CN107836455A - A kind of Synergistic insecticidal containing pteroylglutamic acid - Google Patents
A kind of Synergistic insecticidal containing pteroylglutamic acid Download PDFInfo
- Publication number
- CN107836455A CN107836455A CN201710884666.1A CN201710884666A CN107836455A CN 107836455 A CN107836455 A CN 107836455A CN 201710884666 A CN201710884666 A CN 201710884666A CN 107836455 A CN107836455 A CN 107836455A
- Authority
- CN
- China
- Prior art keywords
- pteroylglutamic acid
- synergistic insecticidal
- cypermethrin
- pteroylglutamic
- synergistic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Synergistic insecticidal containing pteroylglutamic acid, the main active of the Synergistic insecticidal is selected from the combination of one or both of indoxacarb, cypermethrin, chlopyrifos, effective cypermethrin, betacyfluthrin, Biphenthrin, Cupric sulfate, AVM, emamectin-benzoate, imidacloprid, Acetamiprid, chlorfenapyr.Pteroylglutamic acid and insecticide are mixed and made into by regular dosage form using conventional method, in the formulation, the effective content of pteroylglutamic acid is 1 5%.It is the insecticide significant effect that is prepared using this method, environment-friendly, it is a kind of novel environmental friendly insecticide.
Description
Technical field
The present invention relates to agricultural chemical insecticide field, more particularly, to a kind of Synergistic insecticidal containing pteroylglutamic acid and its
Application technology.
Background technology
Agricultural chemicals plays highly important effect in agricultural production, and organic chemical pesticides significantly enhance mankind's control
The ability of disease pest harm, retrieve crop yield loss for us and made great contribution.But rely on and largely make for a long time
With Synthetic Organic Chemistry agricultural chemicals, a systems such as well-known environmental pollution, ecological balance destruction and food security have been had resulted in
Row problem, to promoting agricultural economy to realize that sustainable development brings many detrimental effects.
With the raising of people's health consciousness, persticide residue is reduced, makes great efforts exploitation novel agrochemical and has become when business
It is anxious, dangerous poisonous benzene kind solvent is substituted using green solvent, is the needs of the sustainable development of socio-economy.
Prevention effect scientifically rationally can be improved using agricultural chemicals, delays harmful organism to develop immunity to drugs or expand and uses model
Enclose it is simultaneous control different types of harmful organism, save manpower and dosage, reduce cost, improve drug effect, reduce toxicity, enhancing pair
The security of people, animal.
Pteroylglutamic acid is one of vitamin B complex, a kind of thing for having insecticidal activity of extraction purification from the leaf of spinach
Matter, insecticidal properties are embodied in the conjunction that polypide purine and thymidine are participated in after pteroylglutamic acid is combined with pesticide active ingredient
Into further synthetic DNA and RNA disintegrate eucaryotic cell structure inside polypide, insect are killed, after being combined with pesticide active ingredient
Pteroylglutamic acid easily decompose, oxidizable in atmosphere, the residence time is short, environmentally safe, and insect is not likely to produce the resistance to the action of a drug,
It is insecticide more satisfactory in integrated control.Pteroylglutamic acid with tag, the preparing protodrug of stomach poison function mixes
Had significant synergies during use.
In the prior art, the report being temporarily also used in mixed way insecticide and pteroylglutamic acid without appearance.
The content of the invention
It is an object of the invention to provide a kind of Synergistic insecticidal and its application technology containing pteroylglutamic acid, invention tool
There is environmental-protecting performance high, quick-acting is strong, and residual life is short, the remarkable advantage such as production and application safety.
The embodiment of the present invention is achieved in that a kind of Synergistic insecticidal containing pteroylglutamic acid and its application technology
Main active is indoxacarb, cypermethrin, chlopyrifos, effective cypermethrin, betacyfluthrin, Biphenthrin, killed
One or both of worm list, AVM, emamectin-benzoate, imidacloprid, Acetamiprid, chlorfenapyr combine,
Solvent includes one or more of mixing in the environmentally friendly organic solvents such as aliphatic hydrocarbon methyl esters, D- hesperidenes, turpentine oil, ethyl acetate
Thing, it can be made as needed in the pesticidal preparations industry such as suspending agent, wettable powder, missible oil, microemulsion, aqua or aqueous emulsion
Regular dosage form.
Compared with prior art, the embodiment of the present invention can more intuitively illustrate synergy of the pteroylglutamic acid in insecticide
Effect.
Moreover, suspending agent, wettable powder can be processed into as needed and after insecticide mixture with pteroylglutamic acid
Regular dosage form in the pesticidal preparations industry such as agent, missible oil, microemulsion, aqua or aqueous emulsion.
In order to be better understood from the essence of the present invention, illustrate the technology contents of the present invention, but the present invention with example below
Content be not limited thereto.
The environmentally friendly insecticide of the embodiment of the present invention, various auxiliary agents commonly used in the art can be added as needed on, are matched somebody with somebody
Conventional pesticide formulation needed for being made, such as wettable powder, missible oil, microemulsion, aqueous emulsion or aqua etc..
Embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
Unless otherwise indicated, the percentage employed in the present invention is percetage by weight.
The design of formula produced according to the present invention, prepare a kind of Synergistic insecticidal containing pteroylglutamic acid and its answer
The feasibility and reasonability for supporting the present invention can be proved by following laboratory stability verification process result with technology.
Embodiment 1
1st, target formulation：The indoxacarb suspending agent of 3% emamectin benzoate 7%.
2nd, preparation method：In industry prepared by conventional method, and synergistic component effective dose is preferably 1%.
3rd, stability observing is tested.
3% emamectin benzoate 7% indoxacarb suspending agent is made by above-mentioned laboratory operating procedures, is store through cold storage (0 ± 1 DEG C) 7 days, heat
Under conditions of (54 ± 2 DEG C) 14 days, normal temperature ultraviolet light irradiation 24h, the resolution ratio difference 0.09% of emamectin benzoate/indoxacarb/
0.23%th, 0.33%/0.48%, 1.19%/2.01%.
Embodiment 2
1st, target formulation：The chlorpyrifos ec of 2.5% cypermethrin 22.5%.
2nd, preparation method：In industry prepared by conventional method, and solvent uses turpentine oil, and synergistic component effective dose is preferably
2.5%.
3rd, stability observing is tested.
The chlorpyrifos ec of 2.5% cypermethrin 22.5% is made by above-mentioned laboratory operating procedures, through cold storage (0 ± 1 DEG C) 7
My god, heat storage (54 ± 2 DEG C) 14 days, normal temperature ultraviolet light irradiate 1 day under the conditions of, the resolution ratio difference of cypermethrin/chlopyrifos
For 0.30%/0.22%, 0.68%/0.89%, 1.17%/1.53%.
Embodiment 3
1st, target formulation：4.5% r.
2nd, preparation method：In industry prepared by conventional method, and solvent uses 12% ethyl acetate, and synergistic component effective dose is excellent
Elect 1.5% as.
3rd, stability observing is tested.
4.5% r is made by above-mentioned laboratory operating procedures, through cold storage (0 ± 1 DEG C) 7 days, heat storage (54
± 2 DEG C) 14 days, under conditions of normal temperature ultraviolet light irradiation 24h, the resolution ratio of effective cypermethrin is respectively 0.12%,
0.36%th, 1.38%.
Embodiment 4
1st, target formulation：5% betacyfluthrin water and milk.
2nd, preparation method：In industry prepared by conventional method, and solvent uses 15%D- hesperidenes, and synergistic component effective dose is preferred
For 3%.
3rd, stability observing is tested.
5% betacyfluthrin water and milk is made by above-mentioned laboratory operating procedures, through cold storage (0 ± 1 DEG C) 7 days, heat storage (54
± 2 DEG C) 14 days, under conditions of normal temperature ultraviolet light irradiation 24h, betacyfluthrin resolution ratio is respectively 0.32%,
0.45%th, 1.35%.
Embodiment 5
1st, target formulation：2.5% Biphenthrin water and milk.
2nd, preparation method：In industry prepared by conventional method, and solvent uses 5% ethyl acetate, and synergistic component effective dose is excellent
Elect 1.5% as.
3rd, stability observing is tested.
2.5% Biphenthrin water and milk is made by above-mentioned laboratory operating procedures, through cold storage (0 ± 1 DEG C) 7 days, heat storage (54 ± 2
DEG C) 14 days, under conditions of normal temperature ultraviolet light irradiation 24h, the resolution ratio of Biphenthrin is respectively 0.27%, 0.33%,
1.08%.
Embodiment 6
1st, target formulation：3% Acetamiprid wettable powder.
2nd, preparation method：In industry prepared by conventional method, and synergistic component effective dose is preferably 1.2%.
3rd, stability observing is tested.
3% Acetamiprid wettable powder is made by above-mentioned laboratory operating procedures, through cold storage (0 ± 1 DEG C) 7 days, heat storage (54 ± 2
DEG C) 14 days, under conditions of normal temperature ultraviolet light irradiation 24h, the resolution ratio of Acetamiprid is respectively 0.19%, 0.96%, 1.28%.
Embodiment 7
1st, target formulation：The emamectin benzoate suspending agent of 10% chlorfenapyr 2%.
2nd, preparation method：In industry prepared by conventional method, and synergistic component effective dose is preferably 3%
3rd, stability observing is tested.
10% chlorfenapyr 2% emamectin benzoate suspending agent is made by above-mentioned laboratory operating procedures, through cold storage (0 ± 1 DEG C) 7 days, heat
Store (54 ± 2 DEG C) 14 days, under conditions of normal temperature ultraviolet light irradiation 24h, the resolution ratio of chlorfenapyr/emamectin benzoate is respectively
0.47%/0.22%, 0.55%/0.69%, 1.19%/1.56%.
Embodiment 8：Field control effectiveness test.
Field control effectiveness test shows, adds the preparation of pteroylglutamic acid, after medicine 3 days pest and disease damage preventive effects more than 95%,
Do not add more than the 85% of pteroylglutamic acid drug effect better than control formulation, add the preparation of pteroylglutamic acid, remain to tie up within 5 days after medicine
Hold pest and disease damage preventive effect more than 90%, more than the 85% of pteroylglutamic acid drug effect do not added better than control, and pteroylglutamic acid with
With tag, the preparing protodrug of stomach poison function is used in mixed way when have significant synergies.
Preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention.
Claims (4)
- A kind of 1. Synergistic insecticidal containing pteroylglutamic acid, it is characterised in that：The main active of the Synergistic insecticidal Selected from indoxacarb, cypermethrin, chlopyrifos, effective cypermethrin, betacyfluthrin, Biphenthrin, Cupric sulfate, Avermectin The combination of one or both of element, emamectin-benzoate, imidacloprid, Acetamiprid, chlorfenapyr.
- A kind of 2. Synergistic insecticidal containing pteroylglutamic acid, it is characterised in that：Weight of the pteroylglutamic acid in Synergistic insecticidal Amount percentage composition is 1-5%.
- 3. a kind of Synergistic insecticidal and its application technology containing pteroylglutamic acid according to claim 1, its feature exist In：The formulation of the Synergistic insecticidal can be one in suspending agent, wettable powder, missible oil, microemulsion, aqua, aqueous emulsion Kind.
- A kind of 4. Synergistic insecticidal containing pteroylglutamic acid according to claim 3, it is characterised in that：The formulation is When missible oil, microemulsion, aqueous emulsion, its selected solvent be aliphatic hydrocarbon methyl esters, D- hesperidenes, turpentine oil, one kind in ethyl acetate or Several mixing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710884666.1A CN107836455A (en) | 2017-09-26 | 2017-09-26 | A kind of Synergistic insecticidal containing pteroylglutamic acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710884666.1A CN107836455A (en) | 2017-09-26 | 2017-09-26 | A kind of Synergistic insecticidal containing pteroylglutamic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107836455A true CN107836455A (en) | 2018-03-27 |
Family
ID=61661766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710884666.1A Pending CN107836455A (en) | 2017-09-26 | 2017-09-26 | A kind of Synergistic insecticidal containing pteroylglutamic acid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107836455A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111011368A (en) * | 2019-11-11 | 2020-04-17 | 南京华洲药业有限公司 | Composite insecticidal and acaricidal nano-water agent containing efficient cyhalothrin and emamectin benzoate and application thereof |
-
2017
- 2017-09-26 CN CN201710884666.1A patent/CN107836455A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111011368A (en) * | 2019-11-11 | 2020-04-17 | 南京华洲药业有限公司 | Composite insecticidal and acaricidal nano-water agent containing efficient cyhalothrin and emamectin benzoate and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BRPI0621641A2 (en) | liquid composition, process for the production of liquid composition, and ectoparasite control agent for use in mammals and birds | |
| CN103563899B (en) | High-efficient pesticide composition | |
| CN103283774B (en) | A kind of Pesticidal combination containing spiral shell worm ethyl ester | |
| CN107836455A (en) | A kind of Synergistic insecticidal containing pteroylglutamic acid | |
| CN102228056B (en) | Pesticide composition containing sulfur-fluorine oxime ether and part of organophosphorus pesticides | |
| CN102246839A (en) | Compounded pesticide for controlling diseases and insects of rice and forest | |
| CN102228055A (en) | Pesticide composite containing fenazaquin | |
| CN102805089B (en) | Insect and mite killing composition containing Cyflumetofen and emamectin benzoate | |
| CN105794825A (en) | Insecticide composition containing tetrachlorantraniliprole and carbamic acid esters | |
| CN106376555A (en) | Application technology of trehalose in insecticidal micro-emulsion | |
| CN101263825A (en) | Chlopyrifos and acetamiprid insecticidal composition | |
| CN102037991B (en) | Composite pesticide containing abamectin and cidial | |
| CN104273162A (en) | Efficient insecticide containing chlorfenvinphos, cyphenothrin and amitraz | |
| CN104106587A (en) | Insecticidal composition containing flubendiamide and carbamate | |
| CN101406187A (en) | Composition for killing insects and mites containing tetranoic acid and organophosphorus | |
| CN107646842A (en) | A kind of application technology of synergist in agriculture chemicals fungicide | |
| CN102037992A (en) | Pesticide composition containing abamectin and fenitrothion | |
| CN102763668A (en) | Insecticidal composition containing dinotefuran and emamectin benzoate | |
| CN103238609A (en) | Cycloxaprid-containing insecticidal composition | |
| CN102578114A (en) | Pesticide composite containing emamectin benzoate and tebufenozide | |
| CN105104407B (en) | A kind of Efficient insecticidal composition | |
| CN105557707B (en) | A kind of Pesticidal combination containing flufenzine | |
| CN105746523B (en) | A kind of Pesticidal combination of pyriproxyfen-containing | |
| CN102217636A (en) | Insecticidal composition containing novaluron | |
| CN107258793A (en) | A kind of Pesticidal combination containing four Tolfenpyrads and anabasine |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180327 |