CN107815128A - Adsorbed film with antioxygenic property - Google Patents

Adsorbed film with antioxygenic property Download PDF

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Publication number
CN107815128A
CN107815128A CN201711085490.XA CN201711085490A CN107815128A CN 107815128 A CN107815128 A CN 107815128A CN 201711085490 A CN201711085490 A CN 201711085490A CN 107815128 A CN107815128 A CN 107815128A
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parts
powder
raw material
antioxygenic property
toughener
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张永宏
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2391/00Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C08J2391/06Waxes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2489/00Characterised by the use of proteins; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
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  • Cosmetics (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)
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Abstract

The present invention provides a kind of adsorbed film with antioxygenic property, is mainly made up of following raw material by mass fraction proportioning:8 12 parts of tourmaline powder, 8 12 parts of antigorite powder, 48 parts of 2 benzothiazole sulfenamide of N cyclohexyl, 15 22 parts of activated carbon composite nano fiber, 36 parts of andrographolide, 8 18 parts of graphene, 15 22 parts of chlorinated paraffin, 4 12 parts of carboxylic acid, 58 parts of Soybean Peptide, 7 10 parts of toughener.Electrostatic Absorption film raw material compatibility of the present invention is reasonable, green, has splendid antioxygenic property, and has certain resistance to mould, all without mould growth in oxygen-enriched environment and wet environment.

Description

Adsorbed film with antioxygenic property
Technical field
The present invention relates to bioengineering field of new materials, and in particular to a kind of adsorbed film with antioxygenic property.
Background technology
At present, national coal furnace accounts for the overwhelming majority in electric power, central heating industry.Fire coal boiler fume dedusting technology experienced The process of water film dedusting, bag-type dust to electric precipitation.Put into practice with the raising and using for sack cleaner of national requirements for environmental protection, Occurs the trend using sack cleaner again now.But some shortcomings be present in it, as service life is too short, so as to need through Often change;In addition, long-term use of bag-type dust easily causes equipment obstruction;And high also turn into of power consumption limits the one of its large-scale use Individual key factor.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of adsorbed film with antioxygenic property.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of adsorbed film with antioxygenic property, mainly it is made up of following raw material by mass fraction proportioning:Tourmaline powder 8-12 parts, antigorite powder 8-12 parts, N cyclohexyl 2 benzothiazole sulfenamide 4-8 parts, activated carbon composite nano fiber 15-22 parts, andrographolide 3-6 parts, graphene 8-18 parts, chlorinated paraffin 15-22 parts, carboxylic acid 4-12 parts, Soybean Peptide 5-8 parts, Toughener 7-10 parts;
The toughener is made from the following raw materials in parts by weight:0.9 part of sodium succinate, 6.3 parts of nano titanium oxide, three second 0.5 part of hydramine, 0.1 part of guar gum ether, 0.1 part of bamboo-carbon fibre, its preparation method are that each raw material is well mixed.
Further, mainly it is made up of following raw material by mass fraction proportioning:10 parts of tourmaline powder, antigorite powder 10 Part, 6 parts of N cyclohexyl 2 benzothiazole sulfenamide, 19 parts of activated carbon composite nano fiber, 4 parts of andrographolide, graphene 13 parts, 19 parts of chlorinated paraffin, 8 parts of carboxylic acid, 7 parts of Soybean Peptide, 8 parts of toughener.
Further, Electrostatic Absorption membrane preparation method comprises the following steps:By tourmaline powder, antigorite powder, N- hexamethylenes Base -2-[4-morpholinodithio sulfenamide, activated carbon composite nano fiber, andrographolide, graphene, chlorinated paraffin, carboxylic acid, soybean Peptide, toughener equal proportion in mass ratio are added in reactor, are made under conditions of temperature is 530 DEG C, pressure is 4.3MPa molten Melt thing, and powder is made through drying, crushing, particle diameter is 104 nanometers, and by powder coated into mould, electrostatic is made in compression molding Adsorbed film.
The beneficial effects of the invention are as follows:Electrostatic Absorption film raw material compatibility of the present invention is reasonable, green, has splendid resist Oxidation susceptibility, and have certain resistance to mould, all without mould growth in oxygen-enriched environment and wet environment.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of adsorbed film with antioxygenic property, mainly it is made up of following raw material by mass fraction proportioning:Tourmaline powder 10 parts, 10 parts of antigorite powder, 6 parts of N cyclohexyl 2 benzothiazole sulfenamide, 19 parts of activated carbon composite nano fiber, wear 4 parts of heart lotus lactone, 13 parts of graphene, 19 parts of chlorinated paraffin, 8 parts of carboxylic acid, 7 parts of Soybean Peptide, 8 parts of toughener;
Toughener is made from the following raw materials in parts by weight:0.9 part of sodium succinate, 6.3 parts of nano titanium oxide, triethanolamine 0.5 part, 0.1 part of guar gum ether, 0.1 part of bamboo-carbon fibre, its preparation method be that each raw material is well mixed.
Electrostatic Absorption membrane preparation method comprises the following steps:By tourmaline powder, antigorite powder, N- cyclohexyl -2- benzos Thiazolesulfenamide, activated carbon composite nano fiber, andrographolide, graphene, chlorinated paraffin, carboxylic acid, Soybean Peptide, toughener Equal proportion is added in reactor in mass ratio, fused mass is made under conditions of temperature is 530 DEG C, pressure is 4.3MPa, and pass through Powder is made in dry, crushing, and particle diameter is 104 nanometers, and by powder coated into mould, Electrostatic Absorption film is made in compression molding.
Embodiment 2
A kind of adsorbed film with antioxygenic property, mainly it is made up of following raw material by mass fraction proportioning:Tourmaline powder 8 Part, 8 parts of antigorite powder, 4 parts of N cyclohexyl 2 benzothiazole sulfenamide, 15 parts of activated carbon composite nano fiber, Herba Andrographitis 3 parts of lactone, 8 parts of graphene, 15 parts of chlorinated paraffin, 4 parts of carboxylic acid, 5 parts of Soybean Peptide, 7 parts of toughener;
Toughener is made from the following raw materials in parts by weight:0.9 part of sodium succinate, 6.3 parts of nano titanium oxide, triethanolamine 0.5 part, 0.1 part of guar gum ether, 0.1 part of bamboo-carbon fibre, its preparation method be that each raw material is well mixed.
Electrostatic Absorption membrane preparation method comprises the following steps:By tourmaline powder, antigorite powder, N- cyclohexyl -2- benzos Thiazolesulfenamide, activated carbon composite nano fiber, andrographolide, graphene, chlorinated paraffin, carboxylic acid, Soybean Peptide, toughener Equal proportion is added in reactor in mass ratio, fused mass is made under conditions of temperature is 530 DEG C, pressure is 4.3MPa, and pass through Powder is made in dry, crushing, and particle diameter is 104 nanometers, and by powder coated into mould, Electrostatic Absorption film is made in compression molding.
Embodiment 3
A kind of adsorbed film with antioxygenic property, mainly it is made up of following raw material by mass fraction proportioning:Tourmaline powder 12 parts, 12 parts of antigorite powder, 8 parts of N cyclohexyl 2 benzothiazole sulfenamide, 22 parts of activated carbon composite nano fiber, wear 6 parts of heart lotus lactone, 18 parts of graphene, 22 parts of chlorinated paraffin, 12 parts of carboxylic acid, 8 parts of Soybean Peptide, 10 parts of toughener;
Toughener is made from the following raw materials in parts by weight:0.9 part of sodium succinate, 6.3 parts of nano titanium oxide, triethanolamine 0.5 part, 0.1 part of guar gum ether, 0.1 part of bamboo-carbon fibre, its preparation method be that each raw material is well mixed.
Electrostatic Absorption membrane preparation method comprises the following steps:By tourmaline powder, antigorite powder, N- cyclohexyl -2- benzos Thiazolesulfenamide, activated carbon composite nano fiber, andrographolide, graphene, chlorinated paraffin, carboxylic acid, Soybean Peptide, toughener Equal proportion is added in reactor in mass ratio, fused mass is made under conditions of temperature is 530 DEG C, pressure is 4.3MPa, and pass through Powder is made in dry, crushing, and particle diameter is 104 nanometers, and by powder coated into mould, Electrostatic Absorption film is made in compression molding.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (3)

1. a kind of adsorbed film with antioxygenic property, it is characterised in that be mainly made up of following raw material by mass fraction proportioning: Tourmaline powder 8-12 parts, antigorite powder 8-12 parts, N cyclohexyl 2 benzothiazole sulfenamide 4-8 parts, activated carbon is compound receives Rice fiber 15-22 parts, andrographolide 3-6 parts, graphene 8-18 parts, chlorinated paraffin 15-22 parts, carboxylic acid 4-12 parts, Soybean Peptide 5-8 parts, toughener 7-10 parts;
The toughener is made from the following raw materials in parts by weight:0.9 part of sodium succinate, 6.3 parts of nano titanium oxide, triethanolamine 0.5 part, 0.1 part of guar gum ether, 0.1 part of bamboo-carbon fibre, its preparation method be that each raw material is well mixed.
2. there is the adsorbed film of antioxygenic property as claimed in claim 1, it is characterised in that quality is mainly pressed by following raw material Number proportioning is made:10 parts of tourmaline powder, 10 parts of antigorite powder, 6 parts of N cyclohexyl 2 benzothiazole sulfenamide, activity 19 parts of charcoal composite nano fiber, 4 parts of andrographolide, 13 parts of graphene, 19 parts of chlorinated paraffin, 8 parts of carboxylic acid, 7 parts of Soybean Peptide, increasing Tough dose 8 parts.
3. there is the adsorbed film of antioxygenic property as claimed in claim 1 or 2, it is characterised in that Electrostatic Absorption film preparation side Method comprises the following steps:By tourmaline powder, antigorite powder, N cyclohexyl 2 benzothiazole sulfenamide, activated carbon is compound receives Rice fiber, andrographolide, graphene, chlorinated paraffin, carboxylic acid, Soybean Peptide, toughener equal proportion in mass ratio add reactor In, fused mass is made under conditions of temperature is 530 DEG C, pressure is 4.3MPa, and powder is made through drying, crushing, particle diameter is 104 nanometers, by powder coated into mould, Electrostatic Absorption film is made in compression molding.
CN201711085490.XA 2017-11-07 2017-11-07 Adsorbed film with antioxygenic property Pending CN107815128A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104962018A (en) * 2015-07-14 2015-10-07 常州市盈顺电子有限公司 Polyvinylidene fluoride dust removal adsorption nano film and preparation method thereof
CN105017677A (en) * 2015-06-29 2015-11-04 苏州佑君环境科技有限公司 Electrostatic dust collection adsorption film and production method thereof
CN105111513A (en) * 2015-10-08 2015-12-02 曲阜师范大学 Composite film based on modified natural polymer and application of composite film
CN106084260A (en) * 2016-06-14 2016-11-09 吉林市润成膜科技有限公司 A kind of preparation method of PVDF adsorbed film

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105017677A (en) * 2015-06-29 2015-11-04 苏州佑君环境科技有限公司 Electrostatic dust collection adsorption film and production method thereof
CN104962018A (en) * 2015-07-14 2015-10-07 常州市盈顺电子有限公司 Polyvinylidene fluoride dust removal adsorption nano film and preparation method thereof
CN105111513A (en) * 2015-10-08 2015-12-02 曲阜师范大学 Composite film based on modified natural polymer and application of composite film
CN106084260A (en) * 2016-06-14 2016-11-09 吉林市润成膜科技有限公司 A kind of preparation method of PVDF adsorbed film

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