CN107814615A - A kind of production method of the biogas slurry base foliar fertilizer of efficiently preventing and treating gray mold - Google Patents

A kind of production method of the biogas slurry base foliar fertilizer of efficiently preventing and treating gray mold Download PDF

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Publication number
CN107814615A
CN107814615A CN201710985336.1A CN201710985336A CN107814615A CN 107814615 A CN107814615 A CN 107814615A CN 201710985336 A CN201710985336 A CN 201710985336A CN 107814615 A CN107814615 A CN 107814615A
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foliar fertilizer
biogas slurry
gray mold
added
treating gray
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CN201710985336.1A
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刘青亚
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers

Abstract

A kind of biogas slurry base foliar fertilizer of efficiently preventing and treating gray mold, it is characterized in that, its matrix using biogas slurry as foliar fertilizer, the viscosity of potassium humate and Arabic gum regulation foliar fertilizer, add surface treatment and carry the kaolin after medicine, a great number of elements needed for amino acid fermentation concentrate and crop, obtain a kind of biogas slurry base foliar fertilizer of efficiently preventing and treating gray mold.The foliar fertilizer of the present invention, has certain viscosity, nutrition is comprehensive, green, after spraying crops and industrial crops blade face, is remarkably improved crop yield and efficiently prevents gray mold.

Description

A kind of production method of the biogas slurry base foliar fertilizer of efficiently preventing and treating gray mold
Technical field
The invention belongs to fertilizer field, and in particular to a kind of producer of the biogas slurry base foliar fertilizer of efficiently preventing and treating gray mold Method.
Background technology
With the development of modern agriculture, chemical fertilizer obtains a wide range of applications in agricultural production.But with nitrogen, phosphorus, potassium Deng continuing to increase for fertilizer amount, the trace element that crops take away from soil can also continue to increase, according to incompletely statistics, I The shortage that the soil of state about 70% is different degrees of is micro-.For many years it was verified that obtaining the pass of high crop yield and quality product Key, depend greatly on the balance supply of nutrient.Trace element plays key player in plant, if do not weighed Depending on supplement, the yield and quality of crop can be reduced, even the consequence that No kernels or seeds are gathered, as in a year of scarcity is caused when serious.But mended by soil root fertilizer Fill trace element be not easy it is uniform, easily by soil fixing, utilization rate is low and is absorbed by crops slow.Can using foliage-spray trace element It is microelement-supplementing the best way to overcome disadvantage mentioned above.
The general root system of plant seedling stage is undeveloped, and absorbability is weak, yellow seedling, weak seedling phenomenon easily occurs;The plant growth later stage Root system is senesced, and absorbability is faded, it is impossible to itself to provide enough fertilizer nutrients, is caused seed not plump thin, is produced Amount declines, and quality deteriorates.It can play a part of strong sprout by foliage dressing, improve product quality and increase yield.Adjust in China After the whole structure of agricultural production, industrial crops, vegetables, melon and fruit, fruit tree area greatly increase, quality of the foliar fertilizer to this kind of product(Quality, Nutrient, safety)Significant effect is improved, so doing foliar fertilizer well just seems particularly significant.
Foliage dressing is the important supplement of soil application technology.The traditional approach of soil root fertilizer has been broken in foliage dressing, Can be described as most flexibly, most easily fertilization mode.But in recent years, most foliar fertilizer effective contents of domestic production are low, battalion Foster effect is single, element utilization rate is not high, effect is not sufficiently stable.Foliar fertilizer is not high in technological content high, to be finally embodied in whether It can make in peasant's increasing both production and income, this requires that foliar fertilizer provides more nutritional ingredient as far as possible, to there is higher multielement micro-fertilizer, foot The hard water resistance humic acid of Available Amino Acids and high activity enough measured, will also there is appropriate nitrogen, phosphorus, potassium certainly, but so more Composition compounding also want together it is soluble in water without go out precipitation, it goes without saying that be need it is high-tech.Therefore, concentration is developed The composite multifunction type foliar fertilizer high, nutrition is complete, utilization rate is high is extremely urgent.
The content of the invention
It is an object of the invention to provide a kind of biogas slurry base foliar fertilizer of the efficient preventing and treating gray mold with certain viscosity Preparation method.
To achieve these goals, the present invention adopts the following technical scheme that:
A kind of biogas slurry base foliar fertilizer of efficiently preventing and treating gray mold, it is characterised in that its matrix using biogas slurry as foliar fertilizer, humic acid The viscosity of potassium and Arabic gum regulation foliar fertilizer, add surface treatment and carry the kaolin after medicine, amino acid fermentation tail washings and work A great number of elements needed for thing, obtain a kind of biogas slurry base foliar fertilizer of efficiently preventing and treating gray mold.
The biogas slurry base foliar fertilizer of described efficient preventing and treating gray mold, it is characterised in that it is prepared by following steps:
(1)Kaolin, lime stone mixed grinding are sieved, obtain the particle of 200-250 mesh;Particle after grinding is added to phase When in the deionized water of 12-15 times of particle weight part, ultrasonic disperse 50-60min, add cetyl trimethylammonium bromide and Isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, 70-75 DEG C of constant temperature stirring reaction 5-6h, temperature are reduced to 40-50 DEG C, 1,2- ethylenebis ammonium dithiocarbamate and the ammonia complexing copper of dichloro four are added, continues to stir 2-3h, stands 3-4d, filter, Dry;
(2)Biogas slurry is subjected to filtering and impurity removing with the screen cloth of 500 mesh;By zinc sulfate, manganese sulfate, boric acid, sodium metasilicate with 1:0.7- 0.75:1.2-1.5:1.3-1.6 mass ratio mixing, is added in the biogas slurry after the removal of impurities of 20-25 times of parts by weight, under normal temperature, Stirred with 250-300r/min stir speed (S.S.) to whole dissolvings, obtain solution A;
(3)Potassium humate is added into solution A, magnetic agitation adds step to dissolving(1)Product, ultrasonic vibration disperses 20- 30min, homogenization 30-40min, Arabic gum is added, regulation system pH is 7.5-8,55-60 DEG C of temperature constant magnetic stirring 4- 5h, obtain solution B;
(4)Amino acid fermentation tail washings is added into solution B, 20-30min is stirred with 250-300r/min stir speed (S.S.), added Urea, potassium hydrogen phosphate, ammonium carbonate, continue to stir 20-30min, obtain the biogas slurry base foliar fertilizer of efficiently preventing and treating gray mold.
The preparation method of the biogas slurry base foliar fertilizer of described efficient preventing and treating gray mold, it is characterised in that step(1)Middle kaolinite Soil, lime stone, cetyl trimethylammonium bromide, isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, 1,2- ethylidene The mass ratio of bisdithiocarbamic ammonium and the ammonia complexing copper of dichloro four is 1:0.4-0.5:0.003-0.004:0.01-0.02: 0.03-0.04:0.02-0.03.
The preparation method of the biogas slurry base foliar fertilizer of described efficient preventing and treating gray mold, it is characterised in that step(3)Middle solution A, potassium humate, step(1)Product and Arabic gum mass ratio be 1:0.1-0.12:0.06-0.08:0.04-0.05.
The preparation method of the biogas slurry base foliar fertilizer of described efficient preventing and treating gray mold, it is characterised in that step(4)Middle solution B, the mass ratio of amino acid fermentation tail washings, urea, potassium hydrogen phosphate and ammonium carbonate is 1:0.15-0.18:0.12-0.15:0.06- 0.08:0.08-0.1.
Using above-mentioned technical scheme, beneficial effects of the present invention are:
Biogas slurry is pure natural organic nutrient solution for cultivating, wherein containing the various nutriments needed for plant, as soluble inorganic salt, Amino acid, various plants growth regulator, biological enzyme and multicomponent organic acid and humic acid etc., have and easily absorbed by crops There is higher mineral element bearing capacity using, pre- preventing disease and pest and due to humic acid enriches functional group;This Matrix of the invention using biogas slurry as foliar fertilizer, not only turns waste into wealth, and saves cost, reduces environmental pollution, green, and increases The nutrition of foliar fertilizer of the present invention is comprehensive, is adapted to all kinds of plants to use.In the foliar fertilizer of the present invention potassium humate that adds and Arabic gum, on the one hand impart the certain viscosity of foliar fertilizer, adhesive force of the increase foliar fertilizer on blade face, anti-rain drop erosion stream Lose, on the other hand, improve the antagonism between nutrient, improve the stability of foliar fertilizer.The present invention is by kaolin surface After processing, 1,2- ethylenebis ammonium dithiocarbamate and the ammonia complexing copper of dichloro four are loaded, is dispersed in foliar fertilizer, can prevent and treat Fungi, bacterium and multiple diseases caused by mould, such as gray mold, rot, and plant can be promoted well established and vigorously developing, increase leaf is green Cellulose content, strengthen photosynthesis and drought-resistant ability, there is obvious production-increasing function.The foliar fertilizer of the present invention, has certain viscosity, Nutrition is comprehensive, green, after spraying crops and industrial crops blade face, is remarkably improved crop yield and efficiently prevents grey mold Disease.
Embodiment
The biogas slurry base foliar fertilizer of the efficient preventing and treating gray mold of the present embodiment, it is prepared by following steps:
(1)Kaolin, lime stone mixed grinding are sieved, obtain the particle of 250 mesh;By the particle after grinding be added to equivalent to In the deionized water that 15 times of particle weight part, ultrasonic disperse 60min, cetyl trimethylammonium bromide and isopropyl three are added (dioctylphyrophosphoric acid acyloxy) titanate esters, 75 DEG C of constant temperature stirring reaction 6h, temperature are reduced to 50 DEG C, adds 1,2- ethylenebis Ammonium dithiocarbamate and the ammonia complexing copper of dichloro four, continue to stir 3h, stand 4d, filter, dry;
(2)Biogas slurry is subjected to filtering and impurity removing with the screen cloth of 500 mesh;By zinc sulfate, manganese sulfate, boric acid, sodium metasilicate with 1:0.75: 1.5:1.6 mass ratio mixing, is added in the biogas slurry after the removal of impurities of 25 times of parts by weight, under normal temperature, with 300r/min stirring Speed is stirred to whole dissolvings, obtains solution A;
(3)Potassium humate is added into solution A, magnetic agitation adds step to dissolving(1)Product, ultrasonic vibration disperses 30min, homogenization 40min, Arabic gum is added, regulation system pH is 7.5-8,60 DEG C of temperature constant magnetic stirring 5h, is obtained molten Liquid B;
(4)Amino acid fermentation tail washings is added into solution B, 30min is stirred with 300r/min stir speed (S.S.), adds urea, phosphorus Potassium hydrogen phthalate, ammonium carbonate, continue to stir 30min, obtain the biogas slurry base foliar fertilizer of efficiently preventing and treating gray mold.
The step of the present embodiment(1)Middle kaolin, lime stone, the cetyl trimethylammonium bromide, (dioctyl of isopropyl three Pyrophosphoric acid acyloxy) titanate esters, 1,2- ethylenebis ammonium dithiocarbamate and the ammonia complexing copper of dichloro four mass ratio be 1: 0.5:0.004:0.02:0.04:0.03.
The step of the present embodiment(3)Middle solution A, potassium humate, step(1)Product and Arabic gum mass ratio be 1: 0.12:0.08:0.05.
The step of the present embodiment(4)Middle solution B, amino acid fermentation tail washings, urea, the mass ratio of potassium hydrogen phosphate and ammonium carbonate For 1:0.18:0.15:0.08:0.1.

Claims (5)

1. a kind of biogas slurry base foliar fertilizer of efficiently preventing and treating gray mold, it is characterised in that its matrix using biogas slurry as foliar fertilizer, humic The viscosity of sour potassium and Arabic gum regulation foliar fertilizer, add surface treatment and carry the kaolin after medicine, amino acid fermentation tail washings and A great number of elements needed for crop, obtain a kind of biogas slurry base foliar fertilizer of efficiently preventing and treating gray mold.
2. the biogas slurry base foliar fertilizer of the efficient preventing and treating gray mold according to claims 1, it is characterised in that it by walking as follows Suddenly it is prepared:
(1)Kaolin, lime stone mixed grinding are sieved, obtain the particle of 200-250 mesh;Particle after grinding is added to phase When in the deionized water of 12-15 times of particle weight part, ultrasonic disperse 50-60min, add cetyl trimethylammonium bromide and Isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, 70-75 DEG C of constant temperature stirring reaction 5-6h, temperature are reduced to 40-50 DEG C, 1,2- ethylenebis ammonium dithiocarbamate and the ammonia complexing copper of dichloro four are added, continues to stir 2-3h, stands 3-4d, filter, Dry;
(2)Biogas slurry is subjected to filtering and impurity removing with the screen cloth of 500 mesh;By zinc sulfate, manganese sulfate, boric acid, sodium metasilicate with 1:0.7- 0.75:1.2-1.5:1.3-1.6 mass ratio mixing, is added in the biogas slurry after the removal of impurities of 20-25 times of parts by weight, under normal temperature, Stirred with 250-300r/min stir speed (S.S.) to whole dissolvings, obtain solution A;
(3)Potassium humate is added into solution A, magnetic agitation adds step to dissolving(1)Product, ultrasonic vibration disperses 20- 30min, homogenization 30-40min, Arabic gum is added, regulation system pH is 7.5-8,55-60 DEG C of temperature constant magnetic stirring 4- 5h, obtain solution B;
(4)Amino acid fermentation tail washings is added into solution B, 20-30min is stirred with 250-300r/min stir speed (S.S.), added Urea, potassium hydrogen phosphate, ammonium carbonate, continue to stir 20-30min, obtain the biogas slurry base foliar fertilizer of efficiently preventing and treating gray mold.
3. the preparation method of the biogas slurry base foliar fertilizer of the efficient preventing and treating gray mold according to claims 2, it is characterised in that Step(1)Middle kaolin, lime stone, cetyl trimethylammonium bromide, isopropyl three (dioctylphyrophosphoric acid acyloxy) metatitanic acid The mass ratio of ester, 1,2- ethylenebis ammonium dithiocarbamate and the ammonia complexing copper of dichloro four is 1:0.4-0.5:0.003- 0.004:0.01-0.02:0.03-0.04:0.02-0.03.
4. the preparation method of the biogas slurry base foliar fertilizer of the efficient preventing and treating gray mold according to claims 2, it is characterised in that Step(3)Middle solution A, potassium humate, step(1)Product and Arabic gum mass ratio be 1:0.1-0.12:0.06- 0.08:0.04-0.05.
5. the preparation method of the biogas slurry base foliar fertilizer of the efficient preventing and treating gray mold according to claims 2, it is characterised in that Step(4)Middle solution B, amino acid fermentation tail washings, urea, the mass ratio of potassium hydrogen phosphate and ammonium carbonate are 1:0.15-0.18: 0.12-0.15:0.06-0.08:0.08-0.1.
CN201710985336.1A 2017-10-20 2017-10-20 A kind of production method of the biogas slurry base foliar fertilizer of efficiently preventing and treating gray mold Pending CN107814615A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108947706A (en) * 2018-09-30 2018-12-07 芜湖县兰馨油桃种植专业合作社 A kind of anti-brown rot nectarine foliar fertilizer and preparation method thereof
CN110317118A (en) * 2019-07-16 2019-10-11 福建省农业科学院土壤肥料研究所 2,4 dichlorophenoxyacetic acid butyl ester is improving utilization rate of nitrogen fertilizer and/or is reducing the application in nitrogen loss

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CN102047913A (en) * 2010-09-06 2011-05-11 宁夏农林科学院 Preparation method of biogas liquid composite disinfectant liquid and application thereof
CN102249775A (en) * 2011-04-21 2011-11-23 山东省农业科学院农业资源与环境研究所 Foliage fertilizer based on marsh liquid in domestic marsh gas tank and preparation method thereof
CN103724088A (en) * 2012-10-10 2014-04-16 天津市北方园林生态科学技术研究所 Plant foliar fertilizer prepared from biogas slurry
CN103739394A (en) * 2014-01-03 2014-04-23 灵川县金田农资经营部 Biogas liquid compounded fungicide for preventing and treating gray mold

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102047913A (en) * 2010-09-06 2011-05-11 宁夏农林科学院 Preparation method of biogas liquid composite disinfectant liquid and application thereof
CN101999413A (en) * 2010-11-03 2011-04-06 四川省农业科学院农产品加工研究所 Copper sulfate-ammonia complex and amobam compound water-soluble bactericidal preparation and preparation method thereof
CN102249775A (en) * 2011-04-21 2011-11-23 山东省农业科学院农业资源与环境研究所 Foliage fertilizer based on marsh liquid in domestic marsh gas tank and preparation method thereof
CN103724088A (en) * 2012-10-10 2014-04-16 天津市北方园林生态科学技术研究所 Plant foliar fertilizer prepared from biogas slurry
CN103739394A (en) * 2014-01-03 2014-04-23 灵川县金田农资经营部 Biogas liquid compounded fungicide for preventing and treating gray mold

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108947706A (en) * 2018-09-30 2018-12-07 芜湖县兰馨油桃种植专业合作社 A kind of anti-brown rot nectarine foliar fertilizer and preparation method thereof
CN110317118A (en) * 2019-07-16 2019-10-11 福建省农业科学院土壤肥料研究所 2,4 dichlorophenoxyacetic acid butyl ester is improving utilization rate of nitrogen fertilizer and/or is reducing the application in nitrogen loss
CN110317118B (en) * 2019-07-16 2021-09-14 福建省农业科学院土壤肥料研究所 Application of 2, 4-dichlorphenoxyacetic acid butyl ester in improving utilization rate of nitrogen fertilizer and/or reducing loss of nitrogen element

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Application publication date: 20180320