CN107861259A - The anti-resin lens and preparation method thereof that haze of one kind - Google Patents
The anti-resin lens and preparation method thereof that haze of one kind Download PDFInfo
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- CN107861259A CN107861259A CN201711132317.0A CN201711132317A CN107861259A CN 107861259 A CN107861259 A CN 107861259A CN 201711132317 A CN201711132317 A CN 201711132317A CN 107861259 A CN107861259 A CN 107861259A
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- resin lens
- layer
- haze
- parts
- heat radiating
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
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- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/02—Lenses; Lens systems ; Methods of designing lenses
Abstract
The invention discloses the anti-resin lens and preparation method thereof that haze of one kind.The anti-resin lens that haze include resin lens substrate, are bonded successively with resin lens substrate upper surface anti-haze layer and quick heat radiating layer, anti-layer and the quick heat radiating layer of hazing being bonded successively with resin lens substrate lower surface；Wherein quick heat radiating layer is made up of following raw material：Nano-sized carbon, epoxy resin, dibutyl phthalate, neopelex, citric acid；The anti-layer that hazes is made up of following raw material：Nano silicon, talcum powder, disodium ethylene diamine tetraacetate, alkylolamides, sodium benzoate；The anti-resin lens that haze of the present invention can quickly spread eyeglass environment temperature by quick heat radiating layer while surrounding environment changes, avoid eyeglass heat, anti-fog layer prevents part from forming fog on resin lens surface without the heat of diffusion simultaneously, to expand the scope of application of resin lens.
Description
Technical field
The invention belongs to resin lens technical field, and in particular to the anti-resin lens and preparation method thereof that haze of one kind.
Background technology
Current ophthalmic lens many on the market are all to be made using various carbon hydro carbons and carbon esters polymer as raw material, resin
Eyeglass widely using in glasses market.The glasses of odd number major part resin lens or glass lens, running into hot sky
One layer of water smoke is readily formed when gas, has a strong impact on visual effect, eyes use is caused greatly to perplex.The particularly autumn
In the time in winter, indoor eye preceding layer water smoke is entered from outdoor, what does not all see Chu, it is necessary to clear to glasses progress fog immediately
Remove；The anti-wear performance of resin lens is weaker simultaneously, it is easy to forms cut, influences the transmitance of light, using effect is bad.
Chinese patent CN103439800A discloses a kind of manufacture method of Anti-fog glasses piece, including：First, using electrostatic
Pad pasting is adsorbed, and plastic uptake processing is carried out to the Electrostatic Absorption pad pasting, the Electrostatic Absorption pad pasting is for PET materials and including antifog
Layer, adhered layer and is attached at anti-fog layer and the release layer of adhered layer both side surface；Secondly, using yin, yang mould to plastic uptake processing
Electrostatic Absorption film afterwards carries out radian forming processes, forms the Electrostatic Absorption pad pasting cambered；Finally, by radian shaping
The release layer of the Electrostatic Absorption pad pasting after reason is torn, then the anti-fog layer is affixed on to the inner and outer surfaces of ophthalmic len, is made
Anti-fog glasses piece.Complicated in this invention, sandwich construction easily influences the effect of anti-fog layer, and heat can not be dredged in time
Dissipate, it is antifog ineffective.
Chinese patent CN205539775U discloses a kind of antifog antimicrobial form ophthalmic len, including substrate, the substrate it is outer
Surface is from the inside to the outside successively with stiffening layer, the wear-resisting film layer of anti-scratch, macromolecule hydrophobic anti-fog layer, antibiotic layer；And the substrate
Inner surface from the inside to the outside successively with stiffening layer, the wear-resisting film layer of anti-scratch, green antireflective coating, antibiotic layer.The eyeglass has anti-
While mist function, possesses antibacterial effect；Macromolecule hydrophobic anti-fog layer outer layer also included one layer of antibacterial once in this invention, antifog effect
Fruit is obstructed, while antifog only by hydrophobic, and effect is unsatisfactory.
Chinese patent CN205263336U discloses a kind of ultra-thin antifog aspherical compound eye eyeglass, mainly including basic unit,
The silica coating that is connected successively with basic unit upper surface, zirconium dioxide film, tin indium oxide film layer, carbon nano-fiber film layer,
The silica coating that is connected successively with basic unit lower surface, zirconium dioxide film, safety glass film layer；The basic unit includes refraction
Rate identical resin bed and glassy layer, it is described no less than 3 layers per two layers of resin layer centre one layer of glassy layer of folder, the resin bed
Glassy layer is no less than two layers.Ophthalmic len of the present utility model is due to the composite construction using glass and resin, compared to traditional glass
Ophthalmic len is lighter and non-friable, increases compared to conventional resins ophthalmic len wearability and thinner, and basic unit upper surface is coated with nano-sized carbon
Tunica fibrosa, antifog and static elimination can be played a part of, basic unit lower surface, which is coated with safety glass film layer, can strengthen eyeglass
Wearability, by the antifog antistatic of carbon nano-fiber layer in this invention, it can not radiate in time, anti-fog effect has much room for improvement.
Therefore, the present invention is directed to problem above, and invention one kind can effectively prevent haze resin lens, while production cost
It is low, service life length.
The content of the invention
A kind of anti-resin lens that haze are provided it is an object of the invention to overcome existing deficiency, improve current resin mirror
Piece runs into vapours or hot-air easily hazes, complex manufacturing technology, cost of manufacture it is high the shortcomings that.
In order to solve the above-mentioned technical problem, the present invention takes following technical scheme：
The anti-resin lens that haze of one kind, including resin lens substrate, preventing of be bonded successively with resin lens substrate upper surface
Haze layer and quick heat radiating layer, anti-layer and the quick heat radiating layer of hazing that is bonded successively with resin lens substrate lower surface；It is wherein fast
Fast heat dissipating layer is made up of the raw material of following parts by weight：6 parts~8 parts of nano-sized carbon, 8 parts~15 parts of epoxy resin, phthalic acid two
0.8 part~1 part of butyl ester, 0.2 part~0.8 part of neopelex, 1 part~2 parts of citric acid；It is anti-to haze layer by following weight
The raw material composition of part：6 parts~10 parts of nano silicon, 2 parts~4 parts of talcum powder, disodium ethylene diamine tetraacetate 0.6 part~0.8
Part, 0.4 part~1 part of alkylolamides, 0.8 part~1.2 parts of sodium benzoate.
Further, the quick heat radiating layer of the anti-resin lens that haze is made up of the raw material of following parts by weight：7 parts of nano-sized carbon,
12 parts of epoxy resin, 0.9 part of dibutyl phthalate, 0.4 part of neopelex, 1.6 parts of citric acid；The anti-layer that hazes
It is made up of the raw material of following parts by weight：8 parts of nano silicon, 3 parts of talcum powder, 0.7 part of disodium ethylene diamine tetraacetate, alkylol
0.8 part of acid amides, 1 part of sodium benzoate.
Further, the particle diameter of nano-sized carbon is 10nm~20nm.
Further, the particle diameter of nano silicon is 20nm~40nm.
According to it is another object of the present invention to provide a kind of preparation method of the above-mentioned anti-resin lens that haze, including with
Lower step：
S10, quick heat radiating layer stock：By the nano-sized carbon of the parts by weight, epoxy resin, dibutyl phthalate and ten
Dialkyl benzene sulfonic acids sodium, 0.5h~1.0h is mixed under the conditions of being 95 DEG C~105 DEG C in temperature, adds the citron of the parts by weight
Acid, stir, obtain quick heat radiating layer stock；
S20, the anti-layer stock that haze：By the nano silicon of the parts by weight, talcum powder, disodium ethylene diamine tetraacetate,
Alkylolamides, sodium benzoate are configured to viscosity as 3 × 10 by weight with deionized water-6m2/ s~4 × 10-6m2/ s's is molten
Liquid, and ultrasonic 25min~30min, obtain the anti-layer stock that haze；
S30, anti-resin lens preparation of hazing：Resin lens substrate surface is cleaned and dried, is afterwards obtained S20
It is anti-haze layer stock drip to resin lens substrate upper surface, with spin coater by solution with 1000r/min~2000r/min
Speed rotary coating 5s~10s obtain wet film, be then heat-treated in quick anneal oven, and under resin lens substrate
Surface repeats above-mentioned rotary coating and heat treatment；Resin lens substrate after heat treatment is placed in vacuum coating machines, is obtained with S10
Quick heat radiating layer stock resin lens substrate upper surface after heat treatment plate one layer of quick heat radiating layer, dry cooling after plated film
30min~45min, and above-mentioned vacuum coated is repeated to the resin lens substrate lower surface after heat treatment and operated, obtain described anti-
Haze resin lens.
Further, in S20, nano silicon, talcum powder, disodium ethylene diamine tetraacetate, alkylolamides, benzoic acid
The weight of sodium and deionized water ratio is 4~5：1~2：2~3：2~3：1~2：20~30.
Further, in S30, resin lens substrate surface, which is cleaned and dries concrete operations, is：With absolute ethyl alcohol pair
Resin lens substrate is cleaned 3 times, and 60min~120min is dried under the conditions of being afterwards 55 DEG C~65 DEG C in temperature.
Further, in S30, heat treatment condition is：10 DEG C/min~20 DEG C/min speed be warming up to 105 DEG C~
135 DEG C of holding 5min~10min, 185 DEG C~205 DEG C holding 10min are then warming up to 5 DEG C/min~10 DEG C/min speed
~15min.
Further, in S30, the anti-thickness degree that hazes is 1.80 μm~2.00 μm.
Further, in S30, quick heat radiating thickness degree is 4.20 μm~4.60 μm.
The advantages of the present invention are：
1. the anti-resin lens that haze disclosed by the invention, selection is green, the anti-resin mirror that hazes of addition nano-sized carbon enhancing
Piece prevents mist to vapours in environment or the diffusivity of hot-air, the anti-resin lens that haze of addition nano silicon enhancing
The ability that gas is formed, by adding other auxiliary materials, each several part raw material interacts, reinforced resin eyeglass substrate and it is anti-haze layer with
And the adhesion between quick heat radiating layer, improve the anti-resin lens performance that hazes of the present invention, the common product matter for improving the present invention
Amount, makes its durable in use；
2. can effectively prevent the special-effect of fog in the anti-resin lens that haze disclosed by the invention, resin lens are avoided
During wearing, the problem of being hazed due to eyeglass caused by environmental change or temperature change, while improve the present invention and prevent hazing
The anti-wear performance of resin lens, service life length；
3. the anti-anti- significant effect that hazes of the resin lens that haze disclosed by the invention, can quickly be spread by quick heat radiating layer
The vapours or hot-air of resin lens surrounding environment, eyeglass heat is avoided, while anti-fog layer prevents part without diffusion
Heat forms fog on resin lens surface, to expand the scope of application of resin lens；Quick heat radiating layer can also be used as protection
Film, protect resin lens not to be worn, increase the service life, and its preparation technology advantages of simple, can extensive use；
4. the present invention combines modern advanced technologies, preparation method is simple, processing cost is low, significant effect, and prepared is anti-
The resin lens quality that hazes is good, effectively fog can be prevented to be formed on resin lens, convenient use.
Embodiment
The embodiment of the present invention is described in detail below.It is it should be appreciated that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to limit the invention.
Embodiment 1
The anti-resin lens that haze of one kind
Raw material and composition：(unit：g)
Quick heat radiating layer is made up of the raw material of following parts by weight in the anti-resin lens that haze：Particle diameter is 10nm nano-sized carbon
60g, epoxy resin 80g, dibutyl phthalate 8g, neopelex 2g, citric acid 10g；It is anti-haze layer by with
The raw material composition of lower parts by weight：Particle diameter is 20nm nano silicon 60g, talcum powder 20g, disodium ethylene diamine tetraacetate 6g,
Alkylolamides 4g, sodium benzoate 8g.
It is prepared via a method which：
S10, quick heat radiating layer stock：By the nano-sized carbon of the parts by weight, epoxy resin, dibutyl phthalate and ten
Dialkyl benzene sulfonic acids sodium, 0.5h is mixed under the conditions of being 95 DEG C in temperature, the citric acid of the parts by weight is added, stirs, obtain
Stocked up to quick heat radiating layer；
S20, the anti-layer stock that haze：By the nano silicon of the parts by weight, talcum powder, disodium ethylene diamine tetraacetate,
Alkylolamides, sodium benzoate is with deionized water by weight 4：1：2：2：1：20 are configured to viscosity as 3 × 10-6m2/ s's is molten
Liquid, and ultrasonic 25min, obtain the anti-layer stock that haze；
S30, anti-resin lens preparation of hazing：Resin lens substrate surface is cleaned with absolute ethyl alcohol to resin lens substrate
3 times, 60min is dried under the conditions of being afterwards 55 DEG C in temperature, the anti-layer stock that haze for afterwards obtaining S20 drips to resin lens base
Piece upper surface, solution is obtained into wet film with 1000r/min speed rotary coating 5s with spin coater, then in short annealing
It is heat-treated in stove, heat treatment condition is：10 DEG C/min speed is warming up to 105 DEG C of holding 5min, then with 5 DEG C/min's
Speed is warming up to 185 DEG C of holding 10min, and repeats above-mentioned rotary coating and heat treatment to resin lens substrate lower surface；At heat
Resin lens substrate after reason is placed in vacuum coating machines, the resin that the quick heat radiating layer obtained with S10 is stocked up after heat treatment
Eyeglass substrate upper surface plates one layer of quick heat radiating layer, and cooling 30min is dried after plated film, and to the resin lens substrate after heat treatment
Lower surface repeats above-mentioned vacuum coated operation, obtains the anti-resin lens that haze.
In aforesaid operations, for the anti-thickness degree that hazes for 1.80 μm, quick heat radiating thickness degree is 4.20 μm；The anti-resin lens that haze
Quick heat radiating layer stock and the batch production stocked up for the anti-eyeglass that hazes of the anti-layer that hazes.
Embodiment 2
The anti-resin lens that haze of one kind
Raw material and composition：(unit：g)
Quick heat radiating layer is made up of the raw material of following parts by weight in the anti-resin lens that haze：Particle diameter is 20nm nano-sized carbon
80g, epoxy resin 150g, dibutyl phthalate 10g, neopelex 8g, citric acid 20g；It is anti-haze layer by
The raw material composition of following parts by weight：Particle diameter be 40nm nano silicon 100g, talcum powder 40g, disodium ethylene diamine tetraacetate
8g, alkylolamides 10g, sodium benzoate 12g.
It is prepared via a method which：
S10, quick heat radiating layer stock：By the nano-sized carbon of the parts by weight, epoxy resin, dibutyl phthalate and ten
Dialkyl benzene sulfonic acids sodium, 1.0h is mixed under the conditions of being 105 DEG C in temperature, the citric acid of the parts by weight is added, stirs, obtain
Stocked up to quick heat radiating layer；
S20, the anti-layer stock that haze：By the nano silicon of the parts by weight, talcum powder, disodium ethylene diamine tetraacetate,
Alkylolamides, sodium benzoate is with deionized water by weight 5：2：3：3：2：30 are configured to viscosity as 4 × 10-6m2/ s's is molten
Liquid, and ultrasonic 30min, obtain the anti-layer stock that haze；
S30, anti-resin lens preparation of hazing：Resin lens substrate surface is cleaned with absolute ethyl alcohol to resin lens substrate
3 times, 120min is dried under the conditions of being afterwards 65 DEG C in temperature, the anti-layer stock that haze for afterwards obtaining S20 drips to resin lens
Substrate upper surface, solution is obtained into wet film with 2000r/min speed rotary coating 10s with spin coater, then quick
It is heat-treated in annealing furnace, heat treatment condition is：20 DEG C/min speed is warming up to 135 DEG C of holding 10min, then with 10
DEG C/min speed is warming up to 205 DEG C of holding 15min, and above-mentioned rotary coating and Re Chu repeated to resin lens substrate lower surface
Reason；Resin lens substrate after heat treatment is placed in vacuum coating machines, and the quick heat radiating layer obtained with S10 is stocked up after heat treatment
Resin lens substrate upper surface plate one layer of quick heat radiating layer, cooling 45min is dried after plated film, and to the resin mirror after heat treatment
Piece substrate lower surface repeats above-mentioned vacuum coated operation, obtains the anti-resin lens that haze.
In aforesaid operations, for the anti-thickness degree that hazes for 2.00 μm, quick heat radiating thickness degree is 4.60 μm；The anti-resin lens that haze
Quick heat radiating layer stock and the batch production stocked up for the anti-eyeglass that hazes of the anti-layer that hazes.
Embodiment 3
The anti-resin lens that haze of one kind
Raw material and composition：(unit：g)
Quick heat radiating layer is made up of the raw material of following parts by weight in the anti-resin lens that haze：Particle diameter is 10nm nano-sized carbon
68g, epoxy resin 90g, dibutyl phthalate 8.4g, neopelex 3g, citric acid 12g；It is anti-haze layer by
The raw material composition of following parts by weight：Particle diameter be 20nm nano silicon 76g, talcum powder 24g, disodium ethylene diamine tetraacetate
6.8g, alkylolamides 5.6g, sodium benzoate 9.2g.
It is prepared via a method which：
S10, quick heat radiating layer stock：By the nano-sized carbon of the parts by weight, epoxy resin, dibutyl phthalate and ten
Dialkyl benzene sulfonic acids sodium, 0.6h is mixed under the conditions of being 98 DEG C in temperature, the citric acid of the parts by weight is added, stirs, obtain
Stocked up to quick heat radiating layer；
S20, the anti-layer stock that haze：By the nano silicon of the parts by weight, talcum powder, disodium ethylene diamine tetraacetate,
Alkylolamides, sodium benzoate is with deionized water by weight 4：2：3：2：1：20 are configured to viscosity as 3.5 × 10-6m2/ s's is molten
Liquid, and ultrasonic 25min, obtain the anti-layer stock that haze；
S30, anti-resin lens preparation of hazing：Resin lens substrate surface is cleaned with absolute ethyl alcohol to resin lens substrate
3 times, 80min is dried under the conditions of being afterwards 58 DEG C in temperature, the anti-layer stock that haze for afterwards obtaining S20 drips to resin lens base
Piece upper surface, solution is obtained into wet film with 1500r/min speed rotary coating 6s with spin coater, then in short annealing
It is heat-treated in stove, heat treatment condition is：12 DEG C/min speed is warming up to 115 DEG C of holding 8min, then with 6 DEG C/min's
Speed is warming up to 190 DEG C of holding 10min, and repeats above-mentioned rotary coating and heat treatment to resin lens substrate lower surface；At heat
Resin lens substrate after reason is placed in vacuum coating machines, the resin that the quick heat radiating layer obtained with S10 is stocked up after heat treatment
Eyeglass substrate upper surface plates one layer of quick heat radiating layer, and cooling 30min is dried after plated film, and to the resin lens substrate after heat treatment
Lower surface repeats above-mentioned vacuum coated operation, obtains the anti-resin lens that haze.
In aforesaid operations, for the anti-thickness degree that hazes for 1.86 μm, quick heat radiating thickness degree is 4.30 μm；The anti-resin lens that haze
Quick heat radiating layer stock and the batch production stocked up for the anti-eyeglass that hazes of the anti-layer that hazes.
Embodiment 4
The anti-resin lens that haze of one kind
Raw material and composition：(unit：g)
The anti-resin lens quick heat radiating layer that hazes is made up of the raw material of following parts by weight：Particle diameter is 20nm nano-sized carbon 78g,
Epoxy resin 120g, dibutyl phthalate 9.8g, neopelex 6g, citric acid 18g；It is anti-to haze layer by following
The raw material composition of parts by weight：Particle diameter is 30nm nano silicon 90g, talcum powder 36g, disodium ethylene diamine tetraacetate 7.2g,
Alkylolamides 9g, sodium benzoate 11g.
It is prepared via a method which：
S10, quick heat radiating layer stock：By the nano-sized carbon of the parts by weight, epoxy resin, dibutyl phthalate and ten
Dialkyl benzene sulfonic acids sodium, 0.8h is mixed under the conditions of being 102 DEG C in temperature, the citric acid of the parts by weight is added, stirs, obtain
Stocked up to quick heat radiating layer；
S20, the anti-layer stock that haze：By the nano silicon of the parts by weight, talcum powder, disodium ethylene diamine tetraacetate,
Alkylolamides, sodium benzoate is with deionized water by weight 5：2：3：2：2：30 are configured to viscosity as 3.8 × 10-6m2/ s's is molten
Liquid, and ultrasonic 30min, obtain the anti-layer stock that haze；
S30, anti-resin lens preparation of hazing：Resin lens substrate surface is cleaned with absolute ethyl alcohol to resin lens substrate
3 times, 110min is dried under the conditions of being afterwards 62 DEG C in temperature, the anti-layer stock that haze for afterwards obtaining S20 drips to resin lens
Substrate upper surface, solution is obtained into wet film with 1800r/min speed rotary coating 8s with spin coater, then quickly moved back
It is heat-treated in stove, heat treatment condition is：18 DEG C/min speed be warming up to 125 DEG C holding 8min, then with 10 DEG C/
Min speed is warming up to 200 DEG C of holding 10min, and repeats above-mentioned rotary coating and heat treatment to resin lens substrate lower surface；
Resin lens substrate after heat treatment is placed in vacuum coating machines, and the quick heat radiating layer obtained with S10 is stocked up after heat treatment
Resin lens substrate upper surface plates one layer of quick heat radiating layer, cooling 40min is dried after plated film, disease is to the resin lens after heat treatment
Substrate lower surface repeats above-mentioned vacuum coated operation, obtains the anti-resin lens that haze.
In aforesaid operations, for the anti-thickness degree that hazes for 1.95 μm, quick heat radiating thickness degree is 4.52 μm；The anti-resin lens that haze
Quick heat radiating layer stock and the batch production stocked up for the anti-eyeglass that hazes of the anti-layer that hazes.
Embodiment 5
The anti-resin lens that haze of one kind
Raw material and composition：(unit：g)
The quick heat radiating layer of the anti-resin lens that haze of the anti-resin lens that haze is made up of the raw material of following parts by weight：Particle diameter
For 20nm nano-sized carbon 70g, epoxy resin 120g, dibutyl phthalate 9g, particle diameter is 40nm DBSA
Sodium 4g, citric acid 16g；The anti-layer that hazes is made up of the raw material of following parts by weight：Nano silicon 80g, talcum powder 30g, second two
Amine tetraacethyl disodium 7g, alkylolamides 8g, sodium benzoate 10g.
It is prepared via a method which：
S10, quick heat radiating layer stock：By the nano-sized carbon of the parts by weight, epoxy resin, dibutyl phthalate and ten
Dialkyl benzene sulfonic acids sodium, 0.6h is mixed under the conditions of being 101 DEG C in temperature, the citric acid of the parts by weight is added, stirs, obtain
Stocked up to quick heat radiating layer；
S20, the anti-layer stock that haze：By the nano silicon of the parts by weight, talcum powder, disodium ethylene diamine tetraacetate,
Alkylolamides, sodium benzoate is with deionized water by weight 4：1：2：3：2：30 are configured to viscosity as 3.2 × 10-6m2/ s's is molten
Liquid, and ultrasonic 25min, obtain the anti-layer stock that haze；
S30, anti-resin lens preparation of hazing：Resin lens substrate surface is cleaned with absolute ethyl alcohol to resin lens substrate
3 times, 100min is dried under the conditions of being afterwards 60 DEG C in temperature, the anti-layer stock that haze for afterwards obtaining S20 drips to resin lens
Substrate upper surface, solution is obtained into wet film with 1500r/min speed rotary coating 5s with spin coater, then quickly moved back
It is heat-treated in stove, heat treatment condition is：15 DEG C/min speed be warming up to 120 DEG C holding 10min, then with 6 DEG C/
Min speed is warming up to 195 DEG C of holding 10min, and repeats above-mentioned rotary coating and heat treatment to resin lens substrate lower surface；
Resin lens substrate after heat treatment is placed in vacuum coating machines, and the quick heat radiating layer obtained with S10 is stocked up after heat treatment
Resin lens substrate lower surface plates one layer of quick heat radiating layer, and cooling 35min is dried after plated film, and to the resin lens after heat treatment
Substrate lower surface repeats above-mentioned vacuum coated operation, obtains the anti-resin lens that haze.
In aforesaid operations, for the anti-thickness degree that hazes for 1.86 μm, quick heat radiating thickness degree is 4.35 μm；The anti-resin lens that haze
Quick heat radiating layer stock and the batch production stocked up for the anti-eyeglass that hazes of the anti-layer that hazes.
Experimental example
The anti-resin lens that haze being prepared using the various embodiments described above 1~5, for the anti-resin lens basic nature that hazes
The research of energy, it further demonstrate the effect of the anti-resin lens that haze：
Test 1：To preventing resin lens progress basic performance detection of hazing, test result such as table 1 made from embodiment 1~5
Shown in：
The anti-resin lens basic performance test result that hazes of the embodiment 1~5 of table 1
| Experimental example | Refractive index | Light transmission rate | Fog effect is prevented |
| Embodiment 1 | 1.58 | 94.0% | Effect is good |
| Embodiment 2 | 1.60 | 92.8% | Effect is good |
| Embodiment 3 | 1.63 | 93.9% | Effect is good |
| Embodiment 4 | 1.68 | 93.0% | Effect is good |
| Embodiment 5 | 1.60 | 94.3% | Effect is good |
As can be seen from Table 1, anti-resin lens refractive index height, the translucency of hazing is strong made from embodiment 1~5, while can
Effectively to prevent from hazing, it is adapted to widely use.
Anti- haze that quick heat radiating layer can protect resin lens to resin lens in use in addition, provided by the invention
It is not worn, keeps original gloss, service life length.
The preferred embodiments of the present invention and experimental example are these are only, is not intended to limit the invention, for this area
Technical staff for, the present invention can have various modifications and variations.Within the spirit and principles of the invention, that is made appoints
What modification, equivalent substitution, improvement etc., should be included in the scope of the protection.
Claims (10)
1. the anti-resin lens that haze of one kind, it is characterised in that the anti-resin lens that haze include resin lens substrate, successively with
Anti- haze layer and the quick heat radiating layer of the fitting of resin lens substrate upper surface, preventing of be bonded successively with resin lens substrate lower surface
Haze layer and quick heat radiating layer；Wherein quick heat radiating layer is made up of the raw material of following parts by weight：6 parts~8 parts of nano-sized carbon, asphalt mixtures modified by epoxy resin
8 parts~15 parts of fat, 0.8 part~1 part of dibutyl phthalate, 0.2 part~0.8 part of neopelex, 1 part of citric acid
~2 parts；The anti-layer that hazes is made up of the raw material of following parts by weight：6 parts~10 parts of nano silicon, 2 parts~4 parts of talcum powder, second
0.6 part~0.8 part of edetate disodium, 0.4 part~1 part of alkylolamides, 0.8 part~1.2 parts of sodium benzoate.
2. the anti-resin lens that haze according to claim 1, it is characterised in that the quick of the anti-resin lens that haze dissipates
Thermosphere is made up of the raw material of following parts by weight：7 parts of nano-sized carbon, 12 parts of epoxy resin, 0.9 part of dibutyl phthalate, 12
0.4 part of sodium alkyl benzene sulfonate, 1.6 parts of citric acid；The anti-layer that hazes is made up of the raw material of following parts by weight：8 parts of nano silicon,
3 parts of talcum powder, 0.7 part of disodium ethylene diamine tetraacetate, 0.8 part of alkylolamides, 1 part of sodium benzoate.
3. the anti-resin lens that haze according to claim 1, it is characterised in that the particle diameter of the nano-sized carbon be 10nm~
20nm。
4. the anti-resin lens that haze according to claim 1, it is characterised in that the particle diameter of the nano silicon is
20nm~40nm.
It is 5. a kind of such as the preparation method of the anti-resin lens that haze according to any one of claims 1 to 4, it is characterised in that system
Standby step is as follows：
S10, quick heat radiating layer stock：By the nano-sized carbon of the parts by weight, epoxy resin, dibutyl phthalate and dodecane
Base benzene sulfonic acid sodium salt, 0.5h~1.0h is mixed under the conditions of being 95 DEG C~105 DEG C in temperature, the citric acid of the parts by weight is added, stirs
Mix uniformly, obtain quick heat radiating layer stock；
S20, the anti-layer stock that haze：By the nano silicon of the parts by weight, talcum powder, disodium ethylene diamine tetraacetate, alkyl
Alkylolamides, sodium benzoate are configured to viscosity as 3 × 10 by weight with deionized water-6m2/ s~4 × 10-6m2/ s solution, and
Ultrasonic 25min~30min, obtain the anti-layer stock that haze；
S30, anti-resin lens preparation of hazing：Resin lens substrate surface is cleaned and dried, is afterwards obtained S20 anti-
The layer that hazes stock drips to resin lens substrate upper surface, with spin coater by solution with 1000r/min~2000r/min speed
Rate rotary coating 5s~10s obtains wet film, is then heat-treated in quick anneal oven, and to resin lens substrate lower surface
Repeat above-mentioned rotary coating and heat treatment；Resin lens substrate after heat treatment is placed in vacuum coating machines, is obtained with S10 fast
The resin lens substrate upper surface of fast heat dissipating layer stock after heat treatment plates one layer of quick heat radiating layer, and cooling is dried after plated film
30min~45min, and above-mentioned vacuum coated is repeated to the resin lens substrate lower surface after heat treatment and operated, obtain described anti-
Haze resin lens.
6. preparation method according to claim 5, it is characterised in that in S20, the nano silicon, talcum powder, second
The weight ratio of edetate disodium, alkylolamides, sodium benzoate and deionized water is 4~5：1~2：2~3：2~3：1~
2：20~30.
7. preparation method according to claim 5, it is characterised in that in S30, the resin lens substrate surface carries out clear
Wash and dry concrete operations and be：Resin lens substrate is cleaned 3 times with absolute ethyl alcohol, be afterwards 55 DEG C~65 DEG C conditions in temperature
Lower drying 60min~120min.
8. preparation method according to claim 5, it is characterised in that in S30, the heat treatment condition is：10℃/min
~20 DEG C/min speed is warming up to 105 DEG C~135 DEG C holding 5min~10min, then with 5 DEG C/min~10 DEG C/min speed
Rate is warming up to 185 DEG C~205 DEG C holding 10min~15min.
9. preparation method according to claim 5, it is characterised in that in S30, it is described it is anti-haze thickness degree for 1.80 μm~
2.00μm。
10. preparation method according to claim 5, it is characterised in that in S30, the quick heat radiating thickness degree is 4.20 μ
M~4.60 μm.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109212633A (en) * | 2018-08-13 | 2019-01-15 | 江苏硕延光学眼镜有限公司 | A kind of macromolecule resin eyeglass and its preparation process with shock resistance |
| CN110646871A (en) * | 2019-10-08 | 2020-01-03 | 苏州鑫河镜业有限公司 | High-strength waterproof antibacterial automobile sun visor lens and production process thereof |
| CN112592165A (en) * | 2020-12-14 | 2021-04-02 | 苏州晶生新材料有限公司 | Novel optical coating material with antifogging property and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109212633A (en) * | 2018-08-13 | 2019-01-15 | 江苏硕延光学眼镜有限公司 | A kind of macromolecule resin eyeglass and its preparation process with shock resistance |
| CN110646871A (en) * | 2019-10-08 | 2020-01-03 | 苏州鑫河镜业有限公司 | High-strength waterproof antibacterial automobile sun visor lens and production process thereof |
| CN112592165A (en) * | 2020-12-14 | 2021-04-02 | 苏州晶生新材料有限公司 | Novel optical coating material with antifogging property and preparation method thereof |
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Application publication date: 20180330 |