CN107805353A - A kind of high-performance ABS color master batch and its preparation technology and application - Google Patents
A kind of high-performance ABS color master batch and its preparation technology and application Download PDFInfo
- Publication number
- CN107805353A CN107805353A CN201711127034.7A CN201711127034A CN107805353A CN 107805353 A CN107805353 A CN 107805353A CN 201711127034 A CN201711127034 A CN 201711127034A CN 107805353 A CN107805353 A CN 107805353A
- Authority
- CN
- China
- Prior art keywords
- parts
- master batch
- abs color
- toner
- dispersant
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2425/02—Homopolymers or copolymers of hydrocarbons
- C08J2425/04—Homopolymers or copolymers of styrene
- C08J2425/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
Abstract
A kind of high-performance ABS color master batch and preparation technology and application are disclosed in the present invention, the Masterbatch includes following components by weight：40 50 parts of carrier；30 50 parts of toner；5 10 parts of dispersant；01 parts of filler；Wherein described carrier is at least one of acrylonitrile styrene copolymer, ethylene acrylate copolymer, ethylene methyl acrylate copolymer, styrene-butadiene-copolymer, polystyrene；The toner is the rutile-type blue light titanium dioxide being prepared using common sulfuric acid process；The dispersant is polar waxes, and preferably dispersant is one or two kinds of in maleic anhydride grafted polyethylene wax, maleic anhydride inoculated polypropylene wax；The filler is at least one of calcium stearate, calcium carbonate, barium sulfate.ABS color master batch of the present invention has good combination property, and its product has good mechanical property and preferable processing characteristics.
Description
Technical field
The present invention relates to plastic products technology field, more particularly to a kind of ABS color master batch of good combination property, and the ABS
The preparation technology of Masterbatch and the concrete application of the ABS color master batch.
Background technology
Masterbatch is the coloring plastic formed through fine dispersion by a high proportion of pigment or additive and thermoplastic resin
Agent.Acrylonitrile-butadiene-polyglass (ABS) is widely used in machinery, electrical equipment, traffic as important engineering plastics
Deng in numerous areas.Masterbatch coloring is not only simple to operate, has the advantages that to be easy to coloring, good dispersion, can also avoid colorant
With air contact, prevent the chromaticness caused by aoxidizing and making moist from changing, be usually used in producing the pure product of chromaticness.At present, ABS
Color method mainly has toner coloring, dyeing to draw grain coloring and Masterbatch to colour three kinds of methods.Toner color method is simple, still
The shortcomings that color dot, aberration are whard to control, environmental pollution is larger is produced in the presence of easy；It is by ABS and toner that grain coloring is drawn in dyeing
Melt blending is carried out using mixing facilities after mixing, so as to which the ABS micelles of coloring be made, compared with toner colours, although coloring
Effect increased, but need, by reheating, to improve production cost.
The content of the invention
It is an object of the invention to provide a kind of combination property is preferable, lower-cost ABS color master batch, its product whiteness is equal
Even property is good, has good mechanical property and processing characteristics.Present invention also offers a kind of preparation work of ABS color master batch simultaneously
The application of skill and the ABS color master batch.
In order to solve the above technical problems, present invention employs a kind of high-performance ABS color master batch, include by weight with the following group
Point：Carrier 40-50 parts；Toner 30-50 parts；Dispersant 5-10 parts；Filler 0-1 parts；
Wherein described carrier is acrylonitritrile-styrene resin, vinyl-acrylate copolymer, ethylene-methyl methacrylate
At least one of ester copolymer, SB, polystyrene；
The toner is the rutile-type blue light titanium dioxide being prepared using common sulfuric acid process；
The dispersant is polar waxes, and preferably dispersant is that maleic anhydride grafted polyethylene wax, maleic anhydride grafting are poly-
It is one or two kinds of in propylene wax；
The filler is at least one of calcium stearate, calcium carbonate, barium sulfate.
In above-mentioned technical proposal, further, the toner uses R-248 types titanium dioxide or R-249 type titanium dioxides.
In above-mentioned technical proposal, further, the toner uses R-249 type titanium dioxides.
In above-mentioned technical proposal, further, by weight by the carrier of 40-50 parts, the R-249 type titanium whites of 50-60 parts
The filler composition of powder, the maleic anhydride grafted polyethylene wax of 5-8 parts and 0.4-0.6 parts.
ABS color master batch of the present invention has good combination property, and its product has good mechanical property and preferably added
Work performance.
The preparation technology of above-mentioned ABS color master batch is further related in the present invention, is comprised the following steps：
1) each component is subjected to dispensing by component proportion, in high-speed mixer mix 10-20 minutes, it is to be mixed uniformly after
Take out；
2) mixed formula is added in double screw extruder, the melting temperature of double screw extruder is 180 DEG C -210
DEG C, screw speed 100-200r/min, material is well mixed in double screw extruder, be granulated, dry, extrusion cooling,
Drying-granulating, obtain Masterbatch.
The invention further relates to application of the above-mentioned ABS color masterbatches in plastic membrane product, TiO in the film article2's
Mass fraction is 1%-1.5%.
Embodiment
With reference to specific embodiment, the present invention is described in further detail, the wherein each component in addition to separately illustrating
By weight.
Embodiment 1
ABS color master batch in the embodiment is composed of the following components：
43 parts of polystyrene, 50 parts of R-249 types titanium dioxides (Pangang Group Titanium Industry Co., Ltd), 6.5 parts of maleic acids
Acid anhydride grafted polyethylene wax and 0.5 part of calcium stearate.
Above-mentioned raw materials are mixed 10 minutes in high-speed mixer, uniformly rear taking-up to be mixed；Mixed formula is added
Enter in double screw extruder, the melting temperature of double screw extruder is 180 DEG C, screw speed 100r/min, makes material double
It is well mixed in screw extruder, is granulated, dries, extrusion cooling, drying-granulating, obtains Masterbatch.
A certain amount of above-mentioned Masterbatch is added in ABS, white film is molded by moulding process, made in film
TiO2Mass fraction be 1.0%.
The light transmittance of the film article is 94.8%, and whiteness is uniform.
Its tensile strength of prepared sample is 47.6MPa, and bending strength 77.8MPa, shock resistance is good, have compared with
Good processing characteristics.
Embodiment 2
ABS color master batch in the embodiment is composed of the following components：
50 parts of polystyrene, 42 parts of R-249 types titanium dioxides (Pangang Group Titanium Industry Co., Ltd), 7 parts of maleic anhydrides
Grafted polyethylene wax and 1 part of calcium stearate.
Above-mentioned raw materials are mixed 15 minutes in high-speed mixer, uniformly rear taking-up to be mixed；Mixed formula is added
Enter in double screw extruder, the melting temperature of double screw extruder is 190 DEG C, screw speed 140r/min, makes material double
It is well mixed in screw extruder, is granulated, dries, extrusion cooling, drying-granulating, obtains Masterbatch.
A certain amount of above-mentioned Masterbatch is added in ABS, white film is molded by moulding process, made in film
TiO2Mass fraction be 1.2%.
The light transmittance of the film article is 94.5%, and whiteness is uniform.
Its tensile strength of prepared sample is 48.5MPa, and bending strength 76.4MPa, shock resistance is good, have compared with
Good processing characteristics.
Embodiment 3
ABS color master batch in the embodiment is composed of the following components：
46 parts of polystyrene, 48 parts of R-249 types titanium dioxides (Pangang Group Titanium Industry Co., Ltd), 5.3 parts of maleic acids
Acid anhydride grafted polyethylene wax and 0.7 part of calcium stearate.
Above-mentioned raw materials are mixed 20 minutes in high-speed mixer, uniformly rear taking-up to be mixed；Mixed formula is added
Enter in double screw extruder, the melting temperature of double screw extruder is 200 DEG C, screw speed 160r/min, makes material double
It is well mixed in screw extruder, is granulated, dries, extrusion cooling, drying-granulating, obtains Masterbatch.
A certain amount of above-mentioned Masterbatch is added in ABS, white film is molded by moulding process, made in film
TiO2Mass fraction be 1.5%.
The light transmittance of the film article is 94.2%, and whiteness is uniform.
Its tensile strength of prepared sample is 46.6MPa, and bending strength 77.2MPa, shock resistance is good, have compared with
Good processing characteristics.
Embodiment 4
ABS color master batch in the embodiment is composed of the following components：
40 parts of polystyrene, 50 parts of R-249 types titanium dioxides (Pangang Group Titanium Industry Co., Ltd), 9.2 parts of maleic acids
Acid anhydride grafted polyethylene wax and 0.8 part of calcium stearate.
Above-mentioned raw materials are mixed 12 minutes in high-speed mixer, uniformly rear taking-up to be mixed；Mixed formula is added
Enter in double screw extruder, the melting temperature of double screw extruder is 210 DEG C, screw speed 200r/min, makes material double
It is well mixed in screw extruder, is granulated, dries, extrusion cooling, drying-granulating, obtains Masterbatch.
A certain amount of above-mentioned Masterbatch is added in ABS, white film is molded by moulding process, made in film
TiO2Mass fraction be 1.0%.
The light transmittance of the film article is 95.0%, and whiteness is uniform.
Its tensile strength of prepared sample is 47.1MPa, and bending strength 75.8MPa, shock resistance is good, have compared with
Good processing characteristics.
The present invention specification be considered as it is illustrative and not restrictive, on the basis of the present invention, art technology
Personnel are according to disclosed technology contents, it is not necessary to which performing creative labour can is made some to some of technical characteristics and replaced
Change and deform, within the scope of the present invention.
Claims (6)
1. a kind of high-performance ABS color master batch, it is characterised in that by weight including following components：Carrier 40-50 parts；Toner 30-
50 parts；Dispersant 5-10 parts；Filler 0-1 parts；
Wherein described carrier is that acrylonitritrile-styrene resin, vinyl-acrylate copolymer, ethylene-methyl acrylate are common
At least one of polymers, SB, polystyrene；
The toner is the rutile-type blue light titanium dioxide being prepared using common sulfuric acid process；
The dispersant is polar waxes, and preferably dispersant is maleic anhydride grafted polyethylene wax, maleic anhydride inoculated polypropylene
It is one or two kinds of in wax；
The filler is at least one of calcium stearate, calcium carbonate, barium sulfate.
2. high-performance ABS color masterbatches according to claim 1, it is characterised in that：The toner uses R-248 type titanium dioxides
Or R-249 type titanium dioxides.
3. high-performance ABS color masterbatches according to claim 1, it is characterised in that：The toner uses R-249 type titanium whites
Powder.
4. high-performance ABS color masterbatches according to claim 3, it is characterised in that：By weight by the carrier of 40-50 parts,
The filler composition of the R-249 types titanium dioxide of 50-60 parts, the maleic anhydride grafted polyethylene wax of 5-8 parts and 0.4-0.6 parts.
5. the preparation technology of ABS color master batch described in the claims, it is characterised in that comprise the following steps：
1) each component is subjected to dispensing by component proportion, in high-speed mixer mix 10-20 minutes, it is to be mixed uniformly after take
Go out；
2) mixed formula is added in double screw extruder, the melting temperature of double screw extruder is 180 DEG C -210 DEG C, spiral shell
Bar rotating speed is 100-200r/min, material is well mixed in double screw extruder, is granulated, dries, and extrusion cooling, drying are made
Grain, obtains Masterbatch.
6. applications of ABS color masterbatches described in the claims in plastic membrane product, it is characterised in that the film system
TiO in product2Mass fraction be 1%-1.5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711127034.7A CN107805353A (en) | 2017-11-15 | 2017-11-15 | A kind of high-performance ABS color master batch and its preparation technology and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711127034.7A CN107805353A (en) | 2017-11-15 | 2017-11-15 | A kind of high-performance ABS color master batch and its preparation technology and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107805353A true CN107805353A (en) | 2018-03-16 |
Family
ID=61580211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711127034.7A Withdrawn CN107805353A (en) | 2017-11-15 | 2017-11-15 | A kind of high-performance ABS color master batch and its preparation technology and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107805353A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108774757A (en) * | 2018-06-21 | 2018-11-09 | 浙江工业大学温州科学技术研究院 | A kind of composite filled particle and its preparation method and application being used to prepare high strength non-woven fabric |
| CN110511497A (en) * | 2018-05-22 | 2019-11-29 | 刘武平 | A kind of plastic formula that colorant is not added and recalls porcelain white |
| CN111793320A (en) * | 2020-08-12 | 2020-10-20 | 汕头市邦腾科技有限公司 | High-light-property modified plastic and preparation method and application thereof |
-
2017
- 2017-11-15 CN CN201711127034.7A patent/CN107805353A/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110511497A (en) * | 2018-05-22 | 2019-11-29 | 刘武平 | A kind of plastic formula that colorant is not added and recalls porcelain white |
| CN108774757A (en) * | 2018-06-21 | 2018-11-09 | 浙江工业大学温州科学技术研究院 | A kind of composite filled particle and its preparation method and application being used to prepare high strength non-woven fabric |
| CN111793320A (en) * | 2020-08-12 | 2020-10-20 | 汕头市邦腾科技有限公司 | High-light-property modified plastic and preparation method and application thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180316 |