CN107805444A - Delrin zippers with pulllers Singapore frame oil and preparation method thereof and application method - Google Patents
Delrin zippers with pulllers Singapore frame oil and preparation method thereof and application method Download PDFInfo
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- CN107805444A CN107805444A CN201711173736.9A CN201711173736A CN107805444A CN 107805444 A CN107805444 A CN 107805444A CN 201711173736 A CN201711173736 A CN 201711173736A CN 107805444 A CN107805444 A CN 107805444A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2359/00—Characterised by the use of polyacetals containing polyoxymethylene sequences only
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The present invention relates to a kind of delrin zippers with pulllers Singapore frame oil and preparation method thereof and application method, delrin zippers with pulllers Singapore frame oil includes first chamber and second chamber：The raw material components of first chamber by weight, including：The parts by weight of epoxy resin 80~83, the parts by weight of ethylene glycol monobutyl ether 4~6, the parts by weight of black slurry 8~12, the parts by weight of levelling agent 0.4~0.6 and the parts by weight of adhesion promoter 2~4；The raw material components of second chamber by weight, including：The parts by weight of epoxy hardener 25~35, the parts by weight of ethylene glycol monobutyl ether 30~50 and the parts by weight of isobutanol 25~35；First chamber and second chamber are independently packed.Delrin zippers with pulllers Singapore frame oil provided by the invention, can be applied on POM delrin zippers with pulllers surface, change original single cloudy colour, make surface brighter, fuller；And with performances such as satisfactory acidproof, salt spray resistance and water-wash resistances；Saving of labor, time saving and efficiency high during use.
Description
Technical field
The present invention relates to paint technology field, and in particular to a kind of delrin zippers with pulllers Singapore frame oil and preparation method thereof and user
Method.
Background technology
Delrin zippers with pulllers share occupies whole slide fastener market 40% or so at present, and it, which manufactures material, includes ABS (propylene-fourths two
Alkene-benzene diene copolymers) and two kinds of POM (acetal resin), it is crystallinity thermoplastic plastic, 165~175 DEG C of fusing point,
Property is closest to metal.Two kinds of materials of ABS and POM have high mechanical properties, rigidity, environmental resistance strong and organic solvent resistance
The advantages that, but there is also the shortcomings of easily playing thermal decomposition and acid resistance difference is processed under long-time high temperature.Two kinds of materials of ABS and POM because
Its surface rigidity is strong, density is big, and easily manufactured, color is various, applied to delrin zippers with pulllers industry, is prevalent in low and middle-end city
.The Singapore frame oil of a variety of colors but adheres to less than delrin zippers with pulllers surface at all, and overall appearance color is partially mute, single in addition, and resistance to
Change performance is medium, and middle and high-end market is difficult to push open.Existing universal solution is that physical damage surface adds processing water.In the market should
It is with more processing methods must be compared：Flame treatment (or the physics mode such as corona) is first used, reuses inorganic agent, but actually reach
The effect arrived is general.Two kinds of materials of ABS and POM are compared, and the former intensity is high, are not suitable for new technology and are promoted, so POM materials are opened
Hair prospect is more preferable, is badly in need of a kind of plastic-steel Singapore frame oil at present to solve the problems, such as the bottleneck of the market of POM material plastic-steels.
The content of the invention
For in the prior art the defects of, present invention aims at provide a kind of delrin zippers with pulllers Singapore frame oil and preparation method thereof
With application method, it is applied on POM (acetal resin) delrin zippers with pulllers surface, change original single cloudy colour, make surface more
It is bright, fuller；And with performances such as satisfactory acidproof, salt spray resistance and water-wash resistances；Saving of labor, time saving and efficiency during use
It is high.
To achieve the above object, technical scheme provided by the invention is：
In a first aspect, the invention provides a kind of delrin zippers with pulllers Singapore frame oil, including first chamber and second chamber：The
The raw material components of one composition by weight, including：The parts by weight of epoxy resin 80~83, the weight of ethylene glycol monobutyl ether 4~6
Part, the parts by weight of black slurry 8~12, the parts by weight of levelling agent 0.4~0.6 and the parts by weight of adhesion promoter 2~4；Second chamber
Raw material components by weight, including：The parts by weight of epoxy hardener 25~35, parts by weight of ethylene glycol monobutyl ether 30~50 and different
The parts by weight of butanol 25~35；First chamber and second chamber are independently packed.It should be noted that ethylene glycol only son
Ether, also known as anti-plain boiled water, No. CAS:111-76-2.
Preferably, the preparation method of epoxy hardener includes step：S1：By ethylene glycol monomethyl ether be added drop-wise to triethylene tetramine and
55~65 DEG C of reaction temperature 3.0h~4.0h is kept in the mixed liquor of hydroxyethyl methacrylate, after being added dropwise to complete；S2：By ring
Oxygen tree fat drips are added in the solution that S1 is prepared, and it is 6.5~6.7 that pH value is adjusted after being added dropwise to complete, then 85~95 DEG C of reactions
1.5h~2.0h, obtain epoxy hardener.
Preferably, in step S1, the mol ratio of triethylene tetramine, ethylene glycol monomethyl ether and hydroxyethyl methacrylate is 1:
(1.0~1.5):(2.5~3.0)；In step S2, the mol ratio of epoxy resin and triethylene tetramine is (2.5~2.8):1；Ring
Oxygen tree fat is epoxy resin E51.
Preferably, the raw material components of black slurry by weight, including：The parts by weight of carbon black 15~20, number-average molecular weight are
2500~3000 parts by weight of AEO 5~8, the parts by weight of diethylene glycol 6~8, dimethylethanolamine 10~14
Parts by weight, the parts by weight of APEO 6~10 and the parts by weight of MIT 2~4.
Preferably, the preparation method of black slurry includes step：The raw material components of black slurry are mixed, in 100~500r/
Stirred under min speed of agitator to being uniformly dispersed, obtain slurry；Slurry is ground to particle diameter as 5~10 μm, obtains black slurry.
Preferably, in the raw material components of first chamber, epoxy resin is epoxy resin E44.
Preferably, delrin zippers with pulllers Singapore frame oil includes first chamber and second chamber：The raw material components of first chamber
By weight, including：The parts by weight of epoxy resin 81.5, the parts by weight of ethylene glycol monobutyl ether 5, the parts by weight of black slurry 10, levelling agent
0.5 parts by weight and the parts by weight of adhesion promoter 3；The raw material components of second chamber by weight, including：Epoxy hardener
30 parts by weight, the parts by weight of ethylene glycol monobutyl ether 40 and the parts by weight of isobutanol 30；First chamber and second chamber are independently
Packaging.
Second aspect, the invention provides the preparation method of delrin zippers with pulllers Singapore frame oil, the preparation method bag of first chamber
Include following steps：It is uniformly dispersed after all raw material components of first chamber are mixed, obtains first chamber；Second chamber
Preparation method comprise the following steps：It is uniformly dispersed after all raw material components of second chamber are mixed, obtains the second combination
Thing.
The third aspect, the present invention also protect the application method of delrin zippers with pulllers Singapore frame oil, including step：Inorganic agent is uniformly applied
On delrin zippers with pulllers surface, 115~135 DEG C of 5~7min of continuous baking, delrin zippers with pulllers after being toasted；By delrin zippers with pulllers Singapore frame oil
First chamber and second chamber with 1:1 mass ratio is well mixed, and then smears the surface of delrin zippers with pulllers after baking,
120~135 DEG C of 5~6min of continuous baking again.It should be noted that inorganic agent and polyformaldehyde material are reacted, surface into
Crystallized for another chemicals, surface adhesion force can be greatly improved, paint can be made firmly to be attached to delrin zippers with pulllers surface, greatly
It is big to improve plastic-steel material surface appearance effects and physical and chemical performance.
Preferably, the raw material components of inorganic agent include production of low-temperature foaming agent and dimethylbenzene；The matter of production of low-temperature foaming agent and dimethylbenzene
Amount is than being 1:(1.2~1.4).
Technical scheme provided by the invention, there is following beneficial effect：(1) delrin zippers with pulllers Singapore frame provided by the invention
It oil, can be applied on POM delrin zippers with pulllers surface, there is the performances such as satisfactory acidproof, salt spray resistance and water-wash resistance；(2)
Using delrin zippers with pulllers Singapore frame provided by the invention oil, saving of labor, time saving and efficiency high, process for treating surface is stable, and treatment effect is not
Restricted by factors such as people, equipment, Singapore frame oil on delrin zippers with pulllers can be achieved, changed original single cloudy colour, make surface brighter, fuller
It is full.
The additional aspect and advantage of the present invention will be set forth in part in the description, and will partly become from the following description
Obtain substantially, or recognized by the practice of the present invention.
Embodiment
Below in conjunction with the embodiment of the present invention, technical scheme is clearly and completely described.Implement below
Example is only used for clearly illustrating technical scheme, therefore be intended only as example, and can not limit this hair with this
Bright protection domain.
Experimental method in following embodiments, it is conventional method unless otherwise specified.Examination used in following embodiments
Material is tested, is to be commercially available from regular shops unless otherwise specified.Quantitative test in following examples, is respectively provided with three
Secondary to repeat to test, data are to repeat the average value or mean+SD of experiment three times.In the embodiment of the present invention, attachment is made every effort to promote
Enter agent and be free of polysiloxane non-ionic compound for BYK-4509, levelling agent is the dimethyl-silicons of Efka FL 3772 of BASF AG
Oxygen alkane；Production of low-temperature foaming agent is available from Japanese this model F-20 of pine production of low-temperature foaming agent；The CAS of APEO:9004-
95-9。
Embodiment one
The present embodiment provides a kind of delrin zippers with pulllers Singapore frame oil, raw material components by weight, including first chamber and the
Two compositions：
The raw material components of first chamber by weight, including：The parts by weight of epoxy resin E44 81.5, ethylene glycol only son
The parts by weight of ether 5, the parts by weight of black slurry 10, the parts by weight of levelling agent 0.5 and the parts by weight of adhesion promoter 3；
The raw material components of second chamber by weight, including：The parts by weight of epoxy hardener 30, ethylene glycol monobutyl ether 40
Parts by weight and the parts by weight of isobutanol 30；
First chamber and second chamber are independently packed.
Wherein, the preparation method of epoxy hardener includes step：
S1：Ethylene glycol monomethyl ether is added drop-wise in the mixed liquor of triethylene tetramine and hydroxyethyl methacrylate, be added dropwise to complete
60 DEG C of reaction temperature 3.5h is kept afterwards；The mol ratio of triethylene tetramine, ethylene glycol monomethyl ether and hydroxyethyl methacrylate is 1:
1.2:2.8；
S2：Epoxy resin E51 is added drop-wise in the solution that S1 is prepared, it is 6.6 that pH value is adjusted after being added dropwise to complete, then
90 DEG C of reaction 1.8h, obtain epoxy hardener；The mol ratio of epoxy resin and triethylene tetramine is 2.6:1.
The raw material components of black slurry by weight, including：The parts by weight of carbon black 18, the fatty alcohol that number-average molecular weight is 2800
The parts by weight of APEO 6, the parts by weight of diethylene glycol 7, the parts by weight of dimethylethanolamine 12, the parts by weight of APEO 8 and 2-
The parts by weight of methyl -4- isothiazoline -3- ketone 3；The preparation method of black slurry includes step：The raw material components of black slurry are mixed,
Stirred under 300r/min speed of agitator to being uniformly dispersed, obtain slurry；Slurry is ground to particle diameter as 5~10 μm, obtained
Black slurry.
By above-mentioned raw material, delrin zippers with pulllers Singapore frame oil is prepared：The preparation method of first chamber comprises the following steps：By
It is uniformly dispersed after all raw material components mixing of one composition, obtains first chamber；The preparation method of second chamber includes
Following steps：It is uniformly dispersed after all raw material components of second chamber are mixed, obtains second chamber；First chamber and
Second chamber is independently packed.
Embodiment two
The present embodiment provides a kind of delrin zippers with pulllers Singapore frame oil, raw material components by weight, including first chamber and the
Two compositions：
The raw material components of first chamber by weight, including：The parts by weight of epoxy resin E44 80, ethylene glycol monobutyl ether
6 parts by weight, the parts by weight of black slurry 8, the parts by weight of levelling agent 0.6 and the parts by weight of adhesion promoter 2；
The raw material components of second chamber by weight, including：The parts by weight of epoxy hardener 25, ethylene glycol monobutyl ether 50
Parts by weight and the parts by weight of isobutanol 25；
First chamber and second chamber are independently packed.
Wherein, the preparation method of epoxy hardener includes step：
S1：Ethylene glycol monomethyl ether is added drop-wise in the mixed liquor of triethylene tetramine and hydroxyethyl methacrylate, be added dropwise to complete
55 DEG C of reaction temperature 3.0h is kept afterwards；The mol ratio of triethylene tetramine, ethylene glycol monomethyl ether and hydroxyethyl methacrylate is 1:
1.0:2.5；
S2：Epoxy resin E51 is added drop-wise in the solution that S1 is prepared, it is 6.5 that pH value is adjusted after being added dropwise to complete, then
85 DEG C of reaction 1.5h, obtain epoxy hardener；The mol ratio of epoxy resin and triethylene tetramine is 2.5:1.
The raw material components of black slurry by weight, including：The parts by weight of carbon black 15, the fatty alcohol that number-average molecular weight is 2500
The parts by weight of APEO 8, the parts by weight of diethylene glycol 6, the parts by weight of dimethylethanolamine 14, the parts by weight of APEO 6 and 2-
The parts by weight of methyl -4- isothiazoline -3- ketone 4；The preparation method of black slurry includes step：The raw material components of black slurry are mixed,
Stirred under 100r/min speed of agitator to being uniformly dispersed, obtain slurry；Slurry is ground to particle diameter as 5~10 μm, obtained
Black slurry.
By above-mentioned raw material, delrin zippers with pulllers Singapore frame oil is prepared：The preparation method of first chamber comprises the following steps：By
It is uniformly dispersed after all raw material components mixing of one composition, obtains first chamber；The preparation method of second chamber includes
Following steps：It is uniformly dispersed after all raw material components of second chamber are mixed, obtains second chamber；First chamber and
Second chamber is independently packed.
Embodiment three
The present embodiment provides a kind of delrin zippers with pulllers Singapore frame oil, raw material components by weight, including first chamber and the
Two compositions：
The raw material components of first chamber by weight, including：The parts by weight of epoxy resin E44 83, ethylene glycol monobutyl ether
4 parts by weight, the parts by weight of black slurry 12, the parts by weight of levelling agent 0.4 and the parts by weight of adhesion promoter 4；
The raw material components of second chamber by weight, including：The parts by weight of epoxy hardener 35, ethylene glycol monobutyl ether 30
Parts by weight and the parts by weight of isobutanol 35；
First chamber and second chamber are independently packed.
Wherein, the preparation method of epoxy hardener includes step：
S1：Ethylene glycol monomethyl ether is added drop-wise in the mixed liquor of triethylene tetramine and hydroxyethyl methacrylate, be added dropwise to complete
65 DEG C of reaction temperature 4.0h is kept afterwards；The mol ratio of triethylene tetramine, ethylene glycol monomethyl ether and hydroxyethyl methacrylate is 1:
1.5:3.0；
S2：Epoxy resin E51 is added drop-wise in the solution that S1 is prepared, it is 6.7 that pH value is adjusted after being added dropwise to complete, then
95 DEG C of reaction 2.0h, obtain epoxy hardener；The mol ratio of epoxy resin and triethylene tetramine is 2.8:1.
The raw material components of black slurry by weight, including：The parts by weight of carbon black 20, the fatty alcohol that number-average molecular weight is 3000
The parts by weight of APEO 5, the parts by weight of diethylene glycol 8, the parts by weight of dimethylethanolamine 10, the parts by weight of APEO 10 and 2-
The parts by weight of methyl -4- isothiazoline -3- ketone 2；The preparation method of black slurry includes step：The raw material components of black slurry are mixed,
Stirred under 500r/min speed of agitator to being uniformly dispersed, obtain slurry；Slurry is ground to particle diameter as 5~10 μm, obtained
Black slurry.
By above-mentioned raw material, delrin zippers with pulllers Singapore frame oil is prepared：The preparation method of first chamber comprises the following steps：By
It is uniformly dispersed after all raw material components mixing of one composition, obtains first chamber；The preparation method of second chamber includes
Following steps：It is uniformly dispersed after all raw material components of second chamber are mixed, obtains second chamber；First chamber and
Second chamber is independently packed.
Comparative example one
This comparative example provides a kind of delrin zippers with pulllers Singapore frame oil, raw material components by weight, including first chamber and the
Two compositions：
The raw material components of first chamber by weight, including：The parts by weight of epoxy resin E44 81.5, ethylene glycol only son
The parts by weight of ether 5, the parts by weight of black slurry 10, the parts by weight of levelling agent 0.5 and the parts by weight of adhesion promoter 3；
The raw material components of second chamber by weight, including：The parts by weight of epoxy hardener 30, ethylene glycol monobutyl ether 40
Parts by weight and the parts by weight of isobutanol 30；
First chamber and second chamber are independently packed.
Wherein, the preparation method of epoxy hardener includes step：
S1：Ethylene glycol monomethyl ether is added drop-wise in the mixed liquor of triethylene tetramine and hydroxyethyl methacrylate, be added dropwise to complete
60 DEG C of reaction temperature 3.5h is kept afterwards；The mol ratio of triethylene tetramine, ethylene glycol monomethyl ether and hydroxyethyl methacrylate is 1:
1.2:2.8；
S2：Epoxy resin E51 is added drop-wise in the solution that S1 is prepared, 90 DEG C of reaction 1.8h, are obtained after being added dropwise to complete
Epoxy hardener；The mol ratio of epoxy resin and triethylene tetramine is 2.6:1.
The raw material components of black slurry by weight, including：The parts by weight of carbon black 18, the fatty alcohol that number-average molecular weight is 2800
The parts by weight of APEO 6, the parts by weight of diethylene glycol 7, the parts by weight of dimethylethanolamine 12, the parts by weight of APEO 8 and 2-
The parts by weight of methyl -4- isothiazoline -3- ketone 3；The preparation method of black slurry includes step：The raw material components of black slurry are mixed,
Stirred under 300r/min speed of agitator to being uniformly dispersed, obtain slurry；Slurry is ground to particle diameter as 5~10 μm, obtained
Black slurry.
By above-mentioned raw material, delrin zippers with pulllers Singapore frame oil is prepared：The preparation method of first chamber comprises the following steps：By
It is uniformly dispersed after all raw material components mixing of one composition, obtains first chamber；The preparation method of second chamber includes
Following steps：It is uniformly dispersed after all raw material components of second chamber are mixed, obtains second chamber；First chamber and
Second chamber is independently packed.
Comparative example two
This comparative example provides a kind of delrin zippers with pulllers Singapore frame oil, raw material components by weight, including first chamber and the
Two compositions：
The raw material components of first chamber by weight, including：The parts by weight of epoxy resin E44 81.5, ethylene glycol only son
The parts by weight of ether 5, the parts by weight of black slurry 10, the parts by weight of levelling agent 0.5 and the parts by weight of adhesion promoter 3；
The raw material components of second chamber by weight, including：The parts by weight of epoxy hardener 30, ethylene glycol monobutyl ether 40
Parts by weight and the parts by weight of isobutanol 30；
First chamber and second chamber are independently packed.
Wherein, the preparation method of epoxy hardener includes step：
S1：Ethylene glycol monomethyl ether is added drop-wise in the mixed liquor of triethylene tetramine and hydroxyethyl methacrylate, be added dropwise to complete
60 DEG C of reaction temperature 3.5h is kept afterwards；The mol ratio of triethylene tetramine, ethylene glycol monomethyl ether and hydroxyethyl methacrylate is 1:
1.2:2.8；
S2：Epoxy resin E51 is added drop-wise in the solution that S1 is prepared, it is 6.6 that pH value is adjusted after being added dropwise to complete, then
90 DEG C of reaction 1.8h, obtain epoxy hardener；The mol ratio of epoxy resin and triethylene tetramine is 2.6:1.
The raw material components of black slurry by weight, including：The parts by weight of carbon black 18, the fatty alcohol that number-average molecular weight is 2800
The parts by weight of APEO 6, the parts by weight of APEO 8 and the parts by weight of MIT 3；The system of black slurry
Preparation Method includes step：The raw material components of black slurry are mixed, stirs to being uniformly dispersed, obtains under 300r/min speed of agitator
To slurry；Slurry is ground to particle diameter as 5~10 μm, obtains black slurry.
By above-mentioned raw material, delrin zippers with pulllers Singapore frame oil is prepared：The preparation method of first chamber comprises the following steps：By
It is uniformly dispersed after all raw material components mixing of one composition, obtains first chamber；The preparation method of second chamber includes
Following steps：It is uniformly dispersed after all raw material components of second chamber are mixed, obtains second chamber；First chamber and
Second chamber is independently packed.
Comparative example three
This comparative example provides a kind of delrin zippers with pulllers Singapore frame oil, raw material components by weight, including first chamber and the
Two compositions：
The raw material components of first chamber by weight, including：The parts by weight of epoxy resin E44 81.5, ethylene glycol only son
The parts by weight of ether 5, the parts by weight of black slurry 10, the parts by weight of levelling agent 0.5 and the parts by weight of adhesion promoter 3；
The raw material components of second chamber by weight, including：The parts by weight of epoxy hardener 30, ethylene glycol monobutyl ether 40
Parts by weight and the parts by weight of isobutanol 30；
First chamber and second chamber are independently packed.
Wherein, the preparation method of epoxy hardener includes step：
S1：Ethylene glycol monomethyl ether is added drop-wise in triethylene tetramine, 60 DEG C of reaction temperature 3.5h is kept after being added dropwise to complete；Three
The mol ratio of ethene tetramine and ethylene glycol monomethyl ether is 1:1.2；
S2：Epoxy resin E51 is added drop-wise in the solution that S1 is prepared, it is 6.6 that pH value is adjusted after being added dropwise to complete, then
90 DEG C of reaction 1.8h, obtain epoxy hardener；The mol ratio of epoxy resin and triethylene tetramine is 2.6:1.
The raw material components of black slurry by weight, including：The parts by weight of carbon black 18, the fatty alcohol that number-average molecular weight is 2800
The parts by weight of APEO 6, the parts by weight of diethylene glycol 7, the parts by weight of dimethylethanolamine 12, the parts by weight of APEO 8 and 2-
The parts by weight of methyl -4- isothiazoline -3- ketone 3；The preparation method of black slurry includes step：The raw material components of black slurry are mixed,
Stirred under 300r/min speed of agitator to being uniformly dispersed, obtain slurry；Slurry is ground to particle diameter as 5~10 μm, obtained
Black slurry.
By above-mentioned raw material, delrin zippers with pulllers Singapore frame oil is prepared：The preparation method of first chamber comprises the following steps：By
It is uniformly dispersed after all raw material components mixing of one composition, obtains first chamber；The preparation method of second chamber includes
Following steps：It is uniformly dispersed after all raw material components of second chamber are mixed, obtains second chamber；First chamber and
Second chamber is independently packed.
Below with POM delrin zippers with pulllers as an example, be respectively adopted the embodiment of the present invention one to embodiment three, comparative example one to
The delrin zippers with pulllers Singapore frame oil coating that comparative example three is prepared carries out measure of merit with POM delrin zippers with pulllers.
Modulate conditioner：By production of low-temperature foaming agent F-20 and dimethylbenzene with 1:1.3 mass ratio is well mixed, and is handled
Agent；
Surface treatment：Using slide fastener Singapore frame machine, by way of wheeled roller coating, inorganic agent is uniformly coated onto to delrin zippers with pulllers table
Face, continuous baking 6 minutes, make slide fastener surface produce reaction in the case of a high temperature in 125 DEG C of baking ovens；
Paint：By the first chamber of delrin zippers with pulllers Singapore frame oil and second chamber with 1:1 mass ratio is well mixed；
Using slide fastener Singapore frame machine, by way of wheeled roller coating, delrin zippers with pulllers Singapore frame oil is applied to delrin zippers with pulllers after the baking
Surface, then 125 DEG C of continuous baking 6min.
The above-mentioned POM delrin zippers with pulllers for scribbling delrin zippers with pulllers Singapore frame oil is subjected to 48 hours salt spray tests, 60 seconds nitric acid dousings
Test and washing in 24 hours are tested.
(1) salt spray resistance is tested
Experimental method：Using salt mist tester respectively to different groups scribble delrin zippers with pulllers Singapore frame oil POM delrin zippers with pulllers
Salt spray resistance test experiments are carried out, salting liquid is the sodium chloride solution of 5% concentration, and method of testing is conventional salt spray resistance test side
Method, test 48 hours, observe result.
Experimental result：The POM delrin zippers with pulllers of the delrin zippers with pulllers Singapore frame for scribbling different groups oil after observation cleaning respectively, finds
The POM delrin zippers with pulllers outward appearance that the embodiment of the present invention one is scribbled to the delrin zippers with pulllers Singapore frame oil of embodiment three is unchanged, specifically such as
Shown in table 1.
The salt spray resistance of table 1 is tested
| Group | Cosmetic variation | Group | Cosmetic variation |
| Embodiment one | It is unchanged | Comparative example one | By moderate corrosion |
| Embodiment two | It is unchanged | Comparative example two | By slight erosion |
| Embodiment three | It is unchanged | Comparative example three | Corroded by severe |
(2) acid proof test
Experimental method：Concentrated nitric acid solution is diluted using pure water, prepares and obtains the salpeter solution that mass fraction is 46%, make
For than quasi- solution, the POM delrin zippers with pulllers for the delrin zippers with pulllers Singapore frame oil for scribbling different groups is put into than quasi- solution 60 seconds respectively, then
Take out, observe result.
Experimental result：The POM delrin zippers with pulllers of the delrin zippers with pulllers Singapore frame for scribbling different groups oil after observation cleaning respectively, finds
The POM delrin zippers with pulllers outward appearance that the embodiment of the present invention one is scribbled to the delrin zippers with pulllers Singapore frame oil of embodiment three is unchanged, specifically such as
Shown in table 2.
The acid proof test of table 2
| Group | Cosmetic variation | Group | Cosmetic variation |
| Embodiment one | It is unchanged | Comparative example one | By moderate corrosion |
| Embodiment two | It is unchanged | Comparative example two | By slight erosion |
| Embodiment three | It is unchanged | Comparative example three | Corroded by severe |
(3) water-fastness test
Experimental method：The POM plastic-steels that the delrin zippers with pulllers Singapore frame oil for scribbling different groups is respectively washed using industry washer are drawn
Chain；Wash water condition：50 degree of temperature, addition plus ferment powder 200g, a conduit made of long bamboo oil 100g and float stone 4kg in washing machine, is cleaned 24 hours,
Observe result.
Experimental result：The POM delrin zippers with pulllers of the delrin zippers with pulllers Singapore frame for scribbling different groups oil after observation cleaning respectively, finds
The POM delrin zippers with pulllers outward appearance that the embodiment of the present invention one is scribbled to the delrin zippers with pulllers Singapore frame oil of embodiment three is unchanged, specifically such as
Shown in table 3.
3 water-fastness test of table
| Group | Cosmetic variation | Group | Cosmetic variation |
| Embodiment one | It is unchanged | Comparative example one | It is unchanged |
| Embodiment two | It is unchanged | Comparative example two | Pasta moderate ftractures |
| Embodiment three | It is unchanged | Comparative example three | Pasta slightly ftractures |
It should be noted that unless otherwise indicated, technical term or scientific terminology used in this application should be this hair
The ordinary meaning that bright one of ordinary skill in the art are understood.Unless specifically stated otherwise, otherwise illustrate in these embodiments
Part and relative step, numerical expression and the numerical value of step are not limit the scope of the invention.It is illustrated and described herein
In all examples, unless otherwise prescribed, any occurrence should be construed as merely exemplary, not as limitation, because
This, other examples of exemplary embodiment can have different values.
In the description of the invention, it is to be understood that term " first ", " second " are only used for describing purpose, and can not
It is interpreted as indicating or implies relative importance or imply the quantity of the technical characteristic indicated by indicating.Thus, define " the
One ", one or more this feature can be expressed or be implicitly included to the feature of " second ".In the description of the invention,
" multiple " are meant that two or more, unless otherwise specifically defined.
Finally it should be noted that：Various embodiments above is merely illustrative of the technical solution of the present invention, rather than its limitations；To the greatest extent
The present invention is described in detail with reference to foregoing embodiments for pipe, it will be understood by those within the art that：Its according to
The technical scheme described in foregoing embodiments can so be modified, either which part or all technical characteristic are entered
Row equivalent substitution；And these modifications or replacement, the essence of appropriate technical solution is departed from various embodiments of the present invention technology
The scope of scheme, it all should cover among protection scope of the present invention.
Claims (10)
1. a kind of delrin zippers with pulllers Singapore frame oil, it is characterised in that the delrin zippers with pulllers Singapore frame oil includes first chamber and second group
Compound：
The raw material components of the first chamber by weight, including：The parts by weight of epoxy resin 80~83, ethylene glycol monobutyl ether
4~6 parts by weight, the parts by weight of black slurry 8~12, the parts by weight of levelling agent 0.4~0.6 and the parts by weight of adhesion promoter 2~4；
The raw material components of the second chamber by weight, including：The parts by weight of epoxy hardener 25~35, ethylene glycol only son
The parts by weight of ether 30~50 and the parts by weight of isobutanol 25~35；
The first chamber and the second chamber are independently packed.
2. delrin zippers with pulllers Singapore frame oil according to claim 1, it is characterised in that the preparation method bag of the epoxy hardener
Include step：
S1：Ethylene glycol monomethyl ether is added drop-wise in the mixed liquor of triethylene tetramine and hydroxyethyl methacrylate, protected after being added dropwise to complete
Hold 55~65 DEG C of reaction temperature 3.0h~4.0h；
S2：Epoxy resin is added drop-wise in the solution that the S1 is prepared, it is 6.5~6.7 that pH value is adjusted after being added dropwise to complete, so
85~95 DEG C of reaction 1.5h~2.0h afterwards, obtain the epoxy hardener.
3. delrin zippers with pulllers Singapore frame oil according to claim 2, it is characterised in that：
In step S1, the mol ratio of the triethylene tetramine, the ethylene glycol monomethyl ether and the hydroxyethyl methacrylate is 1:
(1.0~1.5):(2.5~3.0)；
In step S2, the mol ratio of the epoxy resin and the triethylene tetramine is (2.5~2.8):1；The epoxy resin
For epoxy resin E51.
4. delrin zippers with pulllers Singapore frame oil according to claim 1, it is characterised in that the raw material components of the black slurry are by weight
Part meter, including：
The parts by weight of carbon black 15~20, the parts by weight of AEO 5~8 that number-average molecular weight is 2500~3000, diethyl
The parts by weight of glycol 6~8, the parts by weight of dimethylethanolamine 10~14, the parts by weight of APEO 6~10 and the different thiophenes of 2- methyl -4-
The parts by weight of oxazoline -3- ketone 2~4.
5. delrin zippers with pulllers Singapore frame oil according to claim 4, it is characterised in that the preparation method of the black slurry includes step
Suddenly：
The raw material components of the black slurry are mixed, stirs to being uniformly dispersed, obtains under 100~500r/min speed of agitator
Slurry；The slurry is ground to particle diameter as 5~10 μm, obtains the black slurry.
6. delrin zippers with pulllers Singapore frame oil according to claim 1, it is characterised in that：
In the raw material components of the first chamber, the epoxy resin is epoxy resin E44.
7. delrin zippers with pulllers Singapore frame oil according to claim 1, it is characterised in that：The delrin zippers with pulllers Singapore frame oil includes first
Composition and second chamber：
The raw material components of the first chamber by weight, including：The parts by weight of epoxy resin 81.5, ethylene glycol monobutyl ether 5
Parts by weight, the parts by weight of black slurry 10, the parts by weight of levelling agent 0.5 and the parts by weight of adhesion promoter 3；
The raw material components of the second chamber by weight, including：The parts by weight of epoxy hardener 30, ethylene glycol monobutyl ether 40
Parts by weight and the parts by weight of isobutanol 30；
The first chamber and the second chamber are independently packed.
8. the preparation method of the delrin zippers with pulllers Singapore frame oil described in claim any one of 1-7, it is characterised in that：
The preparation method of the first chamber comprises the following steps：Disperse after all raw material components of first chamber are mixed
Uniformly, the first chamber is obtained；
The preparation method of the second chamber comprises the following steps：Disperse after all raw material components of second chamber are mixed
Uniformly, the second chamber is obtained.
9. the application method of the delrin zippers with pulllers Singapore frame oil described in claim any one of 1-7, it is characterised in that including step：
Inorganic agent is evenly coated in delrin zippers with pulllers surface, 115~135 DEG C of 5~7min of continuous baking, plastic-steel is drawn after being toasted
Chain；
By the first chamber of delrin zippers with pulllers Singapore frame oil and second chamber with 1:1 mass ratio is well mixed, and is then applied to
The surface of delrin zippers with pulllers after the baking, then 120~135 DEG C of 5~6min of continuous baking.
10. the application method of delrin zippers with pulllers Singapore frame oil according to claim 9, it is characterised in that：
The raw material components of the inorganic agent include production of low-temperature foaming agent and dimethylbenzene；The matter of the production of low-temperature foaming agent and the dimethylbenzene
Amount is than being 1:(1.2~1.4).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711173736.9A CN107805444A (en) | 2017-11-22 | 2017-11-22 | Delrin zippers with pulllers Singapore frame oil and preparation method thereof and application method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711173736.9A CN107805444A (en) | 2017-11-22 | 2017-11-22 | Delrin zippers with pulllers Singapore frame oil and preparation method thereof and application method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107805444A true CN107805444A (en) | 2018-03-16 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
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| Country | Link |
|---|---|
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107022278A (en) * | 2017-04-27 | 2017-08-08 | 珠海富邦新材料科技有限公司 | Metal zip fastener Singapore frame water paint and preparation method and application |
| CN107236427A (en) * | 2017-07-07 | 2017-10-10 | 珠海富邦新材料科技有限公司 | Aqueous rolling spray pull head paint and preparation method and application |
-
2017
- 2017-11-22 CN CN201711173736.9A patent/CN107805444A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107022278A (en) * | 2017-04-27 | 2017-08-08 | 珠海富邦新材料科技有限公司 | Metal zip fastener Singapore frame water paint and preparation method and application |
| CN107236427A (en) * | 2017-07-07 | 2017-10-10 | 珠海富邦新材料科技有限公司 | Aqueous rolling spray pull head paint and preparation method and application |
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| Title |
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| 《涂料工业》: "水性环氧固化剂的制备及其涂膜性能研究", 《涂料工业》 * |
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Application publication date: 20180316 |