CN107829335A - A kind of stone synthesis carton paperboard and manufacture device and preparation method - Google Patents

A kind of stone synthesis carton paperboard and manufacture device and preparation method Download PDF

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Publication number
CN107829335A
CN107829335A CN201711166384.4A CN201711166384A CN107829335A CN 107829335 A CN107829335 A CN 107829335A CN 201711166384 A CN201711166384 A CN 201711166384A CN 107829335 A CN107829335 A CN 107829335A
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CN
China
Prior art keywords
core plate
facial tissue
stone
outer layer
carton paperboard
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Granted
Application number
CN201711166384.4A
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Chinese (zh)
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CN107829335B (en
Inventor
闫秋玲
赵化阵
轩海涵
轩伟
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Fujian Shixiang Environmental Protection Technology Co.,Ltd.
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Jining Hengsheng Paper Co Ltd
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Publication of CN107829335A publication Critical patent/CN107829335A/en
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30Multi-ply
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/02Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/08Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/28Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/002Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising natural stone or artificial stone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03Non-macromolecular organic compounds
    • D21H17/05Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/35Polyalkenes, e.g. polystyrene
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/64Alkaline compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/66Salts, e.g. alums
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675Oxides, hydroxides or carbonates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06Paper forming aids
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06Paper forming aids
    • D21H21/08Dispersing agents for fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Cartons (AREA)
  • Paper (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of stone to synthesize carton paperboard, it includes outer layer facial tissue, corrugation core plate, bottom facial tissue, the corrugation core plate is waveform core plate, the filler with equilateral triangle cavity is provided with the trough of the waveform core plate, the corrugation core plate is integrated at a temperature of 160 200 DEG C of degree with the lower surface of the outer layer facial tissue and the upper surface melting of bottom facial tissue, and the outer layer facial tissue, bottom facial tissue and corrugation core plate are made by the raw material of following parts by weight:CaCO350 70, CaO3 10, talcum powder 35, polyethylene 35, Tissuemat E 46, zinc stearate 12, compound coupling agent 0.5 2, dispersant 0.5 1, ultra micro foaming agent 0.1 1, antimony oxide 1 1.5, ammonium phosphate 0.5 1, magnesium hydroxide milky suspension 10 15, decabromodiphenyl acid 0.1 0.5, sodium thiosulfate 1.5 2;Using said structure, compression strength height, moisture resistance waterproof, corrosion-resistant, nondiscoloration, folding and the effect with anti-flaming function are realized.

Description

A kind of stone synthesis carton paperboard and manufacture device and preparation method
Technical field
The present invention relates to a kind of stone synthesis carton paperboard and manufacture device and preparation method.
Background technology
At present, but with the increasingly enhancing of people's environmental protection ideas, along with the increasingly deficient and water and soil of Global Forests resource The worsening shortages of resource, the felling of production carton timber needed for paper are all increasingly restricted in many countries, cause corrugation The source of paper box trade lumber fibre is severely impacted.And traditional carton paperboard should not make for a long time in the larger environment of humidity With this can influence its intensity, meet water and discolouration phenomena occurs, pollute goods in case.
Last century the fifties, occur using plastics, calcium carbonate and a variety of auxiliary agents as raw material, given birth to blowing, the tape casting The environmentally friendly synthetic paper of production, it is characterized in that every physical and mechanical properties is better than conventional paper, humidity, waterproof, corrosion-resistant, dimensionally stable Property it is good, meet a variety of requirements of different field, instead of the certain fields of conventional paper, three wastes are arranged in synthetic paper production process Put, it is environmentally safe, and can be excellent ep-type material by synthetic paper repeated recycling utilize.New environmental protection synthesis Paper-stone paper, the advantages of inheriting synthetic paper, and it is subject to innovation realization 3R principles(Reduce, Reuse, Recycle), i.e., Save, recycling recycles principle, and this is the once change of paper industry, new Environment-friendlystone stone paper, and stone paper is done Into cardboard after be made carton, will have conventional cardboard the advantages of not having:Compression strength is big, moisture resistance waterproof, corrosion-resistant, no Decolourize etc..But stone paper can not be applied to traditional carton making technique.
The content of the invention
The purpose of the present invention is a kind of simple in construction, and easy to use, compression strength is big, moisture resistance waterproof, corrosion-resistant, does not take off Color, folding and the stone synthesis carton paperboard with anti-flaming function.
To achieve the above object, the technical scheme is that a kind of stone synthesizes carton paperboard, it includes outer layer facial tissue 1st, corrugation core plate 3, bottom facial tissue 2, it is characterised in that:The corrugation core plate 3 is waveform core plate 7, in the waveform core plate 7 Trough in be provided with the filler with equilateral triangle cavity 6, the corrugation core plate 3 at a temperature of 160-200 DEG C of degree with it is described outside The lower surface of aspect paper 1 and the upper surface melting of bottom facial tissue 2 are integrated, the outer layer facial tissue 1, bottom facial tissue 2 and corrugated core Plate 3 is made by the raw material of following parts by weight:CaCO350-70, CaO3-10, talcum powder 3-5, polyethylene 3-5, Tissuemat E 4-6, zinc stearate 1-2, compound coupling agent 0.5-2, dispersant 0.5-1, ultra micro foaming agent 0.1-1, antimony oxide 1- 1.5, ammonium phosphate 0.5-1, magnesium hydroxide milky suspension 10-15, decabromodiphenyl acid 0.1-0.5, sodium thiosulfate 1.5-2.
Technical scheme can also be that the filler being provided with the trough of the waveform core plate is band equilateral triangle The glass braid of shape cavity 6 and the poly- methyl silicon resin being filled on the glass braid outer wall, the glass braid Filled with agstone, land plaster, clay, the batch mixing of mica powder in equilateral triangle cavity 6.
Technical scheme can also be the outer layer facial tissue 1, bottom facial tissue 2 and corrugation core plate 3 by following heavy The raw material of amount part is made:CaCO360, CaO 8, talcum powder 4, polyethylene 5, Tissuemat E 6, zinc stearate 2, compound coupling Agent 2, dispersant 0.5, ultra micro foaming agent 0.5, antimony oxide 1.2, ammonium phosphate 0.7, magnesium hydroxide milky suspension 10, ten bromines Diphenic acid 0.4, sodium thiosulfate 1.5, terpene resin 1.6, wherein the upper surface of the outer layer surface paper 1 is also coated with ultraviolet suction Receive layer 4.
Technical scheme can also be that the lower surface of the outer layer facial tissue 1 is also bonded with flexible layer 5, the soft quality Layer 5 is made up of the raw material of following parts by weight:CaCO345, CaO 6, talcum powder 4, polyethylene 3, Tissuemat E 4, zinc stearate 1, Compound coupling agent 3, dispersant 1, ultra micro foaming agent 0.8, antimony oxide 1.5, ammonium phosphate 1, magnesium hydroxide milky suspension 15, polyolefin elastomer 12, modified aluminium hydroxide 3.
The second object of the present invention is to provide a kind of device for manufacturing above-mentioned stone synthesis carton paperboard.
To realize above-mentioned second purpose, the technical scheme is that the device of above-mentioned stone synthesis carton paperboard is manufactured, It includes being arranged on support body 8 on foundation ground, and the left end of the support body is provided with mixer 9, is stirred on the support body 8 and described Mix machine 9 right side be sequentially provided with the comminutor 10 of drying device, spiral pushing device 19, the heater 11 with extruder head, Vacuum shaping platform 12, the first haulage gear 17, separating device 13, the second heating apparatus 14, second with charging aperture 15 Draw-gear 18 and shear platform 20.
The third object of the present invention is to provide a kind of method for preparing above-mentioned stone synthesis carton paperboard.
To realize above-mentioned 3rd purpose, the technical scheme is that a kind of method for preparing stone synthesis carton paperboard, It comprises the following steps:
Step is 1.:By CaCO3, CaO, talcum powder, polyethylene, Tissuemat E, zinc stearate, compound coupling agent, dispersant, Ultra micro foaming agent, antimony oxide, ammonium phosphate, magnesium hydroxide milky suspension, decabromodiphenyl acid 0.1-0.5, sodium thiosulfate By mixer 9, uniformly mixing and then progress vacuum drying handle to water content and are less than 2%;
Step is 2.:Above-mentioned dried batch mixing is heated to 160-200 DEG C of progress extruding pelletization through comminutor 10;
Step is 3.:2. granulation that above-mentioned steps are extruded is delivered to the heater 11 with extruder head by spiral pushing device In, the granulation forms melt flow stream at a temperature of 200-210 DEG C, and melt flow stream foams in the ultra micro at a temperature of this It can be foamed under agent effect, the melt flow stream extruded after foamed enters Vacuum shaping platform 12, and the Vacuum shaping platform 12 under vacuum pressure 0.6MPa, is 2-6mm through the first haulage gear 17 traction setting to thickness, it is thick to obtain stone carton paperboard Plate;
Step is 4.:The 3. thick plate of stone carton paperboard that above-mentioned steps obtain is divided into the outer layer surface through separating device 13 Paper 1, corrugation core plate 3, bottom facial tissue 2, then heated through the second heating apparatus 14, heating-up temperature are arranged to 130-140 DEG C, while After segmentation the top of the corrugation core plate 3 and second heating apparatus 14 heating upper feed inlet 15 at add with equilateral The filler of triangular cavity 6, then by the corrugation core plate 3 and the lower surface of the outer layer facial tissue 1 and the upper table of bottom facial tissue 2 Face melting is integrated, then after the traction setting of the second draw-gear 18, after being drawn for second by 55-60 DEG C of low-temperature bake Stone carton paperboard in stress elimination, subsequently enter air cooling equipment, rich mineral paperboard be cooled into setting thickness as 1-1.8mm Stone synthesis carton paperboard 16;
Step is 5.:Stone synthesis carton paperboard 16 is drawn to shear platform 20, according to setting by the second draw-gear Specification sheared, obtain uniform specification stone synthesis carton paperboard 16.
The beneficial effects of the invention are as follows stone synthesis carton paperboard is designed as into outer layer facial tissue 1, corrugation core plate 3, round floor Paper 2, the corrugation core plate 3 are waveform core plate, are provided with the trough of the waveform core plate with equilateral triangle cavity 6 Filler, the corrugation core plate 3 160-200 DEG C degree at a temperature of with the lower surface of the outer layer facial tissue 1 and the upper table of bottom facial tissue 2 Face melting is integrated, and the outer layer facial tissue 1, bottom facial tissue 2 and corrugation core plate 3 are made by the raw material of following parts by weight: CaCO350-70, CaO3-10, talcum powder 3-5, polyethylene 3-5, Tissuemat E 4-6, zinc stearate 1-2, compound coupling agent 0.5-2, dispersant 0.5-1, ultra micro foaming agent 0.1-1, antimony oxide 1-1.5, ammonium phosphate 0.5-1, magnesium hydroxide emulsus are hanged Turbid 10-15, decabromodiphenyl acid 0.1-0.5, sodium thiosulfate 1.5-2;Due to being set between outer layer surface paper 1 and bottom facial tissue 2 Put corrugation core plate 3 and corrugation core plate 3 is set to waveform core plate, band equilateral triangle is provided with the trough of the waveform core plate The filler of shape cavity 6, the intensity of stone synthesis carton paperboard can be so greatly improved, and in production process, without using water Source, sewage effluent, does not produce waste rubbish, does not burn coal, does not discharge smog, and the leftover pieces of stone synthesis carton paperboard can follow Ring utilizes, it is therefore prevented that environmental pollution, and because its main component is CaCO3The carton paperboard produced with auxiliary agent, realize anti- Compressive Strength is high, moisture resistance waterproof, corrosion-resistant, nondiscoloration, folding and the effect with anti-flaming function.
Brief description of the drawings
Fig. 1 is the structural representation of the present invention
Fig. 2 is the structural representation for preparing stone synthesis carton paperboard device
Fig. 3 is Fig. 2 top view
1 in Fig. 1 to 3, outer layer facial tissue, 2, bottom facial tissue, 3, corrugation core plate, 4, UV-absorbing layer, 5, flexible layer, 6, equilateral three Angular cavity, 7, waveform core plate, 8, support body, 9, mixer, 10, comminutor, 11, heater, 12, Vacuum shaping platform, 13rd, separating device, the 14, second heating apparatus, 15, charging aperture, 16, stone synthesis carton paperboard, the 17, first hauling machine Structure, the 18, second draw-gear, 19, spiral pushing device, 20, shear platform.
Embodiment
According to Fig. 1 to 3, the present invention relates to a kind of stone to synthesize carton paperboard, and it includes outer layer facial tissue 1, corrugated core Plate 3, bottom facial tissue 2, the corrugation core plate 3 are waveform core plate 7, are provided with the trough of the waveform core plate 7 with equilateral The filler of triangular cavity 6, lower surface and bottom of the corrugation core plate 3 at a temperature of 160-200 DEG C of degree with the outer layer facial tissue 1 The upper surface melting of aspect paper 2 is integrated, and the outer layer facial tissue 1, bottom facial tissue 2 and corrugation core plate 3 are by following parts by weight Raw material is made:CaCO350-70, CaO3-10, talcum powder 3-5, polyethylene 3-5, Tissuemat E 4-6, zinc stearate 1-2 are compound Type coupling agent 0.5-2, dispersant 0.5-1, ultra micro foaming agent 0.1-1, antimony oxide 1-1.5, ammonium phosphate 0.5-1, hydroxide Magnesium milky suspension 10-15, decabromodiphenyl acid 0.1-0.5, sodium thiosulfate 1.5-2.
Technical scheme is also preferably that the filler being provided with the trough of the waveform core plate is band equilateral triangle The glass braid of shape cavity 6 and the poly- methyl silicon resin being filled on the glass braid outer wall, the glass braid Filled with agstone, land plaster, clay, the batch mixing of mica powder in equilateral triangle cavity 6.
Technical scheme is also preferably the outer layer facial tissue 1, bottom facial tissue 2 and corrugation core plate 3 by following heavy The raw material of amount part is made:CaCO360, CaO 8, talcum powder 4, polyethylene 5, Tissuemat E 6, zinc stearate 2, compound coupling Agent 2, dispersant 0.5, ultra micro foaming agent 0.5, antimony oxide 1.2, ammonium phosphate 0.7, magnesium hydroxide milky suspension 10, ten bromines Diphenic acid 0.4, sodium thiosulfate 1.5, terpene resin 1.6, wherein the upper surface of the outer layer surface paper 1 is also coated with ultraviolet suction Receive layer 4.
Technical scheme is also preferably that the lower surface of the outer layer facial tissue 1 is also bonded with flexible layer 5, the soft quality Layer 5 is made up of the raw material of following parts by weight:CaCO345, CaO 6, talcum powder 4, polyethylene 3, Tissuemat E 4, zinc stearate 1, Compound coupling agent 3, dispersant 1, ultra micro foaming agent 0.8, antimony oxide 1.5, ammonium phosphate 1, magnesium hydroxide milky suspension 15, polyolefin elastomer 12, modified aluminium hydroxide 3.
The device of above-mentioned stone synthesis carton paperboard is manufactured, it includes the support body 8 being arranged on foundation ground, the support body Left end be provided with mixer 9, be sequentially provided with the comminutor of drying device on the support body 8 and on the right side of the mixer 9 10th, spiral pushing device 19, the heater 11 with extruder head, Vacuum shaping platform 12, the first haulage gear 17, separating Device 13, the second heating apparatus 14 with charging aperture 15, the second draw-gear 18 and shear platform 20.
The method for preparing stone synthesis carton paperboard, it comprises the following steps:
Step is 1.:By CaCO3, CaO, talcum powder, polyethylene, Tissuemat E, zinc stearate, compound coupling agent, dispersant, Ultra micro foaming agent, antimony oxide, ammonium phosphate, magnesium hydroxide milky suspension, decabromodiphenyl acid 0.1-0.5, sodium thiosulfate By mixer 9, uniformly mixing and then progress vacuum drying handle to water content and are less than 2%;
Step is 2.:Above-mentioned dried batch mixing is heated to 160-200 DEG C of progress extruding pelletization through comminutor 10;
Step is 3.:2. granulation that above-mentioned steps are extruded is delivered to the heater 11 with extruder head by spiral pushing device In, the granulation forms melt flow stream at a temperature of 200-210 DEG C, and melt flow stream foams in the ultra micro at a temperature of this It can be foamed under agent effect, the melt flow stream extruded after foamed enters Vacuum shaping platform 12, and the Vacuum shaping platform 12 under vacuum pressure 0.6MPa, is 2-6mm through the first haulage gear 17 traction setting to thickness, it is thick to obtain stone carton paperboard Plate;
Step is 4.:The 3. thick plate of stone carton paperboard that above-mentioned steps obtain is divided into the outer layer surface through separating device 13 Paper 1, corrugation core plate 3, bottom facial tissue 2, then heated through the second heating apparatus 14, heating-up temperature are arranged to 130-140 DEG C, while After segmentation the top of the corrugation core plate 3 and second heating apparatus 14 heating upper feed inlet 15 at add with equilateral The filler of triangular cavity 6, then by the corrugation core plate 3 and the lower surface of the outer layer facial tissue 1 and the upper table of bottom facial tissue 2 Face melting is integrated, then after the traction setting of the second draw-gear 18, after being drawn for second by 55-60 DEG C of low-temperature bake Stone carton paperboard in stress elimination, subsequently enter air cooling equipment, rich mineral paperboard be cooled into setting thickness as 1-1.8mm Stone synthesis carton paperboard 16;
Step is 5.:Stone synthesis carton paperboard 16 is drawn to shear platform 20, according to setting by the second draw-gear Specification sheared, obtain uniform specification stone synthesis carton paperboard 16.
The stone synthesis carton paperboard of the said structure of making can greatly reduce production cost, stone is synthesized carton In process of production, without using water source, sewage effluent, does not produce waste rubbish to cardboard, does not burn coal, does not discharge smog, stone The leftover pieces reusable edible of head synthesis carton paperboard, it is therefore prevented that environmental pollution, due between outer layer surface paper and bottom facial tissue Corrugation core plate is set and corrugation core plate is set to waveform core plate, band equilateral triangle is provided with the trough of the waveform core plate The filler of shape cavity, the intensity of stone synthesis carton paperboard can be so greatly improved, and because its main component is CaCO3With The carton paperboard that auxiliary agent is produced, compression strength height is realized, moisture resistance waterproof, corrosion-resistant, nondiscoloration, folding simultaneously has fire-retardant work( The effect of energy.

Claims (6)

1. a kind of stone synthesizes carton paperboard, it includes outer layer facial tissue(1), corrugation core plate(3), bottom facial tissue(2), its feature exists In:The corrugation core plate(3)For waveform core plate(7), in the waveform core plate(7)Trough in be provided with band equilateral triangle Cavity(6)Filler, the corrugation core plate(3)160-200 DEG C degree at a temperature of with the outer layer facial tissue(1)Lower surface and bottom Aspect paper(2)Upper surface melting be integrated, the outer layer facial tissue(1), bottom facial tissue(2)With corrugation core plate(3)By following The raw material of parts by weight is made:CaCO350-70, CaO3-10, talcum powder 3-5, polyethylene 3-5, Tissuemat E 4-6, zinc stearate 1-2, compound coupling agent 0.5-2, dispersant 0.5-1, ultra micro foaming agent 0.1-1, antimony oxide 1-1.5, ammonium phosphate 0.5- 1, magnesium hydroxide milky suspension 10-15, decabromodiphenyl acid 0.1-0.5, sodium thiosulfate 1.5-2.
A kind of 2. stone synthesis carton paperboard according to claim 1, it is characterised in that:The trough of the waveform core plate The filler being inside provided with is band equilateral triangle cavity(6)Glass braid and be filled in poly- on the glass braid outer wall Methyl silicon resin, the glass braid equilateral triangle cavity(6)It is interior to be filled with agstone, land plaster, clay, mica powder Batch mixing.
A kind of 3. stone synthesis carton paperboard according to claim 1, it is characterised in that:The outer layer facial tissue(1), bottom Facial tissue(2)With corrugation core plate(3)It is made by the raw material of following parts by weight:CaCO3 60, CaO 8, talcum powder 4, polyethylene 5, Tissuemat E 6, zinc stearate 2, compound coupling agent 2, dispersant 0.5, ultra micro foaming agent 0.5, antimony oxide 1.2, phosphoric acid Ammonium 0.7, magnesium hydroxide milky suspension 10, decabromodiphenyl acid 0.4, sodium thiosulfate 1.5, terpene resin 1.6, wherein described outer The upper surface of aspect paper 1 is also coated with UV-absorbing layer(4).
A kind of 4. stone synthesis carton paperboard according to claim 3, it is characterised in that:The following table of the outer layer facial tissue 1 Face is also bonded with flexible layer(5), the flexible layer(5)It is made up of the raw material of following parts by weight:CaCO3 45, CaO 6, talcum powder 4, polyethylene 3, Tissuemat E 4, zinc stearate 1, compound coupling agent 3, dispersant 1, ultra micro foaming agent 0.8, antimony oxide 1.5, ammonium phosphate 1, magnesium hydroxide milky suspension 15, polyolefin elastomer 12, modified aluminium hydroxide 3.
A kind of 5. device for preparing any stone synthesis carton paperboards of the claim 1-4, it is characterised in that:It includes The support body being arranged on foundation ground(8), the left end of the support body is provided with mixer(9), the support body(8)Above and described stir Mix machine(9)Right side be sequentially provided with the comminutor of drying device(10), spiral pushing device(19), with extruder head heating dress Put(11), Vacuum shaping platform(12), the first haulage gear(17), separating device(13), band charging aperture(15)Second Heating apparatus(14), the second draw-gear(18)And shear platform(20).
6. usage right requires the method that 5 described devices prepare the stone synthesis carton paperboard, it is characterised in that:It include with Lower step:
Step is 1.:By CaCO3 , CaO, talcum powder, polyethylene, Tissuemat E, zinc stearate, compound coupling agent, dispersant, Ultra micro foaming agent, antimony oxide, ammonium phosphate, magnesium hydroxide milky suspension, decabromodiphenyl acid 0.1-0.5, sodium thiosulfate Pass through mixer(9)Uniformly mixing and then progress vacuum drying handle to water content and are less than 2%;
Step is 2.:By above-mentioned dried batch mixing through comminutor(10)It is heated to 160-200 DEG C of progress extruding pelletization;
Step is 3.:2. granulation that above-mentioned steps are extruded is delivered to the heater with extruder head by spiral pushing device(11) In, the granulation forms melt flow stream at a temperature of 200-210 DEG C, and melt flow stream foams in the ultra micro at a temperature of this It can be foamed under agent effect, the melt flow stream extruded after foamed enters Vacuum shaping platform(12), and the Vacuum shaping is put down Platform(12)Under vacuum pressure 0.6MPa, through the first haulage gear(17)Traction setting to thickness is 2-6mm, obtains stone carton The thick plate of cardboard;
Step is 4.:The 3. thick plate of stone carton paperboard that above-mentioned steps are obtained is through separating device(13)It is divided into the outer layer Facial tissue(1), corrugation core plate(3), bottom facial tissue(2), then through the second heating apparatus(14)Heating, heating-up temperature are arranged to 130- 140 DEG C, while the corrugation core plate after singulation(3)Top and in second heating apparatus(14)The top charging of heating Mouthful(15)Place adds band equilateral triangle cavity(6)Filler, then by the corrugation core plate(3)With the outer layer facial tissue(1) Lower surface and bottom facial tissue(2)Upper surface melting be integrated, then by the second draw-gear(18)After traction setting, pass through 55-60 DEG C of low-temperature bake second is drawn after stone carton paperboard in stress elimination, air cooling equipment is subsequently entered, by stone The stone that cardboard is cooled into setting thickness as 1-1.8mm synthesizes carton paperboard(16);
Step is 5.:The stone is synthesized by carton paperboard by the second draw-gear(16)Draw to shear platform(20), according to The specification of setting is sheared, and obtains the stone synthesis carton paperboard of uniform specification(16).
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CN111572999A (en) * 2020-05-25 2020-08-25 成都新柯力化工科技有限公司 Wood fiber foaming type packaging paperboard and preparation method thereof
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