CN107829533A - A kind of wall decorating veneer - Google Patents
A kind of wall decorating veneer Download PDFInfo
- Publication number
- CN107829533A CN107829533A CN201711120481.XA CN201711120481A CN107829533A CN 107829533 A CN107829533 A CN 107829533A CN 201711120481 A CN201711120481 A CN 201711120481A CN 107829533 A CN107829533 A CN 107829533A
- Authority
- CN
- China
- Prior art keywords
- silica
- pet
- substrate
- decorating veneer
- wall decorating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 59
- 239000003063 flame retardant Substances 0.000 claims abstract description 30
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 27
- 239000000758 substrate Substances 0.000 claims abstract description 17
- 239000000835 fiber Substances 0.000 claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 16
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 238000006068 polycondensation reaction Methods 0.000 claims abstract description 14
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims abstract description 8
- 229910000077 silane Inorganic materials 0.000 claims abstract description 8
- 239000003365 glass fiber Substances 0.000 claims abstract description 6
- 238000007731 hot pressing Methods 0.000 claims abstract description 6
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 6
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 20
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 6
- 125000000143 2-carboxyethyl group Chemical group [H]OC(=O)C([H])([H])C([H])([H])* 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 5
- 238000010348 incorporation Methods 0.000 claims description 4
- 239000005543 nano-size silicon particle Substances 0.000 claims description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 238000012360 testing method Methods 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims 2
- 239000000463 material Substances 0.000 abstract description 13
- 238000005516 engineering process Methods 0.000 abstract description 12
- 230000005855 radiation Effects 0.000 abstract description 5
- 239000007790 solid phase Substances 0.000 abstract description 4
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 abstract description 4
- 238000005054 agglomeration Methods 0.000 abstract description 3
- 230000002776 aggregation Effects 0.000 abstract description 3
- 239000008187 granular material Substances 0.000 abstract description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 29
- 229920000139 polyethylene terephthalate Polymers 0.000 description 28
- 238000006243 chemical reaction Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000011900 installation process Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000009417 prefabrication Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0875—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
-
- B32B17/064—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/067—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of fibres or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/692—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus
- C08G63/6924—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/6926—Dicarboxylic acids and dihydroxy compounds
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0253—Polyolefin fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
- B32B2262/0284—Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2607/00—Walls, panels
- B32B2607/02—Wall papers, wall coverings
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
- E04F2290/045—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against fire
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Laminated Bodies (AREA)
Abstract
A kind of wall decorating veneer, decorated for inner wall of building, including substrate and hot pressing the PET on substrate, the thickness of the substrate is 10 15mm, and the thickness of the PET is 1 3mm;Wherein, the substrate is formed by 65 75%PP fibers and 25 35% glass fibre thermoplastics.The invention provides a kind of wall decorating veneer, using green halogen-free flame retardants, the fire-retardant PET resin of intramolecular is prepared for by copolycondensation technology and solid phase polycondensation technology, silica modified body disperses more uniform in the base simultaneously, and exist with nano micropore structure, the conduction and heat radiation of heat energy in the material can be blocked, effectively lifts the fire resistance of material.And the silica dioxide granule after silane coupler modified alleviates agglomeration, nanometer particle is dispersed into, can more effectively strengthen anti-flammability.
Description
Technical field
The invention belongs to building material field, and in particular to a kind of wall decorating veneer.
Background technology
Building energy conservation be alleviate energy shortage, solve socio-economic development and energy supply it is insufficient this to the most effective of contradiction
One of measure.With respect to other energy-saving building technologies, the superiority of external wall outer insulation is substantially avoided that generation building heat bridge, avoids interior
Metope winter condensation is advantageous to protect agent structure, greatly reduces temperature stress and structural damage is acted on, increase structural life-time.
Heat preservation decoration integrative system is produced, field installation process, favorably on the basis of External Thermal Insulation Technology for External using prefabrication
In improving building industrialization, the standardization of products, construction assembling level, shorten the construction period.
PET (PET) fiber has excellent physical and mechanical properties, be widely used in clothes,
The fields such as blanket, decoration, bedding, turn into the chemical fibre kind that application is most wide, consumption is maximum.But the pole of PET
Limited oxygen index is only 21%, belongs to flammable fiber, greatly limit its application, it would be desirable to which its fire resistance is improved.
Patent CN106968049A discloses fire-retardant acoustic tile and its production technology based on Polyester Fibers, with useless
Old plastics are raw material, regenerative polyester staple fiber, regeneration low melting point Skin-core type terylene chopped fiber are made through melt spinning, in sheet material sheet
The upper surface of body uniformly sprays fire retardant, and bottom surface section thickness dipping fire retardant, cold wind cools after prebake, press polish, cuts
Fire-retardant acoustic tile is obtained after cutting, but this fire-retardant agent method of spray simply carries out flame retardant treatment, flame retardant effect in superficial layer
It is not very high;And a kind of wall decorating veneer is provided in the present invention, using green halogen-free flame retardants, by copolycondensation technology and
Solid phase polycondensation technology is prepared for the fire-retardant PET resin of intramolecular, while silica modified body disperses more uniformly in the base,
And exist with nano micropore structure, the conduction and heat radiation of heat energy in the material can be blocked, effectively lifts the resistance of material
Fire performance.And the silica dioxide granule after silane coupler modified alleviates agglomeration, nanometer particle is dispersed into, can
More effectively strengthen anti-flammability.
The content of the invention
It is an object of the invention to provide a kind of wall decorating veneer, using green halogen-free flame retardants, passes through copolycondensation technology
The fire-retardant PET resin of intramolecular is prepared for solid phase polycondensation technology, while silica modified body is scattered more equal in the base
It is even, and exist with nano micropore structure, the conduction and heat radiation of heat energy in the material can be blocked, effectively lifts material
Fire resistance.
In order to achieve the above object, the technical solution adopted by the present invention is:A kind of wall decorating veneer, filled for inner wall of building
Decorations, including substrate and hot pressing the PET on substrate, the thickness of the substrate are 10-15mm, the thickness of the PET
For 1-3mm;
Wherein, the substrate is formed by 65-75%PP fibers and 25-35% glass fibre thermoplastics;
Wherein, the preparation method of PET is as follows:
1) it is 1 to take ratio:1:0.4 terephthalic acid (TPA), ethylene glycol and 2- carboxyethyl phenyls hypophosphorous acid carries out ester at 250 DEG C
Change reaction, after reacting 40-70min, into polycondensation phase, for temperature control at 280 DEG C, vacuum is maintained at 10-12Pa;Polycondensation is anti-
Flame-retardant PET resin is obtained after the completion of answering;
2) take silica with parts by weight relative to the Flame-retardant PET resin obtained in the step 1) that silica is 3-5%
Successively it is put into high-speed mixer and mixed at high speed is uniform, incorporation time about 5min, is then tested by double-screw extruding pelletizing
Machine is granulated, and Flame Retardant PET Fibres are made.
Preferably, the silica is nano silicon, particle diameter 15-60nm.
Preferably, by silane coupler modified, method of modifying is the silica:Nano silica powder is existed
100 DEG C of dry 24h in vacuum drying chamber;Dried silica is taken to be mixed with 1-METHYLPYRROLIDONE, ultrasonic disperse
30min, silane resin acceptor kh-550 is added in ultrasonic procedure, react and obtain modified nano silicon after 4-6h and disperse
Liquid;Modified precipitation of silica is come out by centrifuging, is placed in 60 DEG C of baking oven and dries.
The beneficial effects of the invention are as follows:
1. using green halogen-free flame retardants, it is fire-retardant that intramolecular is prepared for by copolycondensation technology and solid phase polycondensation technology
PET resin, compared with common PET fiber, fire resistance fibre crystallinity declines so that the dyeability of fiber improves.Flame-retardant PET is fine
Dimension has very excellent fire resistance, and for limited oxygen index up to 35%, fabric leaves the function with self-extinguishment after burning things which may cause a fire disaster.
2. being more than simple blending in system, between particle filled composite and polymer, but there is chemical key connection.So
After one side nano-particle and strand are with chemical bonds, molecular chain movement is made the thing between strand by restraining function
Reason entanglement point is reduced, and equivalent to the class crosslink density for reducing polymer melt, causes melt viscoelasticity to decline.It is smaller in concentration
When modified Nano more uniform can be dispersed in, do not chemically reacted with molecule, very little had an impact to molecule segment.Together
When silica modified body disperse more uniformly, and with nano micropore structure to exist, heat energy can be blocked in material in the base
Conduction and heat radiation in material, effectively lift the fire resistance of material.
Embodiment
With reference to specific embodiment mode, the present invention is described in further detail, to make those skilled in the art join
Book word can be implemented according to this as directed.Obviously, described embodiment is only part of the embodiment of the present invention, rather than entirely
The embodiment in portion.
Embodiment 1:
1) it is silica modified:By nano silica powder 100 DEG C of dryings in vacuum drying chamber that particle diameter is 60nm
24h;Take dried silica to be mixed with 1-METHYLPYRROLIDONE, ultrasonic disperse 30min, it is even that silane is added in ultrasonic procedure
Join agent KH-550, modified nano silicon dioxide dispersion is obtained after reacting 6h;By centrifuging modified dioxy
SiClx is precipitated out, and is placed in 60 DEG C of baking oven and is dried;
2) it is 1 to take ratio:1:0.4 terephthalic acid (TPA), ethylene glycol and 2- carboxyethyl phenyls hypophosphorous acid carries out ester at 250 DEG C
Change reaction, after reacting 40min, into polycondensation phase, for temperature control at 280 DEG C, vacuum is maintained at 12Pa.Polycondensation reaction is completed
Obtain Flame-retardant PET resin afterwards;
3) take modified silica fire-retardant relative to being obtained in the step 2) that silica is 35% with parts by weight
PET resin is successively put into high-speed mixer and mixed at high speed is uniform, incorporation time about 5min, is then made by twin-screw extrusion
Particle test machine is granulated, and Flame Retardant PET Fibres are made;
4) by PET hot pressing on the substrate formed by 65%PP fibers and 35% glass fibre thermoplastic, the thickness of substrate
Spend for 10mm, the thickness of PET is 3mm, that is, obtains wall decorating veneer.
Embodiment 2:
1) it is 1 to take ratio:1:0.4 terephthalic acid (TPA), ethylene glycol and 2- carboxyethyl phenyls hypophosphorous acid carries out ester at 250 DEG C
Change reaction, after reacting 40min, into polycondensation phase, for temperature control at 280 DEG C, vacuum is maintained at 12Pa;Polycondensation reaction is completed
Obtain Flame-retardant PET resin afterwards;
2) take silica first relative to the Flame-retardant PET resin obtained in the step 1) that silica is 35% with parts by weight
After be put into high-speed mixer and mixed at high speed it is uniform, incorporation time about 5min, then pass through double-screw extruding pelletizing testing machine
It is granulated, Flame Retardant PET Fibres is made;
3) by PET hot pressing on the substrate formed by 65%PP fibers and 35% glass fibre thermoplastic, the thickness of substrate
Spend for 10mm, the thickness of PET is 3mm, that is, obtains wall decorating veneer.Relative to wall decorating veneer in embodiment 1, wherein two
Silica is unmodified.
Comparative example 1:
1) it is 1 to take ratio:1:0.4 terephthalic acid (TPA), ethylene glycol and 2- carboxyethyl phenyls hypophosphorous acid carries out ester at 250 DEG C
Change reaction, after reacting 40min, into polycondensation phase, for temperature control at 280 DEG C, vacuum is maintained at 12Pa;Polycondensation reaction is completed
Obtain Flame-retardant PET resin afterwards;
2) by the PET hot pressing obtained in step 1) in the base formed by 65%PP fibers and 35% glass fibre thermoplastic
On plate, the thickness of substrate is 10mm, and the thickness of PET is 3mm, that is, obtains wall decorating veneer.Relative to wall in embodiment 1
Decorative panel, wherein PET resin be not by silica modified.
Wherein, comparative information is as shown in the table:
As seen from the above table, in embodiment 1-2 wall decorating veneer thermal insulation and anti-flammability than excellent performance in comparative example 1,
This is due to that silica disperses more uniformly in the base, and is existed with nano micropore structure, can block heat energy in material
Conduction and heat radiation in material, effectively lift the fire resistance of material.And the silica after silane coupler modified
Grain alleviates agglomeration, is dispersed into nanometer particle, can more effectively strengthen heat-insulating flame-retardant.
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed
With it can be applied to various suitable the field of the invention completely, can be easily for those skilled in the art
Other modification is realized, therefore under the universal limited without departing substantially from claim and equivalency range, it is of the invention and unlimited
In specific details and shown here as the example with description.
Claims (3)
1. a kind of wall decorating veneer, decorated for inner wall of building, it is characterised in that including:The PET of substrate and hot pressing on substrate
Fiber, the thickness of the substrate is 10-15mm, and the thickness of the PET is 1-3mm;
Wherein, the substrate is formed by 65-75%PP fibers and 25-35% glass fibre thermoplastics;
Wherein, the preparation method of PET is as follows:
1) it is 1 to take ratio:1:0.4 terephthalic acid (TPA), ethylene glycol and 2- carboxyethyl phenyls hypophosphorous acid carries out being esterified instead at 250 DEG C
Should, after reacting 40-70min, into polycondensation phase, for temperature control at 280 DEG C, vacuum is maintained at 10-12Pa;Polycondensation reaction is complete
Flame-retardant PET resin is obtained into rear;
2) take silica with parts by weight relative to the Flame-retardant PET resin priority obtained in the step 1) that silica is 3-5%
It is put into high-speed mixer and mixed at high speed is uniform, incorporation time about 5min, is then made by double-screw extruding pelletizing testing machine
Grain, Flame Retardant PET Fibres are made.
2. a kind of wall decorating veneer according to claim 1, it is characterised in that the silica is nanometer titanium dioxide
Silicon, particle diameter 15-60nm.
3. a kind of wall decorating veneer according to claim 1, it is characterised in that the silica passes through silane coupler
Modified, method of modifying is:By nano silica powder in vacuum drying chamber 100 DEG C of dry 24h;Take dried titanium dioxide
Silicon is mixed with 1-METHYLPYRROLIDONE, ultrasonic disperse 30min, and silane resin acceptor kh-550 is added in ultrasonic procedure, reacts 4-6h
Modified nano silicon dioxide dispersion is obtained afterwards;Modified precipitation of silica is come out by centrifuging, is placed in
Dried in 60 DEG C of baking oven.
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CN110041672A (en) * | 2019-04-28 | 2019-07-23 | 杭州大华塑业有限公司 | A kind of fire retardant mylar and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104695043A (en) * | 2015-02-12 | 2015-06-10 | 浙江理工大学 | Preparation method of grafted SiO2 particle cluster orientation reinforced polyester fiber |
CN104892852A (en) * | 2015-04-16 | 2015-09-09 | 黄亨利 | Formula and production process of PET |
CN105464229A (en) * | 2014-08-19 | 2016-04-06 | 南京欧格节能科技有限公司 | External heat-insulation system of external wall |
CN106393918A (en) * | 2016-08-29 | 2017-02-15 | 浙江强盟实业股份有限公司 | Delustering white polyester film and preparation method therefor |
-
2017
- 2017-11-14 CN CN201711120481.XA patent/CN107829533B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105464229A (en) * | 2014-08-19 | 2016-04-06 | 南京欧格节能科技有限公司 | External heat-insulation system of external wall |
CN104695043A (en) * | 2015-02-12 | 2015-06-10 | 浙江理工大学 | Preparation method of grafted SiO2 particle cluster orientation reinforced polyester fiber |
CN104892852A (en) * | 2015-04-16 | 2015-09-09 | 黄亨利 | Formula and production process of PET |
CN106393918A (en) * | 2016-08-29 | 2017-02-15 | 浙江强盟实业股份有限公司 | Delustering white polyester film and preparation method therefor |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110041672A (en) * | 2019-04-28 | 2019-07-23 | 杭州大华塑业有限公司 | A kind of fire retardant mylar and preparation method thereof |
CN110041672B (en) * | 2019-04-28 | 2021-06-01 | 杭州大华塑业有限公司 | Flame-retardant polyester film and preparation method thereof |
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