CN107828560A - A kind of preparation method of soap rice - Google Patents

A kind of preparation method of soap rice Download PDF

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Publication number
CN107828560A
CN107828560A CN201711258951.9A CN201711258951A CN107828560A CN 107828560 A CN107828560 A CN 107828560A CN 201711258951 A CN201711258951 A CN 201711258951A CN 107828560 A CN107828560 A CN 107828560A
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grinding
soap
binder
blade
discharge barrel
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CN201711258951.9A
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CN107828560B (en
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奇德喜
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/02Compositions of detergents based essentially on soap on alkali or ammonium soaps
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D13/00Making of soap or soap solutions in general; Apparatus therefor
    • C11D13/14Shaping
    • C11D13/18Shaping by extrusion or pressing
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D13/00Making of soap or soap solutions in general; Apparatus therefor
    • C11D13/14Shaping
    • C11D13/20Shaping in the form of small particles, e.g. powder or flakes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06Powder; Flakes; Free-flowing mixtures; Sheets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/005Synthetic soaps
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/38Products in which the composition is not well defined

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to a kind of preparation method of soap rice, it is characterized in that:Carry out saponification using natural ox or suet, coconut oil, palm-kernel oil as raw material and soap base is made, and soap base is made to the ㎜ of particle diameter 8~12 neat soap;Neat soap, essence are added in crutcher, the pot temperature that reconciles is maintained at 60~80 DEG C, with agitator that material stirring in crutcher is uniform, wherein:Essence dosage is 1~1.5 wt%;The material to stir is continued through into three-roll mill to be milled, is milled into laminar material, wherein:For clearance control in 0.2~0.4mm, the rotating speed of roller is 15~25r/min between the two pairs of rollers of three-roll mill;Laminar material is continuously introduced into grinding comminutor to be granulated;Vibratory sieve is set in the lower section of grinding comminutor, after shaker vibration is sieved, obtains the soap rice grain that particle diameter is less than or equal to 0.5 ㎜.Its advantage is:Equipment into it is low, energy consumption is low, production efficiency is high, and soap grain of rice footpath is small, and dissolving power is very strong, is more suitable for machine washing and uses.

Description

A kind of preparation method of soap rice
Technical field
The present invention relates to a kind of preparation method of soap rice, belong to articles for washing technical field.
Background technology
Clothes washing has two kinds of washing and dry-cleaning, dry-cleans and is adapted to laundry to use, and is not suitable for home laundry;Everyday home is washed Wash clothing and take washing, washing has two ways again:First, hand-wash, two be washing machine machine washing.Washing clothing has to use Detergent, existing detergent mainly have:Washing powder, liquid detergent, soap, soap powder, every kind of detergent have advantage and disadvantage, washing powder The advantages of be:Convenient machine washing, dirt-removing power is strong, and shortcoming is:Course of dissolution heat release, hinder hand wound body, not readily dissolve, easily deposition, Easily injury clothes fiber and color, are not easy to rinse;The advantages of liquid detergent is:Clothing not fugitive color, dissolution velocity is fast, easily drift Wash, shortcoming is:It is not easy to determine dosage, it is impossible to it is long-term to place, it is perishable;The advantages of soap is:Dirt-removing power is strong, does not burn skin, Shortcoming is:It can not machine-wash, turn to be yellow, harden after clothes washing, be not easy to rinse;Soap powder is common by soap component and a variety of chemical compositions Form, wherein soap component accounting is less than 70%, and its advantage is:Containing extraordinary lime soap dispersant, strong detergency, low bubble, easily rinsing, Water-saving saves time in washing process, and shortcoming is:Containing chemical addition agent, not environmentally, clothing easily remains calcium soap.As people are good for The enhancing of health, environmental consciousness, to washing class Product Safety and it is functional require more and more higher, just above-mentioned four kinds of detergent and Speech, soap are safety and environmental protection, but soap cannot be used for machine-washing the most so that its use is extremely limited, Er Qieqi The shortcomings that easily being turned to be yellow after existing clothes washing in use, hardening, be not easy to rinse more limits the use of soap.It is actual On, soap wash easily turn to be yellow after clothing, harden, be not easy to rinse main cause be make soap base raw material it is impure, and in order to Reduce soap cost and increase clean result and added with additive in soap(Such as:Talcum powder)Caused by.In order to overcome laundry Powder, liquid detergent, soap powder not environmentally the shortcomings that and soap the shortcomings that can not machine-washing, the present inventor has invented " a kind of soap rice and its system Make method " and patent application, application number are proposed by Hongwei Daily Chemical Co., Ltd., Baotou:2016104551017, after more Entitled " a kind of soap rice ".Although the shortcomings that overcoming washing powder, liquid detergent, soap powder in the disclosure in this patent not environmentally, also solves The problem of soap can not machine-wash, but because the manufacturing process of use is straight line expressing technique, manufacture difficulty is high.Extruder goes out Material end is provided with plate face and is uniformly provided with porous bushing of the aperture in 0.5~1mm discharge openings, and for pressure-bearing, the thickness of bushing is not small In 4cm, hole of the perforate footpath between 0.5~1mm on such thick steel plate, also only have military enterprise to accomplish in China, And want to output the hole that aperture is less than 0.5mm, it can accomplish currently without enterprise.Bushing cost is very high as making, and Soap base extrusion is needed by high pressure by such bushing, in order to increase the pressure-bearing of bushing, discharge end done tapered(Loudspeaker Mouth), while groined type reinforcement is set at the back side of bushing, it just can guarantee that soap rice normally produces.Production efficiency is relatively low, and The column soap rice diameter produced is not less than 0.5mm, and solvability is not good enough in actual use.
The content of the invention
It is an object of the invention to provide one kind can will be processed into diameter less than or equal to 0.5 using pure natural raw material soap base ㎜, equipment cost are low, energy consumption is low, soap rice is more soluble, are more suitable for the preparation method for the soap rice that machine washing uses.
Technical scheme is as follows:
1)Entered using 75~85wt% natural ox or suet, 15~25 wt% coconut oil, 0~5 wt% palm-kernel oil as raw material Soap base is made in row saponification, and soap base is made to the ㎜ of particle diameter 8~12 neat soap;
2)Neat soap, essence are added in crutcher, the pot temperature that reconciles is maintained at 60~80 DEG C, with agitator by material in crutcher Stir, wherein:Essence dosage is 1~1.5 wt%;
3)The material to stir is continued through into three-roll mill to be milled, is milled into laminar material, wherein:Three rollers grind For clearance control in 0.2~0.4mm, the rotating speed of roller is 15~25r/min between the two pairs of rollers of grinding machine;
4)Laminar material is continuously introduced into grinding comminutor to be granulated, grinding comminutor includes feed hopper, discharge barrel, binder Impeller, grinding break bar, feed hopper is the infundibulate of opening upwards, and discharge barrel is the cylindrical shape surrounded by side wall and bottom surface, side wall Discharge opening uniformly is densely covered with, a diameter of of discharge opening is less than or equal to 0.5 mm, and discharge barrel is connected to feed hopper lower end;Binder impeller By binder wheel hub and circumferentially the equally spaced binder blade being arranged on binder wheel hub forms, every binder blade and horizontal plane Into 30~52 ° of inclinations angle, grinding break bar equally spaced grinding blade being arranged on grinding wheel hub by grinding wheel hub and circumferentially Composition, the knife face for grinding blade is arc surface, grinds the knife face and horizontal plane of blade, and binder impeller and grinding break bar use Concentric shafts drive, and concentric shafts pass perpendicularly through discharge barrel bottom center, and are connected by bearing with discharge barrel bottom surface, binder impeller position On grinding break bar, binder wheel hub coordinates with grinding spider creep, and grinding knife sheet head is with discharge barrel side wall into 0~15 degree Angle, and coordinate with discharge barrel sidewall spacers, binder impeller rotates horizontally along binder blade pitch angle institute to direction, grinds break bar Rotated horizontally along grinding blade protrusion direction, and binder impeller is opposite with grinding break bar direction of rotation;Material is sent into grinding and is granulated After machine, by the interlobate gap of binder fall into discharge barrel grinding blade between gap in, binder wheel rotation to material to Under pressure, grinding knife wheel rotates, grinds and form abrasive power between blade and discharge barrel side wall, by material by discharge barrel side wall Discharge opening is ground away, and is fallen naturally according to gravity;
5)Vibratory sieve is set in the lower section of grinding comminutor, after shaker vibration is sieved, particle diameter is obtained and is less than or equal to 0.5 ㎜ Soap rice grain.
A diameter of 0.3~0.5 mm of discharge opening of the discharge barrel;
Annular protective cover is wrapped with the side wall of the discharge barrel, regular geometric shape is uniformly provided with the side wall of protective cover The eyelet of shape;
The wall thickness of the protective cover is not less than 0.3 centimetre;
The quantity of binder blade on the binder impeller is 3~9(Blade quantity is determined by the size of equipment), and be odd number Piece;
The quantity for grinding the grinding blade on break bar is 3~12;
In step 4)In by controlling grind the speed of comminutor, binder impeller and the rotating speed for grinding break bar, make grinding blade Temperature is maintained between 30~50 degrees Celsius.
It is an advantage of the invention that:Using pure natural grease as raw material, without any chemical addition agent, safety and environmental protection, have The functions such as potent decontamination, sterilization, skin care;The process reform straight line of original rotary-type Squeezinggranulator of the present invention The production method that " squash type " is granulated, change into the mode of production of " extruding+grinding " so that equipment cost is greatly reduced, energy consumption Also it is greatly reduced, substantially improves the yield of soap rice, production efficiency is greatly improved, and it is also bright to produce soap grain of rice footpath Aobvious to diminish, dissolving power is very strong, is more suitable for machine washing and uses.
Brief description of the drawings
Fig. 1 is the structure principle chart for grinding comminutor;
Fig. 2 is Fig. 1 top view;
Fig. 3 is the cooperation schematic diagram of binder impeller and grinding break bar;
Fig. 4 is the cooperation schematic diagram of discharge barrel and protective cover.
Embodiment
Referring to the drawings, the present invention is with 75~85wt% natural ox or suet, 15~25 wt% coconut oil, 0~5 wt% Palm-kernel oil carry out saponification for raw material soap base be made, and soap base is made to the ㎜ of particle diameter 8~12 neat soap;By neat soap, perfume (or spice) Finishing enters in crutcher, and the pot temperature that reconciles is maintained at 60~80 DEG C, with agitator that material stirring in crutcher is uniform, and stirring is big About 10 minutes, wherein:Essence dosage is 1~1.5 wt%;The material to stir is continued through into three-roll mill to be ground Mill, is milled into laminar material, wherein:Clearance control is in 0.2~0.4mm, the rotating speed of roller between the two pairs of rollers of three-roll mill 15~25r/min;Laminar material is continuously introduced into grinding comminutor to be granulated, grinding comminutor includes feed hopper 1, discharging Cylinder 3, binder impeller 2, grinding break bar 4, feed hopper is the infundibulate of opening upwards, and discharge barrel is the circle surrounded by side wall and bottom surface Tubular, side wall are uniformly densely covered with discharge opening 7, a diameter of 0.3 mm of discharge opening, and discharge barrel is connected to feed hopper lower end;Binder leaf By binder wheel hub and circumferentially equally spaced three binder blades being arranged on binder wheel hub form wheel, every binder blade and Horizontal plane inclination angle at 45 °, by grinding wheel hub and circumferentially, equally spaced six be arranged on grinding wheel hub grind grinding break bar Sharpening sheet forms, and the knife face for grinding blade is arc surface, grinds the knife face and horizontal plane of blade, binder impeller and grinding knife Wheel is driven using concentric shafts, and concentric shafts pass perpendicularly through discharge barrel bottom center, and are connected by bearing with discharge barrel bottom surface, with one heart The outer shaft 5 of axle is connected with grinding wheel hub, and interior axle 6 is connected with binder wheel hub.Binder impeller is on grinding break bar, pressure wheel Hub coordinates with grinding spider creep, grinding knife sheet head and discharge barrel side wall into 0~15 degree of angle, and with discharge barrel sidewall spacers Coordinate, the stainless steel annular protective cover 8 of 0.3 centimetre of wall thickness is wrapped with the side wall of discharge barrel, in the side wall of protective cover Uniformly it is provided with the eyelet 9 of regular hexagon;Binder impeller is rotated horizontally along binder blade pitch angle institute to direction, and grinding break bar edge is ground Sharpening sheet protrusion direction rotates horizontally, and binder impeller is opposite with grinding break bar direction of rotation;After material is sent into grinding comminutor, Fallen into by the interlobate gap of binder in the gap between the grinding blade in discharge barrel, the binder wheel rotation pressure downward to material Power, grinding knife wheel rotate, and grind and form abrasive power between blade and discharge barrel side wall, the discharge opening by material by discharge barrel side wall Grinding is gone out, and is fallen naturally according to gravity, by controlling the speed for grinding comminutor, binder impeller and the rotating speed for grinding break bar, The temperature of grinding blade is set to be maintained between 30~50 degrees Celsius;In the lower section of grinding comminutor, the vibration of three-layer screen is set Sieve, after shaker vibration is sieved, obtain the soap rice grain that particle diameter is 0.3 ㎜.
Embodiment 1:
The soap base composition of raw materials component of soap rice is:Ox or suet 85wt%, refined coconut 15 wt % of oil, add 1.5 in soap base Wt % flavoring essence, manufactured soap rice grain are the ㎜ of length 1~5, the ㎜ of diameter 0.3 cylinder.For washing machine machine washing clothing Thing, dissolving is fast, strong detergency, low bubble, and easily rinsing, dirt-removing power are strong, non-sclerous after clothes washing, not static electrification.
Embodiment 2:
The soap base composition of raw materials component of soap rice is:Ox or suet 80wt%, 15 wt % of refined coconut oil, the wt % of palm-kernel oil 5, 1.2wt % flavoring essence is added in soap base, manufactured soap rice grain is the ㎜ of length 1~5, the ㎜ of diameter 0.3 cylinder.With In washing machine machine washing of clothes, dissolving is fast, strong detergency, low bubble, and easily rinsing, dirt-removing power are strong, non-sclerous after clothes washing, without Electrostatic.
Embodiment 3:
The soap base composition of raw materials component of soap rice is:Ox or suet 75wt%, 22 wt % of refined coconut oil, palm-kernel oil 3wt %, 1 wt % flavoring essence is added in soap base, manufactured soap rice grain is the ㎜ of length 1~5, the ㎜ of diameter 0.3 cylinder.For Washing machine machine washing of clothes, dissolving is fast, strong detergency, low bubble, and easily rinsing, dirt-removing power are strong, non-sclerous after clothes washing, without quiet Electricity.

Claims (6)

1. a kind of preparation method of soap rice, it is characterized in that:
1)Entered using 75~85wt% natural ox or suet, 15~25 wt% coconut oil, 0~5 wt% palm-kernel oil as raw material Soap base is made in row saponification, and soap base is made to the ㎜ of particle diameter 8~12 neat soap;
2)Neat soap, essence are added in crutcher, the pot temperature that reconciles is maintained at 60~80 DEG C, with agitator by material in crutcher Stir, wherein:Essence dosage is 1~1.5 wt%;
3)The material to stir is continued through into three-roll mill to be milled, is milled into laminar material, wherein:Three rollers grind For clearance control in 0.2~0.4mm, the rotating speed of roller is 15~25r/min between the two pairs of rollers of grinding machine;
4)Laminar material is continuously introduced into grinding comminutor to be granulated, grinding comminutor includes feed hopper, discharge barrel, binder Impeller, grinding break bar, feed hopper is the infundibulate of opening upwards, and discharge barrel is the cylindrical shape surrounded by side wall and bottom surface, side wall Discharge opening uniformly is densely covered with, a diameter of of discharge opening is less than or equal to 0.5 mm, and discharge barrel is connected to feed hopper lower end;Binder impeller By binder wheel hub and circumferentially the equally spaced binder blade being arranged on binder wheel hub forms, every binder blade and horizontal plane Into 30~52 ° of inclinations angle, grinding break bar equally spaced grinding blade being arranged on grinding wheel hub by grinding wheel hub and circumferentially Composition, the knife face for grinding blade is arc surface, grinds the knife face and horizontal plane of blade, and binder impeller and grinding break bar use Concentric shafts drive, and concentric shafts pass perpendicularly through discharge barrel bottom center, and are connected by bearing with discharge barrel bottom surface, binder impeller position On grinding break bar, binder wheel hub coordinates with grinding spider creep, and grinding knife sheet head is with discharge barrel side wall into 0~15 degree Angle, and coordinate with discharge barrel sidewall spacers, binder impeller rotates horizontally along binder blade pitch angle institute to direction, grinds break bar Rotated horizontally along grinding blade protrusion direction, and binder impeller is opposite with grinding break bar direction of rotation;Material is sent into grinding and is granulated After machine, by the interlobate gap of binder fall into discharge barrel grinding blade between gap in, binder wheel rotation to material to Under pressure, grinding knife wheel rotates, grinds and form abrasive power between blade and discharge barrel side wall, by material by discharge barrel side wall Discharge opening is ground away, and is fallen naturally according to gravity;
5)Vibratory sieve is set in the lower section of grinding comminutor, after shaker vibration is sieved, particle diameter is obtained and is less than or equal to 0.5 ㎜ Soap rice grain.
2. the preparation method of soap rice according to claim 1, it is characterized in that:The discharge opening a diameter of 0.3 of the discharge barrel ~0.5 mm.
3. the preparation method of soap rice according to claim 1, it is characterized in that:Circle is wrapped with the side wall of the discharge barrel Ring protection cover, the eyelet of regular geometric shapes is uniformly provided with the side wall of protective cover.
4. the preparation method of soap rice according to claim 1, it is characterized in that:The number of binder blade on the binder impeller Measure as 3~9, and be odd number piece.
5. the preparation method of soap rice according to claim 1, it is characterized in that:The quantity of grinding blade on grinding break bar is 3~12.
6. the preparation method of soap rice according to claim 1, it is characterized in that:In step 4)In pass through control grinding comminutor Speed, binder impeller and grind break bar rotating speed, the temperature of grinding blade is maintained between 30~50 degrees Celsius.
CN201711258951.9A 2017-12-04 2017-12-04 A kind of production method of soap rice Active CN107828560B (en)

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WO2022094339A1 (en) * 2020-10-30 2022-05-05 Apeel Technology, Inc. Compositions and methods of preparation thereof
US11447646B2 (en) 2015-09-16 2022-09-20 Apeel Technology, Inc. Precursor compounds for molecular coatings
US11641865B2 (en) 2020-03-04 2023-05-09 Apeel Technology, Inc. Compounds and formulations for protective coatings
US11767278B2 (en) 2015-12-10 2023-09-26 Apeel Technology, Inc. Plant extract compositions for forming protective coatings
US11918003B2 (en) 2016-11-17 2024-03-05 Apeel Technology, Inc. Compositions formed from plant extracts and methods of preparation thereof

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11447646B2 (en) 2015-09-16 2022-09-20 Apeel Technology, Inc. Precursor compounds for molecular coatings
US11767278B2 (en) 2015-12-10 2023-09-26 Apeel Technology, Inc. Plant extract compositions for forming protective coatings
US11918003B2 (en) 2016-11-17 2024-03-05 Apeel Technology, Inc. Compositions formed from plant extracts and methods of preparation thereof
US11641865B2 (en) 2020-03-04 2023-05-09 Apeel Technology, Inc. Compounds and formulations for protective coatings
WO2022094339A1 (en) * 2020-10-30 2022-05-05 Apeel Technology, Inc. Compositions and methods of preparation thereof
US11827591B2 (en) 2020-10-30 2023-11-28 Apeel Technology, Inc. Compositions and methods of preparation thereof
IL302360B1 (en) * 2020-10-30 2024-09-01 Apeel Tech Inc Compositions and methods of preparation thereof

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