CN107858134A - Waterproof anti-corrosion floor adhesive - Google Patents
Waterproof anti-corrosion floor adhesive Download PDFInfo
- Publication number
- CN107858134A CN107858134A CN201711231174.9A CN201711231174A CN107858134A CN 107858134 A CN107858134 A CN 107858134A CN 201711231174 A CN201711231174 A CN 201711231174A CN 107858134 A CN107858134 A CN 107858134A
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- Prior art keywords
- parts
- weight
- adhesive
- waterproof anti
- corrosion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3237—Polyamines aromatic
- C08G18/324—Polyamines aromatic containing only one aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/482—Mixtures of polyethers containing at least one polyether containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
- C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/58—Epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
- C08G18/6484—Polysaccharides and derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6685—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of waterproof anti-corrosion floor adhesive, it is related to adhesive technical field.This waterproof anti-corrosion floor adhesive, include the raw material of following parts by weight：25~60 parts of epoxy resin, 2~25 parts of methyl diphenylene diisocyanate, 2~25 parts of polymethylene multi-phenenyl isocyanate, 3~15 parts of PTMG, 35~50 parts of PPG, 8~30 parts of amido polyethers, expand 25~45 parts of agent of connection, 30~45 parts of cornstarch, 3~5 parts of zinc oxide.The present invention solves the problem of bottom plate adhesive viscosities are inadequate, and waterproof anti-corrosion is not strong enough.
Description
Technical field
The present invention relates to adhesive technical field, especially a kind of waterproof anti-corrosion floor adhesive.
Background technology
PVC plastic athletic floor is widely used in various sports centers, such as：Shuttlecock, table tennis, vollyball, tennis, basket
Ball, handball, the competition and training venue of indoor football, multi-functional venue, all kinds of gymnasiums, dancing room, school, sports goods business
Shop, office, hotel, the space for activities etc. of hospital.Because the activity on plastic floor is very big, people and plastic floor
Exposure it is very big, in active procedure due to abrasion, ponding etc. can corrode the adhesive on floor so as to cause the degumming on floor,
Turnup etc., so bottom plate adhesive is directly connected to the performance such as wear-resisting, corrosion-resistant of plastic floor, select high performance waterproof resistance to
Corrosion adhesive serves very important effect to the service life for extending plastic floor.
The content of the invention
The present invention provides a kind of waterproof anti-corrosion floor adhesive, and it is inadequate that it can solve bottom plate adhesive viscosities, prevents
The problem of water corrosion resistance is not strong enough.
In order to solve the above problems, the technical solution adopted in the present invention is：This waterproof anti-corrosion floor adhesive,
Include the raw material of following parts by weight：25~60 parts of epoxy resin, 2~25 parts of methyl diphenylene diisocyanate, polymethylene is more
2~25 parts of phenyl isocyanate, 3~15 parts of PTMG, 35~50 parts of PPG, 8~30 parts of amido polyethers, expand
Join 25~45 parts of agent, 30~45 parts of cornstarch, 3~5 parts of zinc oxide.
In above-mentioned technical proposal, more specifically technical scheme can also be：By the parts by weight of epoxy resin 25, diphenyl methane
The parts by weight of diisocyanate 2, the parts by weight of polymethylene multi-phenenyl isocyanate 2, the parts by weight of PTMG 3, polycyclic oxygen third
The parts by weight of alkane ethoxylated polyhydric alcohol 35, the parts by weight of end amido polyoxypropylene 8, the parts by weight of diethyl toluene diamine 25, cornstarch
30 parts by weight, the parts by weight of zinc oxide 3 composition.
Further：By the parts by weight of epoxy resin 60, the parts by weight of methyl diphenylene diisocyanate 25, the more benzene of polymethylene
The parts by weight of based isocyanate 25, the parts by weight of PTMG 15, the parts by weight of PPOX ethoxylated polyhydric alcohol 50, hold amido polycyclic
The parts by weight of Ethylene Oxide ether 30, the parts by weight of diethyl toluene diamine 45, the parts by weight of cornstarch 45, the parts by weight of zinc oxide 5 composition.
By adopting the above-described technical solution, the present invention has the advantages that compared with prior art：
The present invention without phenolic aldehyde composition, have no irritating odor, viscous homogeneous, and can rapid curing, waterproof anti-corrosion performance is good.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described：
Embodiment 1：
This waterproof anti-corrosion floor adhesive, the raw material used are as follows：
Epoxy resin 25kg, methyl diphenylene diisocyanate 2kg, polymethylene multi-phenenyl isocyanate 2kg, PolyTHF
Ether 3kg, PPOX ethoxylated polyhydric alcohol 35kg, end amido polyoxypropylene 8kg, diethyl toluene diamine 25kg, corn form sediment
Powder 30kg, zinc oxide 3kg.
The requirement of II class adhesive is detected with reference to as defined in GB/T 14074~1993.The viscosity of the present embodiment is 30
℃0.91Pa.s。
Embodiment 2：
This waterproof anti-corrosion floor adhesive, the raw material used are as follows：
Epoxy resin 45kg, methyl diphenylene diisocyanate 18kg, polymethylene multi-phenenyl isocyanate 18kg, poly- tetrahydrochysene furan
Mutter ether 10kg, PPOX ethoxylated polyhydric alcohol 47kg, holds amido polyoxypropylene 20kg, diethyl toluene diamine 30kg, beautiful
Rice starch 37kg, zinc oxide 5kg.
The requirement of II class adhesive is detected with reference to as defined in GB/T 14074~1993.The viscosity of the present embodiment is 30
℃0.98Pa.s。
Embodiment 3：
This waterproof anti-corrosion floor adhesive, the raw material used are as follows：
Epoxy resin 60kg, methyl diphenylene diisocyanate 25kg, polymethylene multi-phenenyl isocyanate 25kg, poly- tetrahydrochysene furan
Mutter ether 15kg, PPOX ethoxylated polyhydric alcohol 50kg, holds amido polyoxypropylene 30kg, diethyl toluene diamine 45kg, beautiful
Rice starch 45kg, zinc oxide 5kg.
The requirement of II class adhesive is detected with reference to as defined in GB/T 14074~1993.The viscosity of the present embodiment is 30
℃1.24Pa.s。
Claims (3)
1. a kind of waterproof anti-corrosion floor adhesive, it is characterised in that include the raw material of following parts by weight：Epoxy resin 25~
60 parts, 2~25 parts of methyl diphenylene diisocyanate, 2~25 parts of polymethylene multi-phenenyl isocyanate, PTMG 3
~15 parts, 35~50 parts of PPOX ethoxylated polyhydric alcohol, 8~30 parts of end amido polyoxypropylene, diethyl toluene diamine 25
~45 parts, 30~45 parts of cornstarch, 3~5 parts of zinc oxide.
2. waterproof anti-corrosion floor according to claim 1 adhesive, it is characterised in that：By the weight of epoxy resin 25
Part, the parts by weight of methyl diphenylene diisocyanate 2, the parts by weight of polymethylene multi-phenenyl isocyanate 2, the weight of PTMG 3
Measure part, the parts by weight of PPOX ethoxylated polyhydric alcohol 35, the parts by weight of end amido polyoxypropylene 8, the weight of diethyl toluene diamine 25
Measure part, the parts by weight of cornstarch 30, the parts by weight of zinc oxide 3 composition.
3. the waterproof anti-corrosion floor adhesive according to claims 1 or 2, it is characterised in that：By epoxy resin 60
Parts by weight, the parts by weight of methyl diphenylene diisocyanate 25, the parts by weight of polymethylene multi-phenenyl isocyanate 25, PolyTHF
The parts by weight of ether 15, the parts by weight of PPOX ethoxylated polyhydric alcohol 50, the parts by weight of end amido polyoxypropylene 30, diethyltoluene two
The parts by weight of amine 45, the parts by weight of cornstarch 45, the parts by weight of zinc oxide 5 composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711231174.9A CN107858134A (en) | 2017-11-29 | 2017-11-29 | Waterproof anti-corrosion floor adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711231174.9A CN107858134A (en) | 2017-11-29 | 2017-11-29 | Waterproof anti-corrosion floor adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107858134A true CN107858134A (en) | 2018-03-30 |
Family
ID=61704020
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711231174.9A Withdrawn CN107858134A (en) | 2017-11-29 | 2017-11-29 | Waterproof anti-corrosion floor adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107858134A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110229646A (en) * | 2019-05-06 | 2019-09-13 | 阜阳大可新材料股份有限公司 | A kind of fiber board adhesive that water resistance is good |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103013425A (en) * | 2012-12-27 | 2013-04-03 | 南通高盟新材料有限公司 | Adhesive for solid wood floor and preparation method thereof |
| CN104017532A (en) * | 2014-06-27 | 2014-09-03 | 重庆中科力泰高分子材料股份有限公司 | High-strength solvent-free polyurethane adhesive and preparation method thereof |
| CN106146792A (en) * | 2016-05-16 | 2016-11-23 | 天津纽威特橡胶制品股份有限公司 | A kind of one-component moisture-curable polyurethane plastic cement race track material |
| CN106497494A (en) * | 2016-10-14 | 2017-03-15 | 北京工商大学 | A kind of spary coating type no-solvent polyurethane adhesive and preparation method thereof |
-
2017
- 2017-11-29 CN CN201711231174.9A patent/CN107858134A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103013425A (en) * | 2012-12-27 | 2013-04-03 | 南通高盟新材料有限公司 | Adhesive for solid wood floor and preparation method thereof |
| CN104017532A (en) * | 2014-06-27 | 2014-09-03 | 重庆中科力泰高分子材料股份有限公司 | High-strength solvent-free polyurethane adhesive and preparation method thereof |
| CN106146792A (en) * | 2016-05-16 | 2016-11-23 | 天津纽威特橡胶制品股份有限公司 | A kind of one-component moisture-curable polyurethane plastic cement race track material |
| CN106497494A (en) * | 2016-10-14 | 2017-03-15 | 北京工商大学 | A kind of spary coating type no-solvent polyurethane adhesive and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110229646A (en) * | 2019-05-06 | 2019-09-13 | 阜阳大可新材料股份有限公司 | A kind of fiber board adhesive that water resistance is good |
| CN110229646B (en) * | 2019-05-06 | 2021-08-10 | 阜阳大可新材料股份有限公司 | Fiberboard adhesive with good water resistance |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180330 |
|
| WW01 | Invention patent application withdrawn after publication |