CN107856379B - A kind of moulding process of basalt fibre enhancing phenolic board sandwich PMI composite plate - Google Patents
A kind of moulding process of basalt fibre enhancing phenolic board sandwich PMI composite plate Download PDFInfo
- Publication number
- CN107856379B CN107856379B CN201710961489.2A CN201710961489A CN107856379B CN 107856379 B CN107856379 B CN 107856379B CN 201710961489 A CN201710961489 A CN 201710961489A CN 107856379 B CN107856379 B CN 107856379B
- Authority
- CN
- China
- Prior art keywords
- basalt fibre
- phenolic board
- pmi
- fibre enhancing
- composite plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/065—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/42—Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/164—Drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/164—Drying
- B32B2038/166—Removing moisture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2266/00—Composition of foam
- B32B2266/02—Organic
- B32B2266/0214—Materials belonging to B32B27/00
- B32B2266/0242—Acrylic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/718—Weight, e.g. weight per square meter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/72—Density
Abstract
The invention discloses a kind of basalt fibre enhancing phenolic aldehyde sandwich composite board and its moulding process.Basalt fibre enhancing phenolic board, PMI cystosepiment and the basalt fibre of lower layer including upper layer enhance phenolic board, and the basalt fibre on the upper layer enhances between phenolic board and the PMI cystosepiment and the basalt fibre of the lower layer enhances between phenolic board and the PMI cystosepiment by adhesive layer bonding.The present invention is using the phenolic board that basalt fibre enhances as upper and lower panel, using PMI cystosepiment as core material, has higher fire protecting performance, contacts open fire not smoke substantially, and do not have combustion phenomena.Technique is divided into two steps, can effectively solve the problems, such as to will appear in conventional molding processes, be simple and efficient low-risk, and the utilization rate of the PMI foamed material of higher cost can be improved by the moulding process of the composite plate different from conventional moulding process.
Description
Technical field
The present invention relates to fireproof structural material technical field, specifically a kind of basalt fibre enhances phenolic board
The moulding process of sandwich PMI composite plate.
Background technique
Existing sandwich composite board, such as aluminum honeycomb panel, light core steel, there is certain Pros and Cons, such as aluminum honeycomb
Plate is heavier, and high temperature lower panel can be completely disengaged with core material；Light core hardness of steel is too low, is unable to satisfy requirement.
Currently, basalt fibre reinforced epoxy plate sandwich PMI composite plate has been had comprehensive well using flame retardant epoxy
Close performance.This battenboard is made using the PMI foamed material of high-strength light as core material with the epoxy plate of basalt fibre enhancing
For upper and lower panel, formed by lamination or vacuum bag technique one-pass molding, with good fire protecting performance and high-strength light
Performance.But this battenboard still will appear a large amount of white cigarette when contacting open fire, and have the combustion phenomena of short time,
Therefore it is not used as fire protecting performance and requires higher material.
Summary of the invention
The present invention aiming at the shortcomings in the prior art, it is compound to provide a kind of basalt fibre enhancing phenolic board sandwich PMI
The moulding process of plate.
In order to solve the above technical problems, the present invention is addressed by following technical proposals: a kind of basalt fibre enhancing
The moulding process of phenolic board sandwich PMI composite plate, it includes the profound of upper layer which, which enhances phenolic board sandwich PMI composite plate,
Military rock fibre reinforced phenolic plate, PMI cystosepiment and the basalt fibre of lower layer enhance phenolic board, the basalt on the upper layer
Between fibre reinforced phenolic plate and the PMI cystosepiment and the basalt fibre of the lower layer enhances phenolic board and the PMI
It is bonded by adhesive layer between cystosepiment；
The step of its moulding process, is as follows:
One, production basalt fibre enhances phenolic board: 1., prepare mold, glues adhesive tape in Mould operation face surrounding, then
The coating release agent on the operating surface；2., the laying on Mould operation face；3., tile release cloth above laying；4., demoulding
Corresponding auxiliary material and diversion pipe are spread above cloth；5., tear adhesive tape, sealing joint strip is pasted to the ground for tearing adhesive tape
Side cuts exhaust tube and forms No.1 exhaust tube, and No.1 exhaust tube is connect with diversion pipe and at least 50cm stays in mold exterior, together
When No.1 exhaust tube is connect with the sealing joint strip on mold with sealing joint strip；6., vacuum bag film pasted on sealing joint strip
Form closed system；7., cut exhaust tube and form No. two exhaust tubes, with No. two exhaust tubes connection pumped vacuum systems and stay in mold
External No.1 exhaust tube forms the pipeline that can pump closed system inner air；8., open vacuum pump, to entire obturator
System vacuumizes, and examines vacuum degree whether to reach -0.095MPa or more and stablizes；9., entire closed system is put into baking oven baking
Solidification；10., baking after the completion of, close vacuum pump, take out molds and products, demoulding obtain basalt fibre enhancing phenolic board；
Two, bond:, cut basalt fibre enhancing phenolic board, by the basalt fibre cut enhance phenolic board put
Enter baking 12-24h in the baking oven that temperature is 80-100 DEG C and removes free aldehyde and water；, prepare laminated mould, coating release agent；⑬,
Spread basalt fibre enhancing phenolic board, adhesive layer and PMI cystosepiment respectively by product structure on mold；, molding；⑮,
Lamination solidification；, cut to obtain product.
In above-mentioned technical proposal, it is preferred that when step 2. middle berth be fiber dry cloth when, step 4. in auxiliary material be water conservancy diversion
Net, and step 8. after, resin is imported in closed system by diversion pipe.
In above-mentioned technical proposal, it is preferred that when step 2. middle berth be phenolic aldehyde prepreg when, step 4. in auxiliary material be
Gas felt.
In above-mentioned technical proposal, it is preferred that when step 2. use hand paste process and paving be fiber dry cloth when, step 4. in
Auxiliary material be airfelt.
In above-mentioned technical proposal, it is preferred that the adhesive layer is epoxy jelly membrane.
In above-mentioned technical proposal, it is preferred that the adhesive layer is that epoxy resin fills surface felt.
In above-mentioned technical proposal, it is preferred that the adhesive layer is that unsaturated polyester resin fills surface felt.
The beneficial effects of the present invention are: the present invention, using PMI cystosepiment as core material, PMI cystosepiment is different from traditional phenol
Aldehyde cystosepiment, polystyrene foam plate etc. have the up to compression strength of 4MPa and less than 150kg/m3Density, lightweight is high
By force；Enhance phenolic board as upper and lower panel using basalt fibre, chance open fire does not burn and smoke amount is few, can protect well
PMI cystosepiment, and the biggish defect of PMI cystosepiment brittleness is solved, to reach the characteristic of non-ignitable low cigarette and high-strength light.
However, phenolic cure can generate moisture in the process, and PMI cystosepiment chance water will cause strength reduction, furthermore phenolic aldehyde
There are free aldehyde to need to remove in forming process to body nocuousness.Therefore, traditional one-pass molding scheme is not all suitable for
The production of basalt fibre sandwich PMI composite plate.The present invention uses the technical solution of post forming, and it is fine that the first step completes basalt
After the production of dimension enhancing phenolic board, by baking drop low-free formaldehyde and most of moisture can be removed, reduce moisture to PMI foam
The influence of plate, to solve the difficult point in forming process.In addition, basalt fibre enhance phenolic board compared to PMI cystosepiment at
This is lower, and underproof basalt fibre can be enhanced to phenolic board removal before second step adhesion process, to improve PMI bubble
The utilization rate of foam plate reduces risk.
Specific embodiment
Present invention is further described in detail With reference to embodiment: a kind of basalt fibre enhancing phenolic board
Sandwich PMI composite plate, basalt fibre enhancing phenolic board 1, PMI cystosepiment 2 and the basalt fibre of lower layer including upper layer
Enhance phenolic board 1, the basalt fibre on the upper layer enhances between phenolic board 1 and the PMI cystosepiment 2 and the lower layer
Basalt fibre enhancing phenolic board 1 and the PMI cystosepiment 2 between bonded by adhesive layer 3.
(moulding process of embodiment 1, basalt fibre enhancing phenolic board sandwich PMI composite plate)
The following steps are included:
One, dry vacuum technique production basalt fibre enhances phenolic board:
(1) prepare mold, glue adhesive tape, then the coating release agent on the operating surface in Mould operation face surrounding；
(2) laying on Mould operation face, paving is the dry cloth of fiber；
(3) tile release cloth above laying；
(4) flow-guiding screen and diversion pipe are spread above release cloth；
(5) adhesive tape is torn, sealing joint strip is pasted to the place for tearing adhesive tape, exhaust tube is cut and forms No.1
Exhaust tube, No.1 exhaust tube is connect with diversion pipe and at least 50cm stays in mold exterior, while being taken out No.1 with sealing joint strip
Tracheae is connect with the sealing joint strip on mold；
(6) vacuum bag film is pasted and forms closed system on sealing joint strip；
(7) it cuts exhaust tube and forms No. two exhaust tubes, with No. two exhaust tube connection pumped vacuum systems and stay in mold exterior
No.1 exhaust tube, the pipeline of closed system inner air can be pumped by being formed；
(8) vacuum pump is opened, entire closed system is vacuumized, examines whether vacuum degree reaches -0.095MPa or more simultaneously
Stablize；
(9) resin is imported in closed system by diversion pipe；
(10) entire closed system is put into baking oven baking-curing, and one side baking-curing (60 DEG C -80 DEG C/2-4h), one
While continuing to vacuumize；
(11) after the completion of toasting, vacuum pump is closed, takes out molds and products, demoulding obtains basalt fibre enhancing phenolic aldehyde
Plate.
Two, laminating technology bonds:
(12) basalt fibre enhancing phenolic board is cut into suitable dimension, is put into 80-100 DEG C of baking oven baking 12-24h and removes
Remove free aldehyde and water；
(13) prepare laminated mould, coating release agent；
(14) by product structure paving basalt fibre enhancing phenolic board, adhesive layer and PMI cystosepiment on mold；
(15) it molds；
(16) solidify (120-130 DEG C/2-4h)；
(17) it cuts to obtain product.
Adhesive layer is epoxy jelly membrane or epoxy resin fills surface felt or unsaturated polyester resin fills surface felt, wherein
It is that hand pastes liquid epoxies filling surface felt that epoxy resin, which fills surface felt, and it is hand paste that unsaturated polyester resin, which fills surface felt,
Liquid unsaturated polyester resin fills surface felt.
(moulding process of embodiment 2, basalt fibre enhancing phenolic board sandwich PMI composite plate)
The following steps are included:
One, prepreg vacuum technology production basalt fibre enhances phenolic board:
(1) prepare mold, glue adhesive tape, then the coating release agent on the operating surface in Mould operation face surrounding；
(2) laying on Mould operation face, paving is phenolic aldehyde prepreg；
(3) tile release cloth above laying；
(4) airfelt and diversion pipe are spread above release cloth；
(5) adhesive tape is torn, sealing joint strip is pasted to the place for tearing adhesive tape, exhaust tube is cut and forms No.1
Exhaust tube, No.1 exhaust tube is connect with diversion pipe and at least 50cm stays in mold exterior, while being taken out No.1 with sealing joint strip
Tracheae is connect with the sealing joint strip on mold；
(6) vacuum bag film is pasted and forms closed system on sealing joint strip；
(7) it cuts exhaust tube and forms No. two exhaust tubes, with No. two exhaust tube connection pumped vacuum systems and stay in mold exterior
No.1 exhaust tube, the pipeline of closed system inner air can be pumped by being formed；
(8) vacuum pump is opened, entire closed system is vacuumized, examines whether vacuum degree reaches -0.095MPa or more simultaneously
Stablize；
(9)；Entire closed system is put into baking oven baking-curing, and one side baking-curing (60 DEG C -80 DEG C/2-4h), one
While continuing to vacuumize；
(10) after the completion of toasting, vacuum pump is closed, takes out molds and products, demoulding obtains basalt fibre enhancing phenolic aldehyde
Plate.
Two, laminating technology bonds:
(11) basalt fibre enhancing phenolic board is cut into suitable dimension, is put into 80-100 DEG C of baking oven baking 12-24h and removes
Remove free aldehyde and water；
(12) prepare laminated mould, coating release agent；
(13) by product structure paving basalt fibre enhancing phenolic board, adhesive layer and PMI cystosepiment on mold；
(14) it molds；
(15) solidify (120-130 DEG C/2-4h)；
(16) it cuts to obtain product.
Adhesive layer is epoxy jelly membrane or epoxy resin fills surface felt or unsaturated polyester resin fills surface felt, wherein
It is that hand pastes liquid epoxies filling surface felt that epoxy resin, which fills surface felt, and it is hand paste that unsaturated polyester resin, which fills surface felt,
Liquid unsaturated polyester resin fills surface felt.
(moulding process of embodiment 3, basalt fibre enhancing phenolic board sandwich PMI composite plate)
The following steps are included:
One, hand paste vacuum technology production basalt fibre enhances phenolic board:
(1) prepare mold, glue adhesive tape, then the coating release agent on the operating surface in Mould operation face surrounding；
(2) laying on mold, laying refer specifically to the hand paste dry cloth of fiber；
(3) tile release cloth above laying；
(4) airfelt and diversion pipe are spread above release cloth；
(5) adhesive tape is torn, sealing joint strip is pasted to the place for tearing adhesive tape, exhaust tube is cut and forms No.1
Exhaust tube, No.1 exhaust tube is connect with diversion pipe and at least 50cm stays in mold exterior, while being taken out No.1 with sealing joint strip
Tracheae is connect with the sealing joint strip on mold；
(6) vacuum bag film is pasted and forms closed system on sealing joint strip；
(7) it cuts exhaust tube and forms No. two exhaust tubes, with No. two exhaust tube connection pumped vacuum systems and stay in mold exterior
No.1 exhaust tube, the pipeline of closed system inner air can be pumped by being formed；
(8) vacuum pump is opened, entire closed system is vacuumized, examines whether vacuum degree reaches -0.095MPa or more simultaneously
Stablize；
(9)；Entire closed system is put into baking oven baking-curing, and one side baking-curing (60 DEG C -80 DEG C/2-4h), one
While continuing to vacuumize
(10) after the completion of toasting, vacuum pump is closed, takes out molds and products, demoulding obtains basalt fibre enhancing phenolic aldehyde
Plate.
Two, laminating technology bonds:
(11) basalt fibre enhancing phenolic board is cut into suitable dimension, is put into 80-100 DEG C of baking oven baking 12-24h and removes
Remove free aldehyde and water；
(12) prepare laminated mould, coating release agent；
(13) by product structure paving basalt fibre enhancing phenolic board, adhesive layer and PMI cystosepiment on mold；
(14) it molds；
(15) solidify (120-130 DEG C/2-4h)；
(16) it cuts to obtain product.
Adhesive layer is epoxy jelly membrane or epoxy resin fills surface felt or unsaturated polyester resin fills surface felt, wherein
It is that hand pastes liquid epoxies filling surface felt that epoxy resin, which fills surface felt, and it is hand paste that unsaturated polyester resin, which fills surface felt,
Liquid unsaturated polyester resin fills surface felt.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
Invention is explained in detail, those skilled in the art should understand that: it still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features；And these modification or
Replacement, the spirit and scope for technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution.
Claims (7)
1. a kind of moulding process of basalt fibre enhancing phenolic board sandwich PMI composite plate, it is characterised in that: the basalt fibre
Enhancing phenolic board sandwich PMI composite plate includes basalt fibre enhancing phenolic board (1), PMI cystosepiment (2) and the lower layer on upper layer
Basalt fibre enhance phenolic board (1), basalt fibre enhancing phenolic board (1) and the PMI cystosepiment on the upper layer
(2) pass through bonding between and between the basalt fibre of lower layer enhancing phenolic board (1) and the PMI cystosepiment (2)
Layer (3) bonding；
The step of its moulding process, is as follows:
One, production basalt fibre enhances phenolic board: 1., preparing mold, glues adhesive tape in Mould operation face surrounding, then at this
Coating release agent on operating surface；2., the laying on Mould operation face；3., tile release cloth above laying；4., on release cloth
Side spreads corresponding auxiliary material and diversion pipe；5., tear adhesive tape, sealing joint strip is pasted to the place for tearing adhesive tape, cut out
Exhaust tube is taken to form No.1 exhaust tube, No.1 exhaust tube is connect with diversion pipe and at least 50cm stays in mold exterior, is used simultaneously
No.1 exhaust tube is connect by sealing joint strip with the sealing joint strip on mold；6., vacuum bag film pasted formed on sealing joint strip
Closed system；7., cut exhaust tube and form No. two exhaust tubes, with No. two exhaust tubes connection pumped vacuum systems and stay in mold exterior
No.1 exhaust tube, the pipeline of closed system inner air can be pumped by being formed；8., open vacuum pump, to entire closed system take out
Vacuum is examined vacuum degree whether to reach -0.095MPa or more and is stablized；9., entire closed system is put into baking oven baking-curing；
10., baking after the completion of, close vacuum pump, take out molds and products, demoulding obtain basalt fibre enhancing phenolic board；
Two, bond:, cut basalt fibre enhancing phenolic board, by the basalt fibre cut enhance phenolic board be put into temperature
Degree removes free aldehyde and water for baking 12-24h in 80-100 DEG C of baking oven；, prepare laminated mould, coating release agent；, in mould
Spread basalt fibre enhancing phenolic board, adhesive layer and PMI cystosepiment on tool respectively by product structure；, molding；, lamination
Solidification；, cut to obtain product.
2. a kind of moulding process of basalt fibre enhancing phenolic board sandwich PMI composite plate according to claim 1, special
Sign is: when step 2. middle berth be fiber dry cloth when, step 4. in auxiliary material be flow-guiding screen, and step 8. after, pass through
Diversion pipe imports resin in closed system.
3. a kind of moulding process of basalt fibre enhancing phenolic board sandwich PMI composite plate according to claim 1, special
Sign is: when step 2. middle berth be phenolic aldehyde prepreg when, step 4. in auxiliary material be airfelt.
4. a kind of moulding process of basalt fibre enhancing phenolic board sandwich PMI composite plate according to claim 1, special
Sign is: when step 2. use hand paste process and paving be fiber dry cloth when, step 4. in auxiliary material be airfelt.
5. a kind of molding work of basalt fibre enhancing phenolic board sandwich PMI composite plate according to Claims 2 or 3 or 4
Skill, it is characterised in that: the adhesive layer is epoxy jelly membrane.
6. a kind of molding work of basalt fibre enhancing phenolic board sandwich PMI composite plate according to Claims 2 or 3 or 4
Skill, it is characterised in that: the adhesive layer is that epoxy resin fills surface felt.
7. a kind of molding work of basalt fibre enhancing phenolic board sandwich PMI composite plate according to Claims 2 or 3 or 4
Skill, it is characterised in that: the adhesive layer is that unsaturated polyester resin fills surface felt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710961489.2A CN107856379B (en) | 2017-10-17 | 2017-10-17 | A kind of moulding process of basalt fibre enhancing phenolic board sandwich PMI composite plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710961489.2A CN107856379B (en) | 2017-10-17 | 2017-10-17 | A kind of moulding process of basalt fibre enhancing phenolic board sandwich PMI composite plate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107856379A CN107856379A (en) | 2018-03-30 |
| CN107856379B true CN107856379B (en) | 2019-11-01 |
Family
ID=61698686
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710961489.2A Active CN107856379B (en) | 2017-10-17 | 2017-10-17 | A kind of moulding process of basalt fibre enhancing phenolic board sandwich PMI composite plate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107856379B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109604652B (en) * | 2018-11-20 | 2021-01-05 | 浙江中科恒泰新材料科技有限公司 | Manufacturing method of PMI foam sandwich composite board containing fiber material |
| CN112430376A (en) * | 2020-11-23 | 2021-03-02 | 四川玄武岩纤维新材料研究院(创新中心) | Basalt fiber composite material and preparation method and application thereof |
| CN113787784A (en) * | 2021-09-15 | 2021-12-14 | 江苏祥泰电力实业有限公司 | Light anti-aging composite board and bird-proof baffle plate assembly adopting same |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3304882A1 (en) * | 1983-02-12 | 1984-08-16 | Röhm GmbH, 6100 Darmstadt | METHOD FOR PRODUCING A FOAM COMPOSITE BODY |
| CN102848622B (en) * | 2012-09-06 | 2015-10-21 | 江苏兆鋆新材料科技有限公司 | A kind of have sandwich material of PMI foam core material and preparation method thereof |
| CN104742460A (en) * | 2015-04-15 | 2015-07-01 | 洛阳双瑞橡塑科技有限公司 | Passenger car floor of sandwich structure |
| CN105563970A (en) * | 2015-04-20 | 2016-05-11 | 广州金发碳纤维新材料发展有限公司 | Composite structure with PMI sandwich as well as preparation method and application of composite structure |
| CN106337508A (en) * | 2016-08-24 | 2017-01-18 | 湖南大学 | Basalt fiber reinforced foam base composite heat-preservation layer and producing method thereof |
-
2017
- 2017-10-17 CN CN201710961489.2A patent/CN107856379B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN107856379A (en) | 2018-03-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107856379B (en) | A kind of moulding process of basalt fibre enhancing phenolic board sandwich PMI composite plate | |
| CN101830095B (en) | Composite material member with surface function layer and VIMP preparation method thereof | |
| CN106608056B (en) | A kind of phenolic aldehyde panel honeycomb sandwich construction part forming method | |
| CN102529109B (en) | Method for integrally molding wind driven generator blade shell and front edge bonding angle | |
| ATE413962T1 (en) | METHOD FOR PRODUCING A SANDWICH COMPONENT WITH A HONEYCOMB CORE | |
| CN102350752B (en) | Self-guide flow type core material and processing method thereof | |
| CN103737946B (en) | A kind of forming method of two-ply foam sandwich structure polymer matrix composites | |
| CN105128487B (en) | Integrally formed carriage plate for van and manufacturing technology | |
| CN109109341B (en) | Preparation method of wind power blade | |
| CN105082568A (en) | Liquid molding process of special-shaped composite structural part | |
| CN107234839A (en) | The compound flitch and preparation method of sonar dome peculiar to vessel | |
| JP2018518402A (en) | Method for manufacturing composite structure | |
| CN101564895A (en) | Vacuum perfusion infusion forming technique used for speedboat | |
| CN104742382A (en) | Pressure-assisted VARI (vacuum assisted resin infusion) forming device and method | |
| CN109747257A (en) | Ceramic coating composite plate and preparation method thereof | |
| CN110091551A (en) | A kind of rail vehicle inner wall decorative composite material and preparation method thereof | |
| CN101844424A (en) | Compound foamed aluminum particle board and manufacturing process thereof | |
| CN109203516B (en) | Manufacturing method of wind power blade | |
| CN102173136A (en) | Compound glass raw sheet and manufacturing method and application thereof | |
| CN106426981A (en) | Method for gluing hard foam blocks by vacuum resin filling | |
| CN106626702A (en) | Passenger car composite material structure body panel production method | |
| CN112477192A (en) | Forming method of high-rigidity conical-structure carbon fiber composite material pipe | |
| CN104912450B (en) | The Compound door leaf of a kind of global formation and manufacture method thereof | |
| CN207140394U (en) | The integrally formed closing hexahedron shelter of vacuum diversion | |
| CN105383123A (en) | SGP laminated glass and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Huizhong Inventor after: Hu Chaokang Inventor after: Xu Jiayang Inventor after: Wang Guocai Inventor after: Huang Xingming Inventor after: Hu Xianqi Inventor before: Hu Chaokang Inventor before: Wang Guocai Inventor before: Huang Xingming Inventor before: Xu Jiayang Inventor before: Wang Huizhong Inventor before: Hu Xianqi |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Forming process of a basalt fiber reinforced phenolic sandwich PMI composite board Effective date of registration: 20220530 Granted publication date: 20191101 Pledgee: China CITIC Bank Co.,Ltd. Jinhua Dongyang sub branch Pledgor: ZHEJIANG GBF BASALT FIBER CO.,LTD. Registration number: Y2022330000824 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20221116 Granted publication date: 20191101 Pledgee: China CITIC Bank Co.,Ltd. Jinhua Dongyang sub branch Pledgor: ZHEJIANG GBF BASALT FIBER CO.,LTD. Registration number: Y2022330000824 |