipic acid and its ammonium Salt be combined as 9 parts by weight, binary organic carboxyl acid ammonium is 7.5 parts by weight, the hexahydroxylic alcohols is 6 parts by weight, the polyethylene glycol Be 2.3 parts by weight for 6 parts by weight, the waterproof mixture, the hydrogen agent that disappears be 1 parts by weight, the suppression leakage current and liftingization Additive into performance is 0.3 parts by weight, the ethylenediacetate is 0.2 parts by weight.
According to the example of the present invention, the ethylene glycol is 90 parts by weight, the ammonium adipate or adipic acid and its ammonium Salt be combined as 10 parts by weight, binary organic carboxyl acid ammonium is 8 parts by weight, the hexahydroxylic alcohols is 7 parts by weight, the polyethylene glycol is 7 parts by weight, the waterproof mixture are 2.5 parts by weight, the hydrogen agent that disappears is 1 parts by weight, the suppression leakage current and lifting chemical conversion The additive of performance is 0.3 parts by weight, the ethylenediacetate is 0.5 parts by weight.
According to the example of the present invention, the additive for suppressing leakage current and lifting chemical conversion performance is selected from following chemical combination The one or more of thing:Phosphoric acid, phosphorous acid, ortho phosphorous acid, the ammonium salt of phosphate monoester or aforesaid compound.
According to the example of the present invention, the hydrogen agent that disappears is selected from the one or more selected from following compound:To nitro Phenmethylol, 3-nitroacetophenone, ortho-nitroanisole.
The advantages of above additional aspect, will be set forth in part in the description, and partly will become bright from the following description It is aobvious, or recognized by the practice of the present invention.
Embodiment
Embodiment one
A kind of electricity-saving lamp alminium electrolytic condenser electrolyte, include the component of following parts by weight:The ethylene glycol is 60 weight Part, ammonium adipate or adipic acid and its ammonium salt be combined as 8 parts by weight, the binary organic carboxyl acid ammonium is 6 parts by weight, described six First alcohol is 5 parts by weight, the polyethylene glycol is 5 parts by weight, the waterproof mixture is 2 parts by weight, the p nitrobenzyl alcohol is 0.2 parts by weight, the parts by weight of the phosphoric acid 0.1, the ethylenediacetate are 0.05 parts by weight.
Embodiment two
A kind of electricity-saving lamp alminium electrolytic condenser electrolyte, include the component of following parts by weight:The ethylene glycol is 75 weight Part, the ammonium adipate or adipic acid and its ammonium salt be combined as 9 parts by weight, binary organic carboxyl acid ammonium is 7.5 parts by weight, described Hexahydroxylic alcohols is 6 parts by weight, the polyethylene glycol is 6 parts by weight, the waterproof mixture is 2.3 parts by weight, the p-nitrophenyl first Alcohol is 1 parts by weight, the parts by weight of the phosphoric acid 0.3, the ethylenediacetate are 0.2 parts by weight.
Embodiment three
A kind of electricity-saving lamp alminium electrolytic condenser electrolyte, include the component of following parts by weight:The ethylene glycol is 90 weight Part, the ammonium adipate or adipic acid and its ammonium salt be combined as 10 parts by weight, binary organic carboxyl acid ammonium is 8 parts by weight, described Hexahydroxylic alcohols is 7 parts by weight, the polyethylene glycol is 7 parts by weight, the waterproof mixture is 2.5 parts by weight, the p-nitrophenyl first Alcohol is 1 parts by weight, the phosphoric acid is 0.3 parts by weight, the ethylenediacetate is 0.5 parts by weight.
Comparative example one
Phosphoric acid is not used, remaining composition is identical with embodiment one.
Comparative example two
Ethylenediacetate is not used, remaining composition is identical with embodiment one.
Measure of merit
The flash over voltage to electrolyte of above-described embodiment and the electricity-saving lamp alminium electrolytic condenser of comparative example preparation is determined respectively The increment rate of enhancing rate and electrical conductivity.
Table 1
Flash over voltage enhancing rate (%) The increment rate (%) of electrical conductivity
Embodiment 1 32.3 10.1
Embodiment 2 31.5 9.8
Embodiment 3 30.4 9.4
Comparative example 1 20.8 7.3
Comparative example 2 21.2 6.5
Understand that inventor has carried out the screening experiment of substantial amounts of component and dosage early stage, unexpectedly with reference to above table It was found that above-mentioned technical scheme by reasonably match and each component combination have higher flash over voltage and preferably heat Stability, moreover, hexyl adipic acid of the present invention and its ammonium salt have more preferable dissolubility in ethylene glycol, contain the electrolysis The aluminium electrolutic capacitor of liquid has the advantages of proof voltage is high, and capacitor life-span is long.And use using ethylene glycol as main solvent and gather Ethylene glycol is the mixed solvent system of secondary solvent, can reduce the vapour pressure of dicyandiamide solution, further improves work electrolysis The flash over voltage of liquid;It is main solute from binary organic carboxyl acid ammonium, is aided with waterproof mixture and the hydrogen additive that disappears, can effectively suppress Anodic attack, increase electrical conductivity, increase the service life.
Although embodiments of the invention have been shown and described above, it is to be understood that above-described embodiment is example Property, it is impossible to limitation of the present invention is interpreted as, one of ordinary skill in the art within the scope of the invention can be to above-mentioned Embodiment is changed, changed, replacing and modification.

Claims (6)

1. a kind of electricity-saving lamp alminium electrolytic condenser electrolyte, it is characterised in that include the component of following parts by weight:Ethylene glycol 60~90 The parts by weight of combination 8~10 of parts by weight, ammonium adipate or adipic acid and its ammonium salt, the parts by weight of binary organic carboxyl acid ammonium 6~8, six First parts by weight of alcohol 5~7, the parts by weight of polyethylene glycol 5~7, the parts by weight of waterproof mixture 2~2.5, the parts by weight of hydrogen agent 0.2~2 that disappear, suppression The parts by weight of additive 0.1~1, the parts by weight of ethylenediacetate 0.05~0.5 of leakage current processed and lifting chemical conversion performance.
2. electricity-saving lamp alminium electrolytic condenser electrolyte according to claim 1, it is characterised in that the ethylene glycol is 60 weight Part, the ammonium adipate or adipic acid and its ammonium salt be combined as 8 parts by weight, binary organic carboxyl acid ammonium is 6 parts by weight, described six First alcohol is 5 parts by weight, the polyethylene glycol is 5 parts by weight, the waterproof mixture is 2 parts by weight, the hydrogen agent that disappears is 0.2 weight Part, the additive for suppressing leakage current and lifting chemical conversion performance are 0.1 parts by weight, the ethylenediacetate is 0.05 weight Part.
3. electricity-saving lamp alminium electrolytic condenser electrolyte according to claim 1, it is characterised in that the ethylene glycol is 75 weight Part, the ammonium adipate or adipic acid and its ammonium salt be combined as 9 parts by weight, binary organic carboxyl acid ammonium is 7.5 parts by weight, described Hexahydroxylic alcohols is 6 parts by weight, the polyethylene glycol is 6 parts by weight, the waterproof mixture is 2.3 parts by weight, the hydrogen agent that disappears is 1 weight Measure part, the additive for suppressing leakage current and lifting chemical conversion performance is 0.3 parts by weight, the ethylenediacetate is 0.2 weight Measure part.
4. electricity-saving lamp alminium electrolytic condenser electrolyte according to claim 1, it is characterised in that the ethylene glycol is 90 weight Part, the ammonium adipate or adipic acid and its ammonium salt be combined as 10 parts by weight, binary organic carboxyl acid ammonium is 8 parts by weight, described Hexahydroxylic alcohols is 7 parts by weight, the polyethylene glycol is 7 parts by weight, the waterproof mixture is 2.5 parts by weight, the hydrogen agent that disappears is 1 weight Measure part, the additive for suppressing leakage current and lifting chemical conversion performance is 0.3 parts by weight, the ethylenediacetate is 0.5 weight Measure part.
5. electricity-saving lamp alminium electrolytic condenser electrolyte according to claim 1, it is characterised in that described to suppress leakage current and carry The additive for rising chemical conversion performance is selected from the one or more of following compound:Phosphoric acid, phosphorous acid, ortho phosphorous acid, phosphate monoester or The ammonium salt of aforesaid compound.
6. electricity-saving lamp alminium electrolytic condenser electrolyte according to claim 1, it is characterised in that the hydrogen agent that disappears is selected from The one or more of following compound:P nitrobenzyl alcohol, 3-nitroacetophenone, ortho-nitroanisole.
CN201711004440.4A 2017-10-20 2017-10-20 Electricity-saving lamp alminium electrolytic condenser electrolyte Pending CN107863251A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711004440.4A CN107863251A (en) 2017-10-20 2017-10-20 Electricity-saving lamp alminium electrolytic condenser electrolyte

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711004440.4A CN107863251A (en) 2017-10-20 2017-10-20 Electricity-saving lamp alminium electrolytic condenser electrolyte

Publications (1)

Publication Number Publication Date
CN107863251A true CN107863251A (en) 2018-03-30

Family

ID=61696383

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711004440.4A Pending CN107863251A (en) 2017-10-20 2017-10-20 Electricity-saving lamp alminium electrolytic condenser electrolyte

Country Status (1)

Country Link
CN (1) CN107863251A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113257575A (en) * 2021-05-25 2021-08-13 深圳市凯琦佳科技股份有限公司 Ultralow-loss electrolyte suitable for 125 degrees and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101477899A (en) * 2008-12-29 2009-07-08 南通江海电容器股份有限公司 Working electrolyte of aluminum electrolytic capacitor for energy-saving lamp and preparation method thereof
JP2011204949A (en) * 2010-03-26 2011-10-13 Nippon Chemicon Corp Electrolyte for electrolytic capacitor
CN102842430A (en) * 2012-08-06 2012-12-26 深圳新宙邦科技股份有限公司 Aluminum electrolytic capacitor electrolyte and aluminum electrolytic capacitor
CN104167292A (en) * 2014-07-15 2014-11-26 烟台恒迪克能源科技有限公司 Working electrolyte for aluminum electrolytic capacitor of electronic energy-saving lamp
CN105575665A (en) * 2015-12-22 2016-05-11 东莞市久制电子有限公司 Electrolyte for high-conductance and long-life aluminum electrolytic capacitor and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101477899A (en) * 2008-12-29 2009-07-08 南通江海电容器股份有限公司 Working electrolyte of aluminum electrolytic capacitor for energy-saving lamp and preparation method thereof
JP2011204949A (en) * 2010-03-26 2011-10-13 Nippon Chemicon Corp Electrolyte for electrolytic capacitor
CN102842430A (en) * 2012-08-06 2012-12-26 深圳新宙邦科技股份有限公司 Aluminum electrolytic capacitor electrolyte and aluminum electrolytic capacitor
CN104167292A (en) * 2014-07-15 2014-11-26 烟台恒迪克能源科技有限公司 Working electrolyte for aluminum electrolytic capacitor of electronic energy-saving lamp
CN105575665A (en) * 2015-12-22 2016-05-11 东莞市久制电子有限公司 Electrolyte for high-conductance and long-life aluminum electrolytic capacitor and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113257575A (en) * 2021-05-25 2021-08-13 深圳市凯琦佳科技股份有限公司 Ultralow-loss electrolyte suitable for 125 degrees and preparation method thereof
CN113257575B (en) * 2021-05-25 2022-09-20 深圳市凯琦佳科技股份有限公司 Ultralow-loss electrolyte suitable for 125 degrees and preparation method thereof

Similar Documents

Publication Publication Date Title
CN1744247B (en) Aluminium electrolytic capacitor working electrolyte and capacitor obtained thereof
CN106098379B (en) Electrolyte, the preparation method of electrolyte and aluminium electrolutic capacitor
CN101114544A (en) Working electrolyte for wide temperature high voltage aluminium electrolytic capacitor and method for making same thereof
CN103794369B (en) A kind of 700V range high voltage aluminum electrolysis capacitor working electrolytes
CN101866751A (en) Temperature-resistant electrolyte for aluminum electrolysis and application thereof
JP5761728B2 (en) Aluminum electrolytic capacitor electrolyte and aluminum electrolytic capacitor
CN105513801A (en) High temperature resistant, ripple resistant, and long life electrolyte for aluminium electrolytic capacitor and preparation method thereof
CN109192509A (en) A kind of aluminium electrolutic capacitor and its manufacturing method in 600V high pressure high temperature resistance and long service life
CN103811183B (en) A kind of 630V range high voltage aluminum electrolysis capacitor working electrolytes and its manufacture method
CN109935468A (en) A kind of ultralow temperature high voltage patch type aluminum capacitor electrolyte and preparation method thereof
CN104681278A (en) High-voltage aluminium electrolysis capacitor
CN101840786A (en) Working electrolyte of aluminum electrolytic capacitor for energy-saving lamp and preparation method thereof
CN107275093B (en) A kind of 600V electrolyte and preparation method thereof
CN107863251A (en) Electricity-saving lamp alminium electrolytic condenser electrolyte
KR20170138913A (en) Electrolyte for aluminum electrolytic capacitor and aluminum electrolytic capacitor using same
CN105469991A (en) High-sparking and long-service-life electrolyte for aluminum electrolytic capacitor and preparation method therefor
CN104134544A (en) Electrolyte of high-frequency ripple-resistant aluminum electrolytic capacitor
CN105469990A (en) Highly aqueous and high-stability electrolyte used for aluminum electrolytic capacitor and preparation method therefor
CN102254689A (en) Working electrolyte for electrolytic capacitor
CN112382508A (en) Electrolyte of aluminum electrolytic capacitor, preparation method thereof and aluminum electrolytic capacitor
CN101521116A (en) Working electrolyte of electrolytic capacitor
CN109942414A (en) High temperature resistant super-pressure dicarboxylic acid for electrolyte and its preparation method and application
CN105140033B (en) A kind of medium-high voltage aluminum electrolytic capacitor Working electrolyte and preparation method thereof
CN107887164B (en) Working electrolyte of 130 ℃ high-voltage aluminum electrolytic capacitor and preparation method
CN107863250A (en) The electrolyte of the alminium electrolytic condenser of efficient stable

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180330

RJ01 Rejection of invention patent application after publication