CN107841191A - A kind of high adhesion force printing-ink binder and preparation method thereof - Google Patents
A kind of high adhesion force printing-ink binder and preparation method thereof Download PDFInfo
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- CN107841191A CN107841191A CN201711040308.9A CN201711040308A CN107841191A CN 107841191 A CN107841191 A CN 107841191A CN 201711040308 A CN201711040308 A CN 201711040308A CN 107841191 A CN107841191 A CN 107841191A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention discloses a kind of high adhesion force printing-ink binder and preparation method thereof, the high adhesion force printing-ink binder includes according to the raw material of parts by weight：10 15 parts of passion fruit seed, 8 12 parts of cactus seed, 5 15 parts of rosin, 35 parts of polyalcohol, 20 40 parts of soybean oil, 15 25 parts of mineral oil, 0.5 1 parts of catalyst, 0.15 0.2 parts of antioxygen auxiliary agent, 0.2 0.3 parts of water resistant auxiliary agent, 5 10 parts of red yeast rice, 35 parts of glycerine, 0.5 1 parts of gelatinizing agent, 24 parts of galapectite powder, 13 parts of sepiolite powder.The present invention prepares a kind of plant oil-based ink link stuff using mixed vegetable oil and soybean oil as primary raw material, the ink vehicle that the vegetable oil makes can replace traditional ink adhesive using oil as solvent, it is high to cut ink adhesive adhesive force prepared by the present invention, adhesive force reaches 0 grade, adhesion effect is good, it is difficult for drop-off, it can be applied in the printing-ink of cigarette paper, human body is had no toxic side effect.
Description
Technical field
The present invention relates to technical field of ink, specifically a kind of high adhesion force printing-ink binder and preparation method thereof.
Background technology
Edible ink system special ink, not only the general general character with printing-ink, is available for people to eat also as it has
Performance and the surface decoration for being gradually widely used in food, health products and medicine, or the packages printing of such product are main
To be applied to the surfaces and its packet printing related text, pattern etc. such as capsule, tablet, candy, fruit, birds, beasts and eggs to mark, such as
The popular cartoon pattern of the food surface printings such as biscuit, chocolate, candy, fruit, birds, beasts and eggs and the figure that people's appetite can be caused
Picture, figure, word, personalized product can be played a part of, promote sale；It is adapted in the printing of the drug substance surfaces such as capsule, pill
The content of patient is comforted, can not only play a part of consoling consumer, moreover it is possible to better discriminates between counterfeit drug, substandard drug, ensures medication
Safety；Edible ink can be applied in the production of cigarette paper.Pattern, trade mark are directly printed directly on food by edible ink
In product, cigarette and its packaging, this requires ink to have the characteristics of general ink, as picture and text are clear, color is full,
Even, excellent wear-resisting property etc.；What is more important, because ink will be finally eaten, then the security of ink will also have
Absolute guarantee, although edible ink and preparation method thereof in some developed countries first meeting clue, many scientific research institutions and
Strong company all competitively releases the formula and application apparatus of its edible ink, and is obtained into many food companies
The application of work(, still, contain synthesis chemical composition due in existing formula more, non-natural raw material, be extremely difficult to state food medicine
The relevant criterion of product, desired color can not be accessed under specific pH value, and existing pigment has distinctive smell,
Light resistance is poor, and heat resistance is bad, influences the flavor and food container of food, and its technology of preparing is still immature, also there is
Color power is poor, tack is poor, transparency is high, vividness is low, and the rheological property of ink liquid is less than national standard, it is impossible to meets to use
The problem of demand, limit food, the development of medicine printing.
The content of the invention
It is an object of the invention to provide the good high adhesion force printing-ink binder of one kind, easy coloring, performance and
Its preparation method, to solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides following technical scheme：
A kind of high adhesion force printing-ink binder, includes according to the raw material of parts by weight：Passion fruit seed 10-15 parts, celestial being
Slap seed 8-12 parts, rosin 5-15 parts, polyalcohol 3-5 parts, soybean oil 20-40 parts, mineral oil 15-25 parts, catalyst 0.5-1 parts,
Antioxygen auxiliary agent 0.15-0.2 parts, water resistant auxiliary agent 0.2-0.3 parts, red yeast rice 5-10 parts, glycerine 3-5 parts, gelatinizing agent 0.5-1 parts, angstrom
Lip river stone flour 2-4 parts, sepiolite powder 1-3 parts.
As the further scheme of the present invention：The high adhesion force printing-ink binder, according to the raw material bag of parts by weight
Include：Passion fruit seed 11-14 parts, cactus seed 9-11 parts, rosin 8-12 parts, polyalcohol 3.5-4.5 parts, soybean oil 25-35 parts, ore deposit
Thing oil 18-22 parts, catalyst 0.6-0.9 parts, antioxygen auxiliary agent 0.16-0.19 parts, water resistant auxiliary agent 0.22-0.28 parts, red yeast rice 6-9
Part, glycerine 3.5-4.5 parts, gelatinizing agent 0.6-0.9 parts, galapectite powder 2.5-3.5 parts, sepiolite powder 1.5-2.5 parts.
As the further scheme of the present invention：The high adhesion force printing-ink binder, according to the raw material bag of parts by weight
Include：12 parts of passion fruit seed, 10 parts of cactus seed, 10 parts of rosin, 4 parts of polyalcohol, 30 parts of soybean oil, 20 parts of mineral oil, catalyst
0.8 part, 0.18 part of antioxygen auxiliary agent, 0.25 part of water resistant auxiliary agent, 8 parts of red yeast rice, 4 parts of glycerine, 0.8 part of gelatinizing agent, galapectite powder 3
Part, 2 parts of sepiolite powder.
As the further scheme of the present invention：The catalyst is lithium hydroxide.
As further scheme of the invention：The gelatinizing agent is isooctyl acid aluminium.
The preparation method of the high adhesion force printing-ink binder, is comprised the following steps that：
(1) passion fruit seed and cactus seed are well mixed, are put into baking box, design temperature is 60-80 DEG C, toasts 5-
10min, place into pulverizer and crushed, cross 50 mesh sieves, collect sieving particle, using gauze wrapped sieving particle, be put into
In container, add the glucose solution that mass fraction is 5% and flood gauze 2-3cm, arranged the air in container using nitrogen
Go out, sealing container, to being heated to 30-35 DEG C in container, stand 1-2 days, be then cooled to 15-25 DEG C, stand yarn after 8-10h
Cloth takes out, and sterilizing, collects the mixture of gauze wrapped；
(2) said mixture is well mixed with its quality 5-9% absolute ethyl alcohol, places into stream of supercritical carbon dioxide
In body extraction equipment, pressure is set as 32-36MPa, extracts 2-4h, is collected extract, is placed into centrifuge, with 7000r/
Min centrifuges 8-12min, collects supernatant and is put into Rotary Evaporators, and design temperature is 88 DEG C, natural after rotary evaporation 1-2h
Room temperature is cooled to, raffinate is collected, it is standby to obtain mixed vegetable oil；
(3) naturally dry after red yeast rice is cleaned, ball milling 5-7h under 300-500r/min is subsequently placed at, crosses 45-50 mesh sieves,
Red yeast rice powder is prepared into, then in mass ratio 1:8, red yeast rice powder and the ethanol solution of mass fraction 55% are stirred,
The heating water bath 3-5h at 50-70 DEG C；Filter and collect filtrate, rotated at 55-65 DEG C and be evaporated to the 1/5 of original volume, prepared
Concentrate, then in mass ratio 1:10, concentrate and deionized water are stirred and are placed in ultrasonic disperse under 200-300W
8-10min, cooling precipitation 10-14h is then stood, filters and to collect filter cake standby；
(4) mixed vegetable oil, soybean oil and catalyst are added in a kettle, when heating-up temperature is 160-180 DEG C, are added
Enter rosin and filter cake, be stirred, be warming up to 80-100 DEG C of stirring 2-4h；
(5) rosin, polyalcohol, mineral oil, antioxygen auxiliary agent, water resistant auxiliary agent, glycerine, galapectite powder, sepiolite powder are added,
Then stirring and adjusting viscosity adds gelatinizing agent and obtains product to 105000-115000mpa.s/25 DEG C.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention prepares a kind of plant oil-based ink link stuff using mixed vegetable oil and soybean oil as primary raw material, should
The ink vehicle that vegetable oil makes can replace traditional ink adhesive using oil as solvent, cut ink prepared by the present invention
Binder adhesive force is high, and adhesive force reaches 0 grade, and adhesion effect is good, difficult for drop-off, can be applied to the printing-ink of cigarette paper
In, human body is had no toxic side effect.
Embodiment
The technical scheme of this patent is described in more detail with reference to embodiment.
Embodiment 1
A kind of high adhesion force printing-ink binder, includes according to the raw material of parts by weight：10 parts of passion fruit seed, cactus seed
8 parts, 5 parts of rosin, 3 parts of polyalcohol, 20 parts of soybean oil, 15 parts of mineral oil, 0.5 part of lithium hydroxide, 0.15 part of antioxygen auxiliary agent, water resistant
0.2 part of auxiliary agent, 5 parts of red yeast rice, 3 parts of glycerine, 0.5 part of isooctyl acid aluminium, 2 parts of galapectite powder, 1 part of sepiolite powder.
The preparation method of the high adhesion force printing-ink binder, is comprised the following steps that：
(1) passion fruit seed and cactus seed being well mixed, are put into baking box, design temperature is 60 DEG C, toasts 5min,
Place into pulverizer and crushed, cross 50 mesh sieves, collect sieving particle, using gauze wrapped sieving particle, be put into container,
Add the glucose solution that mass fraction is 5% and flood gauze 2cm, discharged the air in container using nitrogen, sealing is held
Device, to being heated to 30 DEG C in container, 1 day is stood, is then cooled to 15 DEG C, takes out gauze after standing 8h, and sterilizing, receive
Collect the mixture of gauze wrapped；
(2) said mixture is well mixed with the absolute ethyl alcohol of its quality 5%, places into supercritical carbon dioxide fluid
In extraction equipment, pressure is set as 32MPa, extracts 2h, is collected extract, is placed into centrifuge, centrifuged with 7000r/min
8min, to collect supernatant and be put into Rotary Evaporators, design temperature is 88 DEG C, and room temperature is naturally cooled to after rotary evaporation 1h,
Raffinate is collected, it is standby to obtain mixed vegetable oil；
(3) naturally dry after red yeast rice is cleaned, ball milling 5h under 300r/min is subsequently placed at, crosses 45 mesh sieves, be prepared into red
Bent ground rice end, then in mass ratio 1:8, red yeast rice powder and the ethanol solution of mass fraction 55% are stirred, at 50 DEG C
Heating water bath 3h；Filter and collect filtrate, rotated at 55 DEG C and be evaporated to the 1/5 of original volume, concentrate is prepared into, then by matter
Measure ratio 1:10, concentrate and deionized water are stirred and are placed in ultrasonic disperse 8min under 200W, then stands cooling precipitation
10h, is filtered and to collect filter cake standby；
(4) mixed vegetable oil, soybean oil and lithium hydroxide are added in a kettle, when heating-up temperature is 160 DEG C, are added
Rosin and filter cake, are stirred, and are warming up to 80 DEG C of stirring 2h；
(5) rosin, polyalcohol, mineral oil, antioxygen auxiliary agent, water resistant auxiliary agent, glycerine, galapectite powder, sepiolite powder are added,
Then stirring and adjusting viscosity adds isooctyl acid aluminium and obtains product to 105000mpa.s/25 DEG C.
Embodiment 2
A kind of high adhesion force printing-ink binder, includes according to the raw material of parts by weight：11 parts of passion fruit seed, cactus seed
9 parts, it is 8 parts of rosin, 3.5 parts of polyalcohol, 25 parts of soybean oil, 18 parts of mineral oil, 0.6 part of lithium hydroxide, 0.16 part of antioxygen auxiliary agent, anti-
0.22 part of water auxiliary agent, 6 parts of red yeast rice, 3.5 parts of glycerine, 0.6 part of isooctyl acid aluminium, 2.5 parts of galapectite powder, 1.5 parts of sepiolite powder.
The preparation method of the high adhesion force printing-ink binder, is comprised the following steps that：
(1) passion fruit seed and cactus seed being well mixed, are put into baking box, design temperature is 65 DEG C, toasts 6min,
Place into pulverizer and crushed, cross 50 mesh sieves, collect sieving particle, using gauze wrapped sieving particle, be put into container,
Add the glucose solution that mass fraction is 5% and flood gauze 2.2cm, discharged the air in container using nitrogen, sealing
Container, to being heated to 31 DEG C in container, 1.2 days are stood, is then cooled to 18 DEG C, is taken out gauze after standing 8.5h, and sterilize
Sterilization, collect the mixture of gauze wrapped；
(2) said mixture is well mixed with the absolute ethyl alcohol of its quality 6%, places into supercritical carbon dioxide fluid
In extraction equipment, pressure is set as 33MPa, extracts 2.5h, is collected extract, is placed into centrifuge, centrifuged with 7000r/min
9min, collect supernatant and be put into Rotary Evaporators, design temperature is 88 DEG C, and room is naturally cooled to after rotary evaporation 1.2h
Temperature, raffinate is collected, it is standby to obtain mixed vegetable oil；
(3) naturally dry after red yeast rice is cleaned, ball milling 5.5h under 350r/min is subsequently placed at, crosses 46 mesh sieves, be prepared into
Red yeast rice powder, then in mass ratio 1:8, red yeast rice powder and the ethanol solution of mass fraction 55% are stirred, at 55 DEG C
Lower heating water bath 3.5h；Filter and collect filtrate, rotated at 58 DEG C and be evaporated to the 1/5 of original volume, be prepared into concentrate, then
In mass ratio 1:10, concentrate and deionized water are stirred and are placed in ultrasonic disperse 8.5min under 220W, is then stood cold
But 11h is precipitated, filters and to collect filter cake standby；
(4) mixed vegetable oil, soybean oil and lithium hydroxide are added in a kettle, when heating-up temperature is 165 DEG C, are added
Rosin and filter cake, are stirred, and are warming up to 85 DEG C of stirring 2.5h；
(5) rosin, polyalcohol, mineral oil, antioxygen auxiliary agent, water resistant auxiliary agent, glycerine, galapectite powder, sepiolite powder are added,
Then stirring and adjusting viscosity adds isooctyl acid aluminium and obtains product to 108000mpa.s/25 DEG C.
Embodiment 3
A kind of high adhesion force printing-ink binder, includes according to the raw material of parts by weight：12 parts of passion fruit seed, cactus seed
10 parts, it is 10 parts of rosin, 4 parts of polyalcohol, 30 parts of soybean oil, 20 parts of mineral oil, 0.8 part of lithium hydroxide, 0.18 part of antioxygen auxiliary agent, anti-
0.25 part of water auxiliary agent, 8 parts of red yeast rice, 4 parts of glycerine, 0.8 part of isooctyl acid aluminium, 3 parts of galapectite powder, 2 parts of sepiolite powder.
The preparation method of the high adhesion force printing-ink binder, is comprised the following steps that：
(1) passion fruit seed and cactus seed being well mixed, are put into baking box, design temperature is 70 DEG C, toasts 8min,
Place into pulverizer and crushed, cross 50 mesh sieves, collect sieving particle, using gauze wrapped sieving particle, be put into container,
Add the glucose solution that mass fraction is 5% and flood gauze 2.5cm, discharged the air in container using nitrogen, sealing
Container, to being heated to 32 DEG C in container, 1.5 days are stood, is then cooled to 20 DEG C, takes out gauze after standing 9h, and sterilized and disappear
Poison, collect the mixture of gauze wrapped；
(2) said mixture is well mixed with the absolute ethyl alcohol of its quality 7.5%, places into stream of supercritical carbon dioxide
In body extraction equipment, pressure is set as 34MPa, extracts 3h, is collected extract, is placed into centrifuge, centrifuged with 7000r/min
10min, collect supernatant and be put into Rotary Evaporators, design temperature is 88 DEG C, and room is naturally cooled to after rotary evaporation 1.5h
Temperature, raffinate is collected, it is standby to obtain mixed vegetable oil；
(3) naturally dry after red yeast rice is cleaned, ball milling 6h under 400r/min is subsequently placed at, crosses 48 mesh sieves, be prepared into red
Bent ground rice end, then in mass ratio 1:8, red yeast rice powder and the ethanol solution of mass fraction 55% are stirred, at 60 DEG C
Heating water bath 4h；Filter and collect filtrate, rotated at 60 DEG C and be evaporated to the 1/5 of original volume, concentrate is prepared into, then by matter
Measure ratio 1:10, concentrate and deionized water are stirred and are placed in ultrasonic disperse 9min under 250W, then stands cooling precipitation
12h, is filtered and to collect filter cake standby；
(4) mixed vegetable oil, soybean oil and lithium hydroxide are added in a kettle, when heating-up temperature is 170 DEG C, are added
Rosin and filter cake, are stirred, and are warming up to 90 DEG C of stirring 3h；
(5) rosin, polyalcohol, mineral oil, antioxygen auxiliary agent, water resistant auxiliary agent, glycerine, galapectite powder, sepiolite powder are added,
Then stirring and adjusting viscosity adds isooctyl acid aluminium and obtains product to 110000mpa.s/25 DEG C.
Embodiment 4
A kind of high adhesion force printing-ink binder, includes according to the raw material of parts by weight：14 parts of passion fruit seed, cactus seed
11 parts, 12 parts of rosin, 4.5 parts of polyalcohol, 35 parts of soybean oil, 22 parts of mineral oil, 0.9 part of lithium hydroxide, 0.19 part of antioxygen auxiliary agent,
0.28 part of water resistant auxiliary agent, 9 parts of red yeast rice, 4.5 parts of glycerine, 0.9 part of isooctyl acid aluminium, 3.5 parts of galapectite powder, 2.5 parts of sepiolite powder.
The preparation method of the high adhesion force printing-ink binder, is comprised the following steps that：
(1) passion fruit seed and cactus seed being well mixed, are put into baking box, design temperature is 75 DEG C, toasts 9min,
Place into pulverizer and crushed, cross 50 mesh sieves, collect sieving particle, using gauze wrapped sieving particle, be put into container,
Add the glucose solution that mass fraction is 5% and flood gauze 2.8cm, discharged the air in container using nitrogen, sealing
Container, to being heated to 34 DEG C in container, 1.8 days are stood, is then cooled to 22 DEG C, is taken out gauze after standing 9.5h, and sterilize
Sterilization, collect the mixture of gauze wrapped；
(2) said mixture is well mixed with the absolute ethyl alcohol of its quality 8%, places into supercritical carbon dioxide fluid
In extraction equipment, pressure is set as 35MPa, extracts 3.5h, is collected extract, is placed into centrifuge, centrifuged with 7000r/min
11min, collect supernatant and be put into Rotary Evaporators, design temperature is 88 DEG C, and room is naturally cooled to after rotary evaporation 1.8h
Temperature, raffinate is collected, it is standby to obtain mixed vegetable oil；
(3) naturally dry after red yeast rice is cleaned, ball milling 6.5h under 450r/min is subsequently placed at, crosses 49 mesh sieves, be prepared into
Red yeast rice powder, then in mass ratio 1:8, red yeast rice powder and the ethanol solution of mass fraction 55% are stirred, at 65 DEG C
Lower heating water bath 4.5h；Filter and collect filtrate, rotated at 62 DEG C and be evaporated to the 1/5 of original volume, be prepared into concentrate, then
In mass ratio 1:10, concentrate and deionized water are stirred and are placed in ultrasonic disperse 9.5min under 280W, is then stood cold
But 13h is precipitated, filters and to collect filter cake standby；
(4) mixed vegetable oil, soybean oil and lithium hydroxide are added in a kettle, when heating-up temperature is 175 DEG C, are added
Rosin and filter cake, are stirred, and are warming up to 95 DEG C of stirring 3.5h；
(5) rosin, polyalcohol, mineral oil, antioxygen auxiliary agent, water resistant auxiliary agent, glycerine, galapectite powder, sepiolite powder are added,
Then stirring and adjusting viscosity adds isooctyl acid aluminium and obtains product to 112000mpa.s/25 DEG C.
Embodiment 5
A kind of high adhesion force printing-ink binder, includes according to the raw material of parts by weight：15 parts of passion fruit seed, cactus seed
12 parts, 15 parts of rosin, 5 parts of polyalcohol, 40 parts of soybean oil, 25 parts of mineral oil, 1 part of lithium hydroxide, 0.2 part of antioxygen auxiliary agent, water resistant
0.3 part of auxiliary agent, 10 parts of red yeast rice, 5 parts of glycerine, 1 part of isooctyl acid aluminium, 4 parts of galapectite powder, 3 parts of sepiolite powder.
The preparation method of the high adhesion force printing-ink binder, is comprised the following steps that：
(1) passion fruit seed and cactus seed are well mixed, are put into baking box, design temperature is 80 DEG C, baking
10min, place into pulverizer and crushed, cross 50 mesh sieves, collect sieving particle, using gauze wrapped sieving particle, be put into
In container, add the glucose solution that mass fraction is 5% and flood gauze 3cm, discharged the air in container using nitrogen,
Sealing container, to being heated to 35 DEG C in container, 2 days are stood, is then cooled to 25 DEG C, is taken out gauze after standing 10h, and sterilize
Sterilization, collect the mixture of gauze wrapped；
(2) said mixture is well mixed with the absolute ethyl alcohol of its quality 9%, places into supercritical carbon dioxide fluid
In extraction equipment, pressure is set as 36MPa, extracts 4h, is collected extract, is placed into centrifuge, centrifuged with 7000r/min
12min, to collect supernatant and be put into Rotary Evaporators, design temperature is 88 DEG C, and room temperature is naturally cooled to after rotary evaporation 2h,
Raffinate is collected, it is standby to obtain mixed vegetable oil；
(3) naturally dry after red yeast rice is cleaned, ball milling 7h under 500r/min is subsequently placed at, crosses 50 mesh sieves, be prepared into red
Bent ground rice end, then in mass ratio 1:8, red yeast rice powder and the ethanol solution of mass fraction 55% are stirred, at 70 DEG C
Heating water bath 5h；Filter and collect filtrate, rotated at 65 DEG C and be evaporated to the 1/5 of original volume, concentrate is prepared into, then by matter
Measure ratio 1:10, concentrate and deionized water are stirred and are placed in ultrasonic disperse 10min under 300W, then stands cooling precipitation
14h, is filtered and to collect filter cake standby；
(4) mixed vegetable oil, soybean oil and lithium hydroxide are added in a kettle, when heating-up temperature is 180 DEG C, are added
Rosin and filter cake, are stirred, and are warming up to 100 DEG C of stirring 4h；
(5) rosin, polyalcohol, mineral oil, antioxygen auxiliary agent, water resistant auxiliary agent, glycerine, galapectite powder, sepiolite powder are added,
Then stirring and adjusting viscosity adds isooctyl acid aluminium and obtains product to 115000mpa.s/25 DEG C.
The present invention prepares a kind of plant oil-based ink link stuff using mixed vegetable oil and soybean oil as primary raw material, should
The ink vehicle that vegetable oil makes can replace traditional ink adhesive using oil as solvent, cut ink prepared by the present invention
Binder adhesive force is high, and adhesive force reaches 0 grade, and adhesion effect is good, difficult for drop-off, can be applied to the printing-ink of cigarette paper
In, human body is had no toxic side effect.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, can also be on the premise of this patent objective not be departed from one skilled in the relevant art's possessed knowledge
Various changes can be made.
Claims (6)
1. a kind of high adhesion force printing-ink binder, it is characterised in that include according to the raw material of parts by weight：Passion fruit seed 10-
15 parts, cactus seed 8-12 parts, rosin 5-15 parts, polyalcohol 3-5 parts, soybean oil 20-40 parts, mineral oil 15-25 parts, catalyst
0.5-1 parts, antioxygen auxiliary agent 0.15-0.2 parts, water resistant auxiliary agent 0.2-0.3 parts, red yeast rice 5-10 parts, glycerine 3-5 parts, gelatinizing agent
0.5-1 parts, galapectite powder 2-4 parts, sepiolite powder 1-3 parts.
2. high adhesion force printing-ink binder according to claim 1, it is characterised in that according to the raw material bag of parts by weight
Include：Passion fruit seed 11-14 parts, cactus seed 9-11 parts, rosin 8-12 parts, polyalcohol 3.5-4.5 parts, soybean oil 25-35 parts, ore deposit
Thing oil 18-22 parts, catalyst 0.6-0.9 parts, antioxygen auxiliary agent 0.16-0.19 parts, water resistant auxiliary agent 0.22-0.28 parts, red yeast rice 6-9
Part, glycerine 3.5-4.5 parts, gelatinizing agent 0.6-0.9 parts, galapectite powder 2.5-3.5 parts, sepiolite powder 1.5-2.5 parts.
3. high adhesion force printing-ink binder according to claim 1, it is characterised in that according to the raw material bag of parts by weight
Include：12 parts of passion fruit seed, 10 parts of cactus seed, 10 parts of rosin, 4 parts of polyalcohol, 30 parts of soybean oil, 20 parts of mineral oil, catalyst
0.8 part, 0.18 part of antioxygen auxiliary agent, 0.25 part of water resistant auxiliary agent, 8 parts of red yeast rice, 4 parts of glycerine, 0.8 part of gelatinizing agent, galapectite powder 3
Part, 2 parts of sepiolite powder.
4. according to any described high adhesion force printing-ink binders of claim 1-3, it is characterised in that the catalyst is
Lithium hydroxide.
5. according to any described high adhesion force printing-ink binders of claim 1-3, it is characterised in that the gelatinizing agent is
Isooctyl acid aluminium.
A kind of 6. preparation method of high adhesion force printing-ink binder as described in claim 1-3 is any, it is characterised in that
Comprise the following steps that：
(1) passion fruit seed and cactus seed are well mixed, are put into baking box, design temperature is 60-80 DEG C, toasts 5-
10min, place into pulverizer and crushed, cross 50 mesh sieves, collect sieving particle, using gauze wrapped sieving particle, be put into
In container, add the glucose solution that mass fraction is 5% and flood gauze 2-3cm, arranged the air in container using nitrogen
Go out, sealing container, to being heated to 30-35 DEG C in container, stand 1-2 days, be then cooled to 15-25 DEG C, stand yarn after 8-10h
Cloth takes out, and sterilizing, collects the mixture of gauze wrapped；
(2) said mixture is well mixed with its quality 5-9% absolute ethyl alcohol, places into supercritical carbon dioxide fluid extraction
Take in device, set pressure as 32-36MPa, extract 2-4h, collect extract, place into centrifuge, with 7000r/min from
Heart 8-12min, collect supernatant and be put into Rotary Evaporators, design temperature is 88 DEG C, natural cooling after rotary evaporation 1-2h
To room temperature, raffinate is collected, it is standby to obtain mixed vegetable oil；
(3) naturally dry after red yeast rice is cleaned, ball milling 5-7h under 300-500r/min is subsequently placed at, crosses 45-50 mesh sieves, prepared
Red yeast rice powder, then in mass ratio 1:8, red yeast rice powder and the ethanol solution of mass fraction 55% are stirred, in 50-
Heating water bath 3-5h at 70 DEG C；Filter and collect filtrate, rotated at 55-65 DEG C and be evaporated to the 1/5 of original volume, be prepared into concentration
Liquid, then in mass ratio 1:10, concentrate and deionized water are stirred and are placed in ultrasonic disperse 8- under 200-300W
10min, cooling precipitation 10-14h is then stood, filters and to collect filter cake standby；
(4) mixed vegetable oil, soybean oil and catalyst are added in a kettle, when heating-up temperature is 160-180 DEG C, add pine
Fragrant and filter cake, is stirred, and is warming up to 80-100 DEG C of stirring 2-4h；
(5) rosin, polyalcohol, mineral oil, antioxygen auxiliary agent, water resistant auxiliary agent, glycerine, galapectite powder, sepiolite powder are added, is stirred
Viscosity is adjusted to 105000-115000mpa.s/25 DEG C, gelatinizing agent is then added and obtains product.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113528246A (en) * | 2021-05-21 | 2021-10-22 | 西安理工大学 | Preparation method of polyfunctional group water-based vegetable oil binder and water-based ink |
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| US20090000512A1 (en) * | 2005-05-27 | 2009-01-01 | Sun Chemical Corporation | Process for preparing a printing ink |
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| US20090000512A1 (en) * | 2005-05-27 | 2009-01-01 | Sun Chemical Corporation | Process for preparing a printing ink |
| CN106496472A (en) * | 2015-09-08 | 2017-03-15 | 天津安光油墨厂有限公司 | A kind of environmental protection type resin binder and its preparation technology |
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| CN113528246A (en) * | 2021-05-21 | 2021-10-22 | 西安理工大学 | Preparation method of polyfunctional group water-based vegetable oil binder and water-based ink |
| CN113528246B (en) * | 2021-05-21 | 2024-04-12 | 东莞市浩彩油墨科技有限公司 | Preparation method of multifunctional water-based vegetable oil binder and water-based ink |
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Application publication date: 20180327 |