CN107858054A - One kind removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating and preparation method thereof - Google Patents
One kind removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating and preparation method thereof Download PDFInfo
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- CN107858054A CN107858054A CN201711103702.2A CN201711103702A CN107858054A CN 107858054 A CN107858054 A CN 107858054A CN 201711103702 A CN201711103702 A CN 201711103702A CN 107858054 A CN107858054 A CN 107858054A
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- electromagnetic radiation
- external wall
- thermal insulating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention provides one kind and removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating, its raw material include following components by weight：30 50 parts of acrylic acid ester emulsion, 25 parts of hollow glass bead, 8 15 parts of diatomite, 20 30 parts of nano titanium oxide, 46 parts of nanometer grade silica, 35 parts of polar mineral tourmaline powder, 12 parts of zinc oxide ultra_fine powderses, 13 parts of titanium dioxide, 35 parts of talcum powder, 46 parts of conducting powder, 0.1 0.3 parts of pH adjusting agent, 0.3 0.5 parts of auxiliary rheological agents, 0.2 0.5 parts of defoamer, 24 parts of coalescents, 0.5 2 parts of thickener, 0.5 1.5 parts of wetting dispersing agent, 14 parts of water-repelling agent, 0.1 0.3 parts of the anti-microbial inoculum of anti-corrosion, 30 50 parts of deionized water.The advantages that present invention also provides its preparation method, and it has except formaldehyde, eliminated the unusual smell, antibacterial and mouldproof, anti-electromagnetic-radiation and release anion, and anti crack performance is high, compression strength is high, heat insulation property is strong, environmental-protecting performance is high.
Description
Technical field
The present invention relates to a kind of exterior coating, and in particular to one kind removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating
And preparation method thereof.
Background technology
The continuous utilization of various energy resources with the continuous development of scientific technology, the continuous enhancing of environmental consciousness.New energy is opened
Hair, energy-saving and emission-reduction are major demands at this stage.New energy development uses along with ocean engineering, blower fan popularization, electric power energy
Many-sided development, the new field of more new environment, for the functional coating that uses with regard to its feature of environmental protection, feature
It there has also been higher requirement.
The content of the invention
It is an object of the invention to provide one kind except formaldehyde, except electromagnetic radiation thermal insulating external wall coating, this kind removes formaldehyde, removed
Electromagnetic radiation thermal insulating external wall coating is using water-and acrylate emulsion as film forming matter, the hollow glass bead of addition, diatom
Soil, nano titanium oxide, nanometer grade silica, polar mineral tourmaline powder, zinc oxide ultra_fine powderses, titanium dioxide, talcum powder, conduction
The functional fillers such as powder, and part of auxiliary is added, the one kind being prepared removes formaldehyde, except electromagnetic radiation thermal insulating external wall applies
Material.This kind eliminates formaldehyde except formaldehyde, except electromagnetic radiation thermal insulating external wall coating not only has, goes to eliminate the unusual smell, antibacterial, mould proof,
Anti-electromagnetic-radiation and release anion, purify the effect of air；And the present invention also has that anti crack performance is high, compression strength is high,
Water resistant abrasive proof, the advantages that nonpoisonous and tasteless, heat insulation property is strong, the feature of environmental protection is high.
It is a kind of except formaldehyde, the preparation side except electromagnetic radiation thermal insulating external wall coating it is a further object of the present invention to provide this
Method.
To realize above-mentioned purpose of the present invention, the present invention is a kind of to remove formaldehyde, except electromagnetic radiation thermal insulating external wall coating uses
Following technical scheme：One kind removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating, its raw material include with the following group by weight
Point：Acrylic acid ester emulsion 30-50 parts, hollow glass bead 2-5 parts, diatomite 8-15 parts, nano titanium oxide 20-30 parts,
Nanometer grade silica 4-6 parts, polar mineral tourmaline powder 3-5 parts, zinc oxide ultra_fine powderses 1-2 parts, titanium dioxide 1-3 parts, talcum powder
3-5 parts, conducting powder 4-6 parts, pH conditioning agent 0.1-0.3 parts, auxiliary rheological agents 0.3-0.5 parts, defoamer 0.2-0.5 parts, into
Film auxiliary agent 2-4 parts, thickener 0.5-2 parts, wetting dispersing agent 0.5-1.5 parts, water-repelling agent 1-4 parts, the anti-microbial inoculum 0.1-0.3 of anti-corrosion
Part, deionized water 30-50 parts.
Further, described hollow glass bead is the hollow beads of 50~150 μm of particle diameter.
Further, described nano titanium oxide is 15~60nm of particle diameter rutile type nano titanic oxide.
Further, described polar mineral tourmaline powder is the tourmaline of the silicate of boracic, and particle diameter is received for 50-500
Rice.
Further, described conducting powder be on the basis of the nano material by activity processing and the doping of the conductive factor at
Reason makes it form firm conductive layer in surface of base.
Further, described thickener is that methylcellulose, one kind in hydroxypropyl methyl cellulose or two kinds are any
The mixture of proportioning.
Further, its preparation method comprises the following steps：
S10, by the amount in formula, sequentially add the anti-microbial inoculum of deionized water, anti-corrosion, wetting agent, pH conditioning agents, auxiliary rheological agents and
Half defoamer, middling speed（1000-1200r/min）Stir 3-5min；
S11, emulsion, hollow glass bead, diatomite, nano titanium oxide, nanoscale dioxy are added on the basis of step S10
SiClx, polar mineral tourmaline powder, zinc oxide ultra_fine powderses, titanium dioxide, talcum powder, conducting powder, at a high speed（2500-3000r/min）
Scattered 20-30min；
S12, then in low speed（600-800 r/min）Stirring is lower to add coalescents, water-repelling agent, second half defoamer, stirring
10-20min, appropriate thickener adjusting coating is finally added to suitable viscosity（85-90KU）, filter produce institute must a finished product one kind remove
Formaldehyde, the thermal insulating external wall coating for eliminating electromagnetic radiation.
Beneficial effects of the present invention：
1st, it is a kind of in the present invention to remove formaldehyde, except the nano level nanometer titanium dioxide of composition in electromagnetic radiation thermal insulating external wall coating
Titanium plays degradable organic pollutant and antibacterial action, by organic pollution it is degradable be water and inorganic ions, remove formaldehyde, go
Except stink, so as in a short time with regard to bacterium can be killed；The effect for more reaching sterilization is combined together with the anti-microbial inoculum of anti-corrosion；
2nd, nanometer grade silica can increase cracking resistance, the conducting powder of favorable dispersibility, it is formed firmly in matrix surface
Conductive layer, make it have electric conductivity, electromagnetic radiation can be effectively eliminated；
3rd, polar mineral tourmaline powder can discharge natural negative ion, so that producing more anions around the house；
If the 4th, hollow glass bead, diatomaceous so that it has good heat-insulation and heat-preservation；Nano titanium oxide shielding is purple
Outside line effect is strong, prevents the infringement of ultraviolet, improves the service life of coating.Meanwhile its higher hardness, density, dielectric
Constant and refractive index, the covering power and tinting strength, tinting power of coating are favorably improved, and have good reflection to the heat radiation in sunlight
Effect；
5th, this kind removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating is using water-and acrylate emulsion as film forming matter, addition
Hollow glass bead, diatomite, nano titanium oxide, nanometer grade silica, polar mineral tourmaline powder, zinc oxide are micro-
The functional fillers such as powder, titanium dioxide, talcum powder, conducting powder, and part of auxiliary is added, the one kind being prepared removes formaldehyde, except electricity
Magnetic radiation thermal insulating external wall coating.This kind except formaldehyde, except electromagnetic radiation thermal insulating external wall coating not only have eliminate formaldehyde,
Go to eliminate the unusual smell, be antibacterial, mould proof, anti-electromagnetic-radiation and release anion, purifying the effect of air；And the present invention also has anticracking
Performance height, compression strength height, water resistant abrasive proof, the advantages that nonpoisonous and tasteless, heat insulation property is strong, the feature of environmental protection is high.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.The specific embodiments described herein are merely illustrative of the present invention, is not used to limit
The present invention.
Embodiment 1
One kind removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating, its raw material include following components by weight：Acrylate
30 parts of emulsion, 2 parts of hollow glass bead, 8 parts of diatomite, 20 parts of nano titanium oxide, 4 parts of nanometer grade silica, polarity ore deposit
3 parts of thing tourmaline powder, 1 part of zinc oxide ultra_fine powderses, 1 part of titanium dioxide, 3 parts of talcum powder, 4 parts of conducting powder, 0.1 part of pH conditioning agents, stream
Become 0.3 part of auxiliary agent, 0.2 part of defoamer, 2 parts of coalescents, 0.5 part of thickener, 0.5 part of wetting dispersing agent, 1 part of water-repelling agent, anti-
Rotten anti-0.1 part of microbial inoculum, 30 parts of deionized water.
Described hollow glass bead is the hollow beads of 50 μm of particle diameter.
Described nano titanium oxide is the nm of particle diameter 15 rutile type nano titanic oxide.
Described polar mineral tourmaline powder is the tourmaline of the silicate of boracic, and particle diameter is 50 nanometers.
Described conducting powder be on the basis of nano material by activity processing and the conductive factor doping treatment make its
Surface of base forms firm conductive layer.
Described thickener is methylcellulose.
Its preparation method comprises the following steps：
S10, by the amount in formula, sequentially add the anti-microbial inoculum of deionized water, anti-corrosion, wetting agent, pH conditioning agents, auxiliary rheological agents and
Half defoamer, middling speed（1000-1200r/min）Stir 3min；
S11, emulsion, hollow glass bead, diatomite, nano titanium oxide, nanoscale dioxy are added on the basis of step S10
SiClx, polar mineral tourmaline powder, zinc oxide ultra_fine powderses, titanium dioxide, talcum powder, conducting powder, at a high speed（2500-3000r/min）
Scattered 20min；
S12, then in low speed（600-800 r/min）Stirring is lower to add coalescents, water-repelling agent, second half defoamer, stirring
10min, appropriate thickener adjusting coating is finally added to suitable viscosity（85-90KU）, filter and produce that institute must finished product be a kind of removes first
Aldehyde, the thermal insulating external wall coating for eliminating electromagnetic radiation.
Embodiment 2
One kind removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating, its raw material include following components by weight：Acrylate
50 parts of emulsion, 5 parts of hollow glass bead, 15 parts of diatomite, 30 parts of nano titanium oxide, 6 parts of nanometer grade silica, polarity
5 parts of mineral tourmaline powder, 2 parts of zinc oxide ultra_fine powderses, 3 parts of titanium dioxide, 5 parts of talcum powder, 6 parts of conducting powder, 0.3 part of pH conditioning agents,
0.5 part of auxiliary rheological agents, 0.5 part of defoamer, 4 parts of coalescents, 2 parts of thickener, 1.5 parts of wetting dispersing agent, 4 parts of water-repelling agent,
0.3 part of the anti-microbial inoculum of anti-corrosion, 50 parts of deionized water.
Described hollow glass bead is the hollow beads of 150 μm of particle diameter.
Described nano titanium oxide is particle diameter 60nm rutile type nano titanic oxide.
Described polar mineral tourmaline powder is the tourmaline of the silicate of boracic, and particle diameter is 500 nanometers.
Described conducting powder be on the basis of nano material by activity processing and the conductive factor doping treatment make its
Surface of base forms firm conductive layer.
Described thickener is hydroxypropyl methyl cellulose.
Its preparation method comprises the following steps：
S10, by the amount in formula, sequentially add the anti-microbial inoculum of deionized water, anti-corrosion, wetting agent, pH conditioning agents, auxiliary rheological agents and
Half defoamer, middling speed（1000-1200r/min）Stir 5min；
S11, emulsion, hollow glass bead, diatomite, nano titanium oxide, nanoscale dioxy are added on the basis of step S10
SiClx, polar mineral tourmaline powder, zinc oxide ultra_fine powderses, titanium dioxide, talcum powder, conducting powder, at a high speed（2500-3000r/min）
Scattered 30min；
S12, then in low speed（600-800 r/min）Stirring is lower to add coalescents, water-repelling agent, second half defoamer, stirring
20min, appropriate thickener adjusting coating is finally added to suitable viscosity（85-90KU）, filter and produce that institute must finished product be a kind of removes first
Aldehyde, the thermal insulating external wall coating for eliminating electromagnetic radiation.
Embodiment 3
One kind removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating, its raw material include following components by weight：Acrylic acid
40 parts of ester emulsion, 4 parts of hollow glass bead, 12 parts of diatomite, 25 parts of nano titanium oxide, 5 parts of nanometer grade silica, pole
4 parts of property mineral tourmaline powder, 1.5 parts of zinc oxide ultra_fine powderses, 2 parts of titanium dioxide, 4 parts of talcum powder, 5 parts of conducting powder, pH conditioning agents 0.2
Part, 0.4 part of auxiliary rheological agents, 0.3 part of defoamer, 3 parts of coalescents, 0.8 part of thickener, 0.9 part of wetting dispersing agent, water-repelling agent 3
Part, 0.2 part of the anti-microbial inoculum of anti-corrosion, 35 parts of deionized water.
Described hollow glass bead is the hollow beads of 80 μm of particle diameter.
Described nano titanium oxide is particle diameter 30nm rutile type nano titanic oxide.
Described polar mineral tourmaline powder is the tourmaline of the silicate of boracic, and particle diameter is 300 nanometers.
Described conducting powder be on the basis of nano material by activity processing and the conductive factor doping treatment make its
Surface of base forms firm conductive layer.
Described thickener is two kinds of methylcellulose, hydroxypropyl methyl cellulose mixtures arbitrarily matched.
Its preparation method comprises the following steps：
S10, by the amount in formula, sequentially add the anti-microbial inoculum of deionized water, anti-corrosion, wetting agent, pH conditioning agents, auxiliary rheological agents and
Half defoamer, middling speed（1000-1200r/min）Stir 4min；
S11, emulsion, hollow glass bead, diatomite, nano titanium oxide, nanoscale dioxy are added on the basis of step S10
SiClx, polar mineral tourmaline powder, zinc oxide ultra_fine powderses, titanium dioxide, talcum powder, conducting powder, at a high speed（2500-3000r/min）
Scattered 25min；
S12, then in low speed（600-800 r/min）Stirring is lower to add coalescents, water-repelling agent, second half defoamer, stirring
15min, appropriate thickener adjusting coating is finally added to suitable viscosity（85-90KU）, filter and produce that institute must finished product be a kind of removes first
Aldehyde, the thermal insulating external wall coating for eliminating electromagnetic radiation.
Claims (7)
1. one kind removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating, it is characterised in that its raw material includes following by weight
Component：Acrylic acid ester emulsion 30-50 parts, hollow glass bead 2-5 parts, diatomite 8-15 parts, nano titanium oxide 20-30
Part, nanometer grade silica 4-6 parts, polar mineral tourmaline powder 3-5 parts, zinc oxide ultra_fine powderses 1-2 parts, titanium dioxide 1-3 parts, talcum
Powder 3-5 parts, conducting powder 4-6 parts, pH conditioning agent 0.1-0.3 parts, auxiliary rheological agents 0.3-0.5 parts, defoamer 0.2-0.5 parts,
Coalescents 2-4 parts, thickener 0.5-2 parts, wetting dispersing agent 0.5-1.5 parts, water-repelling agent 1-4 parts, the anti-microbial inoculum 0.1-0.3 of anti-corrosion
Part, deionized water 30-50 parts.
2. one kind according to claim 1 removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating, it is characterised in that：Institute
The hollow glass bead stated is the hollow beads of 50~150 μm of particle diameter.
3. one kind according to claim 1 removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating, it is characterised in that：Institute
The nano titanium oxide stated is 15~60nm of particle diameter rutile type nano titanic oxide.
4. one kind according to claim 1 removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating, it is characterised in that：Institute
The polar mineral tourmaline powder stated is the tourmaline of the silicate of boracic, and particle diameter is 50-500 nanometers.
5. one kind according to claim 1 removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating, it is characterised in that：Institute
The conducting powder stated is to make it in surface of base shape by the doping treatment of activity processing and the conductive factor on the basis of nano material
Into firm conductive layer.
6. one kind according to claim 1 removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating, it is characterised in that：Institute
The thickener stated is methylcellulose, one kind in hydroxypropyl methyl cellulose or two kinds of mixtures arbitrarily matched.
7. one kind according to claim 1 removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating, it is characterised in that：Its
Preparation method comprises the following steps：
S10, by the amount in formula, sequentially add the anti-microbial inoculum of deionized water, anti-corrosion, wetting agent, pH conditioning agents, auxiliary rheological agents and
Half defoamer, middling speed（1000-1200r/min）Stir 3-5min；
S11, emulsion, hollow glass bead, diatomite, nano titanium oxide, nanoscale dioxy are added on the basis of step S10
SiClx, polar mineral tourmaline powder, zinc oxide ultra_fine powderses, titanium dioxide, talcum powder, conducting powder, at a high speed（2500-3000r/min）
Scattered 20-30min；
S12, then in low speed（600-800 r/min）Stirring is lower to add coalescents, water-repelling agent, second half defoamer, stirring
10-20min, appropriate thickener adjusting coating is finally added to suitable viscosity（85-90KU）, filter produce institute must a finished product one kind remove
Formaldehyde, the thermal insulating external wall coating for eliminating electromagnetic radiation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711103702.2A CN107858054A (en) | 2017-11-10 | 2017-11-10 | One kind removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711103702.2A CN107858054A (en) | 2017-11-10 | 2017-11-10 | One kind removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107858054A true CN107858054A (en) | 2018-03-30 |
Family
ID=61700003
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711103702.2A Pending CN107858054A (en) | 2017-11-10 | 2017-11-10 | One kind removes formaldehyde, except electromagnetic radiation thermal insulating external wall coating and preparation method thereof |
Country Status (1)
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| CN (1) | CN107858054A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110791160A (en) * | 2019-11-12 | 2020-02-14 | 哈尔滨盛世康虹生物技术有限公司 | Graphene liquid-state brushing type electro-catalyst diatom ooze and preparation method and application thereof |
| CN115138195A (en) * | 2021-08-27 | 2022-10-04 | 上海清悠空气净化科技有限公司 | Antibacterial formaldehyde-removing purifying agent and preparation method thereof |
-
2017
- 2017-11-10 CN CN201711103702.2A patent/CN107858054A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110791160A (en) * | 2019-11-12 | 2020-02-14 | 哈尔滨盛世康虹生物技术有限公司 | Graphene liquid-state brushing type electro-catalyst diatom ooze and preparation method and application thereof |
| CN115138195A (en) * | 2021-08-27 | 2022-10-04 | 上海清悠空气净化科技有限公司 | Antibacterial formaldehyde-removing purifying agent and preparation method thereof |
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