CN107861177A - Plated film 3D resin lens and preparation method thereof - Google Patents
Plated film 3D resin lens and preparation method thereof Download PDFInfo
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- CN107861177A CN107861177A CN201710976629.3A CN201710976629A CN107861177A CN 107861177 A CN107861177 A CN 107861177A CN 201710976629 A CN201710976629 A CN 201710976629A CN 107861177 A CN107861177 A CN 107861177A
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- preparation
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- resin lens
- plated film
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
Abstract
The invention discloses a kind of plated film 3D resin lens and preparation method thereof, the preparation method includes：(1) nano-titanium particle is mixed with surface modifier, obtains modified Nano titanium particle；(2) by modified Nano titanium particle and alcoholic solvent according to mass ratio 1 3.5：100 mixing, and 15 20min are reacted at 20 50 DEG C, obtain titanium oxide contained nanometer particle solution；(3) titanium oxide contained nanometer particle solution, ethylene glycol, butyl titanate, ethylenediamine and hardening liquid are mixed, and 10 20min is reacted at 30 55 DEG C, obtain coating liquid；(4) resin lens are put into after being soaked in coating liquid and taken out, carried out baking for the first time successively afterwards and second is toasted, obtain plated film 3D resin lens；It is also insufficient to solve the anti-wear performance of current resin lens, the problem of cut easily occurs using rear surface for a long time.
Description
Technical field
The present invention relates to VR apparatus fields, in particular it relates to a kind of plated film 3D resin lens and preparation method thereof.
Background technology
Since resin lens are born, how manufacturer always allows the performances of light, saturating resin lens if being pursued
Further get a promotion, but the quality of high-quality eyeglass is not only determined by lens materials, its surface coating also functions to heavy to closing
The effect wanted.The anti-wear performance of current resin lens is also insufficient, cut easily occurs using rear surface for a long time.
Therefore it provides a kind of anti-wear performance is more excellent, be less prone to after long-time use cut plated film 3D resin lens and
The problem of its preparation method is urgent need to resolve of the present invention.
The content of the invention
It is an object of the invention to provide a kind of plated film 3D resin lens and preparation method thereof, solve current resin lens
Anti-wear performance it is also insufficient, easily there is the problem of cut using rear surface for a long time.
To achieve these goals, the invention provides a kind of preparation method of plated film 3D resin lens, the preparation side
Method includes：
(1) nano-titanium particle is mixed with surface modifier, obtains modified Nano titanium particle；
(2) by modified Nano titanium particle and alcoholic solvent according to mass ratio 5-8：100 mixing, and react 15- at 55-70 DEG C
20min, obtain titanium oxide contained nanometer particle solution；
(3) titanium oxide contained nanometer particle solution, ethylene glycol, butyl titanate, ethylenediamine and hardening liquid are mixed, and
10-20min is reacted at 20-25 DEG C, obtains coating liquid；
(4) resin lens are put into after being soaked in coating liquid and taken out, carried out baking for the first time successively afterwards and second is dried
It is roasting, obtain plated film 3D resin lens；Wherein, the condition of baking includes for the first time：The temperature of baking be 50-70 DEG C, baking when
Between be 10-15min；The condition of second of baking includes：The temperature of baking is 30-45 DEG C, and the time of baking is 20-25min.
Present invention also offers a kind of plated film 3D resin lens, the plated film 3D resin lens are by above-mentioned preparation method system
.
Pass through above-mentioned technical proposal, the invention provides a kind of preparation method of plated film 3D resin lens, the preparation side
Method includes：Nano-titanium particle is mixed with surface modifier, obtains modified Nano titanium particle；Modified Nano titanium particle and alcohol is molten
Agent is according to mass ratio 5-8：100 mixing, and 15-20min is reacted at 55-70 DEG C, obtain titanium oxide contained nanometer particle solution；Will
Titanium oxide contained nanometer particle solution, ethylene glycol, butyl titanate, ethylenediamine and hardening liquid mixing, and reacted at 20-25 DEG C
10-20min, obtain coating liquid；By resin lens be put into coating liquid soak after take out, afterwards successively carry out for the first time baking and
Second of baking, obtains plated film 3D resin lens；Wherein, the condition of baking includes for the first time：The temperature of baking is 50-70 DEG C,
The time of baking is 10-15min；The condition of second of baking includes：The temperature of baking is 30-45 DEG C, and the time of baking is 20-
25min；Pass through the mating reaction between each raw material and the optimization to process conditions so that obtained plated film 3D resin lens tool
Standby excellent anti-wear performance, while the preparation method is simple, easy to operate, is adapted to be widely popularized.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Embodiment
The embodiment of the present invention is described in detail below.It is it should be appreciated that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to limit the invention.
The end points of disclosed scope and any value are not limited to the accurate scope or value herein, these scopes or
Value should be understood to comprising the value close to these scopes or value.For number range, between the endpoint value of each scope, respectively
It can be combined with each other between the endpoint value of individual scope and single point value, and individually between point value and obtain one or more
New number range, these number ranges should be considered as specific open herein.
The invention provides a kind of preparation method of plated film 3D resin lens, the preparation method includes：
(1) nano-titanium particle is mixed with surface modifier, obtains modified Nano titanium particle；
(2) by modified Nano titanium particle and alcoholic solvent according to mass ratio 5-8：100 mixing, and react 15- at 55-70 DEG C
20min, obtain titanium oxide contained nanometer particle solution；
(3) titanium oxide contained nanometer particle solution, ethylene glycol, butyl titanate, ethylenediamine and hardening liquid are mixed, and
10-20min is reacted at 20-25 DEG C, obtains coating liquid；
(4) resin lens are put into after being soaked in coating liquid and taken out, carried out baking for the first time successively afterwards and second is dried
It is roasting, obtain plated film 3D resin lens；Wherein, the condition of baking includes for the first time：The temperature of baking be 50-70 DEG C, baking when
Between be 10-15min；The condition of second of baking includes：The temperature of baking is 30-45 DEG C, and the time of baking is 20-25min.
In a kind of preferred embodiment of the present invention, in order to further improve the resistance to of obtained plated film 3D resin lens
Grind performance, the one kind of the surface modifier in octadecylamine, hexadecylamine, tetradecylamine or lauryl amine
It is or a variety of.
In a kind of preferred embodiment of the present invention, in order to further improve the resistance to of obtained plated film 3D resin lens
Performance is ground, in step (1), nano-titanium particle is 1 according to mass ratio with surface modifier:10-15 is mixed.
In a kind of preferred embodiment of the present invention, in order to further improve the resistance to of obtained plated film 3D resin lens
Grind performance, one or more of the alcoholic solvent in ethanol, ethylene glycol and methanol.
In a kind of preferred embodiment of the present invention, in order to further improve the resistance to of obtained plated film 3D resin lens
Performance is ground, in step (3), with respect to the titanium oxide contained nanometer particle solution of 100 parts by weight, the dosage of ethylene glycol is 10-20 weights
Part is measured, the dosage of butyl titanate is 15-25 parts by weight, and the dosage of ethylenediamine is 5-8 parts by weight, and the dosage of hardening liquid is 2-8
Parts by weight.
In a kind of preferred embodiment of the present invention, in order to further improve the resistance to of obtained plated film 3D resin lens
Performance is ground, hardening liquid is selected from VH-10 hardening liquids or VH-1.6 hardening liquids.
In a kind of preferred embodiment of the present invention, in order to further improve the resistance to of obtained plated film 3D resin lens
Performance is ground, the average grain diameter of nano-titanium particle is 20-30nm.
In a kind of preferred embodiment of the present invention, in order to further improve the resistance to of obtained plated film 3D resin lens
Performance is ground, in step (3), is mixed by the way of ultrasonic mixing, and the frequency of ultrasonic mixing is 10-20kHz, ultrasonic mixing
Time be 5-8min.
In a kind of preferred embodiment of the present invention, in order to further improve the resistance to of obtained plated film 3D resin lens
Performance is ground, in step (4), the condition of immersion includes：The time of immersion is 20-30min, and the temperature of immersion is 30-35 DEG C.
Present invention also offers a kind of plated film 3D resin lens, the plated film 3D resin lens are by above-mentioned preparation method system
.
The present invention will be described in detail by way of examples below.In following examples, nano-titanium particle is Guangzhou friend
The commercially available product that remote Chemical Co., Ltd. provides, and nano-titanium mean particle size is 20-30nm；Hardening liquid be Xiamen grow sturdily credit science and technology
The trade mark that Co., Ltd provides is VH-10 and VH-1.6 commercially available product.Following film layer wearability detection is with reference to QB 2506-2001
Standard, film layer light transmittance is with reference to QB2457-1999 standards.
Embodiment 1
According to mass ratio it is 1 by nano-titanium particle and octadecylamine:10 are mixed, and obtain modified Nano titanium particle；
By modified Nano titanium particle and alcohol solvent according to mass ratio 5：100 mixing, and 15min is reacted at 55 DEG C, obtain containing oxidation
Titanium nano particle solution；By 100g titanium oxide contained nanometers particle solution, 10g ethylene glycol, 15g butyl titanates, 5g ethylenediamines and
2g hardening liquid VH-10 ultrasonic mixings (frequency of ultrasonic mixing is 10kHz, and the time of ultrasonic mixing is 5min), and at 20 DEG C
10min is reacted, obtains coating liquid；Resin lens are put into taking-up after being soaked in coating liquid, and (time of immersion is 20min, immersion
Temperature be 30 DEG C), carry out baking for the first time and second successively afterwards and toast, obtain plated film 3D resin lens；Wherein, first
The condition of secondary baking includes：The temperature of baking is 50 DEG C, and the time of baking is 10min；The condition of second of baking includes：Baking
Temperature be 30 DEG C, the time of baking is 20min；The film layer wearability of obtained plated film 3D resin lens：Hs=0.45%, film
The light transmittance of layer is 95%.
Embodiment 2
According to mass ratio it is 1 by nano-titanium particle and hexadecylamine:15 are mixed, and obtain modified Nano titanium particle；
By modified Nano titanium particle and ethylene glycol solvent according to mass ratio 8：100 mixing, and 20min is reacted at 70 DEG C, obtain oxygen-containing
Change titanium nano particle solution；By 100g titanium oxide contained nanometers particle solution, 20g ethylene glycol, 25g butyl titanates, 8g ethylenediamines
With 8g hardening liquid VH-10 ultrasonic mixings (frequency of ultrasonic mixing is 20kHz, and the time of ultrasonic mixing is 8min), and at 25 DEG C
Lower reaction 20min, obtains coating liquid；Resin lens are put into taking-up after being soaked in coating liquid, and (time of immersion is 30min, leaching
The temperature of bubble is 35 DEG C), baking for the first time is carried out successively afterwards and second is toasted, and obtains plated film 3D resin lens；Wherein,
The condition once toasted includes：The temperature of baking is 70 DEG C, and the time of baking is 15min；The condition of second of baking includes：Dry
Roasting temperature is 45 DEG C, and the time of baking is 25min；The film layer wearability of obtained plated film 3D resin lens：Hs=0.42%,
The light transmittance of film layer is 93%.
Embodiment 3
According to mass ratio it is 1 by nano-titanium particle and tetradecylamine:12 are mixed, and obtain modified Nano titanium particle；
By modified Nano titanium particle and methanol solvate according to mass ratio 6：100 mixing, and 18min is reacted at 60 DEG C, obtain containing oxidation
Titanium nano particle solution；By 100g titanium oxide contained nanometers particle solution, 15g ethylene glycol, 20g butyl titanates, 7g ethylenediamines and
5g hardening liquid VH-1.6 ultrasonic mixings (frequency of ultrasonic mixing is 15kHz, and the time of ultrasonic mixing is 7min), and at 22 DEG C
15min is reacted, obtains coating liquid；Resin lens are put into taking-up after being soaked in coating liquid, and (time of immersion is 25min, immersion
Temperature be 32 DEG C), carry out baking for the first time and second successively afterwards and toast, obtain plated film 3D resin lens；Wherein, first
The condition of secondary baking includes：The temperature of baking is 60 DEG C, and the time of baking is 12min；The condition of second of baking includes：Baking
Temperature be 35 DEG C, the time of baking is 22min；The film layer wearability of obtained plated film 3D resin lens：Hs=0.46%, film
The light transmittance of layer is 94%.
Comparative example 1
Carried out according to the method for embodiment 3, unlike, by modified Nano titanium particle and alcoholic solvent according to mass ratio 3：
100 mixing, and 10min is reacted at 40 DEG C, obtain titanium oxide contained nanometer particle solution；The film of obtained plated film 3D resin lens
Layer wearability：Hs=0.73%, the light transmittance of film layer is 87%.
Comparative example 2
Carried out according to the method for embodiment 3, unlike, by modified Nano titanium particle and alcoholic solvent according to mass ratio 1：10
Mixing, and 30min is reacted at 80 DEG C, obtain titanium oxide contained nanometer particle solution；The film layer of obtained plated film 3D resin lens
Wearability：Hs=0.81%, the light transmittance of film layer is 88%.
Comparative example 3
Carried out according to the method for embodiment 3, unlike, the condition of baking includes for the first time：The temperature of baking is 40 DEG C,
The time of baking is 8min；The condition of second of baking includes：The temperature of baking is 25 DEG C, and the time of baking is 15min；It is made
Plated film 3D resin lens film layer wearability：Hs=0.93%, the light transmittance of film layer is 84%.
Comparative example 4
Carried out according to the method for embodiment 3, unlike, the condition of baking includes for the first time：The temperature of baking is 75 DEG C,
The time of baking is 18min；The condition of second of baking includes：The temperature of baking is 50 DEG C, and the time of baking is 30min；System
The film layer wearability of the plated film 3D resin lens obtained：Hs=0.92%, the light transmittance of film layer is 83%.
Comparative example 5
Carried out according to the method for embodiment 3, unlike, ethylene glycol, butyl titanate and ethylenediamine are not contained in raw material；
The film layer wearability of obtained plated film 3D resin lens：Hs=0.95%, the light transmittance of film layer is 81%.
The preferred embodiment of the present invention described in detail above, still, the present invention are not limited in above-mentioned embodiment
Detail, in the range of the technology design of the present invention, a variety of simple variants can be carried out to technical scheme, this
A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned embodiment, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can
The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should equally be considered as content disclosed in this invention.
Claims (10)
1. a kind of preparation method of plated film 3D resin lens, it is characterised in that the preparation method includes：
(1) nano-titanium particle is mixed with surface modifier, obtains modified Nano titanium particle；
(2) by modified Nano titanium particle and alcoholic solvent according to mass ratio 5-8：100 mixing, and react 15- at 55-70 DEG C
20min, obtain titanium oxide contained nanometer particle solution；
(3) titanium oxide contained nanometer particle solution, ethylene glycol, butyl titanate, ethylenediamine and hardening liquid are mixed, and in 20-25
10-20min is reacted at DEG C, obtains coating liquid；
(4) resin lens are put into after being soaked in coating liquid and taken out, carried out baking for the first time successively afterwards and second is toasted, obtain
To plated film 3D resin lens；Wherein, the condition of baking includes for the first time：The temperature of baking is 50-70 DEG C, and the time of baking is
10-15min；The condition of second of baking includes：The temperature of baking is 30-45 DEG C, and the time of baking is 20-25min.
2. preparation method according to claim 1, wherein, the surface modifier is selected from octadecylamine, cetyl
One or more in amine, tetradecylamine or lauryl amine.
3. preparation method according to claim 1, wherein, in step (1), nano-titanium particle and surface modifier according to
Mass ratio is 1:10-15 is mixed.
4. preparation method according to claim 1, wherein, one kind in ethanol, ethylene glycol and methanol of alcoholic solvent or
It is a variety of.
5. preparation method according to claim 1, wherein, in step (3), with respect to being received containing titanium oxide for 100 parts by weight
Rice grain solution, the dosage of ethylene glycol are 10-20 parts by weight, and the dosage of butyl titanate is 15-25 parts by weight, the use of ethylenediamine
Measure as 5-8 parts by weight, the dosage of hardening liquid is 2-8 parts by weight.
6. preparation method according to claim 1, wherein, hardening liquid is selected from VH-10 hardening liquids or VH-1.6 hardening liquids.
7. preparation method according to claim 1, wherein, the average grain diameter of nano-titanium particle is 20-30nm.
8. preparation method according to claim 1, wherein, in step (3), mix by the way of ultrasonic mixing, and
The frequency of ultrasonic mixing is 10-20kHz, and the time of ultrasonic mixing is 5-8min.
9. preparation method according to claim 1, wherein, in step (4), the condition of immersion includes：The time of immersion
For 20-30min, the temperature of immersion is 30-35 DEG C.
10. a kind of plated film 3D resin lens, it is characterised in that the plated film 3D resin lens are by any one in claim 1-9
Preparation method described in is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710976629.3A CN107861177A (en) | 2017-10-19 | 2017-10-19 | Plated film 3D resin lens and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710976629.3A CN107861177A (en) | 2017-10-19 | 2017-10-19 | Plated film 3D resin lens and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107861177A true CN107861177A (en) | 2018-03-30 |
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ID=61697281
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| CN201710976629.3A Pending CN107861177A (en) | 2017-10-19 | 2017-10-19 | Plated film 3D resin lens and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2898863Y (en) * | 2005-12-30 | 2007-05-09 | 上海三联(集团)有限公司茂昌眼镜公司 | Superhard antifouling resin spectacles lens |
| CN103257377A (en) * | 2012-02-21 | 2013-08-21 | 江苏华天通科技有限公司 | Coated CR39 resin lens |
| CN103293709A (en) * | 2013-05-08 | 2013-09-11 | 江苏视博光学眼镜有限公司 | Eye protection eyeglass lens and preparation method thereof |
| CN103383473A (en) * | 2013-07-01 | 2013-11-06 | 吉林化工学院 | Novel film-coated antifogging spectacle lens |
| CN105785484A (en) * | 2016-05-06 | 2016-07-20 | 浙江工贸职业技术学院 | Self-cleaning optical resin lens and preparation method therefor |
| CN106674853A (en) * | 2016-12-02 | 2017-05-17 | 安徽长庚光学科技有限公司 | High-light transmission and abrasion-resistant type resin lens sheet plating film material |
-
2017
- 2017-10-19 CN CN201710976629.3A patent/CN107861177A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2898863Y (en) * | 2005-12-30 | 2007-05-09 | 上海三联(集团)有限公司茂昌眼镜公司 | Superhard antifouling resin spectacles lens |
| CN103257377A (en) * | 2012-02-21 | 2013-08-21 | 江苏华天通科技有限公司 | Coated CR39 resin lens |
| CN103293709A (en) * | 2013-05-08 | 2013-09-11 | 江苏视博光学眼镜有限公司 | Eye protection eyeglass lens and preparation method thereof |
| CN103383473A (en) * | 2013-07-01 | 2013-11-06 | 吉林化工学院 | Novel film-coated antifogging spectacle lens |
| CN105785484A (en) * | 2016-05-06 | 2016-07-20 | 浙江工贸职业技术学院 | Self-cleaning optical resin lens and preparation method therefor |
| CN106674853A (en) * | 2016-12-02 | 2017-05-17 | 安徽长庚光学科技有限公司 | High-light transmission and abrasion-resistant type resin lens sheet plating film material |
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Application publication date: 20180330 |
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