CN107827441B - Ceramic material and preparation method thereof - Google Patents

Ceramic material and preparation method thereof Download PDF

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CN107827441B
CN107827441B CN201711094057.2A CN201711094057A CN107827441B CN 107827441 B CN107827441 B CN 107827441B CN 201711094057 A CN201711094057 A CN 201711094057A CN 107827441 B CN107827441 B CN 107827441B
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ceramic material
carbon fiber
titanium dioxide
tourmaline powder
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CN107827441A (en
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庄勇
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Dehua Jianyi Ceramics Co., Ltd
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Dehua Jianyi Ceramics Co Ltd
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Abstract

the invention provides a ceramic material and a preparation method thereof, wherein the ceramic material comprises the following components: 6-20 parts of zirconium dioxide; 10-20 parts of aluminum nitride, 10-30 parts of zinc silicate, 4-8 parts of barium chromate, 30-50 parts of diatomite, 1-8 parts of carbon fiber tube, 8-19 parts of borax, 10-20 parts of ferrous oxide, 40-60 parts of bentonite, 3-9 parts of titanium dioxide and 8-20 parts of magnesium tourmaline powder. Compared with the prior art, the carbon fiber tube, the ferrous oxide, the titanium dioxide and the magnesium tourmaline powder adopted by the invention have antibacterial effect, and all raw materials have synergistic effect, so that the prepared ceramic material has good antibacterial effect. In addition, the ceramic material prepared by the invention has good mechanical property.

Description

ceramic material and preparation method thereof
Technical Field
The invention relates to the technical field of ceramics, in particular to a ceramic material and a preparation method thereof.
background
Ceramic materials are inorganic non-metallic materials made from natural or synthetic compounds through shaping and high-temperature sintering, and can be used as structural materials and cutter materials, and ceramic materials also can be used as functional materials because of certain special properties. Due to the particularity of the raw materials and the preparation process, the ceramic material has natural porosity. The presence of porosity ensures that the ceramic material has particularly good properties and allows a reduction in the weight of the ceramic material. The ceramic prepared from different raw materials has different properties, and during the process of preparing the ceramic material, fibrous substances are usually added to increase the porosity and the pore size of the ceramic material so as to mutually communicate a large number of pores.
Ceramic materials and methods for their preparation have been widely reported in the prior art, for example, chinese patent application No. 201380067388.0 reports a ceramic material comprising a metal oxide obtained by calcination of hydrotalcite, which is used for the preparation of transparent ceramics having an RIT value of > 40% at a light wavelength of 300nm, 600nm or 1500 nm. The Chinese patent document with the application number of 201510557300.4 reports an improved ceramic material, which comprises, by weight, 30-40 parts of barium titanate, 35-40 parts of zirconium dioxide, 15-20 parts of aluminum nitride, 10-15 parts of diatomite, 4-8 parts of methyl triacetoxysilane, 1-2 parts of foamed nickel, 1-2 parts of germanium and 1-5 parts of a component A, wherein the component A is a mixture of magnesium oxide and gallium oxide, and the weight ratio of the magnesium oxide to the gallium oxide is 1: (0.05-0.1).
However, none of the ceramic materials reported above have an antibacterial function. The inventor considers to provide a ceramic material with an antibacterial function and a preparation method thereof.
Disclosure of Invention
The invention aims to provide a ceramic material and a preparation method thereof, which have good antibacterial function.
In view of the above, the present invention provides a ceramic material, comprising the following components: 6-20 parts of zirconium dioxide; 10-20 parts of aluminum nitride, 10-30 parts of zinc silicate, 4-8 parts of barium chromate, 30-50 parts of diatomite, 1-8 parts of carbon fiber tube, 8-19 parts of borax, 10-20 parts of ferrous oxide, 40-60 parts of bentonite, 3-9 parts of titanium dioxide and 8-20 parts of magnesium tourmaline powder.
preferably, the aluminum nitride is 10 to 15 parts by weight.
Preferably, the zinc silicate is 15 to 25 parts by weight.
Preferably, the barium chromate is 5 to 7 parts by weight.
Preferably, the carbon fiber tube is 2 to 6 parts by weight.
Preferably, 10 to 15 parts by weight of borax.
Preferably, the ferrous oxide accounts for 15 to 18 parts by weight.
Preferably, the titanium dioxide is 5 to 8 parts by weight.
Preferably, 10-15 parts by weight of the magnesium tourmaline powder.
correspondingly, the invention also provides a preparation method of the ceramic material, which comprises the following steps: 6-20 parts by weight of zirconium dioxide; 10-20 parts of aluminum nitride, 10-30 parts of zinc silicate, 4-8 parts of barium chromate, 30-50 parts of diatomite, 1-8 parts of carbon fiber tube, 8-19 parts of borax, 10-20 parts of ferrous oxide, 40-60 parts of bentonite, 3-9 parts of titanium dioxide and 8-20 parts of magnesium tourmaline powder, and sintering at 800-850 ℃ for 3-10 hours to obtain the ceramic material.
The invention provides a ceramic material and a preparation method thereof, wherein the ceramic material comprises the following components: 6-20 parts of zirconium dioxide; 10-20 parts of aluminum nitride, 10-30 parts of zinc silicate, 4-8 parts of barium chromate, 30-50 parts of diatomite, 1-8 parts of carbon fiber tube, 8-19 parts of borax, 10-20 parts of ferrous oxide, 40-60 parts of bentonite, 3-9 parts of titanium dioxide and 8-20 parts of magnesium tourmaline powder. Compared with the prior art, the carbon fiber tube, the ferrous oxide, the titanium dioxide and the magnesium tourmaline powder adopted by the invention have antibacterial effect, and all raw materials have synergistic effect, so that the prepared ceramic material has good antibacterial effect. In addition, the ceramic material prepared by the invention has good mechanical property.
Detailed Description
For a further understanding of the invention, reference will now be made to the preferred embodiments of the invention by way of example, and it is to be understood that the description is intended to further illustrate features and advantages of the invention, and not to limit the scope of the claims.
The embodiment of the invention discloses a ceramic material, which comprises the following components: 6-20 parts of zirconium dioxide; 10-20 parts of aluminum nitride, 10-30 parts of zinc silicate, 4-8 parts of barium chromate, 30-50 parts of diatomite, 1-8 parts of carbon fiber tube, 8-19 parts of borax, 10-20 parts of ferrous oxide, 40-60 parts of bentonite, 3-9 parts of titanium dioxide and 8-20 parts of magnesium tourmaline powder.
Preferably, the aluminum nitride is 10 to 15 parts by weight, the zinc silicate is 15 to 25 parts by weight, the barium chromate is 5 to 7 parts by weight, the carbon fiber tube is 2 to 6 parts by weight, the borax is 10 to 15 parts by weight, the ferrous oxide is 15 to 18 parts by weight, the titanium dioxide is 5 to 8 parts by weight, and the magnesium tourmaline powder is 10 to 15 parts by weight.
Correspondingly, the invention also provides a preparation method of the ceramic material, which comprises the following steps: 6-20 parts by weight of zirconium dioxide; 10-20 parts of aluminum nitride, 10-30 parts of zinc silicate, 4-8 parts of barium chromate, 30-50 parts of diatomite, 1-8 parts of carbon fiber tube, 8-19 parts of borax, 10-20 parts of ferrous oxide, 40-60 parts of bentonite, 3-9 parts of titanium dioxide and 8-20 parts of magnesium tourmaline powder, and sintering at 800-850 ℃ for 3-10 hours to obtain the ceramic material.
according to the scheme, the ceramic material provided by the invention has good high-temperature resistance, high mechanical strength and good comprehensive performance. According to the invention, zinc silicate, barium chromate, diatomite, borax and bentonite are added on the basis of zirconium dioxide and aluminum nitride, so that the hardness, strength and high temperature resistance of the material are improved. The adopted carbon fiber tube, the ferrous oxide, the titanium dioxide and the magnesium tourmaline powder have antibacterial effects, and all raw materials have synergistic effects, so that the prepared ceramic material has a good antibacterial effect.
For further understanding of the present invention, the following embodiments are provided to illustrate the technical solutions of the present invention in detail, and the scope of the present invention is not limited by the following embodiments.
The raw materials adopted in the embodiment of the invention are all commercially available.
Example 1
The invention relates to a ceramic material, which comprises the following components in parts by weight: 10 parts of zirconium dioxide, 15 parts of aluminum nitride, 20 parts of zinc silicate, 5 parts of barium chromate, 40 parts of diatomite, 3 parts of carbon fiber tubes, 10 parts of borax, 15 parts of ferrous oxide, 50 parts of bentonite, 6 parts of titanium dioxide and 10 parts of magnesium tourmaline powder.
The preparation method comprises the following steps:
Mixing 10 parts of zirconium dioxide, 15 parts of aluminum nitride, 20 parts of zinc silicate, 5 parts of barium chromate, 40 parts of diatomite, 3 parts of carbon fiber tubes, 10 parts of borax, 15 parts of ferrous oxide, 50 parts of bentonite, 6 parts of titanium dioxide and 10 parts of magnesium tourmaline powder, and sintering at 800 ℃ for 5 hours to obtain the ceramic material.
Example 2
The invention relates to a ceramic material, which comprises, by weight, 10 parts of zirconium dioxide, 15 parts of aluminum nitride, 20 parts of zinc silicate, 5 parts of barium chromate, 40 parts of diatomite, 3 parts of carbon fiber tubes, 10 parts of borax, 15 parts of ferrous oxide, 50 parts of bentonite, 6 parts of titanium dioxide and 10 parts of magnesium tourmaline powder.
The preparation method comprises the following steps:
Mixing 10 parts of zirconium dioxide, 15 parts of aluminum nitride, 20 parts of zinc silicate, 5 parts of barium chromate, 40 parts of diatomite, 3 parts of carbon fiber tubes, 10 parts of borax, 15 parts of ferrous oxide, 50 parts of bentonite, 6 parts of titanium dioxide and 10 parts of magnesium tourmaline powder, and sintering at 800 ℃ for 5 hours to obtain the ceramic material.
example 3
The invention relates to a ceramic material, which comprises the following components in parts by weight: 20 parts of zirconium dioxide, 10 parts of aluminum nitride, 30 parts of zinc silicate, 4 parts of barium chromate, 30 parts of diatomite, 8 parts of carbon fiber tubes, 19 parts of borax, 20 parts of ferrous oxide, 40 parts of bentonite, 3 parts of titanium dioxide and 8 parts of magnesium tourmaline powder.
The preparation method comprises the following steps:
Mixing 20 parts of zirconium dioxide, 10 parts of aluminum nitride, 30 parts of zinc silicate, 4 parts of barium chromate, 30 parts of diatomite, 8 parts of carbon fiber tubes, 19 parts of borax, 20 parts of ferrous oxide, 40 parts of bentonite, 3 parts of titanium dioxide and 8 parts of magnesium tourmaline powder, and sintering at 800 ℃ for 5 hours to obtain the ceramic material.
Example 4
The invention relates to a ceramic material, which comprises the following components in parts by weight: 6 parts of zirconium dioxide, 20 parts of aluminum nitride, 10 parts of zinc silicate, 8 parts of barium chromate, 50 parts of diatomite, 8 parts of carbon fiber tubes, 8 parts of borax, 10 parts of ferrous oxide, 60 parts of bentonite, 9 parts of titanium dioxide and 20 parts of magnesium tourmaline powder.
The preparation method comprises the following steps:
6 parts of zirconium dioxide, 20 parts of aluminum nitride, 10 parts of zinc silicate, 8 parts of barium chromate, 50 parts of diatomite, 8 parts of carbon fiber tubes, 8 parts of borax, 10 parts of ferrous oxide, 60 parts of bentonite, 9 parts of titanium dioxide and 20 parts of magnesium tourmaline powder are mixed and sintered for 5 hours at 800 ℃ to obtain the ceramic material.
Example 5
The invention relates to a ceramic material, which comprises the following components in parts by weight: 12 parts of zirconium dioxide, 15 parts of aluminum nitride, 22 parts of zinc silicate, 6 parts of barium chromate, 42 parts of diatomite, 5 parts of carbon fiber tubes, 12 parts of borax, 15 parts of ferrous oxide, 45 parts of bentonite, 6 parts of titanium dioxide and 18 parts of magnesium tourmaline powder.
the preparation method comprises the following steps:
Mixing 12 parts of zirconium dioxide, 15 parts of aluminum nitride, 22 parts of zinc silicate, 6 parts of barium chromate, 42 parts of diatomite, 5 parts of carbon fiber tubes, 12 parts of borax, 15 parts of ferrous oxide, 45 parts of bentonite, 6 parts of titanium dioxide and 18 parts of magnesium tourmaline powder, and sintering at 800 ℃ for 5 hours to obtain the ceramic material.
The performance of the ceramic materials prepared by the embodiments of the present invention were respectively tested, and the results are shown in table 1.
Table 1 results of performance tests of ceramic materials prepared in accordance with examples of the present invention
The above description of the embodiments is only intended to facilitate the understanding of the method of the invention and its core idea. It should be noted that, for those skilled in the art, it is possible to make various improvements and modifications to the present invention without departing from the principle of the present invention, and those improvements and modifications also fall within the scope of the claims of the present invention.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

Claims (10)

1. a ceramic material, comprising the following components:
6-20 parts of zirconium dioxide; 10-20 parts of aluminum nitride, 10-30 parts of zinc silicate, 4-8 parts of barium chromate, 30-50 parts of diatomite, 1-8 parts of carbon fiber tube, 8-19 parts of borax, 10-20 parts of ferrous oxide, 40-60 parts of bentonite, 3-9 parts of titanium dioxide and 8-20 parts of magnesium tourmaline powder.
2. ceramic material according to claim 1,
10-15 parts of aluminum nitride.
3. Ceramic material according to claim 1,
15-25 parts of zinc silicate.
4. Ceramic material according to claim 1,
5-7 parts of barium chromate.
5. Ceramic material according to claim 1,
2-6 parts of carbon fiber tube.
6. Ceramic material according to claim 1,
10-15 parts of borax.
7. Ceramic material according to claim 1,
15-18 parts of ferrous oxide.
8. Ceramic material according to claim 1,
5-8 parts of titanium dioxide.
9. Ceramic material according to claim 1,
10-15 parts of magnesium tourmaline powder.
10. The preparation method of the ceramic material is characterized by comprising the following steps:
6-20 parts by weight of zirconium dioxide; 10-20 parts of aluminum nitride, 10-30 parts of zinc silicate, 4-8 parts of barium chromate, 30-50 parts of diatomite, 1-8 parts of carbon fiber tube, 8-19 parts of borax, 10-20 parts of ferrous oxide, 40-60 parts of bentonite, 3-9 parts of titanium dioxide and 8-20 parts of magnesium tourmaline powder, and sintering at 800-850 ℃ for 3-10 hours to obtain the ceramic material.
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DE102012023318A1 (en) * 2012-11-29 2014-06-05 Refratechnik Holding Gmbh Use of unfired refractory products as delivery of large volume industrial furnaces and industrial furnaces lined with unfired refractory products
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