CN107828431A - A kind of method of the converting fuel oil of shell class discarded object microwave radiation technology - Google Patents
A kind of method of the converting fuel oil of shell class discarded object microwave radiation technology Download PDFInfo
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- CN107828431A CN107828431A CN201711077276.XA CN201711077276A CN107828431A CN 107828431 A CN107828431 A CN 107828431A CN 201711077276 A CN201711077276 A CN 201711077276A CN 107828431 A CN107828431 A CN 107828431A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
- C10B47/28—Other processes
- C10B47/32—Other processes in ovens with mechanical conveying means
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G5/00—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas
- C10G5/06—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas by cooling or compressing
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1003—Waste materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Processing Of Solid Wastes (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
A kind of method of the converting fuel oil of shell class discarded object microwave radiation technology, regulate and control downdraft rapid microwave pyrolytic reaction device, 500 750 DEG C of sets target pyrolysis temperature, intended catalyzed 200 500 DEG C of temperature, regulation microwave power is 1000 9000W, charging rate is 5 50kg/h, and mixing speed is 20 120 r/min；When pyrolysis temperature, catalytic temperature reach the desired value of setting, shell class discarded object is continuously added in microwave reaction chamber by feeding screw, agitator pull-type agitation up and down；Pyrolysis residue is discharged into storage slag device；Pyrogenic steam enters liquid header through catalytic reforming, bio-fuel-oil, and biological flue gas is collected by gas collector.The present invention can operate continuously industry, be adapted to industrialized production, the reaction time is short, and side reaction is few, and pyrogenic steam can carry out effective catalytic reforming, improves the quality of biological flue gas.
Description
Technical field
The present invention relates to a kind of method of the converting high valuable chemicals of shell class discarded object rapid microwave.
Background technology
Biomass energy, which has, is distributed wide, renewable, cleanliness（Sulphur, nitrogen content are low）, the advantages that greenhouse gas emissions are few,
It is substitute energy source for petroleum most with prospects on the earth.China's biomass energy is extremely abundant, and developable biomass resource is dived
Power is huge, including agriculture, forestry biomass discarded object, house refuse and organic waste etc..Biomass pyrolytic liquefaction technology by
Researcher more and more payes attention to, and the technology is with relatively low cost, the production technology of serialization by the biologies of low energy densities
Matter is converted into the bio oil of high-energy-density, reduces the volume of biomass, is easy to store and transports.But the fast speed heat of biomass
The bio oil oxygen content height of solution gained, calorific value is low, heat endurance is poor, viscosity is high, acidity is big, corrosivity is strong, therefore its is further
Application receive larger limitation.It is worth noting that, these shortcomings are all closely related with oxygen content height in bio oil.In order to carry
The high biological oil quality of gained, biomass catalyzing fast pyrolysis oil production（Catalytic fast pyrolysis, CFP）Technology meets the tendency of
And give birth to, fast pyrogenation and catalytic reforming liquefaction technology are combined by the technology, to lift its quality before bio oil condenses, are reduced
Bio oil oxygen content, improve hydrocarbon content.
At present, microwave starts to be applied as a kind of Novel heating mode in biomass CFP technologies.Microwave heating
Essence is energy dissipation of the microwave in material, and compared with traditional heating mode, microwave heating has following advantage：（1）Heating
Uniformly；（2）Save energy consumption：（3）Without hysteresis effect；（4）Just with operation；（5）Safety non-pollution.The present inventor's early-stage Study will be micro-
Ripple auxiliary catalysis fast pyrogenation（Microwave-assisted catalytic fast pyrolysis, MACFP）Technology application
Hydrocarbon fuel and biological flue gas are prepared in biomass pyrolytic, achieves a series of progress.
It is worth noting that, although MACFP technologies being capable of uniformly heated material, promotion hydrocarbon generation, but the technology is passing
Thermal effect, catalyst etc. still suffer from a series of distinct issues, including：（1）In terms of heat-transfer effect：Biomass and catalyst
The shortcomings of microwave absorption factor amount is few, dielectric constant is low and heating rate is too slow be present, while in traditional microwave pyrolytic process
Pyrolysis temperature is difficult to regulate and control respectively with catalytic temperature.（2）In terms of catalyst：Microwave current auxiliary catalysis fast pyrolysis technology is mostly
Easily passivation be present and inactivate, separate the defects of difficult in situ catalytic, catalyst.
The content of the invention
The method that the object of the invention provides a kind of converting fuel oil of shell class discarded object microwave radiation technology, its technique is simple,
With continuous operation property, it is adapted to industrialized production, the efficient utilization of biomass resource can be achieved.
What the present invention was achieved through the following technical solutions.
A kind of method of the converting fuel oil of shell class discarded object microwave radiation technology of the present invention, as follows.
Regulate and control downdraft rapid microwave pyrolytic reaction device, 500-750 DEG C of sets target pyrolysis temperature, intended catalyzed temperature
200-500 DEG C, regulation microwave power is 1000-9000W, and charging rate 5-50kg/h, mixing speed is 20-120 r/min.
When pyrolysis temperature, catalytic temperature reach the desired value of setting, shell class discarded object is continuous by feeding screw
Add in microwave reaction chamber, meanwhile, agitator pull-type agitation up and down.
Shell class discarded object is rapidly heated pyrolysis, and caused residue is discharged into storage slag device by orifice plate, is set below orifice plate
Putting anti-gray dividing plate prevents residue from entering gas outlet, and pyrogenic steam passes through high temperature spherical carbide silicon bed in the presence of aspiration pump negative pressure
Layer enters the gas outlet on storage slag device top, and subsequently into Catalyst packing pipe catalytic reforming, life is condensed into finally by condenser
Thing fuel oil enters liquid header, and uncondensable biological flue gas is collected by gas collector.
Shell class discarded object of the present invention includes peanut shell, melon seed cases, pine nut shell, walnut shell, oil tea shell.
Downdraft rapid microwave pyrolytic reaction device of the present invention is by control system（1）, feeding screw（2）, stir
Mix device（3）, heat-insulation layer（4）, microwave magnetron（5）, microwave reaction chamber（6）, thermocouple（7）, spherical carbide silicon（8）, orifice plate
（9）, storage slag device（10）, anti-gray dividing plate（11）, gas outlet（12）, Catalyst packing pipe（13）, heating mantle（14）, condenser
（15）, liquid header（16）, aspiration pump（17）, gas collector（18）Composition.
Feeding screw（2）With microwave reaction chamber（6）Top is connected, microwave reaction chamber（6）Inside there is agitator（3）With it is spherical
Carborundum（8）, outside is followed successively by heat-insulation layer（4）With microwave magnetron（5）, bottom is orifice plate（9）, microwave reaction chamber（6）Outer wall
Embedded with thermocouple（7）, store up slag device（10）With microwave reaction chamber（6）It is connected, centre is separated with orifice plate（9）, store up slag device（10）Inside is set
There is anti-gray dividing plate（11）, top is provided with gas outlet（12）, Catalyst packing pipe（13）With gas outlet（12）It is connected, Catalyst packing
Pipe（13）Outside is heating mantle（14）, condenser（15）With Catalyst packing pipe（13）It is connected, condenser（15）Bottom is provided with liquid
Body collector（16）, aspiration pump（17）With condenser（15）It is connected, aspiration pump（17）Gas vent connects gas collector（18）.
Control system（1）By cable respectively with microwave magnetron（5）, feeding screw（2）, agitator（3）, thermocouple
（7）, heating mantle（14）Connection, to regulate and control microwave power, charging rate, mixing speed, pyrolysis temperature and catalytic temperature.
Described heat-insulation layer（4）Material be alumina silicate fibre.
Described microwave magnetron（5）Quantity be 2-10, each power output is 1-1.5 Kw, and frequency is
2450MHz, the type of cooling are water cooling.
Described microwave reaction chamber（6）Material for high temperature resistant wave-permeable ceramics.
Described spherical carbide silicon（8）A diameter of 2-4cm.
Described orifice plate（9）Bore dia be 1-3cm.
The advantages of apparatus of the present invention, is there is continuous operation property, is adapted to industrialized production, shell class discarded object is in high fever
Pyrolysis temperature is rapidly achieved under the effect of spherical carbide silicon bed, shortens the reaction time, reduces side reaction, pyrogenic steam passes through
High fever spherical carbide silicon bed, promote tar destruction, while catalyst service life is extended by external catalyst, and pyrolysis is steamed
Vapour carries out effective catalytic reforming, effectively improves bio-fuel-oil quality.
Brief description of the drawings
Fig. 1 is the structural representation of the embodiment of the present invention.
Wherein, 1 it is control system, 2 be feeding screw, 3 be agitator, 4 be heat-insulation layer, 5 be microwave magnetron, 6 is
Microwave reaction chamber, 7 be thermocouple, 8 be spherical carbide silicon, 9 be orifice plate, 10 be storage slag device, 11 be anti-gray dividing plate, 12 be outlet
Mouthful, 13 be Catalyst packing pipe, 14 be heating mantle, 15 be condenser, 16 be liquid header, 17 be aspiration pump, 18 be gas
Collector.
Embodiment
The present invention will be further illustrated by the examples that follow with reference to accompanying drawing.
Embodiment 1.
As shown in figure 1, it is 550 DEG C by control system sets target pyrolysis temperature, intended catalyzed temperature is 300 DEG C, is adjusted
Section microwave power is 6000 W, and charging rate 20kg/h, mixing speed is 60 r/min, when reaching sets target temperature,
Melon seed cases are continuously added in microwave reaction chamber by feeding screw, and pull-type agitation, melon seed cases are rapidly heated agitator up and down
Pyrolysis, caused residue are discharged into storage slag device by orifice plate, set anti-gray dividing plate to prevent residue from entering gas outlet below orifice plate,
Pyrogenic steam enters the gas outlet on storage slag device top in the presence of aspiration pump negative pressure by high temperature spherical carbide silicon bed, then
Into Catalyst packing pipe catalytic reforming, it is condensed into bio-fuel-oil finally by condenser and enters liquid header, fuel oil yield
For 55%, hydrocarbon content 57%.
Embodiment 2.
As shown in figure 1, it is 650 DEG C by control system sets target pyrolysis temperature, intended catalyzed temperature is 250 DEG C, is adjusted
Section microwave power is 8000 W, and charging rate 30kg/h, mixing speed is 60 r/min, when reaching sets target temperature,
Peanut shell is continuously added in microwave reaction chamber by feeding screw, and pull-type agitation, peanut shell are rapidly heated agitator up and down
Pyrolysis, caused residue are discharged into storage slag device by orifice plate, set anti-gray dividing plate to prevent residue from entering gas outlet below orifice plate,
Pyrogenic steam enters the gas outlet on storage slag device top in the presence of aspiration pump negative pressure by high temperature spherical carbide silicon bed, then
Into Catalyst packing pipe catalytic reforming, it is condensed into bio-fuel-oil finally by condenser and enters liquid header, fuel oil yield
For 56%, hydrocarbon content 62%.
Embodiment 3.
As shown in figure 1, it is 750 DEG C by control system sets target pyrolysis temperature, intended catalyzed temperature is 350 DEG C, is adjusted
Section microwave power is 6000 W, and charging rate 20kg/h, mixing speed is 60 r/min, when reaching sets target temperature,
Oil tea shell is continuously added in microwave reaction chamber by feeding screw, and pull-type agitation, oil tea shell are rapidly heated agitator up and down
Pyrolysis, caused residue are discharged into storage slag device by orifice plate, set anti-gray dividing plate to prevent residue from entering gas outlet below orifice plate,
Pyrogenic steam enters the gas outlet on storage slag device top in the presence of aspiration pump negative pressure by high temperature spherical carbide silicon bed, then
Into Catalyst packing pipe catalytic reforming, it is condensed into bio-fuel-oil finally by condenser and enters liquid header, fuel oil yield
For 49%, hydrocarbon content 60%.
Embodiment 4.
As shown in figure 1, it is 550 DEG C by control system sets target pyrolysis temperature, intended catalyzed temperature is 300 DEG C, is adjusted
Section microwave power is 6000 W, and charging rate 20kg/h, mixing speed is 60 r/min, when reaching sets target temperature,
Pine nut shell is continuously added in microwave reaction chamber by feeding screw, and pull-type agitation, pine nut shell are rapidly heated agitator up and down
Pyrolysis, caused residue are discharged into storage slag device by orifice plate, set anti-gray dividing plate to prevent residue from entering gas outlet below orifice plate,
Pyrogenic steam enters the gas outlet on storage slag device top in the presence of aspiration pump negative pressure by high temperature spherical carbide silicon bed, then
Into Catalyst packing pipe catalytic reforming, it is condensed into bio-fuel-oil finally by condenser and enters liquid header, fuel oil yield
For 57%, hydrocarbon content 60%.
Claims (2)
- A kind of 1. method of the converting fuel oil of shell class discarded object microwave radiation technology, it is characterized in that as follows：Regulate and control downdraft rapid microwave pyrolytic reaction device, 500-750 DEG C of sets target pyrolysis temperature, intended catalyzed temperature 200- 500 DEG C, regulation microwave power is 1000-9000W, and charging rate 5-50kg/h, mixing speed is 20-120 r/min；When pyrolysis temperature, catalytic temperature reach the desired value of setting, shell class discarded object is continuously added to by feeding screw In microwave reaction chamber, meanwhile, agitator pull-type agitation up and down；Shell class discarded object is rapidly heated pyrolysis, and caused residue is discharged into storage slag device by orifice plate；Pyrogenic steam is being evacuated Enter the gas outlet on storage slag device top in the presence of pump negative pressure by high temperature spherical carbide silicon bed, subsequently into Catalyst packing Pipe catalytic reforming, it is condensed into bio-fuel-oil finally by condenser and enters liquid header, uncondensable biological flue gas passes through Gas collector is collected；Described downdraft rapid microwave pyrolytic reaction device is by control system, feeding screw, agitator, heat-insulation layer, microwave Magnetron, microwave reaction chamber, thermocouple, spherical carbide silicon, orifice plate, storage slag device, anti-gray dividing plate, gas outlet, Catalyst packing pipe, Heating mantle, condenser, liquid header, aspiration pump, gas collector composition；Feeding screw is connected with microwave reaction chamber top, and microwave reaction intracavitary has agitator and spherical carbide silicon, and outside is successively For heat-insulation layer and microwave magnetron, bottom is orifice plate, and microwave reaction cavity outer wall is embedded with thermocouple, stores up slag device and microwave reaction chamber phase Even, centre is separated with orifice plate, is provided with anti-gray dividing plate inside storage slag device, top is provided with gas outlet, Catalyst packing pipe and gas outlet phase Even, it is heating mantle outside Catalyst packing pipe, condenser is connected with Catalyst packing pipe, and condenser is collected provided with liquid Device, aspiration pump are connected with condenser, aspiration pump gas vent connection gas collector；Control system is connected with microwave magnetron, feeding screw, agitator, thermocouple, heating mantle respectively by cable, to adjust Control microwave power, charging rate, mixing speed, pyrolysis temperature and catalytic temperature.
- 2. a kind of method of the converting fuel oil of shell class discarded object microwave radiation technology according to claim 1, it is characterized in that Described shell class discarded object is peanut shell, melon seed cases, pine nut shell, walnut shell or oil tea shell.
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841442A (en) * | 2018-06-08 | 2018-11-20 | 安徽省宝天农贸有限公司 | A kind of preparation method of high-quality sesame oil |
| CN108865402A (en) * | 2018-06-08 | 2018-11-23 | 安徽省宝天农贸有限公司 | A kind of preparation method of rapeseed oil |
| CN109054899A (en) * | 2018-09-12 | 2018-12-21 | 太原理工大学 | A kind of gasifying powder coal device and gasification process |
| CN109054884A (en) * | 2018-09-12 | 2018-12-21 | 太原理工大学 | A method of utilizing lignite and soap stock copyrolysis preparation hydrocarbon-rich oil |
| CN110066671A (en) * | 2019-05-13 | 2019-07-30 | 华南理工大学 | The biomass microwave catalytic pyrolysis method and its integrated apparatus of catalyst regeneration |
| CN110066670A (en) * | 2019-05-13 | 2019-07-30 | 华南理工大学 | The biomass continuous catalysis method for pyrolysis and integrated apparatus of catalyst regeneration |
| CN110437858A (en) * | 2019-08-26 | 2019-11-12 | 华南理工大学 | A kind of method and apparatus of the reproducible micro ware auxiliary catalysis fast pyrogenation house refuse of catalyst |
| CN110964554A (en) * | 2019-12-24 | 2020-04-07 | 哈尔滨工业大学 | Microwave plastic waste oil production device and use method thereof |
| CN115962469A (en) * | 2023-01-09 | 2023-04-14 | 北京鑫风绿能科技有限公司 | Rotary catalytic pyrolysis device and method |
| CN110066671B (en) * | 2019-05-13 | 2024-06-07 | 华南理工大学 | Catalyst regenerated biomass microwave catalytic pyrolysis method and integrated device thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85109267A (en) * | 1984-12-25 | 1986-07-02 | 株式会社荏原制作所 | Waste treatment method and equipment |
| CN1912465A (en) * | 2006-09-11 | 2007-02-14 | 山东大学 | Method and device for pyrolysising bio-matter using microwave |
| WO2010033512A1 (en) * | 2008-09-16 | 2010-03-25 | Regents Of The University Of Minnesota | Improved process for preparing bio-oils from biomass |
| WO2015029377A1 (en) * | 2013-08-27 | 2015-03-05 | 独立行政法人国立高等専門学校機構 | Hydrogen generation device and hydrogen generation method |
| CN104560074A (en) * | 2013-10-22 | 2015-04-29 | 中国石油化工股份有限公司 | System for preparing bio-oil and activated carbon by microwave pyrolysis |
| CN105087036A (en) * | 2015-07-24 | 2015-11-25 | 南昌大学 | Method for quickly pyrolyzing sludge to prepare bio-oil and soil improver by microwave assisted catalysis |
| CN106675661A (en) * | 2015-11-05 | 2017-05-17 | 中国石油化工股份有限公司大连石油化工研究院 | Method for continuous pyrolysis and gasification of material |
| CN106753482A (en) * | 2017-01-18 | 2017-05-31 | 武汉大学 | A kind of biomass pyrolytic catalytic cracking preparing aromatic hydrocarbon integrated reacting device and application method |
-
2017
- 2017-11-06 CN CN201711077276.XA patent/CN107828431B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85109267A (en) * | 1984-12-25 | 1986-07-02 | 株式会社荏原制作所 | Waste treatment method and equipment |
| CN1912465A (en) * | 2006-09-11 | 2007-02-14 | 山东大学 | Method and device for pyrolysising bio-matter using microwave |
| WO2010033512A1 (en) * | 2008-09-16 | 2010-03-25 | Regents Of The University Of Minnesota | Improved process for preparing bio-oils from biomass |
| WO2015029377A1 (en) * | 2013-08-27 | 2015-03-05 | 独立行政法人国立高等専門学校機構 | Hydrogen generation device and hydrogen generation method |
| CN104560074A (en) * | 2013-10-22 | 2015-04-29 | 中国石油化工股份有限公司 | System for preparing bio-oil and activated carbon by microwave pyrolysis |
| CN105087036A (en) * | 2015-07-24 | 2015-11-25 | 南昌大学 | Method for quickly pyrolyzing sludge to prepare bio-oil and soil improver by microwave assisted catalysis |
| CN106675661A (en) * | 2015-11-05 | 2017-05-17 | 中国石油化工股份有限公司大连石油化工研究院 | Method for continuous pyrolysis and gasification of material |
| CN106753482A (en) * | 2017-01-18 | 2017-05-31 | 武汉大学 | A kind of biomass pyrolytic catalytic cracking preparing aromatic hydrocarbon integrated reacting device and application method |
Non-Patent Citations (1)
| Title |
|---|
| 汪洋: "《潜力无穷的生物质能》", 30 September 2014, 甘肃科学技术出版社 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841442A (en) * | 2018-06-08 | 2018-11-20 | 安徽省宝天农贸有限公司 | A kind of preparation method of high-quality sesame oil |
| CN108865402A (en) * | 2018-06-08 | 2018-11-23 | 安徽省宝天农贸有限公司 | A kind of preparation method of rapeseed oil |
| CN109054899A (en) * | 2018-09-12 | 2018-12-21 | 太原理工大学 | A kind of gasifying powder coal device and gasification process |
| CN109054884A (en) * | 2018-09-12 | 2018-12-21 | 太原理工大学 | A method of utilizing lignite and soap stock copyrolysis preparation hydrocarbon-rich oil |
| CN110066671A (en) * | 2019-05-13 | 2019-07-30 | 华南理工大学 | The biomass microwave catalytic pyrolysis method and its integrated apparatus of catalyst regeneration |
| CN110066670A (en) * | 2019-05-13 | 2019-07-30 | 华南理工大学 | The biomass continuous catalysis method for pyrolysis and integrated apparatus of catalyst regeneration |
| CN110066671B (en) * | 2019-05-13 | 2024-06-07 | 华南理工大学 | Catalyst regenerated biomass microwave catalytic pyrolysis method and integrated device thereof |
| CN110066670B (en) * | 2019-05-13 | 2024-06-07 | 华南理工大学 | Catalyst regenerated biomass continuous catalytic pyrolysis method and integrated device |
| CN110437858A (en) * | 2019-08-26 | 2019-11-12 | 华南理工大学 | A kind of method and apparatus of the reproducible micro ware auxiliary catalysis fast pyrogenation house refuse of catalyst |
| CN110964554A (en) * | 2019-12-24 | 2020-04-07 | 哈尔滨工业大学 | Microwave plastic waste oil production device and use method thereof |
| CN115962469A (en) * | 2023-01-09 | 2023-04-14 | 北京鑫风绿能科技有限公司 | Rotary catalytic pyrolysis device and method |
| CN115962469B (en) * | 2023-01-09 | 2023-10-13 | 北京鑫风绿能科技有限公司 | Rotary catalytic pyrolysis device and method |
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