CN107814535A - A kind of concrete with good ductility - Google Patents

A kind of concrete with good ductility Download PDF

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Publication number
CN107814535A
CN107814535A CN201711149389.6A CN201711149389A CN107814535A CN 107814535 A CN107814535 A CN 107814535A CN 201711149389 A CN201711149389 A CN 201711149389A CN 107814535 A CN107814535 A CN 107814535A
Authority
CN
China
Prior art keywords
concrete
good ductility
sand
sand form
ore
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711149389.6A
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Chinese (zh)
Inventor
郭胡健
孙连军
胡万伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Wan Gang New Building Materials Technology Co Ltd
Original Assignee
Anhui Wan Gang New Building Materials Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Wan Gang New Building Materials Technology Co Ltd filed Critical Anhui Wan Gang New Building Materials Technology Co Ltd
Priority to CN201711149389.6A priority Critical patent/CN107814535A/en
Publication of CN107814535A publication Critical patent/CN107814535A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/023Chemical treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of concrete with good ductility, it is related to building material technical field, is made up of following component:Cement, miberal powder, flyash, sand, pitch, coupling agent, glass fibre, nitridation titanium valve, polycarboxylate water-reducer, modified rosin rock ore in sand form, disecoctylmaleate sodium sulfonate, water containing ethyl cellulose;The present invention passes through substantial amounts of experimental study, by the synergy for adding modified rosin rock ore in sand form and pitch containing ethyl cellulose, the intensity of concrete can not only effectively be improved, physical features, caking property, response to temperature and the durability of pitch can be changed to a certain extent simultaneously, extension ability of the pitch in certain temperature environment can greatly be improved.

Description

A kind of concrete with good ductility
Technical field
The invention belongs to building material technical field, and in particular to a kind of concrete with good ductility.
Background technology
Concrete is the widest construction material of modern Application, and it has abundant raw material, cheap, technique is simple, strong The advantages that degree is high, good endurance.Ready-mixed concrete is one kind of concrete, refers to by cement, gathers materials, water and mixes as needed The components such as the additive that enters, mineral admixture by a certain percentage mixing plant sold after metering, mixing and use transport vehicle The concrete mix of place to use is transported at the appointed time.Because site operation has greater environmental impacts, premixing mixes Solidifying soil receives more and more attention.But existing concrete ductility is poor, after the concrete has set, heat or when being cooled Expand with heat and contract with cold more serious, underbead crack easily occur, its service life is greatly lowered.
The content of the invention
The purpose of the present invention is to be directed to the problem of existing, there is provided a kind of concrete with good ductility.
The present invention is achieved by the following technical solutions:
A kind of concrete with good ductility, is made up of following component by weight:Cement 78-85, miberal powder 9-13, powder Coal ash 15-18, sand 200-300, pitch 13-18, coupling agent 1-3, glass fibre 2-5, nitridation titanium valve 1-5, polycarboxylic acids diminishing Agent 2-6, modified rosin rock ore in sand form 20-30, disecoctylmaleate sodium sulfonate 1-3, water 60-80 containing ethyl cellulose.
Further, the cement is any in portland cement or aluminate cement.
Further, the miberal powder is ground phosphate rock.
Further, the sand fineness is 60-80 mesh.
Further, the coupling agent is that any of titanate coupling agent, organo-silicon coupling agent or two kinds are any mixed Close.
Further, the glass fiber diameter is 50 μm.
Further, the modified rosin rock ore in sand form preparation method containing ethyl cellulose is:
Pitchstone ore in sand form is crushed, crosses 500 mesh, then evenly spreads in the sulfuric acid solution that mass fraction is 0.15%, matches somebody with somebody Into the pitchstone ore in sand form suspension that mass fraction is 10.2%, stirring 80min is subsequently placed in microwave reactor at 98 DEG C, Regulation microwave irradiation power is 800W, and radiation temperature is 60 DEG C, handles 10min;Ethyl cellulose is pressed into 80g:150mL ratio It is added in absolute ethyl alcohol, mixed liquor is obtained after stirring;The mixed liquor is pressed 1:6 volume ratios are added to by microwave treatment In pitchstone ore in sand form suspension afterwards, 68 DEG C are heated to, is stirred 2 hours with 1200r/min rotating speeds, then naturally cools to room Temperature, then filtered, cleaned using deionized water, be dried to constant weight, produced.
The present invention has advantages below compared with prior art:The present invention passes through substantial amounts of experimental study, contains second by addition The modified rosin rock ore in sand form of base cellulose and the synergy of pitch, the intensity of concrete can not only be effectively improved, simultaneously Physical features, caking property, response to temperature and the durability of pitch can be changed to a certain extent, pitch can greatly be improved and existed Extension ability in certain temperature environment, enables adaptation to more weathers, and enables pitch in concrete surface shape Cheng Genghou adhesive film, surface adhesion performance is improved, the temperature sensitivity of concrete can be especially reduced, not only improve The ability of anti-deformation of concrete at high temperature, further improve concrete viscoplasticity at low temperature and ductility.By adopting With the synergy of each raw material in the present invention, the combination property of concrete can be further improved, compression strength and anti-folding are strong Degree improves more than 10%, and the salt-resistance and impermeability of concrete are further enhanced, moreover it is possible to hinder inside concrete micro-crack Development, make the effect of concrete activeness and quietness.
Embodiment
Embodiment 1
A kind of concrete with good ductility, is made up of following component by weight:Cement 78, miberal powder 9, flyash 15th, sand 200, pitch 13, coupling agent 1, glass fibre 2, nitridation titanium valve 1, polycarboxylate water-reducer 2, changing containing ethyl cellulose Property pitchstone ore in sand form 20, disecoctylmaleate sodium sulfonate 1, water 60.
Further, the cement is any in portland cement or aluminate cement.
Further, the miberal powder is ground phosphate rock.
Further, the sand fineness is 60 mesh.
Further, the coupling agent is that any of titanate coupling agent, organo-silicon coupling agent or two kinds are any mixed Close.
Further, the glass fiber diameter is 50 μm.
Further, the modified rosin rock ore in sand form preparation method containing ethyl cellulose is:
Pitchstone ore in sand form is crushed, crosses 500 mesh, then evenly spreads in the sulfuric acid solution that mass fraction is 0.15%, matches somebody with somebody Into the pitchstone ore in sand form suspension that mass fraction is 10.2%, stirring 80min is subsequently placed in microwave reactor at 98 DEG C, Regulation microwave irradiation power is 800W, and radiation temperature is 60 DEG C, handles 10min;Ethyl cellulose is pressed into 80g:150mL ratio It is added in absolute ethyl alcohol, mixed liquor is obtained after stirring;The mixed liquor is pressed 1:6 volume ratios are added to by microwave treatment In pitchstone ore in sand form suspension afterwards, 68 DEG C are heated to, is stirred 2 hours with 1200r/min rotating speeds, then naturally cools to room Temperature, then filtered, cleaned using deionized water, be dried to constant weight, produced.
Embodiment 2
A kind of concrete with good ductility, is made up of following component by weight:Cement 85, miberal powder 13, flyash 18th, sand 300, pitch 18, coupling agent 3, glass fibre 5, nitridation titanium valve 5, polycarboxylate water-reducer 6, changing containing ethyl cellulose Property pitchstone ore in sand form 30, disecoctylmaleate sodium sulfonate 3, water 80.
Further, the cement is any in portland cement or aluminate cement.
Further, the miberal powder is ground phosphate rock.
Further, the sand fineness is 80 mesh.
Further, the coupling agent is that any of titanate coupling agent, organo-silicon coupling agent or two kinds are any mixed Close.
Further, the glass fiber diameter is 50 μm.
Further, the modified rosin rock ore in sand form preparation method containing ethyl cellulose is:
Pitchstone ore in sand form is crushed, crosses 500 mesh, then evenly spreads in the sulfuric acid solution that mass fraction is 0.15%, matches somebody with somebody Into the pitchstone ore in sand form suspension that mass fraction is 10.2%, stirring 80min is subsequently placed in microwave reactor at 98 DEG C, Regulation microwave irradiation power is 800W, and radiation temperature is 60 DEG C, handles 10min;Ethyl cellulose is pressed into 80g:150mL ratio It is added in absolute ethyl alcohol, mixed liquor is obtained after stirring;The mixed liquor is pressed 1:6 volume ratios are added to by microwave treatment In pitchstone ore in sand form suspension afterwards, 68 DEG C are heated to, is stirred 2 hours with 1200r/min rotating speeds, then naturally cools to room Temperature, then filtered, cleaned using deionized water, be dried to constant weight, produced.
Embodiment 3
A kind of concrete with good ductility, is made up of following component by weight:Cement 80, miberal powder 12, flyash 16th, sand 250, pitch 16, coupling agent 2, glass fibre 3, nitridation titanium valve 3, polycarboxylate water-reducer 4, changing containing ethyl cellulose Property pitchstone ore in sand form 25, disecoctylmaleate sodium sulfonate 2, water 70.
Further, the cement is any in portland cement or aluminate cement.
Further, the miberal powder is ground phosphate rock.
Further, the sand fineness is 70 mesh.
Further, the coupling agent is that any of titanate coupling agent, organo-silicon coupling agent or two kinds are any mixed Close.
Further, the glass fiber diameter is 50 μm.
Further, the modified rosin rock ore in sand form preparation method containing ethyl cellulose is:
Pitchstone ore in sand form is crushed, crosses 500 mesh, then evenly spreads in the sulfuric acid solution that mass fraction is 0.15%, matches somebody with somebody Into the pitchstone ore in sand form suspension that mass fraction is 10.2%, stirring 80min is subsequently placed in microwave reactor at 98 DEG C, Regulation microwave irradiation power is 800W, and radiation temperature is 60 DEG C, handles 10min;Ethyl cellulose is pressed into 80g:150mL ratio It is added in absolute ethyl alcohol, mixed liquor is obtained after stirring;The mixed liquor is pressed 1:6 volume ratios are added to by microwave treatment In pitchstone ore in sand form suspension afterwards, 68 DEG C are heated to, is stirred 2 hours with 1200r/min rotating speeds, then naturally cools to room Temperature, then filtered, cleaned using deionized water, be dried to constant weight, produced.
Comparative example 1:Differed only in embodiment 1 and the modified rosin rock ore in sand form containing ethyl cellulose is replaced with into common pine Fat rock ore in sand form.
Comparative example 2:Differed only in embodiment 1 and do not add pitch.
Comparative example 3:Differed only in embodiment 1 and do not add glass fibre.
Ductility test is carried out to embodiment and comparative example concrete:
Table 1
Ductility % Compression strength MPa
Embodiment 1 6.83 9.68
Embodiment 2 6.55 9.53
Embodiment 3 6.39 9.59
Comparative example 1 3.21 6.23
Comparative example 2 3.06 8.06
Comparative example 3 5.68 9.52
As can be seen from Table 1, the concrete that prepared by the present invention has good ductility and compression strength.

Claims (7)

1. a kind of concrete with good ductility, it is characterised in that be made up by weight of following component:Cement 78- 85th, miberal powder 9-13, flyash 15-18, sand 200-300, pitch 13-18, coupling agent 1-3, glass fibre 2-5, nitridation titanium valve 1-5, polycarboxylate water-reducer 2-6, modified rosin rock ore in sand form 20-30, maleic acid di-sec-octyl sulfonic acid containing ethyl cellulose Sodium 1-3, water 60-80.
2. a kind of concrete with good ductility as claimed in claim 1, it is characterised in that the cement is silicate It is any in cement or aluminate cement.
3. a kind of concrete with good ductility as claimed in claim 1, it is characterised in that the miberal powder is phosphorus ore Powder.
4. a kind of concrete with good ductility as claimed in claim 1, it is characterised in that the sand fineness is 60-80 mesh.
5. a kind of concrete with good ductility as claimed in claim 1, it is characterised in that the coupling agent is metatitanic acid Any of ester coupling agent, organo-silicon coupling agent or two kinds of any mixing.
A kind of 6. concrete with good ductility as claimed in claim 1, it is characterised in that the glass fiber diameter For 50 μm.
7. a kind of concrete with good ductility as claimed in claim 1, it is characterised in that described to contain ethyl cellulose Modified rosin rock ore in sand form preparation method be:
Pitchstone ore in sand form is crushed, crosses 500 mesh, then evenly spreads in the sulfuric acid solution that mass fraction is 0.15%, matches somebody with somebody Into the pitchstone ore in sand form suspension that mass fraction is 10.2%, stirring 80min is subsequently placed in microwave reactor at 98 DEG C, Regulation microwave irradiation power is 800W, and radiation temperature is 60 DEG C, handles 10min;Ethyl cellulose is pressed into 80g:150mL ratio It is added in absolute ethyl alcohol, mixed liquor is obtained after stirring;The mixed liquor is pressed 1:6 volume ratios are added to by microwave treatment In pitchstone ore in sand form suspension afterwards, 68 DEG C are heated to, is stirred 2 hours with 1200r/min rotating speeds, then naturally cools to room Temperature, then filtered, cleaned using deionized water, be dried to constant weight, produced.
CN201711149389.6A 2017-11-18 2017-11-18 A kind of concrete with good ductility Pending CN107814535A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Publications (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112358252A (en) * 2020-11-11 2021-02-12 广州市广丰混凝土有限公司 Anti-freezing cracking concrete and preparation method thereof
CN114434595A (en) * 2022-04-11 2022-05-06 山东景明生态园林有限公司 Low-shrinkage high-strength concrete and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105198272A (en) * 2015-09-02 2015-12-30 王嘉文 Concrete expansive agent
CN105439509A (en) * 2015-12-15 2016-03-30 苏州万盛混凝土有限公司 Asphalt concrete composition
CN106082823A (en) * 2016-06-20 2016-11-09 安徽金丰新型建材有限公司 A kind of modified asphalt concrete
CN106316260A (en) * 2016-08-23 2017-01-11 陈广圣 High-efficiency energy-saving concrete

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105198272A (en) * 2015-09-02 2015-12-30 王嘉文 Concrete expansive agent
CN105439509A (en) * 2015-12-15 2016-03-30 苏州万盛混凝土有限公司 Asphalt concrete composition
CN106082823A (en) * 2016-06-20 2016-11-09 安徽金丰新型建材有限公司 A kind of modified asphalt concrete
CN106316260A (en) * 2016-08-23 2017-01-11 陈广圣 High-efficiency energy-saving concrete

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112358252A (en) * 2020-11-11 2021-02-12 广州市广丰混凝土有限公司 Anti-freezing cracking concrete and preparation method thereof
CN114434595A (en) * 2022-04-11 2022-05-06 山东景明生态园林有限公司 Low-shrinkage high-strength concrete and preparation method thereof

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Application publication date: 20180320