CN107797382A

CN107797382A - Coloured composition

Info

Publication number: CN107797382A
Application number: CN201710780670.3A
Authority: CN
Inventors: 织田胜成; 栂井学
Original assignee: Sumitomo Chemical Co Ltd
Current assignee: Sumitomo Chemical Co Ltd
Priority date: 2016-09-06
Filing date: 2017-09-01
Publication date: 2018-03-13
Anticipated expiration: 2037-09-01
Also published as: JP6974081B2; TWI778975B; TW201815983A; CN107797382B; KR20180027371A; JP2018040001A; KR102450273B1

Abstract

The present invention relates to coloured composition, and it includes compound and the resin that formula (I) represents.In formula (I), R^N1And R^N2Represent there can be the aliphatic alkyl that the carbon number of substituent is 1~40 independently of each other.R^N3Represent can the carbon number with substituent for 1~40 alkyl or can the heterocyclic radical with substituent.R¹~R⁸Hydrogen atom, CO R are represented independently of each other¹⁰²、‑COO‑R¹⁰¹、‑OCO‑R¹⁰²、‑COCO‑R¹⁰²、‑O‑R¹⁰²、‑SO₂‑R¹⁰¹、‑SO₂N(R¹⁰²)₂、‑CON(R¹⁰²)₂、‑N(R¹⁰²)₂、‑NHCO‑R¹⁰²、‑NHCO‑N(R¹⁰²)₂、‑NHCOOR¹⁰²、‑OCON(R¹⁰²)₂, halogen atom, cyano group, nitro, SO₃M、‑CO₂M, can the carbon number with substituent be 1~40 alkyl or can the heterocyclic radical with substituent.R¹⁰¹Represent can the carbon number with substituent for 1~40 alkyl or can the heterocyclic radical with substituent.R¹⁰²Represent hydrogen atom, can the carbon number with substituent for 1~40 alkyl or can the heterocyclic radical with substituent.M represents hydrogen atom or alkali metal atom.A^g‑Represent g valency anion.G represents 1~14 integer.

Description

Coloured composition

Technical field

The present invention relates to the compound useful as colouring agent and coloured composition.

Background technology

Dyestuff has been used for utilizing reflection in the field such as fibrous material, liquid crystal display device, ink-jet (ink jet) Light or transmitted light and carry out color and show.As the dyestuff, it is known to coumarin 6 (the Japanese Unexamined Patent Publication 2006- that following formula represents No. 154740 publications).

The content of the invention

The present invention includes following invention.

[1] coloured composition, it includes compound and the resin that formula (I) represents.

[in formula (I), R^N1And R^N2Represent there can be the aliphatic that the carbon number of substituent is 1~40 independently of each other Alkyl.

R^N3Represent can the carbon number with substituent for 1~40 alkyl or can the heterocyclic radical with substituent.

R¹~R⁸Hydrogen atom ,-CO-R are represented independently of each other¹⁰²、-COO-R¹⁰¹、-OCO-R¹⁰²、-COCO-R¹⁰²、-O- R¹⁰²、-SO₂-R¹⁰¹、-SO₂N(R¹⁰²)₂、-CON(R¹⁰²)₂、-N(R¹⁰²)₂、-NHCO-R¹⁰²、-NHCO-N(R¹⁰²)₂、- NHCOOR¹⁰²、-OCON(R¹⁰²)₂, halogen atom, cyano group, nitro ,-SO₃M、-CO₂M, can be with the carbon number of substituent 1~40 alkyl or the heterocyclic radical can with substituent.

R¹⁰¹Represent can the carbon number with substituent for 1~40 alkyl or can the heterocyclic radical with substituent.

R¹⁰²Represent hydrogen atom, can the carbon number with substituent for 1~40 alkyl or can be with substituent Heterocyclic radical.

M represents hydrogen atom or alkali metal atom.

R¹⁰¹、R¹⁰²And M exist it is multiple in the case of, they can be the same or different.

A^g-Represent the anion of g valencys.G represents 1~14 integer.]

[2] coloured composition as described in [1], wherein, A^g-For containing in the group being made up of tungsten, molybdenum, silicon and phosphorus The anion or fluo anion of at least one kind of element and oxygen as indispensable element.

[3] coloured composition as any one of [1]~[2], wherein, A^g-Containing selected from being made up of tungsten and phosphorus The anion or fluo anion of at least one kind of element and oxygen as indispensable element in group.

[4] coloured composition as any one of [1]~[3], wherein, A^g-Containing selected from being made up of tungsten and phosphorus The anion of at least one kind of element and oxygen as indispensable element in group.

[5] coloured composition as any one of [1]~[4], wherein, R^N1And R^N2Can independently of one another have The carbon number of substituted base is 1~10 alkyl.

[6] coloured composition as any one of [1]~[5], the coloured composition also include solvent.

[7] coloured composition as any one of [1]~[6], the coloured composition also comprising yellow colorants, Orange colorant or red stain.

[8] cured composition for color, it includes the coloured composition and polymerism any one of [1]~[7] Compound.

[9] cured composition for color as described in [8], the cured composition for color also include polymerization initiator.

[10] colour filter (color filter), its be as the coloured composition any one of [1]~[7] or What the cured composition for color [8] or described in [9] was formed.

[11] liquid crystal display device, it includes the colour filter described in [10].

[12] compound that formula (I-B) represents.

[in formula (I-B),

R^N1And R^N2Represent there can be the aliphatic alkyl that the carbon number of substituent is 1~40 independently of each other.

M represents hydrogen atom or alkali metal atom.

B^h-Represent to contain at least one kind of element and oxygen in the group being made up of tungsten, molybdenum, silicon and phosphorus as indispensable element The anion of h valencys.

H represents 1~14 integer.]

[13] compound as described in [12], wherein, B^h-To contain at least one kind of member in the group being made up of tungsten and phosphorus Element and anion of the oxygen as indispensable element.

[14] compound as described in [12] or [13], wherein, R^N1And R^N2Can independently of one another have substituent Carbon number is 1~10 alkyl.

Embodiment

The coloured composition of the present invention includes compound that formula (I) represents (following, sometimes referred to as compound (I).) and tree Fat (following, sometimes referred to as resin (B).).

Compound (I) also includes its dynamic isomer, their salt.

Compound (I) can use as colouring agent.

One kind or two or more compound (I) can be included in the coloured composition of the present invention.

The coloured composition of the present invention can include solvent (following, sometimes referred to as solvent (E).).

In addition, compound (I) is preferably dispersed in solvent (E).

The coloured composition of the present invention can be beyond inclusion compound (I) colouring agent (following, sometimes referred to as colouring agent (A1).Moreover, compound (I) and colouring agent (A1) are referred to as " colouring agent (A) " sometimes below.).

One kind or two or more colouring agent can be included in colouring agent (A1).

Colouring agent (A1) preferably comprises yellow colorants, orange colorant or red stain.

In addition, the cured composition for color of the present invention includes：Compound (I)；In resin (B) and solvent (E) at least One；With polymerizable compound (C).

The cured composition for color of the present invention can include polymerization initiator (D).

The cured composition for color of the present invention can include polymerization and trigger auxiliary agent (D1).

The coloured composition of the present invention can also include levelling agent (leveling agent) (F) and antioxidant.

＜ compounds (I) ＞

Compound (I) is the compound that formula (I) represents.

[in formula (I),

M represents hydrogen atom or alkali metal atom.

A^g-Represent the anion of g valencys.

G represents 1~14 integer.]

R^N1And R^N2The carbon number of the aliphatic alkyl of expression is 1~40, preferably 1~30, more preferably 1~20, is entered One step is preferably 1~15, and particularly preferably 1~10.

R^N1And R^N2The aliphatic alkyl of expression can be saturation or unsaturation, can be chain or alicyclic ring.

As R^N1And R^N2The saturation of expression or unsaturated chain aliphatic alkyl, can enumerate methyl, ethyl, propyl group, fourth Base, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl, dodecyl, heptadecyl, octadecyl and eicosane Straight-chain alkyls such as base etc.；Isopropyl, isobutyl group, sec-butyl, the tert-butyl group, (2- ethyls) butyl, isopentyl, neopentyl, uncle penta Base, (1- methyl) amyl group, (2- methyl) amyl group, (1- ethyls) amyl group, (3- ethyls) amyl group, isohesyl, (5- methyl) hexyl, Branched-chain alkyl such as (2- ethyls) hexyl and (3- ethyls) heptyl etc.；Vinyl, 1- acrylic, 2- acrylic (pi-allyl), (1- Methyl) vinyl, 2- cyclobutenyls, 3- cyclobutenyls, 1,3- butadienyls, (1- (2- acrylic)) vinyl, (1,2- dimethyl) The alkenyl such as acrylic and 2- pentenyls；Etc..The carbon number of saturation or unsaturated chain alkyl is preferably 1~30, more excellent Elect 1~20, more preferably 1~15, especially preferably 1~10 as, further more preferably 1~8.Especially it is more preferably 1~5.Wherein, carbon number be 1~10, the alkyl of the more preferably straight or branched that carbon number is 1~8 be it is especially preferred, Methyl or ethyl are particularly preferred.

As R^N1And R^N2The saturation of expression or unsaturated alicyclic type hydrocarbon, cyclopropyl, 1- methylcyclopropyl groups, ring can be enumerated Butyl, cyclopenta, cyclohexyl, suberyl, 1- methylcyclohexyls, 2- methylcyclohexyls, 3- methylcyclohexyls, 4- methyl cyclohexanes Base, 1,2- Dimethylcyclohexyls, 1,3- Dimethylcyclohexyls, 1,4- Dimethylcyclohexyls, 2,3- Dimethylcyclohexyls, 2,4- bis- Methylcyclohexyl, 2,5- Dimethylcyclohexyls, 2,6- Dimethylcyclohexyls, 3,4- Dimethylcyclohexyls, 3,5- dimethyleyelohexanes Base, 2,2- Dimethylcyclohexyls, 3,3- Dimethylcyclohexyls, 4,4- Dimethylcyclohexyls, cyclooctyl, 2,4,6- 3-methyl cyclohexanols Base, 2,2,6,6- tetramethyl-rings hexyl, 3,3,5,5- tetramethyl-rings hexyl, 4- pentylcyclohexyls, 4- octyl groups cyclohexyl, 4- hexamethylenes The cycloalkyl such as butylcyclohexyl；The cycloalkenyl groups such as cyclohexenyl group (such as hexamethylene -2- alkene, hexamethylene -3- alkene), cycloheptenyl, cyclo-octene base； Norborneol alkyl, adamantyl, bicyclic [2.2.2] octyl etc..The carbon number of saturation or undersaturated alicyclic type hydrocarbon is excellent Elect 3~30, more preferably 3~20 as, be still more preferably 4~20, and then more preferably 4~15, it is further especially excellent Elect 5~15, most preferably 5~10 as.Wherein, especially preferably cyclopenta, cyclohexyl, suberyl, cyclooctyl.

R^N1And R^N2The aliphatic alkyl of expression can also be by aliphatic alkyl and carbon number cited hereinabove be 1 What~40 aromatic hydrocarbyl (such as at least one kind of and aromatic hydrocarbyl in chain alkyl and alicyclic type hydrocarbon) combined Group.

As the aromatic hydrocarbyl, phenyl, o-tolyl, a tolyl, p-methylphenyl, 2,3- dimethyl benzenes can be enumerated Base, 2,4- 3,5-dimethylphenyls, 2,5- 3,5-dimethylphenyls, 2,6- 3,5-dimethylphenyls, 3,4- 3,5-dimethylphenyls, 3,5- dimethyl benzenes Base, 4- ethenylphenyls, o-isopropyl phenyl, an isopropyl phenyl, p-isopropyl phenyl, o-tert-butyl phenyl, a tert-butyl group Phenyl, to tert-butyl-phenyl, mesitylene base (mesityl group), 4- ethylphenyls, 4- butyl phenyls, 4- amyl groups phenyl, 2,6- double (2- propyl group) phenyl, 4- cyclohexyl phenyls, 2,4,6- trimethylphenyls, 4- octyl phenyls, 4- ethenylphenyls, 1- naphthalenes The aromatic series such as base, 2- naphthyls, 5,6,7,8- tetrahydrochysene -1- naphthyls, 5,6,7,8- tetrahydrochysene -2- naphthyls, fluorenyl, phenanthryl, anthryl, pyrenyl Alkyl；Etc..The carbon number of aforementioned fragrance race alkyl is preferably 6~30, more preferably 6~20, more preferably 6~ 15。

As by aromatic hydrocarbyl (such as chain hydrocarbon that aliphatic alkyl and carbon number cited hereinabove are 1~40 At least one kind of and aromatic hydrocarbyl in base and alicyclic type hydrocarbon) group that combines, benzyl, phenethyl, 1- first can be enumerated The aralkyl such as base -1- phenylethyls；The aromatic yl alkenyls such as phenyl vinyl (styryl (phenyl vinyl))；Phenylacetylene The aromatic yl polysulfide yls such as base；Xenyl, terphenyl etc. are bonded with the phenyl of more than 1 phenyl；Cyclohexyl methyl phenyl, benzyl benzene Base, (dimethyl (phenyl) methyl) phenyl etc..On R^N1、R^N2The group of expression, as by alkyl cited hereinabove (such as Chain alkyl and alicyclic type hydrocarbon) group that combines can be such as Cvclopropvlmethvl, cyclopropylethyl, cyclobutylmethyl Base, CYCLOBUTYLETHYL, cyclopentyl-methyl, cyclopentyl ethyl, cyclohexyl methyl, 2- methylcyclohexylmethyls, cyclohexyl-ethyl, gold Firm alkyl methyl etc. is bonded with the alkyl of the alicyclic type hydrocarbon of more than 1.

The carbon number of foregoing hydrocarbon is preferably 4~30, and more preferably 6~30, it is still more preferably 6~20, more enters one Step is preferably 4~20, more preferably 4~15, particularly preferably 6~15.

R^N3、R¹~R⁸、R¹⁰¹And R¹⁰²The carbon number of the alkyl of expression be 1~40, preferably 1~30, more preferably 1~ 20, more preferably 1~15, particularly preferably 1~10.

R^N3、R¹~R⁸、R¹⁰¹And R¹⁰²The alkyl that the carbon number of expression is 1~40 can be aliphatic alkyl and aromatic series Alkyl, the aliphatic alkyl can be saturation or unsaturation, can be chain or alicyclic ring.

As R^N3、R¹~R⁸、R¹⁰¹And R¹⁰²The saturation of expression or unsaturated chain alkyl, can enumerate methyl, ethyl, third Base, butyl, amyl group, hexyl, heptyl, octyl group, nonyl, decyl, undecyl, dodecyl, heptadecyl, octadecyl and Straight-chain alkyls such as eicosyl etc.；Isopropyl, isobutyl group, sec-butyl, the tert-butyl group, (2- ethyls) butyl, isopentyl, new penta Base, tertiary pentyl, (1- methyl) amyl group, (2- methyl) amyl group, (1- ethyls) amyl group, (3- ethyls) amyl group, isohesyl, (5- methyl) Branched-chain alkyls such as hexyl, (2- ethyls) hexyl and (3- ethyls) heptyl etc.；Vinyl, 1- acrylic, 2- acrylic (allyls Base), (1- methyl) vinyl, 2- cyclobutenyls, 3- cyclobutenyls, 1,3- butadienyls, (1- (2- acrylic)) vinyl, (1,2- Dimethyl) alkenyl such as acrylic and 2- pentenyls；Etc..The carbon number of above-mentioned saturation or unsaturated chain alkyl is preferably 1~30, more preferably 1~20, more preferably 1~15, especially preferably 1~10, further more preferably 1~8.Its In, carbon number is 1~10, the alkyl of the more preferably straight or branched that carbon number is 1~8 be it is especially preferred, methyl or Ethyl is particularly preferred.

As R^N3、R¹~R⁸、R¹⁰¹And R¹⁰²The saturation of expression or unsaturated alicyclic type hydrocarbon, cyclopropyl, 1- first can be enumerated Cyclopropyl, cyclobutyl, cyclopenta, cyclohexyl, suberyl, 1- methylcyclohexyls, 2- methylcyclohexyls, 3- methylcyclohexyls, 4- methylcyclohexyls, 1,2- Dimethylcyclohexyls, 1,3- Dimethylcyclohexyls, 1,4- Dimethylcyclohexyls, 2,3- diformazan basic rings Hexyl, 2,4- Dimethylcyclohexyls, 2,5- Dimethylcyclohexyls, 2,6- Dimethylcyclohexyls, 3,4- Dimethylcyclohexyls, 3,5- Dimethylcyclohexyl, 2,2- Dimethylcyclohexyls, 3,3- Dimethylcyclohexyls, 4,4- Dimethylcyclohexyls, cyclooctyl, 2,4,6- Trimethylcyclohexyl, 2,2,6,6- tetramethyl-rings hexyl, 3,3,5,5- tetramethyl-rings hexyl, 4- pentylcyclohexyls, 4- octyl group rings The cycloalkyl such as hexyl, 4- cyclohexylcyclohexyls；Cyclohexenyl group (such as hexamethylene -2- alkene, hexamethylene -3- alkene), cycloheptenyl, cyclo-octene The cycloalkenyl groups such as base；Norborneol alkyl, adamantyl, bicyclic [2.2.2] octyl etc..Foregoing saturation or undersaturated ester ring type The carbon number of alkyl is preferably 3~30, and more preferably 3~20, it is still more preferably 4~20, and then more preferably 4~ 15, further particularly preferably 5~15, most preferably 5~10.Wherein, especially preferably cyclopenta, cyclohexyl, suberyl, ring Octyl group.

As R^N3、R¹~R⁸、R¹⁰¹And R¹⁰²The aromatic hydrocarbyl of expression, can enumerate phenyl, o-tolyl, a tolyl, P-methylphenyl, 2,3- 3,5-dimethylphenyls, 2,4- 3,5-dimethylphenyls, 2,5- 3,5-dimethylphenyls, 2,6- 3,5-dimethylphenyls, 3,4- diformazans Base phenyl, 3,5- 3,5-dimethylphenyls, 4- ethenylphenyls, o-isopropyl phenyl, an isopropyl phenyl, p-isopropyl phenyl, neighbour Tert-butyl-phenyl, a tert-butyl-phenyl, to tert-butyl-phenyl, mesitylene base, 4- ethylphenyls, 4- butyl phenyls, 4- amyl groups Phenyl, 2,6- double (2- propyl group) phenyl, 4- cyclohexyl phenyls, 2,4,6- trimethylphenyls, 4- octyl phenyls, 4- vinyl benzenes Base, 1- naphthyls, 2- naphthyls, 5,6,7,8- tetrahydrochysene -1- naphthyls, 5,6,7,8- tetrahydrochysene -2- naphthyls, fluorenyl, phenanthryl, anthryl, pyrenyl Deng aromatic hydrocarbyl；Etc..The carbon number of aforementioned fragrance race alkyl is preferably 6~30, and more preferably 6~20, it is further excellent Elect 6~15 as.

R^N3、R¹~R⁸、R¹⁰¹And R¹⁰²The alkyl of expression can also be by alkyl cited hereinabove (such as aromatic hydrocarbon It is at least one kind of in base and chain alkyl and alicyclic type hydrocarbon) group that combines, can enumerate benzyl, phenethyl, 1- methyl- The aralkyl such as 1- phenylethyls；The aromatic yl alkenyls such as phenyl vinyl (styryl)；The aromatic yl polysulfide yls such as phenylene-ethynylene；Biphenyl Base, terphenyl etc. are bonded with the phenyl of more than 1 phenyl；Cyclohexyl methyl phenyl, benzyl phenyl, (dimethyl (phenyl) first Base) phenyl etc..

On R^N3、R¹~R⁸、R¹⁰¹And R¹⁰²The group of expression, as by alkyl cited hereinabove (such as chain alkyl And alicyclic type hydrocarbon) group that combines, can be such as Cvclopropvlmethvl, cyclopropylethyl, cyclobutylmethyl, cyclobutyl Ethyl, cyclopentyl-methyl, cyclopentyl ethyl, cyclohexyl methyl, 2- methylcyclohexylmethyls, cyclohexyl-ethyl, adamantyl first Base etc. is bonded with the alkyl of the alicyclic type hydrocarbon of more than 1.

The carbon number of foregoing hydrocarbon is preferably 4~30, and more preferably 6~30, it is still more preferably 6~20, in addition, more Preferably 4~20, more preferably 4~15, particularly preferably 6~15.

R^N1And R^N2Aliphatic alkyl, the R of expression^N3、R¹~R⁸、R¹⁰¹And R¹⁰²The alkyl of expression can have substituent.Take Dai Jike thinks 1 valency, or divalent.For the substituent of divalent, preferably 2 chemical bondings in same carbon atom and Form double bond.

As the substituent of 1 valency, can enumerate：

Methoxyl group, ethyoxyl, propoxyl group, isopropoxy, butoxy, isobutoxy, sec-butoxy, tert-butoxy, amyl group Epoxide, hexyl epoxide, (2- ethyls) hexyl epoxide, heptyl epoxide, octyl group epoxide, nonyl epoxide, decyl epoxide, undecyl oxygen Base, dodecyl epoxide, (2- ethyls) hexyl epoxide, eicosyl epoxide, 1- phenyl ethoxies, 1- methyl isophthalic acids-phenyl ethoxy Base, phenyl epoxide, o-tolyl epoxide, 2,3- 3,5-dimethylphenyls epoxide, 2,4- 3,5-dimethylphenyls epoxide, 2,5- 3,5-dimethylphenyls Epoxide, 2,6- 3,5-dimethylphenyls epoxide, 3,4- 3,5-dimethylphenyls epoxide, 3,5- 3,5-dimethylphenyls epoxide, 2,2- dicyano phenyl Epoxide, 2,3- dicyano phenyl epoxide, 2,4- dicyano phenyl epoxide, 2,5- dicyano phenyl epoxide, 2,6- dicyano phenyl Epoxide, 3,4- dicyano phenyl epoxide, 3,5- dicyano phenyl epoxide, 4- methoxyphenyls epoxide, 2- methoxyphenyls epoxide, 3- methoxyphenyls epoxide, 4- ethoxyl phenenyls epoxide, 2- ethoxyl phenenyls epoxide, 3- ethoxyl phenenyl epoxides etc. and following The group etc. that represents of chemical formula be bonded with one side alkyl that carbon number is 1~20 (preferably carbon number is 1~10) or Its deriveding group (such as pass through carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), the alkyl that carbon number is 1~10 The group that sulfamoyl (alkyl sulfamoyl) (preferably octyl group sulfamoyl) etc. performs the derivatization) epoxide；

Methylsulfany, ethylsulfanyl, propyl group sulfenyl, butyl sulfenyl, tert. butyl-sulphenyl, pentylthio, hexyl sulfenyl, (2- Ethyl) hexyl sulfenyl, heptyl sulfenyl, octylthio, nonyl sulfenyl, decyltliio, undecyl sulfenyl, dodecyl sulfenyl, Eicosyl sulfenyl, phenylsulfartyl and o-tolyl sulfenyl etc. be bonded with carbon number be 1~20 (preferably carbon number be 1~ 10) sulfenyl (sulfanyl) of alkyl；

Epoxy radicals, oxetanylmethoxy, tetrahydrofuran base, THP trtrahydropyranyl；

Formoxyl；Acetyl group, propiono, bytyry, 2,2- Dimethylpropanoyls, valeryl, caproyl, (2- ethyls) oneself Acyl group, heptanoyl group, caprylyl, pelargonyl group, capryl, hendecane acyl group, dodecane acyl group, heneicosane acyl group, benzoyl Deng and the group etc. that represents of following chemical formula be bonded with the alkyl that carbon number is 1~20 (preferably carbon number is 1~11) Or its deriveding group (such as pass through carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), the alkane that carbon number is 1~10 The group that base sulfamoyl (preferably octyl group sulfamoyl) etc. performs the derivatization) carbonyl (make the carbonyl be alkanoyl In the case of, carbon number is preferably 2~12)；

Methoxycarbonyl, ethoxy carbonyl, propoxycarbonyl, butoxy carbonyl, tert-butoxycarbonyl, amyl group epoxide carbonyl Base, hexyl Epoxide carbonyl, (2- ethyls) hexyl Epoxide carbonyl, heptyl Epoxide carbonyl, octyl group Epoxide carbonyl, nonyl Epoxide carbonyl, Decyloxycarbonyl, undecyl Epoxide carbonyl, dodecyl Epoxide carbonyl, eicosyl Epoxide carbonyl, phenyloxycarbonyl, It is 1~20 (preferably carbon atom that group that o-tolyl Epoxide carbonyl etc. and following chemical formula represent etc., which is bonded with carbon number, Number is 1~10) alkyl or its deriveding group (such as pass through carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), carbon The group that alkylsulfamoyl group (preferably octyl group sulfamoyl) etc. that atomicity is 1~10 performs the derivatization) epoxide carbonyl Base；

Amino；N- methylaminos, N, N- dimethylaminos, N- ethylaminos, N, N- diethylaminos, N- propylcarbamics, N, N- dipropylamino, N- isopropylaminos, N, N- diisopropylaminoethyls, N- butylaminos, N, N- dibutylaminos, N- isobutyls Base amino, N, N- diisobutylaminos, N- s-butylaminos, N, N- di-sec-butyls amino, N- tert-butylaminos, bis- tertiary fourth of N, N- Base amino, N- pentyl aminos, N, N- dipentylaminos, N- (1- ethyl propyls) amino, N, N- bis- (1- ethyl propyls) amino, N- Hexylamino, N, N- dihexyls amino, N- (2- ethyls) hexylamino, N, N- bis- (2- ethyls) hexylamino, N- heptyl amino, N, N- diheptyl amino, N- octyl aminos, N, N- dioctylaminos, N- nonylaminos, N, N- dinonyl amino, N- phenylaminos Base, N, N- diphenyl aminos, N, N- ethylmethylaminos, N, N- propyl-methylaminos, N, N- isopropylmethylaminos, N, N- fourths Vlmethyl, N- Decylaminos, N, N- decyls methylamino, N- undecyls amino, N, N- undecyls methylamino, N- Dodecylamino, N, N- dodecyl methyls amino, N- eicosyls amino, N, N- eicosyls methylamino, N, uncle N- Group that butyl methyl amino, N, N- phenylmethyl aminos etc. and following chemical formula represent etc. is by 1 or 2 carbon numbers Alkyl for 1~20 (preferably carbon number is 1~10) or its deriveding group (such as pass through carboxyl, sulfo group, nitro, hydroxyl, halogen Plain (preferably chlorine atom), alkylsulfamoyl group (preferably octyl group sulfamoyl) that carbon number is 1~10 etc. perform the derivatization and Into group) substitution amino；

Sulfamoyl；N- Methylsulfamoyls, N, N- DimethylsuIfamoyls, N- ethylsulfamovls, N, N- diethyl Sulfamoyl, N- propylsulfamovs, N, N- dipropyl sulfamoyl, N- isopropylsulfamoyls base, N, N- diisopropyl ammonia sulphurs Acyl group, N- Butylsulfamoyls base, N, N- dibutylamines sulfonyl, N- isobutyl groups sulfamoyl, N, N- diisobutyls sulfamoyl, N- sec-butyls sulfamoyl, N, N- di-sec-butyls sulfamoyl, N- tert-butyl groups sulfamoyl, N, N- di-t-butyls sulfamoyl, N- amyl groups sulfamoyl, N, N- diamyl sulfamoyl, N- (1- ethyl propyls) sulfamoyl, N, N- bis- (1- ethyl propyls) ammonia Sulfonyl, N- hexyls sulfamoyl, N, N- dihexyls sulfamoyl, N- (2- ethyls) hexyl sulfamoyl, (the 2- second of N, N- bis- Base) hexyl sulfamoyl, N- heptyl sulfamoyl, N, N- diheptyls sulfamoyl, N- octyl groups sulfamoyl, N, N- dioctyl ammonia Sulfonyl, N, N- octyl methyls sulfamoyl, N- nonyls sulfamoyl, N, N- dinonyl sulfamoyl, N- phenyl sulfamoyls base, N, N- diphenyl sulfamoyl, N, N- ethyl-methyls sulfamoyl, N, N- hydroxypropyl methyls sulfamoyl, N, N- isopropyl methyl ammonia Sulfonyl, N, N- butyl methyls sulfamoyl, N- decyls sulfamoyl, N, N- decyls Methylsulfamoyl, N- undecyl ammonia Sulfonyl, N, N- undecyls Methylsulfamoyl, N- dodecyls sulfamoyl, N, N- dodecyl methyls sulfamoyl, N- eicosyls sulfamoyl, N, N- eicosyls Methylsulfamoyl, N, N- tertbutyl methyls sulfamoyl, N, N- phenyl first Group that base sulfamoyl etc. and following chemical formula represent etc. is 1~20 (preferably carbon number by 1 or 2 carbon numbers For 1~10) alkyl or its deriveding group (such as to pass through carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), carbon former The group that alkylsulfamoyl group (preferably octyl group sulfamoyl) etc. that subnumber is 1~10 performs the derivatization) substitution ammonia sulphur Acyl group；

Formylamino；Acetyl-amino, propanoylamino, bytyry amino, 2,2- dimethylpropionylaminos, valeryl Base amino, caproyl amino, (2- ethyls) caproyl amino, heptanoyl group amino, octanoylamino, pelargonyl group amino, capryl Amino, hendecane acyl amino, dodecane acyl amino, heneicosane acyl amino, benzoyl-amido etc. and following change Group that formula represents etc. is through being bonded with the alkyl or its derivative base that carbon number is 1~20 (preferably carbon number is 1~12) Group (such as pass through carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), the alkylsulfamoyl group that carbon number is 1~10 The group that (preferably octyl group sulfamoyl) etc. performs the derivatization) carbonyl substitution amino (make the carbonylamino be alkane In the case of acyl amino, carbon number is preferably 1~12)；

Hydroxyl；The halogen atoms such as fluorine atom, chlorine atom, bromine atoms and iodine atom；

Carboxyl ,-CO₂M²(M²For alkali metal, preferably lithium, sodium, potassium)；Sulfo group ,-SO₃M²(M²For alkali metal, preferably lithium, Sodium, potassium)；Nitro；Cyano group；Formoxyl epoxide；Acetoxyl group, propiono epoxide, bytyry epoxide, 2,2- Dimethylpropanoyl oxygen Base, valeryl epoxide, caproyl epoxide, (2- ethyls) caproyl epoxide, heptanoyl group epoxide, caprylyl epoxide, pelargonyl group epoxide, Capryl epoxide, hendecane acyloxy, dodecane acyloxy, heneicosane acyloxy, benzoyl epoxide etc. and with Under the group etc. that represents of chemical formula be bonded with alkyl that carbon number is 1~20 (preferably carbon number is 1~10) or it spreads out Life group (such as pass through carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), the alkyl ammonia sulphur that carbon number is 1~10 The group that acyl group (preferably octyl group sulfamoyl) etc. performs the derivatization) carbonyl epoxide (make the carbonyl epoxide be alkane acyl In the case of base epoxide, carbon number is preferably 1~10)；

Methyl sulphonyl, ethylsulfonyl, sulfonyl propyl base, butyl sulfonyl, pentylsulfonyl, hexyl sulfonyl, (2- Ethyl) hexyl sulfonyl, heptyl sulfonyl, octyl group sulfonyl, nonyl sulfonyl, decyl sulfonyl, undecyl sulfonyl, ten What dialkylsulfamide base, eicosyl sulfonyl, phenyl sulfonyl, p-methylphenyl sulfonyl etc. and following chemical formula represented Group etc. is bonded with the alkyl that carbon number is 1~20 (preferably carbon number is 1~10) or its deriveding group and (such as passes through carboxylic Base, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl group (the preferably octyl group ammonia sulphur that carbon number is 1~10 Acyl group) etc. the group that performs the derivatization) sulfonyl；

Carbamoyl；N- methylcarbamoyls, N, N- formyl-dimethylaminos, N- ethylaminocarbonyls, N, N- diethylaminos formoxyl, N- propvlcarbamovls, N, N- dipropylaminos formoxyl, N- isopropylcarbamoyls, N, N- diisopropylaminoethyl formoxyl, N- Butylcarbamoyls, N, N- dibutylaminos formoxyl, N- isobutylamino formyls Base, N, N- diisobutylaminos formoxyl, N- s-butylaminos formoxyl, N, N- di-sec-butyls carbamoyl, the N- tert-butyl groups Carbamoyl, N, N- di-t-butyls carbamoyl, N- pentylcarbamoys, N, N- dipentylaminos formoxyl, N- (1- Ethyl propyl) carbamoyl, N, N- bis- (1- ethyl propyls) carbamoyl, N- hexylaminos formoxyl, N, N- dihexyls Carbamoyl, N- (2- ethyls) hexylamino formoxyl, N, N- bis- (2- ethyls) hexylamino formoxyl, N- heptyl amino first Acyl group, N, N- diheptyls carbamoyl, N- octyl aminos formoxyl, N, N- dioctylaminos formoxyl, N- nonylamino first Acyl group, N, N- octyl methyls carbamoyl, N, N- octyl groups Butylcarbamoyl, N, N- dinonyl carbamoyl, N- benzene Base carbamoyl, N, N- diphenylcarbamoyls, N, N- ethylmethylaminos formoxyl, N, N- propyl-methylamino formyls Base, N, N- isopropylmethylaminos formoxyl, N, N- butyl methyls carbamoyl, N- Decylaminos formoxyl, N, N- decyls Methylcarbamoyl, N- undecyls carbamoyl, N, N- undecyls methylcarbamoyl, N- dodecylaminos Formoxyl, N, N- dodecyl methyls carbamoyl, N- eicosyls carbamoyl, N, N- eicosyl methylamino first The base that acyl group, N, N- tertbutyl methyls carbamoyl, N, N- phenylmethyl amino formoxyls etc. and following chemical formula represent Group etc. (such as is passed through by alkyl that 1 or 2 carbon numbers are 1~20 (preferably carbon number is 1~10) or its deriveding group Carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl group (the preferably octyl group ammonia that carbon number is 1~10 Sulfonyl) etc. the group that performs the derivatization) substitution carbamoyl；

Trifluoromethyl, perfluoro-ethyl, perfluoro propyl, perfluoroisopropyl, perfluoro butyl, perfluoropentyl, perfluoro hexyl, perfluor Heptyl, perfluoro capryl, perfluor nonyl, perfluoro decyl, perfluor undecyl, perfluorododecyl, perfluor eicosyl, perfluor ring The fluorine atoms such as hexyl, perfluorophenyl instead of the alkyl that the carbon number that whole hydrogen atoms forms is 1~20；

It is perfluoro-ethyl methyl, perfluoro propyl methyl, perfluoroisopropyl methyl, perfluoro butyl methyl, perfluoropentyl methyl, complete Fluorine hexyl methyl, perfluor hept-ylmethyl, perfluoro capryl methyl, perfluor nonanylmethyl, perfluoro decyl methyl, perfluor undecyl first The carbon number that there are whole hydrogen atoms to be replaced by fluorine atoms for base, perfluorododecyl methyl, perfluor eicosyl methyl etc. is 1 The alkyl that the alkyl of~20 straight or branched is 1~20 as the carbon number of substituent；

2- fluorophenyls, 3- fluorophenyls, 4- fluorophenyls and 2,4,6- trifluorophenyls etc. substitute a part of hydrogen atom to form with fluorine Carbon number be 1~20 (preferably carbon number is 1~10) alkyl；

-CO-SH、-CO-S-CH₃、-CO-S-CH₂CH₃、-CO-S-CH₂-CH₂-CH₃、-CO-S-CH₂-CH₂-CH₂-CH₃Deng With alkyl linked sulfenyl carbonyl (thiocarbonyl) ,-CO- that carbon number is 1~20 (preferably carbon number is 2~10) S-C₆H₅Deng the sulfenyl carbonyl being bonded with the aryl that carbon number is 6~20；

Following chemical formula represent as *-COCO-R (in formula, R is hydrogen atom, carbon number is 1~20 alkyl (such as meeting the alkyl that carbon number is 1~20 in alkyl listed above) or its deriveding group (such as by carboxyl, sulphur Base, nitro, hydroxyl, halogen (preferably chlorine atom), the alkylsulfamoyl group (preferably octyl group sulfamoyl) that carbon number is 1~10 Etc. the group performed the derivatization)) group；

*-NRCONR as following chemical formula expression₂(in formula, R is hydrogen atom, carbon number is 1~20 hydrocarbon Base (such as meeting the alkyl that carbon number is 1~20 in alkyl listed above) or its deriveding group (such as by carboxyl, Sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl group (the preferably octyl group sulfonamides that carbon number is 1~10 Base) etc. the group that performs the derivatization), the R mutually can be the same or different, and can be mutually bonded and form ring) Group；

*-OCONR as following chemical formula expression₂(in formula, R is hydrogen atom, carbon number is 1~20 alkyl (such as meeting the alkyl that carbon number is 1~20 in alkyl listed above) or its deriveding group (such as by carboxyl, sulphur Base, nitro, hydroxyl, halogen (preferably chlorine atom), the alkylsulfamoyl group (preferably octyl group sulfamoyl) that carbon number is 1~10 Etc. the group performed the derivatization), the R mutually can be the same or different, and can be mutually bonded and form ring) base Group；

Following chemical formula represent as *-NRCOOR (in formula, R is hydrogen atom, carbon number is 1~20 alkyl (such as meeting the alkyl that carbon number is 1~20 in alkyl listed above) or its deriveding group (such as by carboxyl, sulphur Base, nitro, hydroxyl, halogen (preferably chlorine atom), the alkylsulfamoyl group (preferably octyl group sulfamoyl) that carbon number is 1~10 Etc. the group performed the derivatization), the R mutually can be the same or different, and can be mutually bonded and form ring) base Group；

*-OP(O)(OCH₃)₂Deng *-OP (O) (OR)₂(in formula, R is hydrogen atom, alkyl that carbon number is 1~20 (such as Meet the alkyl that carbon number is 1~20 in alkyl listed above) or its deriveding group (such as by carboxyl, sulfo group, nitre Base, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl group (preferably octyl group sulfamoyl) that carbon number is 1~10 etc. enter The group that row derivatization forms), the R mutually can be the same or different, and can be mutually bonded and form ring) group；

*-Si(CH₃)₃、*-Si(CH₂CH₃)₃、*-Si(C₆H₅)₃And *-Si (CH (CH₃)₂)₃Deng *-SiR₃(in formula, R is hydrogen Atom, the alkyl that carbon number is 1~20 (such as meeting the alkyl that carbon number is 1~20 in alkyl listed above) or Its deriveding group (such as pass through carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), the alkyl that carbon number is 1~10 The group that sulfamoyl (preferably octyl group sulfamoyl) etc. performs the derivatization), the R mutually can be the same or different, Can be mutually bonded and form ring) group；Etc..

As the substituent of divalent, oxo (oxo) base, thio (thioxo) base can be enumerated, imino group, through carbon number be 1 The alkyl-substituted imino group of~20 (preferably carbon number is 1~10), the imido substituted through the aryl that carbon number is 6~20 Base etc..As through alkyl-substituted imino group, CH can be enumerated₃- N=, CH₃-CH₂- N=, CH₃-(CH₂)₂- N=, CH₃-(CH₂)₃- N=etc..As the imino group substituted through aryl, C can be enumerated₆H₅- N=etc..

Substituent as carbon number for 1~40 alkyl, it can preferably enumerate group s1 substituent.As shown below spreads out Raw group is preferably by carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), the alkyl ammonia that carbon number is 1~10 The group that sulfonyl (preferably octyl group sulfamoyl) etc. performs the derivatization.

[group s1]

Carbon number is bonded with one side as 1~20 alkyl or the epoxide of its deriveding group；

Carbon number is bonded with as 1~20 alkyl or the carbonyl of its deriveding group；

Carbon number is bonded with as 1~20 alkyl or the Epoxide carbonyl of its deriveding group；

Amino；It is the amino that 1~20 alkyl or its deriveding group substitute by 1 or 2 carbon numbers；Sulfamoyl； It is the sulfamoyl that 1~20 alkyl or its deriveding group substitute by 1 or 2 carbon numbers；

Carbon number is bonded with as 1~20 alkyl or the carbonylamino of its deriveding group；

Hydroxyl；Halogen atom；-CO₂(M represents hydrogen atom or alkali metal atom to M (preferably carboxyl), preferably represents that hydrogen is former Son.)；-SO₃(M represents hydrogen atom or alkali metal atom to M (preferably sulfo group), preferably represents hydrogen atom.)；

Nitro；Cyano group；Carbon number is bonded with as 1~20 alkyl or the carbonyl epoxide of its deriveding group；It is bonded with carbon Atomicity is 1~20 alkyl or the sulfonyl of its deriveding group；Carbamoyl；It is 1~20 by 1 or 2 carbon numbers Alkyl or its deriveding group substitution carbamoyl；It is 1 that fluorine atom, which instead of the carbon number that whole hydrogen atoms forms, ~20 alkyl；

The alkyl for the straight or branched for being 1~20 with the carbon number that whole hydrogen atoms are replaced by fluorine atoms is as substitution The carbon number of base is 1~20 alkyl；Fluorine instead of the alkyl that the carbon number that a part of hydrogen atom forms is 1~20；Oxygen Dai Ji.

Substituent as carbon number for 1~40 alkyl, it can more preferably enumerate group s2 substituent.

[group s2]

Carbon number is bonded with one side as 1~10 alkyl or the epoxide of its deriveding group；

Carbon number is bonded with as 1~10 alkyl or the carbonyl of its deriveding group；

Carbon number is bonded with as 1~10 alkyl or the Epoxide carbonyl of its deriveding group；

Amino；The amino substituted by the alkyl that 1 or 2 carbon numbers are 1~10；

Sulfamoyl；It is the sulfamoyl that 1~10 alkyl or its deriveding group substitute by 1 or 2 carbon numbers；Key Close the alkyl for thering is carbon number to be 1~10 or the carbonylamino of its deriveding group；Hydroxyl；Fluorine atom, chlorine atom, bromine atoms；

-CO₂(M represents hydrogen atom or alkali metal atom to M (preferably carboxyl), preferably represents hydrogen atom.)；-SO₃M (preferably sulphurs Base) (M represents hydrogen atom or alkali metal atom, preferably represents hydrogen atom.)；Nitro；Cyano group；Carbon number is bonded with as 1~10 Alkyl or its deriveding group carbonyl epoxide；Carbon number is bonded with as 1~10 alkyl or the sulfonyl of its deriveding group； Carbamoyl；It is the carbamoyl that 1~10 alkyl or its deriveding group substitute by 1 or 2 carbon numbers；Fluorine atom It instead of the alkyl that the carbon number that whole hydrogen atoms forms is 1~10；The carbon being replaced by fluorine atoms with whole hydrogen atoms The alkyl that the alkyl for the straight or branched that atomicity is 1~10 is 1~10 as the carbon number of substituent；Fluorine instead of one The alkyl that the carbon number for dividing hydrogen atom to form is 1~10；Oxo base.

As R^N3、R¹~R⁸、R¹⁰¹And R¹⁰²The carbon number with substituent represented is 1~40 alkyl, can be enumerated The carbon number of substituent with 1 valency or divalent is 1~40 alkyl, can preferably enumerate the substituent with 1 valency or divalent Saturation that carbon number is 1~30 or unsaturated chain alkyl, the carbon number of substituent with 1 valency or divalent are 3~30 Saturation or unsaturated alicyclic type hydrocarbon, have 1 valency or divalent substituent carbon number be 6~30 aromatic hydrocarbyl or The group that the carbon number of substituent that alkyl combines, having 1 valency or divalent is 1~30,

Can more preferably enumerate with group s1 substituent carbon number be 1~20 saturation or unsaturated chain alkyl, Saturation or unsaturated alicyclic type hydrocarbon that the carbon number of substituent with group s1 is 3~20, there is the substituent for organizing s1 The carbon number of substituent that the aromatic hydrocarbyl or alkyl that carbon number is 6~20 combine, having group s1 is 1~ 20 group,

The carbon number that the substituent with group s2 can particularly preferably be enumerated is 1~15 saturation or unsaturated chain hydrocarbon The saturation or unsaturated alicyclic type hydrocarbon, the substituent with group s2 that base, the carbon number with the substituent for organizing s2 are 3~15 Carbon number be 6~15 aromatic hydrocarbyl or alkyl combine, the carbon number of substituent that there is group s2 be 1 ~15 group.

As R^N3、R¹~R⁸、R¹⁰¹And R¹⁰²The heterocyclic radical of expression, it can be monocyclic or polycyclic, preferably include Heterocycle of the hetero atom as the inscape of ring.As hetero atom, nitrogen-atoms, oxygen atom and sulphur atom etc. can be enumerated.

The carbon number of heterocyclic radical is preferably 3~30, more preferably 3~22, more preferably 3~20, further more Preferably 3~18, further more preferably 3~15, particularly preferably 3~14.

As the heterocycle comprising nitrogen-atoms, can enumerate：

Monocyclic system's saturated heterocyclic such as aziridine, azetidine, pyrrolidines, piperidines, piperazine；

The pyrazoles such as the pyrroles such as 2,5- dimethyl pyrroles, 2- methylpyrazoles, 3- methylpyrazoles, imidazoles, 1,2,3- triazoles, 1,2, The five-membered ring such as 4- triazoles system unsaturated heterocycle；

The hexa-atomic ring system unsaturated heterocycle such as the pyrimidines such as pyridine, pyridazine, 6- methylpyrimidines, pyrazine, 1,3,5- triazines；

Indazole, indoline, isoindoline, indoles, indolizine, benzimidazole, quinoline, isoquinolin, 5,6,7,8- tetrahydrochysenes (3- first Base) quinoxaline, quinazoline, cinnolines, phthalazines, naphthyridines, purine, pteridine, benzopyrazoles, the benzo such as quinoxaline, 3- methyl-quinoxalines The fused bicyclic such as piperidines system heterocycle；

The fused tricyclic such as carbazole, acridine, azophenlyene system heterocycle；Etc..

As the heterocycle comprising oxygen atom, can enumerate：

Oxirane, oxetanes, tetrahydrofuran, oxinane, 1,3- dioxanes, 1,4- dioxanes Monocyclic system's saturated heterocyclics such as hexane, 1- cyclopenta dioxolane；1,4- dioxo spiros [4.5] decane, 1,4- dioxo spiros [4.5] the second cycle line saturated heterocyclic such as nonane；

The lactone system such as α-second lactone, beta-propiolactone, gamma-butyrolacton, gamma-valerolactone and δ-valerolactone heterocycle；

The five-membered ring system such as furans such as 2,3- dimethyl furans, 2,5- dimethyl furans unsaturated heterocycle；

The hexa-atomic ring system unsaturated heterocycle such as 2H- pyrans, 4H- pyrans；

Chromene, the benzene such as 1- benzofurans, 4- methyl chromenes and two Evil luxuriant (benzodioxole), chroman and different The fused bicyclic such as chroman system heterocycle；

The fused tricyclic such as xanthene, dibenzofurans system heterocycle；Etc..

As the heterocycle comprising sulphur atom, can enumerate：The five-membered ring such as dithiolane system saturated heterocyclic；Thia hexamethylene (thiane), the hexa-atomic ring system saturated heterocyclic of 1,3- dithiane, 2- methyl isophthalic acids, 3- dithiane etc.；3 methyl thiophene, 2- carboxy thiophenes Deng the five-membered ring system such as benzothiopyran derivatives such as thiophene, 4H- thiapyrans, benzo tetrahydric thiapyran unsaturated heterocycle；The fused bicyclics such as benzothiophene It is heterocycle etc.；The fused tricyclic such as thianthrene, dibenzothiophenes system heterocycle；Etc..

As the heterocycle for including nitrogen-atoms and oxygen atom, can enumerate：

The monocyclic system such as morpholine, 2-Pyrrolidone, 2- N-methyl-2-2-pyrrolidone Ns, 2- piperidones, 2- methyl -2- piperidones is full And heterocycle；

Monocyclic system's unsaturated heterocycles such as 4- Jia Ji oxazole Deng oxazoles, 2- methyl-isoxazoles, 3- methyl-isoxazoles Deng isoxazoles；

The fused bicyclic systems such as benzoxazole, benzoisoxazole, benzoxazine, benzo dioxane, benzimidazoline Heterocycle；The fused tricyclic such as phenoxazine system heterocycle；Etc..

As the heterocycle for including nitrogen-atoms and sulphur atom, can enumerate：

The monocyclic heterocycles such as the thiazoles such as 3- methylthiazols, 2,4- dimethylthiazoles；The fused bicyclic such as benzothiazole system heterocycle；

The fused tricyclic such as phenthazine system heterocycle；Etc..

Above-mentioned heterocycle can also be the group that combination alkyl listed above forms, and can enumerate such as tetrahydrofuran ylmethyl Deng.

Above-mentioned heterocycle can also be the heterocycle that following chemical formula represents.

Above-mentioned heterocyclic radical can be R¹~R³、R⁵~R⁸In more than 2 heterocyclic radicals for being bonded and being formed.Such heterocycle Base includes R¹~R³、R⁵~R⁸The phenyl ring being bonded has ring structures more than 2 rings inside.As ring knots more than 2 rings Structure, the structure of such as following formula can be enumerated.

It should be noted that the bonding position of above-mentioned heterocycle is the portion after the arbitrary hydrogen atom disengaging included in each ring Point.

R^N3、R¹~R⁸、R¹⁰¹And R¹⁰²The heterocyclic radical of expression can have substituent.As the substituent, can enumerate and R^N1 And R^N2Aliphatic alkyl, the R of expression^N3、R¹~R⁸、R¹⁰¹And R¹⁰²The substituent identical substitution that the alkyl of expression can have Base.In addition, in the case where foregoing heterocycle includes nitrogen-atoms as its constitution element, row above can be bonded with the nitrogen-atoms The alkyl of act is as substituent.In addition, in the case where foregoing heterocycle includes nitrogen-atoms as its constitution element, can be former in the nitrogen Alkyl listed above is bonded with son as substituent.

As the preference of the substituent, can enumerate and R^N1And R^N2Aliphatic alkyl, the R of expression^N3、R¹~R⁸、R¹⁰¹And R¹⁰²The preference identical example for the substituent that the alkyl of expression can have.

As R^N3、R¹~R⁸、R¹⁰¹And R¹⁰²The heterocyclic radical with substituent represented, taking with 1 valency or divalent can be enumerated Dai Ji heterocyclic radical, the heterocyclic radical of the substituent with group s1 can be preferably enumerated, can more preferably enumerate the substituent with group s2 Heterocyclic radical.

The substituent (the first substituent) that above-mentioned alkyl or heterocyclic radical can have can be 1 or more than 2,2 with On substituent it is separate, can be the same or different.In addition, for foregoing first substituent, in one part Included in alkyl on bonding have other substituents (the second substituent).Second substituent can be from same with the first substituent Group in select.

Hereinafter, to R¹~R⁸- CO-R¹⁰²、-COO-R¹⁰¹、-OCO-R¹⁰²、-COCO-R¹⁰²、-O-R¹⁰²、-SO₂-R¹⁰¹、- SO₂N(R¹⁰²)₂、-CON(R¹⁰²)₂、-N(R¹⁰²)₂、-NHCO-R¹⁰²、-NHCO-N(R¹⁰²)₂、-NHCOOR¹⁰²、-OCON(R¹⁰²)₂, halogen Plain atom ,-SO₃M、-CO₂M is illustrated.

It is used as-CO-R¹⁰², formoxyl can be enumerated；Acetyl group, propiono, bytyry, 2,2- Dimethylpropanoyls, valeryl Base, caproyl, (2- ethyls) caproyl, heptanoyl group, caprylyl, pelargonyl group, capryl, hendecane acyl group, dodecane acyl group, two It is 1~40 (preferably carbon that group that hendecane acyl group, benzoyl etc. and above-mentioned chemical formula represent etc., which is bonded with carbon number, Atomicity is 1~20) alkyl or its deriveding group (such as pass through carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine be former Son), the group that performs the derivatization of the alkylsulfamoyl group (preferably octyl group sulfamoyl) etc. that carbon number is 1~10) Carbonyl, it can preferably enumerate and be bonded with the carbonyl of the alkyl that carbon number is 1~10 and (make in the case that the carbonyl is acyl group, carbon is former Subnumber is 2~41) etc..It is preferred that the hydrocarbon for being bonded with that carbon number is 1~11 (further preferred carbon number is 1~10) can be enumerated Carbonyl of base or its deriveding group (in the case of making the carbonyl for alkanoyl, carbon number is more preferably 2~12) etc..

It is used as-COO-R¹⁰¹, methoxycarbonyl, ethoxy carbonyl, propoxycarbonyl, tert-butoxycarbonyl, fourth oxygen can be enumerated Base carbonyl, amyl group Epoxide carbonyl, hexyl Epoxide carbonyl, (2- ethyls) hexyl Epoxide carbonyl, heptyl Epoxide carbonyl, octyl group epoxide carbonyl Base, nonyl Epoxide carbonyl, decyloxycarbonyl, undecyl Epoxide carbonyl, dodecyl Epoxide carbonyl, phenyloxycarbonyl, It is 1~40 (preferably carbon atom that group that eicosyl Epoxide carbonyl etc. and above-mentioned chemical formula represent etc., which is bonded with carbon number, Number be 1~20) alkyl Epoxide carbonyl, can preferably enumerate be bonded with carbon number be 1~10 alkyl or its deriveding group (such as pass through carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), the alkylsulfamoyl group that carbon number is 1~10 The group that (preferably octyl group sulfamoyl) etc. performs the derivatization) Epoxide carbonyl etc..

It is preferred that the Epoxide carbonyl etc. for being bonded with alkyl that carbon number is 1~10 or its deriveding group can be enumerated.

It is used as-OCO-R¹⁰², formoxyl epoxide can be enumerated；Acetoxyl group, propiono epoxide, bytyry epoxide, 2,2- diformazans Base propiono epoxide, valeryl epoxide, caproyl epoxide, (2- ethyls) caproyl epoxide, heptanoyl group epoxide, caprylyl epoxide, Pelargonyl group epoxide, capryl epoxide, hendecane acyloxy, dodecane acyloxy, heneicosane acyloxy, benzoyl Group that epoxide etc. and above-mentioned chemical formula represent etc. is 1~40 (preferably carbon number is 1~20) with being bonded with carbon number Alkyl carbonyl linkage epoxide, can more preferably enumerate the alkyl or its deriveding group for being bonded with that carbon number is 1~10 (such as it is bonded with the carbonyl epoxide, (excellent by alkylsulfamoyl group of carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom) Select octyl group sulfamoyl) etc. the group that performs the derivatization) carbonyl epoxide (make the situation that the carbonyl epoxide is acyloxy Under, carbon number is 2~41) etc., can preferably enumerate be bonded with carbon number be 1~11 (further preferred carbon number is 1~ 10) the carbonyl epoxide of alkyl or its deriveding group (makes in the case that the carbonyl epoxide is acyloxy, carbon number is more preferably For 2~12) etc..

It is used as-COCO-R¹⁰², methyl oxalyl, Ethyl oxalyl base, propyl group oxalyl group, butyl oxalyl group, amyl group can be enumerated Oxalyl group, hexyl oxalyl group, (2- ethyls) hexyl oxalyl group, heptyl oxalyl group, octyl group oxalyl group, nonyl oxalyl group, decyl grass Acyl group, undecyl oxalyl group, dodecyl oxalyl group, eicosyl oxalyl group, cyclopenta oxalyl group, cyclohexyl oxalyl group, Group that phenyl oxalyl group, p-methylphenyl oxalyl group etc. and above-mentioned chemical formula represent etc. is bonded with carbon number as 1~40 The alkyl of (preferably carbon number be 1~20) or its deriveding group (such as by carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably Chlorine atom), the base that performs the derivatization of the alkylsulfamoyl group (preferably octyl group sulfamoyl) etc. that carbon number is 1~10 Group) oxalyl group etc..

It is used as-O-R¹⁰², hydroxyl can be enumerated；Methoxyl group, ethyoxyl, propoxyl group, isopropoxy, butoxy, isobutoxy, Sec-butoxy, tert-butoxy, amyl group epoxide, hexyl epoxide, heptyl epoxide, octyl group epoxide, nonyl epoxide, decyl epoxide, 11 Alkyl oxy, dodecyl epoxide, (2- ethyls) hexyl epoxide, eicosyl epoxide, 1- phenyl ethoxies, 1- methyl isophthalic acids-benzene Base oxethyl, phenyl epoxide, 2,3- 3,5-dimethylphenyls epoxide, 2,4- 3,5-dimethylphenyls epoxide, 2,5- 3,5-dimethylphenyls epoxide, 2, 6- 3,5-dimethylphenyls epoxide, 3,4- 3,5-dimethylphenyls epoxide, 3,5- 3,5-dimethylphenyls epoxide, 2,2- dicyano phenyl epoxide, 2, 3- dicyano phenyl epoxide, 2,4- dicyano phenyl epoxide, 2,5- dicyano phenyl epoxide, 2,6- dicyano phenyl epoxide, 3, 4- dicyano phenyl epoxide, 3,5- dicyano phenyl epoxide, 4- methoxyphenyls epoxide, 2- methoxyphenyls epoxide, 3- methoxies Base phenyl epoxide, 4- ethoxyl phenenyls epoxide, 2- ethoxyl phenenyls epoxide, 3- ethoxyl phenenyl epoxides etc. and above-mentioned chemistry Group that formula represents etc. is bonded with the alkyl or its deriveding group (example that carbon number is 1~40 (preferably carbon number is 1~20) Such as by carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), carbon number be 1~10 alkylsulfamoyl group (preferably Octyl group sulfamoyl) etc. the group that performs the derivatization) epoxide, it is 1~10 that can preferably enumerate and be bonded with carbon number Epoxide of alkyl etc..

It is preferred that the epoxide etc. for being bonded with alkyl that carbon number is 1~10 or its deriveding group can be enumerated.

It is used as-SO₂-R¹⁰¹, methyl sulphonyl, ethylsulfonyl, sulfonyl propyl base, butyl sulfonyl, amyl group sulphur can be enumerated Acyl group, hexyl sulfonyl, (2- ethyls) hexyl sulfonyl, heptyl sulfonyl, octyl group sulfonyl, nonyl sulfonyl, decyl sulphonyl Base, undecyl sulfonyl, dodecyl sulfonyl, eicosyl sulfonyl, phenyl sulfonyl, p-methylphenyl sulfonyl etc., And group for representing of above-mentioned chemical formula etc. be bonded with alkyl that carbon number is 1~40 (preferably carbon number is 1~20) or Its deriveding group (such as pass through carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), the alkyl that carbon number is 1~10 The group that sulfamoyl (preferably octyl group sulfamoyl) etc. performs the derivatization) sulfonyl etc., can preferably enumerate and be bonded with Alkyl or the sulfonyl of its deriveding group that carbon number is 1~10 etc..

It is used as-SO₂N(R¹⁰²)₂, can enumerate：

Sulfamoyl；

N- Methylsulfamoyls, N- ethylsulfamovls, N- propylsulfamovs, N- isopropylsulfamoyls base, N- butyl Sulfamoyl, N- isobutyl groups sulfamoyl, N- sec-butyls sulfamoyl, N- tert-butyl groups sulfamoyl, N- amyl groups sulfamoyl, N- (1- ethyl propyls) sulfamoyl, N- hexyls sulfamoyl, N- (2- ethyls) hexyl sulfamoyl, N- heptyl sulfamoyl, N- Octyl group sulfamoyl, N- nonyls sulfamoyl, N- decyls sulfamoyl, N- undecyls sulfamoyl, N- dodecyl ammonia sulphurs Group that acyl group, N- eicosyls sulfamoyl, N- phenyl sulfamoyl bases etc. and above-mentioned chemical formula represent etc. is by 1 carbon original Subnumber is that the alkyl of 1~40 (preferably carbon number is 1~20) or its deriveding group (such as pass through carboxyl, sulfo group, nitro, hydroxyl Base, halogen (preferably chlorine atom), alkylsulfamoyl group (preferably octyl group sulfamoyl) that carbon number is 1~10 etc. are derived Change the group that forms) sulfamoyl of substitution etc.；

N, N- DimethylsuIfamoyl, N, N- ethyl-methyls sulfamoyl, N, N- diethyl aminos sulfonyl, N, N- propyl group first Base sulfamoyl, N, N- dipropyl sulfamoyl, N, N- isopropyl methyls sulfamoyl, N, N- diisopropyls sulfamoyl, N, N- tertbutyl methyls sulfamoyl, N, N- diisobutyls sulfamoyl, N, N- di-sec-butyls sulfamoyl, N, N- di-t-butyl ammonia Sulfonyl, N, N- butyl methyls sulfamoyl, N, N- dibutylamines sulfonyl, N, N- diamyl sulfamoyl, (the 1- second of N, N- bis- Base propyl group) sulfamoyl, N, N- dihexyls sulfamoyl, N, N- bis- (2- ethyls) hexyl sulfamoyl, N, N- diheptyl ammonia sulphurs Acyl group, N, N- octyl methyls sulfamoyl, N, N- dioctyls sulfamoyl, N, N- dinonyl sulfamoyl, N, N- decyl methyl Sulfamoyl, N, N- undecyls Methylsulfamoyl, N, N- dodecyl methyls sulfamoyl, N, N- eicosyl methyl ammonia The quilts such as the group that sulfonyl, N, N- phenyl methyls sulfamoyl, N, N- diphenyl sulfamoyls etc. and above-mentioned chemical formula represent 2 carbon numbers be 1~40 (preferably carbon number is 1~20) alkyl or its deriveding group (such as by carboxyl, sulfo group, Nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl group (preferably octyl group sulfamoyl) that carbon number is 1~10 etc. The group performed the derivatization) substitution sulfamoyl etc.,

It is preferred that the sulfamoyl substituted by 1 or 2 carbon numbers for 1~10 alkyl or its deriveding group can be enumerated Deng.

As-CON (R¹⁰²)₂, can enumerate：

Carbamoyl；

N- methylcarbamoyls, N- ethylaminocarbonyls, N- propvlcarbamovls, N- isopropylamino formyls Base, N- Butylcarbamoyls, N- butylcarbamoyls, N- s-butylaminos formoxyl, N- t-Butylcarbamoyls, N- pentylcarbamoys, N- (1- ethyl propyls) carbamoyl, N- hexylaminos formoxyl, N- (2- ethyls) hexylamino Formoxyl, N- heptyl carbamoyl, N- octyl aminos formoxyl, N- nonylcarbamoyls, N- Decylaminos formoxyl, N- Undecyl carbamoyl, N- dodecylaminos formoxyl, N- eicosyls carbamoyl, N- phenylcarbamoyls Deng and the group etc. that represents of above-mentioned chemical formula by alkyl that 1 carbon number is 1~40 (preferably carbon number is 1~20) Or its deriveding group (such as pass through carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), the alkane that carbon number is 1~10 The group that base sulfamoyl (preferably octyl group sulfamoyl) etc. performs the derivatization) substitution carbamoyl etc.；

N, N- formyl-dimethylamino, N, N- ethylmethylaminos formoxyl, N, N- diethylaminos formoxyl, N, N- Propyl-methylamino formoxyl, N, N- dipropylaminos formoxyl, N, N- isopropylmethylaminos formoxyl, N, N- diisopropyls Carbamoyl, N, N- tertbutyl methyls carbamoyl, N, N- diisobutylaminos formoxyl, N, N- di-sec-butyl amino first Acyl group, N, N- di-t-butyls carbamoyl, N, N- butyl methyls carbamoyl, N, N- dibutylaminos formoxyl, N, N- Butyl octyl carbamoyl, N, N- dipentylaminos formoxyl, N, N- bis- (1- ethyl propyls) carbamoyl, N, N- bis- oneself Base carbamoyl, N, N- bis- (2- ethyls) hexylamino formoxyl, N, N- diheptyls carbamoyl, N, N- octyl methyl ammonia Base formoxyl, N, N- dioctylaminos formoxyl, N, N- dinonyl carbamoyl, N, N- decyls methylcarbamoyl, N, N- undecyls methylcarbamoyl, N, N- dodecyl methyls carbamoyl, N, N- eicosyl methylcarbamoyls The quilt such as base, N, the group that N- phenylmethyl aminos formoxyl, N, N- diphenylcarbamoyls etc. and above-mentioned chemical formula represent 2 carbon numbers be 1~40 (preferably carbon number is 1~20) alkyl or its deriveding group (such as by carboxyl, sulfo group, Nitro, hydroxyl, halogen (preferably chlorine atom), alkylsulfamoyl group (preferably octyl group sulfamoyl) that carbon number is 1~10 etc. The group performed the derivatization) substitution carbamoyl etc.,

It is preferred that the carbamoyl substituted by 1 or 2 carbon numbers for 1~10 alkyl or its deriveding group can be enumerated Deng.

As-N (R¹⁰²)₂, can enumerate：

Amino；N- methylaminos, N- ethylaminos, N- propylcarbamics, N- isopropylaminos, N- butylaminos, N- isobutyls Base amino, N- s-butylaminos, N- tert-butylaminos, N- pentyl aminos, N- hexylaminos, N- (2- ethyls) hexylamino, N- Heptyl amino, N- octyl aminos, N- nonylaminos, N- Decylaminos, N- undecyls amino, N- dodecylaminos, N- bis- Group that ten alkyl aminos, N- phenyl aminos etc. and above-mentioned chemical formula represent etc. is 1~40 (preferably carbon by 1 carbon number Atomicity is 1~20) alkyl or its deriveding group (such as pass through carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine be former Son), the group that performs the derivatization of the alkylsulfamoyl group (preferably octyl group sulfamoyl) etc. that carbon number is 1~10) take The amino in generation etc.；

N, N- dimethylamino, N, N- ethylmethylaminos, N, N- diethylaminos, N, N- propyl-methylaminos, N, N- Dipropylamino, N, N- isopropylmethylaminos, N, N- diisopropylaminoethyls, N, N- tertbutyl methyls amino, the isobutyl of N, N- bis- Base amino, N, N- di-sec-butyls amino, N, N- di-t-butyls amino, N, N- butyl methyls amino, N, N- dibutylaminos, N, N- Dipentylamino, N, N- bis- (1- ethyl propyls) amino, N, N- dihexyls amino, N, N- bis- (2- ethyls) hexylamino, N, N- Diheptyl amino, N, N- dioctylaminos, N, N- dinonyl amino, N, N- decyls methylamino, N, N- undecyl methyl ammonia Base, N, N- dodecyl methyls amino, N, N- eicosyls methylamino, N, N- phenylmethyl aminos, N, N- diphenyl aminos Deng and the group etc. that represents of above-mentioned chemical formula by alkyl that 2 carbon numbers are 1~40 (preferably carbon number is 1~20) Or its deriveding group (such as pass through carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), the alkane that carbon number is 1~10 The group that base sulfamoyl (preferably octyl group sulfamoyl) etc. performs the derivatization) substitution amino etc.,

It is preferred that it is amino that 1~10 alkyl or its deriveding group substitute etc. that can enumerate by 1 or 2 carbon numbers.

It is used as-NHCO-R¹⁰², Formylamino can be enumerated；Acetyl-amino, propanoylamino, bytyry amino, 2,2- Dimethylpropionylamino, pentanoylamino, caproyl amino, (2- ethyls) caproyl amino, heptanoyl group amino, caprylyl ammonia Base, pelargonyl group amino, decanoylamino, hendecane acyl amino, dodecane acyl amino, heneicosane acyl amino, benzene first Group that acyl amino etc. and above-mentioned chemical formula represent etc. be bonded with carbon number be 1~40 (preferably carbon number be 1~ Alkyl 20) or its deriveding group (such as be by carboxyl, sulfo group, nitro, hydroxyl, halogen (preferably chlorine atom), carbon number The group that 1~10 alkylsulfamoyl group (preferably octyl group sulfamoyl) etc. performs the derivatization) carbonylamino (make the carbonyl In the case that base amino is acyl amino, carbon number is 1~40) etc.,

(make the carbonyl it is preferred that can enumerate and be bonded with carbon number for 1~10 alkyl or the carbonylamino of its deriveding group In the case that amino is alkanoylamino, carbon number is more preferably 1~10) etc..

As-NHCON (R¹⁰²)₂, group cited hereinabove etc. can be enumerated.

It is used as-NHCOOR¹⁰², group cited hereinabove etc. can be enumerated.

As-OCON (R¹⁰²)₂, group cited hereinabove etc. can be enumerated.

As halogen atom, preferably fluorine atom, chlorine atom, bromine atoms and iodine atom etc..

It is used as-SO₃M and-CO₂M M, hydrogen atom can be enumerated；The alkali metal atoms such as lithium atom, sodium atom and potassium atom, it is excellent Choosing can enumerate hydrogen atom, sodium atom, potassium atom.

Above-mentioned-CO-R¹⁰²、-COO-R¹⁰²、-OCO-R¹⁰²、-COCO-R¹⁰²、-O-R¹⁰²、-SO₂-R¹⁰²、-SO₂N(R¹⁰²)₂、- CON(R¹⁰²)₂、-N(R¹⁰²)₂、-NHCO-R¹⁰²、-NHCON(R¹⁰²)₂、-NHCOOR¹⁰²、-OCON(R¹⁰²)₂In the substituent that includes (the first substituent) can be 1 or more than 2, and the substituent of more than 2 is separate, can be the same or different.

In addition, for foregoing first substituent, it is bonding on the alkyl included in one part to there are other to take Dai Ji (the second substituent).Second substituent can select from the group same with the first substituent.

The compound that formula (I) represents can also have part-structure as shown below in addition to it can have above-mentioned group.

R^N1And R^N2Preferably aliphatic alkyl, aralkyl, (cycloalkyl) alkyl, the aliphatic alkyl through hydroxyl substitution, warp The aliphatic alkyl of the epoxide substitution for the alkyl that carbon number is 1~20, more preferably straight-chain or side chain are bonded with one side Shape alkyl, straight-chain or branched alkenyl, cycloalkyl, aralkyl, (cycloalkyl) alkyl, the straight-chain or branch substituted through hydroxyl Chain-like alkyl, straight-chain or branched-chain alkyl through alkoxy substitution.

R^N1And R^N2It can be the same or different.

R^N3Preferably aliphatic alkyl, more preferably straight-chain or branched-chain alkyl, more preferably straight-chain alkyl.

R⁴Preferably hydrogen atom, R¹~R⁸More preferably hydrogen atom.

A in the compound that formula (I) represents^g-Represent the anion of g valencys.G represents 1~14 integer, preferably represents 1~10 Integer, more preferably represent 1~8 integer, further preferably represent 1~6 integer, particularly preferably represent 1~4 integer.

As A^g-, known anion can be enumerated.As A^g-, specifically, can enumerate：

The halide ions such as fluoride ion, chloride ion, bromide ion, iodide ion；

OH^-；CN^-；NO₃ ^-；NO₂ ^-；ClO^-；ClO₂ ^-；ClO₃ ^-；ClO₄ ^-；MnO₄ ^-；CH₃CO₂ ^-、C₆H₅CO₂ ^-；Tosylate is cloudy Ion；HCO₃ ^-；H₂PO₄ ^-；HSO₄ ^-；HS^-；SCN^-；H(COO)₂ ^-；

[Al(OH)₄]^-、[Al(OH)₄(H₂O)₂]^-；[Ag(CN)₂]^-；[Cr(OH)₄]^-；[AuCl₄]^-；O^2-；S^2-；O₂ ^2-； SO₄ ^2-、HSO₄ ^-；SO₃ ^2-；S₂O₃ ^2-；CO₃ ^2-；CrO₄ ^2-；Cr₂O₇ ^2-；(COO)₂ ^2-；HPO₄ ^2-；[Zn(OH)₄]^2-；[Zn(CN)₄]^2-； [CuCl₄]^2-；PO₄ ^3-；[Fe(CN)₆]^3-；[Ag(S₂O₃)₂]^3-；[Fe(CN)₆]^4-；CH₃O^-、CH₃CH₂O^-、(CH₃)₃CO^-It is former Deng carbon Alkoxide ion, the C that subnumber is 1~20₆H₅O^-Deng the aryloxy ion that carbon number is 6~20；

Fluo anion；Contain at least one kind of element and oxygen in the group being made up of tungsten, molybdenum, silicon and phosphorus as required Anion of element etc..

From the aspect of improving heat resistance, reducing sublimability, A^g-Preferably fluo anion or containing selected from by tungsten, molybdenum, Anion as indispensable element of at least one kind of element and oxygen in the group of silicon and phosphorus composition, more preferably contain be selected from by tungsten with The anion or fluo anion of at least one kind of element and oxygen as indispensable element in the group of phosphorus composition, more preferably contains By the anion of at least one kind of element and oxygen as indispensable element in the group being made up of tungsten and phosphorus.

As fluo anion, such as CF can be enumerated₃CO₂ ^-And following formula (III)s, (IV), (V), the group of (VI) expression.

[in formula (III), W³And W⁴Fluorine atom or the fluoro-alkyl that carbon number is 1~4 are represented independently of each other, or, W³With W⁴It is integrally formed and represents the fluorinated alkanes diyl (alkanediyl) that carbon number is 1~4.]

[in formula (IV), W⁵~W⁷Fluorine atom or the fluoro-alkyl that carbon number is 1~4 are represented independently of each other.]

[in formula (V), Y¹Represent the fluorinated alkanes diyl that carbon number is 1~4.]

[in formula (VI), Y²Represent the fluoro-alkyl that carbon number is 1~4.]

In formula (III), (IV) and (VI), as the fluoro-alkyl that carbon number is 1~4, preferably perfluoroalkyl.As The perfluoroalkyl ,-CF can be enumerated₃、-CF₂CF₃、-CF₂CF₂CF₃、-CF(CF₃)₂、-CF₂CF₂CF₂CF₃、-CF₂CF(CF₃)₂、-C (CF₃)₃Deng.

In formula (III) and (V), as the fluorinated alkanes diyl that carbon number is 1~4, preferably perfluoroalkane diyl, it can lift Go out-CF₂-、-CF₂CF₂-、-CF₂CF₂CF₂-、-C(CF₃)₂-、-CF₂CF₂CF₂CF₂- etc..

The anion (hereinafter sometimes referred to " anion (III) ") represented as formula (III), can enumerate formula (III- respectively 1) anion (following, sometimes referred to as " anion (III-1) "~" anion (III-6) ") that~formula (III-6) represents.

The anion (hereinafter sometimes referred to " anion (IV) ") represented as formula (IV), formula (IV-1) expression can be enumerated Anion (IV-1).

The anion (hereinafter sometimes referred to " anion (V) ") represented as formula (V), can enumerate formula (V-1)~formula respectively (V-4) anion (hereinafter sometimes referred to " anion (V-1) "~" anion (V-4) ") represented.

As formula (VI) represent anion (hereinafter sometimes referred to " anion (VI) "), can enumerate respectively formula (VI-1)~ The anion (hereinafter sometimes referred to " anion (VI-1) "~" anion (VI-4) ") that formula (VI-4) represents.

Fluo anion can be selected from by CF₃CO₂ ^-, anion (III), anion (IV), anion (V) and anion (VI) at least one kind of anion in the group of composition.Wherein, preferably CF₃CO₂ ^-, it is anion (III-1), anion (III-2), cloudy Ion (III-6), anion (IV-1), anion (V-1), anion (VI-1), anion (VI-2), anion (VI-3), More preferably CF₃CO₂ ^-, anion (III-2), anion (IV-1), anion (VI-1).

As anion, it can enumerate and make containing at least one kind of element and oxygen in the group being made up of tungsten, molybdenum, silicon and phosphorus For the anion of indispensable element.Tungsten is preferably comprised as the heteropoly acid of indispensable element or the anion of isopolyacid, more preferably phosphorus tungsten The anion of acid, silico-tungstic acid and tungsten system isopolyacid.For the anion, if such as having fluo anion (excellent Select anion (VI-1)) by formula (I) represent coloring compound and carry out anion exchange, then be favorably improved heat resistance.

As such tungsten that contains as the heteropoly acid of indispensable element or the anion of isopolyacid, such as Keggin can be enumerated Type phosphotungstic acid ion α-[PW₁₂O₄₀]^3-, Dawson type phosphotungstic acid ions α-[P₂W₁₈O₆₂]^6-、β-[P₂W₁₈O₆₂]^6-, Keggin-type silicon Wolframic acid ion α-[SiW₁₂O₄₀]^4-、β-[SiW₁₂O₄₀]^4-、γ-[SiW₁₂O₄₀]^4-, in addition, as other examples, can enumerate [P₂W₁₇O₆₁]^10-、[P₂W₁₅O₅₆]^12-、[H₂P₂W₁₂O₄₈]^12-、[NaP₅W₃₀O₁₁₀]^14-、α-[SiW₉O₃₄]^10-、γ-[SiW₁₀O₃₆]^8-、 α-[SiW₁₁O₃₉]^8-、β-[SiW₁₁O₃₉]^8-、[W₆O₁₉]^2-、[W₁₀O₃₂]^4-、WO₄ ^2-Deng.Wherein, more preferably Keggin-type phosphotungstic acid from Sub- α-[PW₁₂O₄₀]^3-。

Compound (I) is preferably compound (following, the sometimes referred to as compound (I-B) that formula (I-B) represents.).Compound (I) when being compound (I-B), excellent heat resistance.

[in formula (I-B), R^N1、R^N2、R^N3、R¹~R⁸、R¹⁰¹、R¹⁰²And M represents implication same as described above.

H represents 1~14 integer.]

In formula (I-B), as B^h-, can enumerate and A is used as in formula (I)^g-And the moon for the g valencys with tungsten, molybdenum etc. enumerated Ion identical anion.

As the preferable B in formula (I-B)^h-, can enumerate and as the A in formula (I)^g-And enumerate contain be selected from by tungsten, At least one kind of element and oxygen in the group of molybdenum, silicon and phosphorus composition is as the preference identical in the anion of the g valencys of indispensable element Example.

As compound (I), the compound or its alkali metal salt shown in table 1~10 can be enumerated.

It should be noted that in table 1~10, " Me " represents methyl, and " Et " represents ethyl, and " Bu " represents butyl, " TBu " table Show the tert-butyl group, " Hex " represents hexyl, and " Oct " represents octyl group, and " 2EH " represents 2- ethylhexyls, and " CHM " represents cyclohexyl methyl, " CH " represents cyclohexyl, and " PH " represents phenyl, and " BZ " represents benzyl, and " NPR " represents propyl group, and " IPR " represents isopropyl, " IBu " Represent isobutyl group, " EOE " expression-CH₂CH₂OCH₂CH₃, " ALL " represents pi-allyl, and " HYE " represents 2- hydroxyethyls,

" COM " expression-CO-CH₃, " COE " expression-COO-CH₂CH₃, " OCM " expression-OCO-CH₃, " OME " expression-O- CH₃,

" SOT " represents tosyl, " SNH " expression-SO₂NH-CH₂CH(CH₂CH₃)((CH₂)₃CH₃), " SN2 " expression- SO₂N(CH₃)((CH₂)₇CH₃), " CNM " expression-CONHCH₃, " CN2 " expression-CON (CH₃)C₆H₅, " NPH " expression-NHC₆H₅, " NOT " expression-N ((CH₂)₇CH₃)₂, " NCO " expression-NHCO ((CH₂)₄CH₃), " F " represents fluorine atom, and " Cl " represents chlorine atom, " Br " represents bromine atoms, and " CN " represents cyano group,

" NO2 " represents nitro, " SUA " expression-SO₃H, " CBA " expression-CO₂H,

" CHO " expression-CHO,

" OCH " expression-OCOH, " OH " expression-OH, " SFM " expression-SO₂NH₂, " CBM " expression-CONH₂,

" NH2 " expression-NH₂, " NCH " expression-NHCOH, " III-1 "~" III-6 " represent anion (III-1)~cloudy from Sub (III-6),

" IV-1 " represents anion (IV-1), and " V-1 "~" V-4 " represents anion (V-1)~anion (V-4), " VI- 1 "~" VI-4 " represents anion (VI-1)~anion (VI-4).

[table 1]

[table 2]

[table 3]

[table 4]

[table 5]

[table 6]

[table 7]

[table 8]

[table 9]

[table 10]

Compound (I-1) is, for example, the compound that formula (I-1) represents.

From the viewpoint of being readily synthesized, preferably compound (I-1)~compound (I-312), more preferably compound (I-1)~compound (I-156), more preferably compound (I-1)~compound (I-24), especially preferably compound (I-13)~compound (I-24).

Wherein, compound of the invention (I) is particularly preferably compound (I-14).

The compound (I) of the present invention can be by making compound that formula (II) represents (following, sometimes referred to as compound (II).) Compound (following, the sometimes referred to as compound (II-1) represented with formula (II-1).) react and obtain, in addition, also can be by making Resulting compound is further with containing at least one kind of element and oxygen in the group being made up of tungsten, silicon and phosphorus as required The compound of element is reacted and obtained.

[in formula (II) and formula (II-1), R¹~R⁸、R^N1、R^N2、R^N3And g represents implication same as described above, A ' represents upward State A^g-The group of g electronics is provided.]

The compound represented as formula (II-1), can enumerate alkylating agent.As alkylating agent, can enumerate：It is preferred that carbon is former Haloalkyl (chloromethyl, bromomethyl or the iodos such as subnumber is 1~10, the haloalkyl that more preferably carbon number is 1~3 Methyl etc.)；It is preferred that carbon number is 2~10, the carbon that more preferably carbon number is 2~6, further preferred carbon number is 2~4 Acid dialkyl ester (dimethyl carbonate or diethyl carbonate etc.)；It is preferred that carbon number be 1~10, more preferably carbon number be 1~ 6th, further preferred carbon number is 1~4 etc. dialkyl sulfate (dimethyl suflfate or dithyl sulfate etc.)；It is preferred that carbon is former Subnumber is 2~10, the paraffin sulfonates Arrcostab that more preferably carbon number is 2~6, further preferred carbon number is 2~4 (methyl mesylate, ethyl sulfonic acid ethyl ester, ethyl methane sulfonate, ethylsulfonate, Methyl triflate, trifluoromethanesulfonic acid ethyl ester Deng).

Abovementioned alkyl agent is preferably methylating agent, ethylating agent, propyl group agent, butyl agent etc., more preferably methyl Agent.

Relative to 1 mole compound (II), the usage amount of alkylating agent is preferably less than more than 1 mole 20 moles, more excellent Elect less than more than 1 mole 10 moles as.

Reaction temperature is preferably 0~150 DEG C, more preferably 10~100 DEG C.In order that the coloring compound that formula (I) represents The dissolubility of precursor is abundant, can be mixed in advance with defined organic solvent in 70~100 DEG C or so of temperature.Reaction time is excellent Elect as 10 minutes~24 hours, more preferably 1 hour~12 hours.

From the aspect of yield, preferably reacted in organic solvent.As organic solvent, toluene, diformazan can be enumerated The aromatic hydrocarbon solvents such as benzene；The aliphatic hydrocarbon solvents such as hexane；The halogenated hydrocarbon solvents such as chlorobenzene, dichloro-benzenes, dichloromethane, chloroform；First The alcoholic solvents such as alcohol, ethanol, isopropanol, butanol；The nitro hydrocarbon solvent such as nitrobenzene；The ketone solvents such as acetone, methyl iso-butyl ketone (MIBK)；Acetic acid The ester solvents such as ethyl ester；The ether solvents such as ether, tetrahydrofuran；The nitrile solvent such as acetonitrile；N,N-dimethylformamide, N, N- dimethyl second The amide solvents such as acid amides, 1-Methyl-2-Pyrrolidone；Etc., optimization aromatic hydrocarbon solvent, more preferably toluene and dimethylbenzene.Phase For 1 mass parts compound (II), the usage amount of organic solvent is preferably more than 1 mass parts below 300 mass parts, more preferably More than 1 mass parts below 100 mass parts.

The method that compound is obtained from reactant mixture is not particularly limited, and can use known various methods.It can lift Go out and for example reactant mixture is filtered, washed with the aromatic hydrocarbon solvents equal solvent such as toluene, it is residual by what is obtained The method that excess is dried.As needed, further can be entered using the method or silica gel column chromatography that are recrystallized using solvent Row purifying.The compound that obtained compound for example represents as formula (I).

Next, the method that the anion for the compound for representing formula (I) carries out ion exchange can be used, as the party Method, addition can be enumerated and contain the chemical combination of at least one kind of element and oxygen as indispensable element in the group being made up of tungsten, silicon and phosphorus Method of thing etc. etc..

Contain compound (this of at least one kind of element and oxygen in the group being made up of tungsten, silicon and phosphorus as indispensable element In specification, hereinafter also referred to anionite) manufactured using known conventional process, commercially available product also can be used directly. As such compound, can enumerate such as corresponding heteropolyacid salt, isopolyacid salt or silicate, phosphate or Phosphotungstic acid, silico-tungstic acid, phosphomolybdic acid and silicomolybdic acid etc..

1 mole of the compound represented relative to formula (I), the usage amount of anionite is preferably more than 0.01 mole 5 Below mole, more preferably less than more than 0.01 mole 1 mole.

As reaction temperature, preferably 0~150 DEG C, more preferably 10~100 DEG C.As reaction time, preferably 10 points Clock~36 hour, more preferably 10 minutes~24 hours.

From the aspect of yield, preferably the reaction is carried out in water, organic solvent or their mixture.As organic molten Agent, the aromatic hydrocarbon solvents such as toluene, dimethylbenzene can be enumerated；The aliphatic hydrocarbon solvents such as hexane；Chlorobenzene, dichloro-benzenes, dichloromethane, chlorine It is imitative to wait halogenated hydrocarbon solvent；The alcoholic solvents such as methanol, ethanol, isopropanol, butanol；The nitro hydrocarbon solvent such as nitrobenzene；Acetone, methyl tert-butyl The ketone solvents such as base ketone；The ester solvents such as ethyl acetate；The ether solvents such as ether, tetrahydrofuran；The nitrile solvent such as acetonitrile；N, N- dimethyl methyl The amide solvents such as acid amides, DMAC N,N' dimethyl acetamide, 1-Methyl-2-Pyrrolidone；Etc..As carrying out the molten of above-mentioned reaction Agent, water, alcoholic solvent, ketone solvent, ether solvents, nitrile solvent, amide solvent or their mixture can be enumerated, can more preferably be enumerated Water, alcoholic solvent, ketone solvent, nitrile solvent, amide solvent or their mixture, can further preferably enumerate water, alcoholic solvent or it Mixture, can particularly preferably enumerate water, methanol or their mixture.

The mass parts of compound 1 represented relative to formula (I), the usage amount of organic solvent is preferably more than 1 mass parts 1000 Below mass parts, more preferably more than 10 mass parts below 500 mass parts.

According to the above method, then the anion for the compound that can be represented formula (I) carries out ion exchange, so as to be formed The suitable compound for improving heat resistance, reduce sublimability.

Compound (II) can be by making compound that formula (VII) represents (following, sometimes referred to as compound in the presence of base (VII).) compound (following, the sometimes referred to as compound (VIII) that is represented with formula (VIII).) react and manufacture.

[in formula (VII) and formula (VIII), R¹~R³、R⁵~R⁸、R^N1And R^N2Represent implication same as described above, R⁹Represent carbon Atomicity is 1~20 alkyl.]

As R⁹The carbon number of expression is 1~20 alkyl, can enumerate methyl, ethyl, propyl group, isopropyl, butyl, different Butyl, sec-butyl, tert-butyl group etc., it can preferably enumerate the alkyl that carbon number is 1~6.

As alkali, the organic bases such as triethylamine, piperidines can be enumerated, its usage amount is commonly angled relative to 1 mole compound (VII) For be 0.05~20 mole.

Relative to 1 mole compound (II), the usage amount of compound (VIII) is usually 1~10 mole, preferably 1~4 Mole.

The reaction of compound (VII) and compound (VIII) is generally implemented in the presence of the solvent, as the solvent, can lift It is molten to go out the ethers such as alcoholic solvent, the tetrahydrofurans such as the nitrile such as acetonitrile solvent, methanol, ethanol, 2- propyl alcohol, n-butyl alcohol, 1- amylalcohols, 1- octanols The aromatic hydrocarbon solvents such as the aliphatic hydrocarbon solvents such as the ester solvents such as the ketone solvents such as agent, acetone, ethyl acetate, hexane, toluene, dichloromethane The amide solvent such as the halogenated hydrocarbon solvents such as alkane, chloroform and DMF, 1-METHYLPYRROLIDONE, it is molten can preferably to enumerate nitrile Agent, alcoholic solvent and aromatic hydrocarbon solvents, it can more preferably enumerate acetonitrile, methanol and toluene.Its usage amount is commonly angled relative to 1 mass parts It is 1~100 mass parts for compound (VII).

Reaction temperature is usually 0~200 DEG C, preferably 0~150 DEG C.Reaction time is usually 0.5~36 hour.

After reaction terminates, for example, by that will be difficult to mix the solvent that compound (II) dissolves with obtained reactant mixture Close, filtered, so as to extractable compound (II).As needed, the side recrystallized using solvent can further be utilized Method or silica gel column chromatography are purified.

Compound (VII) can be by making compound that formula (IX) represents (following, sometimes referred to as compound in a solvent (IX).) compound (following, the sometimes referred to as compound (X) that is represented with formula (X).) react and manufacture.

[in formula (IX) and formula (X), R⁵~R⁹Represent implication same as described above, R¹⁰Represent the alkane that carbon number is 1~4 Base.]

As R¹⁰The carbon number of expression is 1~4 alkyl, can enumerate methyl, ethyl, propyl group and butyl.

Relative to 1 mole compound (IX), the usage amount of compound (X) is usually 1~5 mole, preferably 1~3 mole.

As solvent, the alcoholic solvents such as methanol can be enumerated, its usage amount be commonly angled relative to for 1 mass parts compound (IX) be 1~200 mass parts.

Reaction temperature is usually -20~100 DEG C, and the reaction time is usually 1~72 hour.

After reaction terminates, for example, as needed, by the way that reactant mixture is mixed with water or methanol, then filtered, So as to extractable compound (VII).In addition, after reaction terminates, for example, as needed, by the way that reactant mixture is mixed with water, Then extracted with the organic solvent not soluble in water such as ethyl acetate, obtained organic layer is concentrated, so as to extractable chemical combination Thing (VII).As needed, further can be purified using the method or silica gel column chromatography that are recrystallized using solvent.

Compound (X) such as can according to the method described in J.Med.Chem.2012,55,3398-3413 known to side Method is manufactured.

The coloured composition of the present invention can include compound of more than two kinds (I).As needed, can by compound (I) with Dyestuff or pigment (colouring agent A1) beyond compound (I) function together as colouring agent (A).

The coloured composition of the present invention includes at least one of resin (B) and solvent (E) and aforesaid compound (1), excellent Choosing includes both resin (B) and solvent (E) and aforesaid compound (1).

＜ resins (B) ＞

Resin (B) is preferably alkali soluble resins, more preferably has and comes from selected from by unsaturated carboxylic acid and unsaturated carboxylic acid The polymer of the construction unit of at least one kind of monomer (a) (hereinafter sometimes referred to " (a) ") in the group of acid anhydride composition.

Resin (B) is preferably with from the ring-type ether structure and ethylenic unsaturated bond that carbon number is 2~4 The construction unit of monomer (b) (hereinafter sometimes referred to " (b) ") and the copolymer of other construction units.

As other structures unit, can enumerate：From monomer (c) (still, itself and the monomer (a) that can be copolymerized with monomer (a) And monomer (b) is different.Hereinafter sometimes referred to " (c) ") construction unit, there is the construction unit etc. of ethylenic unsaturated bond.

As (a), can enumerate for example：

Acrylic acid, methacrylic acid, crotonic acid and adjacent vinyl benzoic acid, a vinyl benzoic acid, to vinyl benzene first The unsaturated monocarboxylics such as acid；

Maleic acid, fumaric acid, citraconic acid, mesaconic acid, itaconic acid, 3- vinylphthalic acids, 4- vinyl neighbours benzene two Formic acid, 3,4,5,6- tetrahydrophthalic acids, 1,2,3,6- tetrahydrophthalic acids, dimethyl tetrahydro phthalic acid and 1,4- The unsaturated dicarboxylics such as cyclohexene dicarboxylic acid；

Methyl -5- ENB -2,3- dicarboxylic acids, bicyclic [2.2.1] hept-2-ene" of 5- carboxyls, 5,6- dicarboxyls are bicyclic Bicyclic [2.2.1] hept-2-ene" of [2.2.1] hept-2-ene", 5- carboxymethyls and bicyclic [2.2.1] hept-2-ene" of 5- carboxyethyls etc. contain carboxylic The bicyclic unsaturated compound of base；

The carboxylic acid anhydrides such as the acid anhydride of above-mentioned unsaturated dicarboxylic in addition to fumaric acid and mesaconic acid；

Mono succinate (2- (methyl) acryloyl group epoxide ethyl) ester and phthalic acid list (2- (methyl) acryloyl group oxygen Base ethyl) more than 2 yuan of the polybasic carboxylic acid such as ester single ((methyl) the acryloyl group epoxide alkyl) esters of unsaturation；

The such unsaturated esters of acrylic acid containing hydroxyl and carboxyl in same molecule of α-(hydroxymethyl) acrylic acid Deng.

In these, in terms of the copolyreaction, from the aspect of the dissolubility of obtained resin in alkaline aqueous solution, preferably Acrylic acid, methacrylic acid and maleic anhydride etc..

(b) the ring-type ether structure for referring to there is carbon number to be 2~4 is (for example, selected from by oxirane ring, oxa- ring Butane ring and tetrahydrofuran ring group into group in it is at least one kind of) and ethylenic unsaturated bond polymerizable compound.(b) preferably For the cyclic ether and the monomer of (methyl) acryloyl group epoxide for being 2~4 with carbon number.

As (b), the monomer (b1) that can be enumerated for example with oxiranyl and ethylenic unsaturated bond is (following to be sometimes referred to as For " (b1) "), the monomer (b2) (hereinafter sometimes referred to " (b2) ") with oxetanylmethoxy and ethylenic unsaturated bond and with Monomer of tetrahydrofuran base and ethylenic unsaturated bond (b3) (hereinafter sometimes referred to " (b3) ") etc..

As (b1), can enumerate for example：With the unsaturated aliphatic hydrocarbon progress epoxidation by straight-chain or branched Into structure monomer (b1-1) (hereinafter sometimes referred to " (b1-1) ") and with by ester ring type unsaturated hydrocarbons carry out epoxidation and Into structure monomer (b1-2) (hereinafter sometimes referred to " (b1-2) ").

As (b1-1), it is however preferred to have the monomer of glycidyl and ethylenic unsaturated bond.As (b1-1), specifically For, can enumerate (methyl) glycidyl acrylate, (methyl) propenoic acid beta-methylglycidyl esters, (methyl) propenoic acid beta- Ethyl glycidyl ester, glycidyl vinyl ether, vinylbenzyl glycidyl base ether, Alpha-Methyl vinyl benzyl shrink Double (glycidyl oxy methyl) styrene of glyceryl ether, 2,3-, 2,4- double (glycidyl oxy methyl) styrene, 2, Double (glycidyl oxy methyl) styrene of 5-, double (glycidyl oxy methyl) styrene of 2,6-, 2,3,4- tri- (shrink Glyceryl epoxide methyl) styrene, 2,3,5- tri- (glycidyl oxy methyl) styrene, (the glycidyls of 2,3,6- tri- Epoxide methyl) styrene, (glycidyl oxy methyl) styrene of 3,4,5- tri- and (the glycidyl epoxide first of 2,4,6- tri- Base) styrene etc..

As (b1-2), vinylcyclohexene list oxide (vinylcyclohexene monoxide), 1,2- can be enumerated Epoxy -4- vinyl cyclohexanes are (for example, CELLOXIDE (registration mark) 2000；(strain) Daicel systems), (methyl) acrylic acid 3, 4- epoxycyclohexanecarboxylates are (for example, CYCLOMER (registration mark) A400；(strain) Daicel systems), (methyl) acrylic acid 3,4- rings Oxygen cyclohexylmethyl is (for example, CYCLOMER (registration mark) M100；(strain) Daicel systems), formula (BI) represent compound and formula (BII) compound represented etc..

[in formula (BI) and formula (BII), R^aAnd R^bHydrogen atom or the alkyl that carbon number is 1~4 are represented independently of each other, The hydrogen atom included in the alkyl can be optionally substituted by a hydroxyl group.

X^aAnd X^bSingly-bound, *-R are represented independently of each other^c-、*-R^c-O-、*-R^c- S- or *-R^c-NH-。

R^cRepresent the alkane 2 basis that carbon number is 1~6.

* the chemical bond being connected with O is represented.]

The compound represented as formula (BI), the compound that any formula represents in formula (BI-1)~formula (BI-15) can be enumerated Deng can preferably enumerate formula (BI-1), formula (BI-3), formula (BI-5), formula (BI-7), formula (BI-9) and formula (BI-11)~formula (BI- 15) compound represented, the chemical combination that formula (BI-1), formula (BI-7), formula (BI-9) and formula (BI-15) represent can more preferably be enumerated Thing.

The compound represented as formula (BII), the change that any formula in formula (BII-1)~formula (BII-15) represents can be enumerated Compound etc., it can preferably enumerate formula (BII-1), formula (BII-3), formula (BII-5), formula (BII-7), formula (BII-9) and formula (BII- 11) compound that~formula (BII-15) represents, can more preferably enumerate formula (BII-1), formula (BII-7), formula (BII-9) and formula (BII-15) compound represented.

The compound that the compound and formula (BII) that formula (BI) represents represent can be used alone respectively, also can be by formula (BI) The compound that the compound and formula (BII) of expression represent is used in combination.By they and use in the case of, by mole on the basis of count, formula (BI) containing ratio for the compound that the compound and formula (BII) represented represents is preferably 5:95~95:5, more preferably 10:90 ~90:10, more preferably 20:80~80:20.

As (c), can enumerate for example：(methyl) methyl acrylate, (methyl) ethyl acrylate, the positive fourth of (methyl) acrylic acid Ester, (methyl) sec-butyl acrylate, (methyl) tert-butyl acrylate, (methyl) 2-EHA, (methyl) acrylic acid Dodecyl ester, (methyl) lauryl acrylate, (methyl) stearyl acrylate base ester, (methyl) acrylic acid ring pentyl ester, (first Base) three ring [5.2.1.0 of acrylic acid^2,6] decane -8- base esters, the ring [5.2.1.0 of (methyl) acrylic acid three^2,6] decane -9- base esters, Ring [the 5.2.1.0 of (methyl) acrylic acid three^2,6] decene -8- base esters, the ring [5.2.1.0 of (methyl) acrylic acid three^2,6] decene -9- bases Ester, (methyl) acrylic acid Bicvclopentyl epoxide ethyl ester (dicyclopentanyl oxyethyl (meth) acrylate), (first Base) isobornyl acrylate, (methyl) acrylic acid adamantane esters, (methyl) allyl acrylate, (methyl) acrylic acid alkynes (methyl) acrylate such as propyl ester, (methyl) phenyl acrylate, (methyl) acrylic acid naphthalene ester and (methyl) benzyl acrylate；

(methyl) propylene containing hydroxyl such as (methyl) acrylic acid 2- hydroxy methacrylates and (methyl) acrylic acid 2- hydroxy propyl esters Acid esters；

The dicarboxylic diesters such as diethyl maleate, diethyl fumarate and diethyl itaconate；

Bicyclic [2.2.1] hept-2-ene", 5- methyl bicycles [2.2.1] hept-2-ene", bicyclic [2.2.1] hept-2-ene" of 5- ethyls, Bicyclic [2.2.1] hept-2-ene" of 5- hydroxyls, bicyclic [2.2.1] hept-2-ene" of 5- hydroxymethyls, 5- (2 '-hydroxyethyl) are bicyclic Bicyclic [2.2.1] hept-2-ene" of [2.2.1] hept-2-ene", 5- methoxyl groups, bicyclic [2.2.1] hept-2-ene" of 5- ethyoxyls, 5,6- dihydroxies Bicyclic [2.2.1] hept-2-ene" of base, bicyclic [2.2.1] hept-2-ene"s of 5,6- bis- (hydroxymethyl), 5,6- bis- (2 '-hydroxyethyl) are double Bicyclic [2.2.1] hept-2-ene" of ring [2.2.1] hept-2-ene", 5,6- dimethoxys, bicyclic [2.2.1] the hept- 2- of 5,6- diethoxies Bicyclic [2.2.1] hept-2-ene" of alkene, 5- hydroxy-5-methyl bases, bicyclic [2.2.1] hept-2-ene" of 5- hydroxyl -5- ethyls, 5- hydroxyl first Bicyclic [2.2.1] hept-2-ene" of base -5- methyl bicycles [2.2.1] hept-2-ene", 5- tert-butoxycarbonyls, 5- cyclohexyl Epoxide carbonyls Bicyclic [2.2.1] hept-2-ene" of bicyclic [2.2.1] hept-2-ene", 5- phenyloxycarbonyls, 5,6- double (tert-butoxycarbonyls) are bicyclic The bicyclic unsaturated compound such as [2.2.1] hept-2-ene" and double (cyclohexyl Epoxide carbonyl) bicyclic [2.2.1] hept-2-ene"s of 5,6-；

N-phenylmaleimide, N- N-cyclohexylmaleimides, N- benzyl maleimides, 3- dimaleoyl imino benzene Formic acid N- succinimide esters, 4- maleimidobutyric acid N- succinimide esters, 6- maleimidocaproic acid N- ambers The dicarbapentaborane acyls such as imide ester, 3- maleimidoproprionic acid N- succinimide esters and N- (9- acridinyls) maleimide are sub- Amine derivative；

Styrene, α-methylstyrene, vinyltoluene and to the aromatic series containing vinyl such as methoxy styrene Compound；The nitriles containing vinyl such as (methyl) acrylonitrile；The halogenated hydrocarbons such as vinyl chloride and vinylidene chloride；(methyl) acrylamide etc. Acid amides containing vinyl；The esters such as vinyl acetate；1,3- butadiene, isoprene and 2,3- dimethyl -1,3- butadiene etc. Diene；Etc..

In these, from the aspect of copolyreaction and heat resistance, optimization styrene, vinyltoluene, (methyl) propylene Three ring [5.2.1.0 of acid^2,6] decane -8- base esters, the ring [5.2.1.0 of (methyl) acrylic acid three^2,6] decane -9- base esters, (methyl) third Ring [the 5.2.1.0 of olefin(e) acid three^2,6] decene -8- base esters, the ring [5.2.1.0 of (methyl) acrylic acid three^2,6] decene -9- base esters, N- phenyl Maleimide, N- N-cyclohexylmaleimides, N- benzyl maleimides, bicyclic [2.2.1] hept-2-ene" and (methyl) propylene Acid benzyl ester etc..

Construction unit with ethylenic unsaturated bond is preferably the construction unit with (methyl) acryloyl group.With this The resin of the construction unit of sample can by for the polymer with the construction unit from (a) and/or (b), make can be with (a) And/or the monomer with ethylenic unsaturated bond carries out addition and obtained in the group of radical reaction possessed by (b).

As such construction unit, can enumerate makes the addition of (methyl) glycidyl acrylate in (methyl) acrylic acid list Construction unit that member forms, make construction unit and make that the 2- hydroxy methacrylates addition of (methyl) acrylic acid forms in maleic anhydride units Construction unit that the addition of (methyl) acrylic acid forms in (methyl) glycidyl acrylate unit etc..In addition, these structure lists Member is when having hydroxyl, can also enumerate construction unit that further addition carboxylic acid anhydrides forms as the knot with ethylenic unsaturated bond Structure unit.

Polymer with the construction unit from (a) for example can by the presence of polymerization initiator, gather composition The monomer of the construction unit of compound is polymerize and manufactured in a solvent.Polymerization initiator and solvent etc. are not particularly limited, can Use polymerization initiator and solvent usually used in the field.For example, as polymerization initiator, azo-compound can be enumerated (2,2 '-azobis isobutyronitrile, 2,2 '-azo double (2,4- methyl pentane nitriles) etc.), organic peroxide (benzoyl peroxide Deng), as solvent, as long as the solvent that each monomer is dissolved.

It should be noted that for obtained polymer, reacted solution can be used directly, it is possible to use warp Solution obtained by concentration or dilution, the material that also the methods of utilizing reprecipitation can be used to be obtained in the form of solid (powder).

As needed, carboxylic acid or the catalysts of carboxylic acid anhydrides and cyclic ether (such as three (dimethylamino first can be used Base) phenol etc.) and polymerization inhibitor (such as quinhydrones etc.) etc..

As carboxylic acid anhydrides, maleic anhydride, citraconic anhydride, itaconic anhydride, 3- vinylphthalic acids acid anhydride, 4- second can be enumerated Alkenyl phthalic anhydride, 3,4,5,6- tetrabydrophthalic anhydrides, 1,2,3,6- tetrabydrophthalic anhydrides, dimethyl tetrahydro Phthalic anhydride and bicyclic [2.2.1] the hept-2-ene" acid anhydride of 5,6- dicarboxyls etc..

As resin (B), specifically, (methyl) acrylic acid 3,4- epoxycyclohexanecarboxylates/(methyl) propylene can be enumerated Acid copolymer, the ring [5.2.1.0 of (methyl) acrylic acid 3,4- epoxies three^2,6] decyl ester/(methyl) acrylic copolymer, (methyl) Glycidyl acrylate/(methyl) benzyl acrylate/(methyl) acrylic copolymer, (methyl) glycidyl acrylate/ Styrene/(methyl) acrylic copolymer, the ring [5.2.1.0 of (methyl) acrylic acid 3,4- epoxies three^2,6] decyl ester/(methyl) third Olefin(e) acid/N- N-cyclohexylmaleimides copolymer, the ring [5.2.1.0 of (methyl) acrylic acid 3,4- epoxies three^2,6] decyl ester/(first Base) acrylic acid/N- N-cyclohexylmaleimides/(methyl) acrylic acid 2- hydroxy methacrylates copolymer, (methyl) acrylic acid 3,4- rings Ring [the 5.2.1.0 of oxygen three^2,6] decyl ester/(methyl) acrylic acid/vinyl toluene copolymer, (methyl) acrylic acid 3,4- epoxies three Ring [5.2.1.0^2,6] decyl ester/(methyl) acrylic acid/(methyl) 2-EHA copolymer, (methyl) acrylic acid 3, Ring [the 5.2.1.0 of 4- epoxies three^2,6] decyl ester/ring [5.2.1.0 of (methyl) acrylic acid three^2,6] decene base ester/(methyl) acrylic acid/ N- N-cyclohexylmaleimides copolymer, 3- methyl -3- (methyl) acryloyl group epoxide methy oxetane/(methyl) propylene Acid/styrol copolymer, (methyl) benzyl acrylate/(methyl) acrylic copolymer, styrene/(methyl) acrylic copolymer And Japanese Unexamined Patent Publication 9-106071 publications, Japanese Unexamined Patent Publication 2004-29518 publications and Japanese Unexamined Patent Publication 2004-361455 Resin described in each publication of publication etc..

Wherein, as resin (B), the copolymerization of the construction unit from (a) and the construction unit from (b) is preferably included Thing.

For resin (B), two or more can be combined, in this case, it is preferred that resin (B) is comprised at least and is selected from One or more of following substances：Ring [the 5.2.1.0 of (methyl) acrylic acid 3,4- epoxies three^2,6] decyl ester/(methyl) acrylic acid is common Polymers, (methyl) acrylic acid 3, the ring [5.2.1.0 of 4- epoxies three^2,6] decyl ester/(methyl) acrylic acid/N- cyclohexyl maleimides Amine/(methyl) acrylic acid 2- hydroxy methacrylate copolymers, (methyl) acrylic acid 3, the ring [5.2.1.0 of 4- epoxies three^2,6] decyl ester/(first Base) acrylic acid/vinyl toluene copolymer, and (methyl) acrylic acid 3, the ring [5.2.1.0 of 4- epoxies three^2,6] decyl ester/(first Base) acrylic acid/(methyl) 2-EHA copolymer.

The weight average molecular weight (Mw) according to polystyrene conversion of resin (B) is preferably 3,000~100,000, more preferably For 5,000~50,000, more preferably 5,000~30,000.[weight average molecular weight (Mw)/number is equal for the decentralization of resin (B) Molecular weight (Mn)] it is preferably 1.1~6, more preferably 1.2~4.

The acid number (value to be converted with solid state component) of resin (B) is preferably 10~300mg-KOH/g, more preferably 20~ 250mg-KOH/g, more preferably 30~200mg-KOH/g.Herein, acid number is as required for neutralization 1g resins (B) The amount (mg) of potassium hydroxide and the value determined, such as can be titrated and be obtained by using potassium hydroxide aqueous solution.

In coloured composition, the containing ratio of resin (B) is preferably 3~99 matter for the total amount of solid state component Measure %, more preferably more preferably 5~99 mass %, 7~95 mass %.

＜ solvents (E) ＞

On solvent (E), for example, it is molten to enumerate ester solvent (include-COO- in intramolecular and be free of-O- solvent), ether Agent (including-O- and solvent without-COO- in intramolecular), ether-ether solvent (including-COO- and-O- solvent in intramolecular), Ketone solvent (intramolecular include-CO- and without-COO- solvent), alcoholic solvent (intramolecular include OH and without-O- ,- CO- and-COO- solvent), aromatic hydrocarbon solvents, amide solvent and dimethyl sulfoxide (DMSO) etc..

As ester solvent, methyl lactate, ethyl lactate, butyl lactate, 2- hydroxy-methyl isobutyl acids, acetic acid second can be enumerated Ester, n-butyl acetate, isobutyl acetate, amyl formate, isoamyl acetate, butyl propionate, isopropyl isobutyrate, ethyl butyrate, fourth Acid butyl ester, methyl pyruvate, ethyl pyruvate, Propyl pyruvate, methyl acetoacetate, ethyl acetoacetate, ethyl cyclohexyl alcohol Ester and gamma-butyrolacton etc..

As ether solvents, ethylene glycol single methyl ether, ethylene glycol monomethyl ether, ethylene glycol monopropyl ether, ethylene glycol can be enumerated Single-butyl ether, diethylene glycol monomethyl ether, TC, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, third Glycol list ethylether, propylene glycol monopropyl ether, glycol monobutyl ether, 3- methoxyl groups-n-butyl alcohol, 3- methoxyl group -3- methyl fourths Alcohol, tetrahydrofuran, oxinane, 1,4- dioxanes, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethyl Glycol methyl ethyl ether, diethylene glycol dipropyl ether, diethylene glycol dibutyl ether, methyl phenyl ethers anisole, phenetole and methylanisole etc..

As ether-ether solvent, methoxy menthyl acetate, ethyl methoxyacetate, methoxyacetic acid butyl ester, ethoxy can be enumerated Acetic acid methyl ester, ethoxy ethyl acetate, 3- methoxy methyl propionates, 3- methoxypropionates, 3- ethoxypropanoates, 3- ethoxyl ethyl propionates, 2- methoxy methyl propionates, 2- methoxypropionates, 2- methoxy propyls propyl propionate, 2- ethyoxyls Methyl propionate, 2- ethoxyl ethyl propionates, 2- methoxyl groups -2 Methylpropionic acid methyl esters, 2- ethyoxyls -2 Methylpropionic acid ethyl ester, second Sour 3- methoxybutyls, acetic acid 3- methyl -3- methoxybutyls, propylene glycol monomethyl ether, propylene glycol monoethyl second Acid esters, propylene glycol monopropyl ether acetic acid esters, ethylene glycol single methyl ether acetic acid esters, ethylene glycol monomethyl ether acetate, diethylene glycol Single monoethyl ether acetate, diethylene glycol monobutyl ether acetic acid esters and dipropylene glycol methyl ether acetic acid esters etc..

As ketone solvent, 4- hydroxy-4-methyl-2-pentanones, acetone, 2- butanone, 2-HEPTANONE, 3- heptanone, 4- heptan can be enumerated Ketone, 4-methyl-2 pentanone, cyclopentanone, cyclohexanone and isophorone etc..

As alcoholic solvent, methanol, ethanol, propyl alcohol, butanol, hexanol, cyclohexanol, ethylene glycol, propane diols and glycerine can be enumerated Deng.

As aromatic hydrocarbon solvents, benzene,toluene,xylene and mesitylene etc. can be enumerated.

As amide solvent, DMF, DMA and 1-METHYLPYRROLIDONE can be enumerated Deng.

These solvents also and can use two or more.

For the total amount of coloured composition, the containing ratio of solvent (E) is preferably 40~99 mass %, more preferably 50~95 mass %.

In the coloured composition of the present invention, compound (I) is preferably dispersed in solvent (E).

For compound (I), as needed, following processing can be implemented：Rosin processing；Using having imported acidic-group Or the surface treatment of the progress such as derivative of basic group；Compound (I) surface is connect using high-molecular compound etc. Branch processing；Handled using the micronized of the progress such as sulfuric acid particles method；For removing being carried out using organic solvent, water etc. for impurity Carrying out washing treatment；Processing for being removed ionic impurity using ion-exchange etc. etc..Preferably, the particle diameter of compound (I) is big Cause uniform.For compound (I), by containing dispersant and carrying out decentralized processing, compound (I) can be formed in dispersion liquid In dispersed state.

As dispersant, surfactant etc. can be enumerated, can be cation system, anion system, nonionic system and both sexes Any of surfactant.Specifically, surfactant of Polyester, more amine systems and acrylic acid series etc. etc. can be enumerated. These dispersants may be used alone or in combination two or more and use.As dispersant, if being represented with trade name, KP can be enumerated (SHIN-ETSU HANTOTAI's chemical industry (strain) system), FLOWLEN (common prosperity society chemistry (strain) system), SOLSPERSE (registration mark) (Zeneca (strain) System), EFKA (registration mark) (BASF (strain) systems), AJISPER (registration mark) (Ajinomoto Fine-Techno Co., Inc. make), Disperbyk (registration mark) (BYK-Chemie (strain) systems), BYK (registration mark) (BYK-Chemie (strain) systems) Deng.

In the case of using dispersant, relative to 100 mass parts compounds (I), the use of dispersant (solid state component) Amount is preferably below 300 mass parts, more preferably more than 5 mass parts below 100 mass parts.If the usage amount of dispersant is above-mentioned In the range of, then the tendency that can obtain the coloured composition of dispersity evenly be present.

For the containing ratio of the compound (I) in coloured composition, in the total amount of coloured composition, it is usually 0.1~60 mass %, preferably 0.5~50 mass %, more preferably 1~40 mass %.

In coloured composition, the containing ratio of compound (I) leads to for the total amount of the solid state component of coloured composition Often it is below the mass % of more than 1 mass % 90, preferably more than 1 mass % below 80 mass %, more preferably more than 2 mass % Below 75 mass %.

The coloured composition of the present invention can be beyond inclusion compound (I) colouring agent (following, sometimes referred to as colouring agent (A1).).One kind or two or more colouring agent can be included in colouring agent (A1).Colouring agent (A1) preferably comprises yellow colorants, orange Chromatic colorant agent or red stain.

＜ colouring agents (A1) ＞

Colouring agent (A1) can be dyestuff or pigment.As dyestuff, known dyestuff can be used, dye can be enumerated Material is indexed described in (The Society of Dyers and Colourists publication) and Dyeing Note (Se Ran companies) Dyestuff.According to chemical constitution, azo dyes, anthraquinone dye, triphenhlmethane dye, xanthene dye and phthalocyanine dye can be enumerated Deng.These dyestuffs may be used alone or in combination two or more and use.

Specifically, the dyestuff of following such Colour Index (C.I.) numbering can be enumerated.

C.I. solvent yellow 14,15,23,24,25,38,62,63,68,79,81,82,83,89,94,98,99,162；

C.I. Indian yellow 1,3,7,9,11,17,23,25,29,34,36,38,40,42,54,65,72,73,76,79,98, 99、111、112、113、114、116、119、123、128、134、135、138、139、140、144、150、155、157、160、 161、163、168、169、172、177、178、179、184、190、193、196、197、199、202、203、204、205、207、 212、214、220、221、228、230、232、235、238、240、242、243、251；

C.I. active yellow 2,76,116；

C.I. directly Huang 2,4,28,33,34,35,38,39,43,44,47,50,54,58,68,69,70,71,86,93, 94、95、98、102、108、109、129、132、136、138、141；

C.I. disperse yellow 51,54,76；

C.I. solvent orange 2,7,11,15,26,41,54,56,99；

C.I. acid orange 6,7,8,10,12,26,50,51,52,56,62,63,64,74,75,94,95,107,108, 149、162、169、173；

C.I. reactive orange 16；

C.I. direct orange 26,34,39,41,46,50,52,56,57,61,64,65,68,70,96,97,106,107；

C.I. solvent red 24,49,90,91,111,118,119,122,124,125,127,130,132,143,145, 146、150、151、155、160、168、169、172、175、181、207、218、222、227、230、245、247；

C.I. acid red 52,73,80,91,92,97,138,151,211,274,289；

C.I. acid violet 34,102；

C.I. disperse violet 26,27；

C.I. solvent violet 11,13,14,26,31,36,37,38,45,47,48,51,59,60；

C.I. solvent blue 19 4,18,35,36,45,58,59,59:1、63、68、69、78、79、83、94、97、98、100、 101、102、104、105、111、112、122、128、132、136、139；

C.I. acid blue 25,27,40,45,78,80,112；

C.I. direct indigo plant 40；

C.I. disperse blue 1,14,56,60；

C.I. solvent green 1,3,5,28,29,32,33；

C.I. acid green 3,5,9,25,27,28,41；

C.I. Viride Nitens 1；

C.I. vat green 1 etc..

As pigment, known pigment can be used, for example, Colour Index (The Society of Dyers can be enumerated And Colourists are published) in be classified as the pigment of " pigment (Pigment) ".They can be used alone, or also can group Close two or more and use.

Specifically, can enumerate：

C.I. pigment yellow 1,3,12,13,14,15,16,17,20,24,31,53,83,86,93,94,109,110,117, 125th, the yellow uitramarine such as 128,129,137,138,139,147,148,150,153,154,166,173,185,194,214；

C.I. the orange pigment such as pigment orange 13,31,36,38,40,42,43,51,55,59,61,64,65,71,73；

C.I. Pigment Red 9,97,105,122,123,144,149,166,168,176,177,179,180,192,209, 215th, the red pigment such as 216,224,242,254,255,264,265,266,268,269,273；

C.I. pigment blue 15,15:3、15:4、15:6th, the blue pigment such as 60；

C.I. the violet pigment such as pigment violet 1,19,23,29,32,36,38；

C.I. the viridine green such as pigment Green 7,36,58,59.

Colouring agent (A1) is preferably comprising more than a kind in yellow colorants, orange colorant and red stain Colouring agent.

Yellow colorants can select from following substances：

Above-mentioned C.I. solvent yellows 14,15,23,24,25,38,62,63,68,79,81,82,83,89,94,98,99, 162；C.I. Indian yellow 1,3,7,9,11,17,23,25,29,34,36,38,40,42,54,65,72,73,76,79,98,99, 111、112、113、114、116、119、123、128、134、135、138、139、140、144、150、155、157、160、161、 163、168、169、172、177、178、179、184、190、193、196、197、199、202、203、204、205、207、212、 214、220、221、228、230、232、235、238、240、242、243、251；

C.I. active yellow 2,76,116；

C.I. the weld such as disperse yellow 51,54,76；

C.I. pigment yellow 1,3,12,13,14,15,16,17,20,24,31,53,83,86,93,94,109,110,117, 125th, the yellow uitramarine such as 128,129,137,138,139,147,148,150,153,154,166,173,185,194,214.

As yellow colorants, preferably weld and yellow uitramarine, more preferably yellow uitramarine, further preferred quinophthalone Yellow uitramarine, yellow uitramarine and isoindoline yellow pigment containing metal, particularly preferred C.I. pigment Yellow 12s 9,138,139, 150、185。

Orange colorant can select from following substances：

Above-mentioned C.I. solvent orange 2s, 7,11,15,26,41,54,56,99；

C.I. reactive orange 16；

C.I. the orange such as direct orange 26,34,39,41,46,50,52,56,57,61,64,65,68,70,96,97,106,107 Color dyestuff；

C.I. the orange pigment such as pigment orange 13,31,36,38,40,42,43,51,55,59,61,64,65,71,73.

As orange colorant, preferably orange and orange pigment, more preferably orange pigment, further preferred C.I. face Material orange 13,31,36,38,40,42,43,51,55,59,61,64,65,71,73.

Red stain can select from following substances：

Above-mentioned C.I. solvent red 24s, 49,90,91,111,118,119,122,124,125,127,130,132,143, 145、146、150、151、155、160、168、169、172、175、181、207、218、222、227、230、245、247；

C.I. the orchil such as acid red 52,73,80,91,92,97,138,151,211,274,289；

C.I. Pigment Red 9,97,105,122,123,144,149,166,168,176,177,179,180,192,209, 215th, the red pigment such as 216,224,242,254,255,264,265,266,268,269,273.

As red stain, preferably orchil and red pigment, more preferably azo dyes, anthraquinone dye, triphenyl Methane dye, xanthene dye, dyestuff, AZOpigments, diketopyrrolo-pyrrole pigment, anthraquinone pigment, xanthene pigment, face Material, further preferred C.I. acid reds 52, C.I. paratoneres 144,177,179,242,254,269.

In addition, as yellow colorants, orange colorant or red stain, Japanese Unexamined Patent Publication 2013-235257 can be used Xanthene compound described in number publication etc..

In the case that the coloured composition of the present invention includes colouring agent (A1) and solvent (E), previously prepared coloring can be included Agent (A1) and the liquid containing colouring agent (A1) of solvent (E), the liquid preparation coloring that then use should be containing colouring agent (A1) Composition.In the case where colouring agent (A1) does not dissolve in solvent (E), the liquid containing colouring agent (A1) can be by making colouring agent (A1) it is scattered in solvent (E) and is mixed and prepared.Liquid containing colouring agent (A1) can include to be contained in coloured composition Part or all of some solvents (E).

The coloured composition of the present invention preferably by the compound that represents formula (I), resin, solvent (E) and includes coloring The liquid containing colouring agent (A1) of agent (A1) and solvent (E) is mixed and manufactured.It is preferably following as above-mentioned manufacture method Method：Compound, resin and solvent (E) mixing for being represented formula (I) using ball mill etc., are prepared coloured composition, will obtained Coloured composition, the method that is mixed with the liquid containing colouring agent (A1) comprising colouring agent (A1) and solvent (E).

For colouring agent (A1), as needed, following processing can be implemented：Rosin processing；Using having imported acidic groups The surface treatment of the progress such as the colouring agent derivative of group or basic group；Using high-molecular compound etc. to colouring agent (A1) surface The grafting processing of progress；Handled using the micronized of the progress such as sulfuric acid particles method；For remove impurity using organic solvent, The carrying out washing treatment of the progress such as water；Processing for being removed ionic impurity using ion-exchange etc. etc..Preferably, colouring agent (A1) Particle diameter it is generally uniform.For colouring agent (A1), by containing dispersant and carrying out decentralized processing, colouring agent can be formed (A1) state dispersed in the liquid containing colouring agent (A1).Colouring agent (A1) discriminably individually carries out scattered place Reason, also can will carry out decentralized processing after a variety of mixing.

In the case of using dispersant to prepare the above-mentioned liquid containing colouring agent (A1), relative to 100 mass parts Colouring agent (A1), the usage amount of the dispersant (solid state component) is preferably below 300 mass parts, more preferably more than 5 mass parts Below 100 mass parts.When the usage amount of the dispersant is in above-mentioned scope, exists and can obtain dispersity containing evenly The tendency of the liquid of colouring agent (A1).

For the containing ratio of the colouring agent (A1) in the liquid containing colouring agent (A1), containing colouring agent (A1) In the total amount of liquid, usually 0.1~60 mass %, preferably 0.5~50 mass %, more preferably 1~40 mass %.

In liquid containing colouring agent (A1), the containing ratio of colouring agent (A1) is usual for the total amount of solid state component For below the mass % of more than 1 mass % 90, preferably more than 1 mass % below 80 mass %, more preferably more than 2 mass % 75 Below quality %.

After the previously prepared liquid containing colouring agent (A1) comprising colouring agent (A1) and solvent (E), use this contain In the case that the liquid of colouring agent (A1) prepares the coloured composition of the present invention, the liquid containing colouring agent (A1) can include in advance Part or all of the resin (B) contained in coloured composition, preferably a part.By including resin (B) in advance, so as to Further improve the dispersion stabilization of the liquid containing colouring agent (A1).

On the content of the resin (B) in the liquid containing colouring agent (A1), relative to 100 mass parts colouring agents (A1) Speech, more preferably for example, 1~500 mass parts, preferably 5~200 mass parts, 10~100 mass parts.

On the containing ratio of the colouring agent (A) for being combined compound (I) and colouring agent (A1) in coloured composition, For the total amount of solid state component, usually more than 1 mass % below 90 mass %, 80 matter preferably more than 1 mass % Below % is measured, more preferably more than 2 mass % below 75 mass %.

For compound (I) containing ratio, in colouring agent (A) total amount, usually more than 0.001 mass %, Preferably more than 0.003 mass %, more preferably more than 0.005 mass %, the upper limit is below 100 mass %, is preferably Below 99.999 mass %, more preferably below 99.997 mass %.

It is excellent relative to 100 mass parts compounds (I), the content of colouring agent (A1) in the case of comprising colouring agent (A1) Elect as more than 0.1 mass parts, more preferably more than 0.5 mass parts, more preferably more than 1 mass parts, preferably 10000 matter Measure below part, more preferably below 5000 mass parts.

The cured composition for color of the present invention includes：Compound (I)；At least one of resin (B) and solvent (E)； With polymerizable compound (C).

＜ polymerizable compounds (C) ＞

Polymerizable compound (C) is can be gathered by the living radical caused by polymerization initiator (D) and/or acid The compound of conjunction, the compound of ethylenic unsaturated bond for example, with polymerism etc., it is preferably (methyl) acroleic acid esterification Compound.

As the polymerizable compound with 1 ethylenic unsaturated bond, for example, nonyl phenyl carbitol propylene can be enumerated Acid esters, acrylic acid 2- hydroxyl -3- phenoxy-propyls, 2- ethylhexyl carbitols acrylate, acrylic acid 2- hydroxy methacrylates, N- second Vinyl pyrrolidone etc. and above-mentioned monomer (a), monomer (b) and monomer (c).

As the polymerizable compound with 2 ethylenic unsaturated bonds, for example, 1,6- hexylene glycols two (methyl) can be enumerated Acrylate, ethylene glycol two (methyl) acrylate, neopentyl glycol two (methyl) acrylate, triethylene glycol two (methyl) propylene Double (acryloyl-oxyethyl) ethers and 3- methyl pentanediols two (methyl) acrylate etc. of acid esters, bisphenol-A.

Wherein, polymerizable compound (C) is preferably the polymerizable compound with more than 3 ethylenic unsaturated bonds.Make For such polymerizable compound, for example, trimethylolpropane tris (methyl) acrylate, pentaerythrite three (methyl) can be enumerated Acrylate, pentaerythrite four (methyl) acrylate, dipentaerythritol five (methyl) acrylate, (first of dipentaerythritol six Base) acrylate, tripentaerythritol eight (methyl) acrylate, tripentaerythritol seven (methyl) acrylate, tetrapentaerythritol Ten (methyl) acrylate, tetrapentaerythritol nine (methyl) acrylate, three (2- (methyl) acryloyl group epoxide ethyl) isocyanides Urea acid esters, glycol-modified pentaerythrite four (methyl) acrylate, glycol-modified dipentaerythritol six (methyl) acrylic acid Ester, propylene glycol modified pentaerythrite four (methyl) acrylate, propylene glycol modified dipentaerythritol six (methyl) acrylate, oneself Lactone-modified (methyl) acrylate of pentaerythrite four and caprolactone modification dipentaerythritol six (methyl) acrylate etc., can be excellent Elect (methyl) acrylate of dipentaerythritol five and dipentaerythritol six (methyl) acrylate.

The weight average molecular weight of polymerizable compound (C) is preferably more than 150 2, less than 900, and more preferably more than 250 1, Less than 500.

On polymerizable compound (C) containing ratio, in cured composition for color, relative to the total amount of solid state component For, preferably 1~65 mass %, more preferably 3~60 mass %, more preferably 5~55 mass %.

＜ polymerization initiators (D) ＞

Polymerization initiator (D) as long as can by light, heat effect and produce living radical, acid etc. so as to trigger polymerization Compound, be not particularly limited, known polymerization initiator can be used.

As polymerization initiator (D), can enumerate O- acyl groups oxime compound, alkyl phenones (alkylphenone) compound, Bisglyoxaline (biimidazole) compound, triaizine compounds and acylphosphine oxide compound etc..

As O- acyl group oxime compounds, for example, N- benzoyls Oxy-1-(4- phenylsulfartyls can be enumerated (phenylsulfanyl) phenyl) butane-1- ketone-2- imines, N- benzoyls Oxy-1-(4- phenylsulfartyls phenyl) octane- 1- ketone-2- imines, N- benzoyls Oxy-1-(4- phenylsulfartyls phenyl)-3- cyclopenta propane-1- ketone-2- imines, N- acetyl Base Oxy-1-(4- phenylsulfartyls phenyl)-3- cyclopenta propane-1- ketone-2- imines, N- acetyl group Oxy-1-(4- phenylsulfartyls Phenyl)-3- cyclohexyl propane-1- ketone-2- imines, N- acetyl group Oxy-1-[9- ethyls-6- (2- methyl benzoyls)-9H- Carbazole-3- bases] ethane-1- imines, N- acetyl group Oxy-1-[9- ethyls-6- { 2- methyl-4- (3,3- dimethyl-2,4- dioxies Heterocycle phenyl-methyl epoxide) benzoyl-9H- carbazole-3- bases] ethane-1- imines, N- acetyl group Oxy-1-[9- ethyls-6- (2- methyl benzoyls)-9H- carbazole-3- bases]-3- cyclopenta propane-1- imines and N- benzoyls Oxy-1-[9- ethyls- 6- (2- methyl benzoyls) -9H- carbazole -3- bases] -3- cyclopenta propane -1- ketone -2- imines etc..In addition, as O- acyl group oximes Compound, it is possible to use IRGACURE OXE01, OXE02 (being made above for BASF (strain)) and N-1919 ((strain) ADEKA companies System) etc. commercially available product.Wherein, as O- acyl group oxime compounds, it is preferably selected from by N- benzoyls Oxy-1-(4- phenylsulfartyl benzene Base) butane-1- ketone-2- imines, N- benzoyls Oxy-1-(4- phenylsulfartyls phenyl) octane-1- ketone-2- imines and N- benzene first It is at least one kind of in the group of acyloxy -1- (4- phenylsulfartyls phenyl) -3- cyclopenta propane -1- ketone -2- imines composition, it is more excellent Select N- benzoyls Oxy-1-(4- phenylsulfartyls phenyl) octane-1- ketone-2- imines.

As alkyl phenones compound, 2- methyl -2- morpholinoes (morpholino) -1- (4- methylsulfany benzene can be enumerated Base) propane -1- ketone, 2- dimethylaminos -1- (4- morphlinophenyls) -2- benzyls butane -1- ketone and 2- (dimethylamino) -2- [(4- aminomethyl phenyls) methyl] -1- [4- (4- morpholinyls (morpholinyl)) phenyl] butane -1- ketone etc..As alkyl phenones Compound, it is possible to use the commercially available product such as IRGACURE 369,907,379 (being above BASF AG's system).

As alkyl phenones compound, 2- hydroxy-2-methyl -1- phenyl-propane -1- ketone, 2- hydroxyl -2- first can be also enumerated (4- (2- hydroxyl-oxethyls) phenyl propane -1- ketone, 1- hydroxycyclohexylphenylketones, (4- is different by 2- hydroxy-2-methyls -1- by base -1- Acrylic phenyl) propane -1- ketone oligomer, α, α-diethoxy acetophenone and benzil dimethyl ketal.

As united imidazole, for example, 2,2 '-bis- (2- chlorphenyls) -4,4 ', 5 can be enumerated, 5 '-tetraphenyl bisglyoxaline, 2,2 '-bis- (2,3- dichlorophenyls) -4,4 ', 5,5 '-tetraphenyl bisglyoxaline is (for example, with reference to Japanese Unexamined Patent Publication 6-75372 public affairs Report, Japanese Unexamined Patent Publication 6-75373 publications etc.), 2,2 '-bis- (2- chlorphenyls) -4,4 ', 5,5 '-tetraphenyl bisglyoxaline, 2,2 ' - Double (2- chlorphenyls) -4,4 ', 5,5 '-four (alkoxyl phenyl) bisglyoxaline, 2,2 '-bis- (2- chlorphenyls) -4,4 ', 5,5 '-four (two Alkoxyl phenyl) bisglyoxaline, 2,2 '-bis- (2- chlorphenyls) -4,4 ', 5,5 '-four (tri-alkoxy phenyl) bisglyoxalines (for example, ginseng See Japanese Patent Publication 48-38403 publications, Japanese Unexamined Patent Application 62-174204 publications etc.) and 4,4 ', the phenyl quilt of 5,5 '-position The imidazolium compounds that alkoxy carbonyl (carboalkoxy) substitution forms is (for example, with reference to Japanese Unexamined Patent Publication 7-10913 publications Deng) etc..

As triaizine compounds, 2,4- double (trichloromethyl) -6- (4- methoxyphenyls) -1,3,5-triazines, 2 can be enumerated, Double (trichloromethyl) -6- (4- methoxyl groups the naphthyl) -1,3,5- triazines of 4-, double (the trichloromethyl) -6- piperonyls -1,3,5- three of 2,4- Double (trichloromethyl) -6- (4- the methoxyl-styrenes) -1,3,5- triazines of piperazine, 2,4-, double (trichloromethyl) -6- (2- (5- of 2,4- Methylfuran -2- bases) vinyl) -1,3,5- triazines, double (the trichloromethyl) -6- (2- (furans -2- bases) vinyl) -1 of 2,4-, Double (trichloromethyl) -6- (2- (4- diethylamino -2- aminomethyl phenyls) the vinyl) -1,3,5- triazines of 3,5- triazines, 2,4- and Double (trichloromethyl) -6- (2- (3,4- Dimethoxyphenyls) vinyl) -1,3,5- triazines of 2,4- etc..

As acylphosphine oxide compound, TMDPO etc. can be enumerated.

In addition, as polymerization initiator (D), benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin can be enumerated The benzoin compound such as isopropyl ether, benzoin isobutyl ether；Benzophenone, o-benzoyl yl benzoic acid methyl esters, 4- phenyl two Benzophenone, 4- benzoyls -4 '-dimethyl diphenyl sulfide, 3,3 ', 4,4 '-four (t-butyl peroxy carbonyl) benzophenone and 2, The benzophenone cpds such as 4,6- tri-methyl benzophenones；The naphtoquinone compounds such as 9,10- phenanthrenequione, 2- EAQs and camphorquinone；10- Butyl -2- chloro-acridines ketone, benzil, methyl benzoylformate and titanocenes compound etc..

They are preferably applied in combination with the initiation auxiliary agent (D1) (especially amine) described later that polymerize.

Polymerization initiator (D) is preferably to include to be selected from by alkyl phenones compound, triaizine compounds, acylphosphine oxide chemical combination The polymerization initiator of at least one of the group of thing, O- acyl groups oxime compound and united imidazole composition, is more preferably included The polymerization initiator of O- acyl group oxime compounds.

For polymerization initiator (D) containing ratio, in the total amount of the solid state component in cured composition for color, Preferably 0.001~40 mass %, more preferably 0.01~30 mass %.

The cured composition for color of the present invention can contain polymerization and trigger auxiliary agent (D1).

＜ polymerizations trigger auxiliary agent (D1) ＞

It is to promote to trigger the poly- of the polymerizable compound of polymerization using polymerization initiator that polymerization, which triggers auxiliary agent (D1), The compound or sensitizer closed and used.In the case where triggering auxiliary agent (D1) containing polymerization, generally, it can be with polymerization initiator (D) it is applied in combination.

Trigger auxiliary agent (D1) as polymerization, amines, alkoxy anthracene compound, thioxanthone compounds and carboxylic acid can be enumerated Compound etc..

As amines, triethanolamine, methyl diethanolamine, triisopropanolamine, 4- dimethylamino benzene first can be enumerated Sour methyl esters, EDMAB, 4- dimethylaminobenzoic acids isopentyl ester, benzoic acid 2- dimethylaminoethyls Ester, 4- dimethylaminobenzoic acid 2- ethylhexyls, N, N- dimethyl-p-toluidines, 4,4 '-bis- (dimethylamino) hexichol first Ketone (common name Michler's keton (Michler ' s ketone)), 4,4 '-bis- (diethylamino) benzophenone and 4,4 '-bis- (ethyl first Base amino) benzophenone etc., preferably enumerate 4,4 '-bis- (diethylamino) benzophenone.In addition, as amines, The commercially available products such as EAB-F (hodogaya chemical industry (strain) system) can be used.

As alkoxy anthracene compound, 9,10- dimethoxys anthracene, EDMO, 9,10- can be enumerated Diethoxy anthracene, 2- ethyl -9,10- diethoxies anthracene, 9,10- dibutoxies anthracene and 2- ethyl -9,10- dibutoxy anthracenes etc..

As thioxanthone compounds, ITX, ITX, 2,4- diethyl thioxanthenes can be enumerated Ketone, the clopenthixal ketones of 2,4- bis- and the chloro- 4- propoxythioxanthones of 1- etc..

As carboxylic acid compound, can enumerate phenylsulfartyl acetic acid, aminomethyl phenyl ethyl thioglycollic acid, ethylphenyl ethyl thioglycollic acid, Methylethyl phenyl ethyl thioglycollic acid, 3,5-dimethylphenyl ethyl thioglycollic acid, methoxyphenyl ethyl thioglycollic acid, Dimethoxyphenyl sulfenyl second Acid, chlorophenyl sulfanyl acetic acid, dichlorophenyl ethyl thioglycollic acid, N-phenylglycine, phenoxyacetic acid, naphthylthio acetic acid, N- naphthalenes Base glycine and naphthoxy acetic acid etc..

When triggering auxiliary agent (D1) using these polymerizations, for its containing ratio, in cured composition for color In the total amount of solid state component, preferably 0.001~30 mass %, more preferably 0.01~20 mass %.

The coloured composition of the present invention can also contain levelling agent (F) and antioxidant.

＜ levelling agents (F) ＞

As levelling agent (F), silicone based surfactants, fluorine system surfactant and having with fluorine atom can be enumerated Machine silicon systems surfactant etc..They can have polymerizable group on side chain.

As silicone based surfactants, surfactant that there is siloxanes key in intramolecular etc. can be enumerated.Specifically For, can enumerate Toray Silicone DC3PA, Toray Silicone SH7PA, Toray Silicone DC11PA, Toray Silicone SH21PA、Toray Silicone SH28PA、Toray Silicone SH29PA、Toray Silicone SH30PA, Toray Silicone SH8400 (Dow Corning Toray Co., Ltd. system), KP321, KP322, KP323, KP324, KP326, KP340, KP341 (SHIN-ETSU HANTOTAI's chemical industry (strain) system), TSF400, TSF401, TSF410, TSF4300, TSF4440, TSF4445, TSF4446, TSF4452 and TSF4460 (Momentive Performance Materials Japan contracts commercial firm system) etc..

As fluorine system surfactant, surfactant that there is fluorocarbon chain in intramolecular etc. can be enumerated.Specifically, may be used Enumerate Fluorad (registration mark) FC430, Fluorad FC431 (Sumitomo 3M Ltd. systems), MEGAFAC (registrars Mark) F142D, MEGAFAC F171, MEGAFAC F172, MEGAFAC F173, MEGAFAC F177, MEGAFAC F183, MEGAFAC F554, MEGAFAC R30, MEGAFAC RS-718-K (DIC (strain) systems), EFTOP (registration mark) EF301, EFTOP EF303、EFTOP EF351、EFTOP EF352(Mitsubishi Materials Electronic Chemicals Co., Ltd. systems), Surflon (registration mark) S381, Surflon S382, Surflon SC101, the Surflon SC105 (rising suns Nitre (strain) is made) and E5844 (Daikin Fine Chemical Kenkyusho, K.K. system) etc..

As the silicone based surfactants with fluorine atom, can enumerate has siloxanes key and fluorocarbon chain in intramolecular Surfactant etc..Specifically, can enumerate MEGAFAC (registration mark) R08, MEGAFAC BL20, MEGAFAC F475, MEGAFAC F477 and MEGAFAC F443 (DIC (strain) systems) etc..

During containing levelling agent (F), on its containing ratio, for the total amount of coloured composition, usually 0.0005 Below the mass % of more than quality % 1, preferably more than 0.001 mass % below 0.5 mass %, more preferably 0.001 mass % Below the mass % of the above 0.2, more preferably more than 0.002 mass % below 0.1 mass %, particularly preferably 0.005 matter Measure below the mass % of more than % 0.1.When the containing ratio of levelling agent (F) is in above-mentioned scope, the flatness of colour filter may be such that Well.

＜ antioxidants ＞

From improve colouring agent heat resistance and light resistance from the viewpoint of, antioxidant may be used alone or in combination 2 kinds with Above use.As antioxidant, as long as industrial usually used antioxidant, is not particularly limited, can be used Phenol antioxidant, phosphorous antioxidant and sulphur system antioxidant etc..

As above-mentioned phenol antioxidant, for example, (the イ Le ガノッ Network ス 1010 of Irganox 1010 can be enumerated：Ji Wusi Alcohol four [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic ester], BASF (strain) system), (the イ Le ガノッ Network of Irganox 1076 ス1076：3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid stearyl, BASF (strain) system), (イ of Irganox 1330 ルガノックス1330：3,3 ', 3 ", 5,5 ', 5 "-six tert-butyl group-a, a ', a "-three pairs of (bases of mesitylene -2,4,6- three) first Phenol, BASF (strain) system), (the イ Le ガノッ Network ス 3114 of Irganox 3114：(3,5- di-t-butyl -4- hydroxyl the benzyls of 1,3,5- tri- Base) -1,3,5-triazines -2,4,6 (1H, 3H, 5H)-triketones, BASF (strain) system), (the イ Le ガノッ Network ス of Irganox 3790 3790：1,3,5- tri- ((the 4- tert-butyl group -3- hydroxyl -2,6- xylyls) methyl) -1,3,5- triazines -2,4,6 (1H, 3H, 5H) - Triketone, BASF (strain) system), (the イ Le ガノッ Network ス 1035 of Irganox 1035：Thio diethylene pair [3- (3,5- di-t-butyls- 4- hydroxy phenyls) propionic ester], BASF (strain) system), (the イ Le ガノッ Network ス 1135 of Irganox 1135：Double (the 1,1- diformazans of 3,5- Base ethyl) -4- hydroxy phenylpropionic acids C7-C9 pendant alkyl group esters, BASF (strain) system), Irganox 1520L (イ Le ガノッ Network ス 1520L：4,6- double (octylthio methyl) orthoresols, BASF (strain) systems), Irganox 3125 (イ Le ガノッ Network ス 3125, BASF (strain) make), (the イ Le ガノッ Network ス 565 of Irganox 565：Double (n-octyl the sulfenyl) -6- of 2,4- (4- hydroxyls -3 ', 5 ' - Di-tert-butyl amido) -1,3,5-triazines, BASF (strain) system), Adekastab AO-80 (アデカスタ Block AO-80：3,9- Double oxygen of (2- (3- (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propiono epoxide) -1,1- dimethyl ethyls) -2,4,8,10- four Miscellaneous spiral shell (5,5) hendecane, (strain) ADEKA systems), Sumilizer BHT (スミライザー BHT, Sumitomo Chemical (strain) system), Sumilizer GA-80 (スミライザー GA-80, Sumitomo Chemical (strain) system), Sumilizer GS (スミライザー GS, Sumitomo Chemical (strain) is made), Cyanox 1790 (シアノッ Network ス 1790, (strain) Cytec systems) and vitamin E (Eisai Co., Ltd. make) etc..

As above-mentioned phosphorous antioxidant, for example, (the イ Le ガ Off ォス 168 of Irgafos 168 can be enumerated：Phosphorous acid three (2,4- di-tert-butyl-phenyl) ester, BASF (strain) system), Irgafos12 (イ Le ガ Off ォス 12：Three [2- [[2,4,8,10- tetra- Tert-butyl group dibenzo [d, f] [miscellaneous English in the heptan -6- bases of 1,3,2] Delnavs] epoxide] ethyl] amine, BASF (strain) system), Irgafos 38 (イルガフォス38：Double (2,4- double (1,1- the dimethyl ethyl) -6- aminomethyl phenyls) ethyl esters of phosphorous acid, BASF (strain) System), Adekastab 329K ((strain) ADEKA systems), Adekastab PEP36 ((strain) ADEKA systems), Adekastab PEP-8 ((strain) ADEKA systems), Sandstab P-EPQ (Clariant company systems), Weston 618 (ウェスト Application 618, GE companies System), Weston 619G (ウェスト Application 619G, GE company system), Ultranox 626 (ウ Le トラノッ Network ス 626, GE companies System) and Sumilizer GP (スミライザー GP：6- [3- (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propoxyl group] -2,4, 8,10- tetra-terts dibenzo [d, f] [the miscellaneous English in heptan (dioxaphosphepin) of 1.3.2] Delnavs) (Sumitomo Chemical (strain) system) Deng.

As above-mentioned sulphur system antioxidant, for example, thiodipropionate dilauryl, the Pork and beans of thio-2 acid two can be enumerated The dialkyl thiodipropionate compound such as cool base ester and thio-2 acid distearyl base ester and four [methylene (3- dodecanes Base sulfenyl) propionic acid ester group] β-alkylmercaptopropionates compound of polyalcohol such as methane etc..

＜ other compositions ＞

As needed, coloured composition of the invention can contain filler, other high-molecular compounds, closely sealed accelerator, Known additive in the technical field such as light stabilizer, chain-transferring agent.

As closely sealed accelerator, such as vinyltrimethoxy silane, VTES, vinyl can be enumerated Three (2- methoxy ethoxies) silane, 3- glycidyloxypropyls trimethoxy silane, 3- glycidoxypropyls Dimethoxysilane, 3- glycidoxypropyls diethoxy silane, 2- (3,4- epoxycyclohexyls) ethyl trimethoxy Silane, 3- chloropropylmethyldimethoxysilanes, 3- r-chloropropyl trimethoxyl silanes, 3- methylacryloyl epoxide propyl group front threes TMOS, 3-mercaptopropyi trimethoxy silane, 3- mercaptopropyls trimethoxy silane, the ethoxy of 3- NCOs propyl group three Base silane, N-2- (amino-ethyl) -3- amino propyl methyls dimethoxysilane, N-2- (amino-ethyl) -3- aminopropyl first Base diethoxy silane, N-2- (amino-ethyl) -3- TSL 8330s, 3- TSL 8330s, APTES, N- phenyl -3- TSL 8330s and the ethoxy of N- phenyl -3- aminopropyls three Base silane etc..

＜ colour filters ＞

Colour filter can be formed by the coloured composition or cured composition for color of the present invention.As formation colored pattern Method, photoetching process, ink-jet method, print process etc. can be enumerated, can preferably enumerate photoetching process.Photoetching process is following methods：Will be above-mentioned Cured composition for color is coated on substrate and is dried and forms cured composition for color layer, will be somebody's turn to do across photomask Color solidification compound layer exposes, and is developed.In photoetching process, cured composition for color preferably comprises polymerization initiator (D).By in photolithography in exposure when without using photomask and/or without development, so as to be formed as above-mentioned coloring The coloring film of the solidfied material of solidification compound layer.The colored pattern being formed as described above, coloring film can be regard as this The colour filter of invention.

The thickness of the colour filter of making is not particularly limited, and can suitably be adjusted according to purpose, purposes etc., for example, 0.1~ 30 μm, preferably 0.1~20 μm, more preferably 0.5~6 μm.

As substrate, glass plate, resin plate can be used, silicon, to form on aforesaid substrate aluminium, silver, silver/copper/palldium alloy thin Substrate obtained from film etc..Other color-filter layers, resin bed, transistor and circuit etc. can be formed on these substrates.

Being formed based on photolithographic each color pixel can be carried out using known or usual device, condition.For example, can be according to Following manner makes.

First, cured composition for color is coated on substrate, by heat drying (prebake conditions) and/or be dried under reduced pressure And remove the volatile ingredients such as solvent so as to be dried, obtain smooth cured composition for color layer.

As coating method, spin-coating method, slot coated method and slot coated and spin-coating method (slit and spin can be enumerated Coating) etc..

Next, for cured composition for color layer, exposed across the photomask for forming target coloration pattern Light.In order to equably irradiate parallel rays or progress photomask to whole plane of exposure and form cured composition for color The accurate contraposition of the substrate of layer, preferably using exposure devices such as mask aligner and steppers.

By making the cured composition for color layer after exposure be contacted with developer solution to be developed, so as on substrate Form colored pattern.By development, the unexposed portion of cured composition for color layer is dissolved in developer solution and is removed.

As developer solution, for example, it is preferable to the alkalization such as potassium hydroxide, sodium acid carbonate, sodium carbonate and TMAH The aqueous solution of compound.

Developing method can be any method in sheathed immersion method (puddle method), infusion process and spray-on process etc.. In addition, can be by substrate with arbitrary angle tilt in development.

Substrate after preferred pair development is washed.

Furthermore it is preferred that toasted after being carried out to obtained colored pattern.

Above-mentioned colour filter is used as in display device (for example, liquid crystal display device, organic el device, Electronic Paper etc.) and solid The colour filter that is used in picture pick-up device, especially as the colour filter used in liquid crystal display device it is useful.

[embodiment]

Hereinafter, embodiment is enumerated to further illustrate the present invention, but the present invention is not obviously limited by following embodiments, Certainly it also can suitably be changed and be implemented in the range of it can meet above-mentioned following purport, they are all contained in this hair Within bright technical scope.

Unless otherwise specified, then " quality % " and " mass parts " of " % " and " part " expression in each example.

In following synthesis example, the structure of compound utilizes NMR (JMM-ECA-500；JEOL's (strain) makes) or matter Compose (LC；The type of Agilent systems 1200, MASS；Agilent LC/MSD6130 types) confirm.

Resin utilizes GPC method according to the weight average molecular weight (Mw) of polystyrene conversion and the measure of number-average molecular weight (Mn) Carry out under the following conditions.

Device：HLC-8120GPC (Tosoh (strain) systems)

Post：TSK-GELG2000HXL

Column temperature：40℃

Solvent：Tetrahydrofuran

Flow velocity：1.0mL/ minute

Analyze the solid component concentration of sample：0.001~0.01 mass %

Sample size：50μL

Detector：RI

Correction standard substance：TSK STANDARD POLYSTYRENE F-40、F-4、F-288、A-2500、A-500 (Tosoh (strain) systems)

The weight average molecular weight (Mw) and number-average molecular weight (Mn) that are converted according to polystyrene that will be obtained through the above way The ratio between (Mw/Mn) be used as decentralization.

Embodiment 1

By the 737 parts of mixing of 14.4 parts of coumarin 6 (Tokyo chemical conversion industry (strain) system) and toluene, it is stirred in 87 DEG C.To 10.1 parts of Methyl triflate is added in the mixture.The mixture stir within 3 hours in 87 DEG C.It is mixed to this in 10 DEG C Compound is stirred.The mixture is filtered, obtained residue is washed 6 times for 433 parts with toluene.By the residue in 60 DEG C are dried under reduced pressure, and obtain 20.8 parts of the compound of formula (I-2) expression.

The identification ＞ for the compound that ＜ formulas (I-2) represent

(mass spectrum) ionization mode=ESI+：M/z=365 [M-CF₃SO₃]⁺

Accurate molecular weight (Exact Mass)：514

1500 parts of mixing of 5.00 parts of compound and methanol that formula (I-2) is represented.Phosphotungstic acid water is added into the mixture The mixture of 104 parts of 10.4 parts of compound (Sigma Aldrich Japan (strain) systems) and methanol.The mixture is filtered, By the 500 parts of washings of methanol of obtained residue.The residue is dried under reduced pressure in 60 DEG C, obtains formula (I-14) expression 12.4 parts of compound.

The identification ＞ for the compound that ＜ formulas (I-14) represent

(mass spectrum) ionization mode=ESI+：M/z=365 [(M-PW₁₂O₄₀)/3]⁺

Accurate molecular weight (Exact Mass)：3974

(Evaluation of Heat Tolerance)

Device (SII NanoTechnology TG/DTA6200) is determined simultaneously using differential thermal-thermogravimetric, in embodiment 1 Obtained compound carries out means of differential scanning calorimetry measure.The sample size used in measure once is 5mg.Measurement temperature is from most 45 DEG C of first beginnings, are warming up to 550 DEG C, so as to be measured with 5 DEG C per minute of speed.In a nitrogen atmosphere, weight is obtained Slip turns into 5% temperature T₅(under blanket of nitrogen).Show the result in table 11.

[table 11]

As shown in Table 11, the heat resistance of compound of the invention is high.

Synthesis example 1

Nitrogen is flowed into appropriate amount into the flask with reflux condensing tube, dropping funel and agitator, is replaced as nitrogen gas Atmosphere, load 280 parts of propylene glycol monomethyl ether, while stirring, while being heated to 80 DEG C.Next, it was added dropwise third through 5 hours 38 parts of olefin(e) acid, the ring [5.2.1.0 of acrylic acid 3,4- epoxies three^2,6] decane -8- base esters and the ring of acrylic acid 3,4- epoxies three [5.2.1.0^2,6] decane -9- base esters 289 parts of mixture, the mixed solution of 125 parts of propylene glycol monomethyl ether.It is another Aspect, 2,2- azos double (2,4- methyl pentane nitriles) are dissolved in propylene glycol monomethyl ether 235 for 33 parts through dropwise addition in 6 hours Mixed solution obtained from part.After completion of dropwise addition, at such a temperature keep 4 hours, be subsequently cooled to room temperature, obtain solid-state into It is divided into the solution of 35.0% copolymer (resin B 1).The weight average molecular weight (Mw) of obtained resin B 1 is 8800, and decentralization is 2.1 solution acid number is 28mg-KOH/g.

Synthesis example 2

Nitrogen is flowed into appropriate amount into the flask with reflux condensing tube, dropping funel and agitator, is replaced as nitrogen gas Atmosphere, load 257 parts of ethyl lactate, while stirring, while being heated to 75 DEG C.Next, methacrylic acid 81 was added dropwise through 5 hours Part, the ring [5.2.1.0 of acrylic acid 3,4- epoxies three^2,6] decane -8- base esters and the ring [5.2.1.0 of acrylic acid 3,4- epoxies three^2,6] last of the ten Heavenly stems The mixed solution of 25 parts of 369 parts of mixture, the ethyl lactate of alkane -9- base esters.On the other hand, it was added dropwise through 5 hours by 2,2- azos 11 parts of double (2,4- methyl pentane nitriles) is dissolved in mixed solution obtained from 162 parts of ethyl lactate.After completion of dropwise addition, in the temperature Degree is lower to be kept for 5 hours, is then added 95 parts of ethyl lactate, is cooled to room temperature, obtains the copolymer (tree that solid state component is 47.7% Fat B2) solution.The weight average molecular weight (Mw) of obtained resin B 2 is 8100, and decentralization 1.9, solution acid number is 53mg- KOH/g。

Synthesis example 3

Nitrogen is flowed into appropriate amount into the flask with reflux condensing tube, dropping funel and agitator, is replaced as nitrogen gas Atmosphere, load 371 parts of propylene glycol monomethyl ether, while stirring, while being heated to 85 DEG C.Next, it was added dropwise third through 4 hours 54 parts of olefin(e) acid, the ring [5.2.1.0 of acrylic acid 3,4- epoxies three^2,6] decane -8- base esters and the ring of acrylic acid 3,4- epoxies three [5.2.1.0^2,6] 225 parts of the mixtures of decane -9- base esters, 81 parts of vinyltoluene (isomer mixture), propylene glycol monomethyl The mixed solution that 80 parts of ether acetic acid ester.On the other hand, it was added dropwise through 5 hours by polymerization initiator 2, double (2, the 4- dimethyl of 2- azos Valeronitrile) 30 parts be dissolved in solution obtained from 160 parts of propylene glycol monomethyl ether.The completion of dropwise addition of initiator solution Afterwards, kept for 4 hours at such a temperature, be subsequently cooled to room temperature, obtain the copolymer (resin B 3) that solid state component is 37.5% Solution.The weight average molecular weight (Mw) of obtained resin B 3 is 10600, and decentralization 2.01, solution acid number is 43mg-KOH/g.

Synthesis example 4

Nitrogen is flowed into appropriate amount into the flask with reflux condensing tube, dropping funel and agitator, is replaced as nitrogen gas Atmosphere, load 54 parts of ethyl lactate, 141 parts of propylene glycol monomethyl ether, while stirring, while being heated to 85 DEG C.Next, 35 parts of acrylic acid, the ring [5.2.1.0 of acrylic acid 3,4- epoxies three was added dropwise through 5 hours^2,6] decane -8- base esters and acrylic acid 3,4- rings Ring [the 5.2.1.0 of oxygen three^2,6] decane -9- base esters 161 parts of 23 parts of mixture, N-cyclohexylmaleimide, methacrylic acid 2- hydroxyls The mixed solution of 12 parts of base ethyl ester, 493 parts of propylene glycol monomethyl ether.On the other hand, it was added dropwise through 6 hours by 2,2- azos 3 parts of double (2,4- methyl pentane nitriles) is dissolved in mixed solution obtained from 78 parts of propylene glycol monomethyl ether.Knot is added dropwise Shu Hou, kept for 4 hours at such a temperature, be subsequently cooled to room temperature, obtain the copolymer (resin B 4) that solid state component is 24.4% Solution.The weight average molecular weight (Mw) of obtained resin B 4 is 8400, and decentralization 2.1, solution acid number is 26mg-KOH/g.

[film thickness measuring]

Use Japanese vacuum technique (strain) DEKTAK3 measure thickness processed.

[preparation of sublimability experiment resin combination (SJS)]

Following substances are mixed, so as to being elevated property experiment resin combination (SJS),

Resin：Methacrylic acid/benzyl methacrylate (mol ratio：30/70) copolymer (field ridge chemical industry (strain) System, weight average molecular weight (Mw) they are 10700, acid number 70-mgKOH/g) 33.8% propylene glycol monomethyl ether solution 40 Part；

Polymerizable compound：Dipentaerythritol acrylate (KAYARAD (registration mark) DPHA；Japanese chemical drug (strain) System) 5.8 parts；

Polymerization initiator：N- benzoyls Oxy-1-(4- phenylsulfartyls phenyl) octane-1- ketone-2- imines (IRGACURE (registration mark) OXE01；BASF Japan company systems)

0.58 part；

Levelling agent：Polyether modified silicon oil (Toray Silicone SH8400；Dow Corning Toray Co.,Ltd. System) 0.010 part；

Solvent：47 parts of propylene glycol monomethyl ether；

Solvent：6.8 parts of propylene glycol monomethyl ether.

[formation of sublimability experiment resin coated film (SJSM)]

In glass substrate (the EAGLE XG of 2 inch squares；Corning company systems) on, passed through using spin-coating method coating upper The sublimability experiment resin combination (SJS) that the mode of stating obtains, in 100 DEG C, volatile ingredient was set to volatilize through 3 minutes.After cooling, Use exposure machine (TME-150RSK；Topcon Corporation systems), under air atmosphere, with 150mJ/cm²Light exposure (on the basis of 365nm) carries out light irradiation.In an oven, carry out heating for 2 hours in 220 DEG C, form sublimability experiment resin Coated film (SJSM) (2.2 μm of thickness).

Embodiment 2

Following substances are mixed, so as to obtain coloured composition 1,

Colouring agent (A)：14 parts of the compound that formula (I-2) represents；

Resin (B)：480 parts of 1 solution of resin B；

Solvent (E)：6.2 parts of propylene glycol monomethyl ether；

Solvent (E)：500 parts of METHYLPYRROLIDONE；And

Surfactant：Polyether modified silicon oil (Toray Silicone SH8400；Dow Corning Toray Co., Ltd. make) 0.063 part.

Embodiment 3

Following substances are mixed, so as to obtain coloured composition 2,

Colouring agent (A)：36 parts of the compound that formula (I-14) represents；

Resin (B)：410 parts of 1 solution of resin B；

Solvent (E)：6.2 parts of propylene glycol monomethyl ether；

Solvent (E)：540 parts of METHYLPYRROLIDONE；And

Embodiment 4

Following substances are mixed, so as to obtain coloured composition 3,

Colouring agent (A)：10 parts of the compound that formula (I-14) represents；

Resin (B)：97 parts of 2 solution of resin B；

Solvent (E)：180 parts of METHYLPYRROLIDONE；

Solvent (E)：26 parts of 4- hydroxy-4-methyl-2-pentanones；

Solvent (E)：2.0 parts of propylene glycol monomethyl ether；And

Surfactant：Polyether modified silicon oil (Toray Silicone SH8400；Dow Corning Toray Co., Ltd. make) 0.020 part.

Embodiment 5

Following substances are mixed,

Colouring agent (A)：10 parts of the compound that formula (I-14) represents,

Dispersant (BYK-LPN21324；BYK-Chemie Japan Co. Ltd. systems)

10 parts,

Resin (B)：11 parts of 1 solution of resin B, and

Solvent (E)：160 parts of propylene glycol monomethyl ether

Using ball mill, the compound that formula (I-14) represents is disperseed, so as to prepare coloured composition,

Following substances are mixed, so as to obtain coloured composition 4,

100 parts of the coloured composition prepared through the above way；

Resin (B)：55 parts of 1 solution of resin B；

Solvent (E)：3.6 parts of propylene glycol monomethyl ether；And

Surfactant：Polyether modified silicon oil (Toray Silicone SH8400；Dow Corning Toray Co., Ltd. make) 0.010 part.

Comparative example 1

Following substances are mixed, so as to obtain coloured composition 5,

Colouring agent (A)：11 parts of coumarin 6；

Resin (B)：350 parts of 2 solution of resin B；

Solvent (E)：6.2 parts of propylene glycol monomethyl ether；

Solvent (E)：630 parts of N,N-dimethylformamide；And

Surfactant：Polyether modified silicon oil (Toray Silicone SH8400；Dow Corning Toray Co., Ltd. make) 0.063 part

[sublimability evaluation]

Embodiment 6

In glass substrate (the EAGLE XG of 2 inch squares；Corning company systems) on, it is coated with colour cell using spin-coating method Compound 1,3 minutes prebake conditions then are carried out in 100 DEG C, form coloring compositions nitride layer.Made using Japanese vacuum technique (strain) DEKTAK3 determines thickness.Make the coloring coated film and the distillation obtained through the above way to separate the state at 70 μm of interval Property experiment with resin coated film (SJSM) relatively, in 220 DEG C carry out 40 minutes after toast.Use colour examining machine (OSP-SP-200； OLYMPUS company systems), aberration (Δ Eab*) of the measure sublimability experiment before and after the heating of resin coated film (SJSM).If color Poor (Δ Eab*) is more than 5.0, then it represents that colouring agent has sublimability.Show the result in table 12.In table 12, zero represents colouring agent Without sublimability, × expression colouring agent has sublimability.

Embodiment 7

Coloured composition 1 is replaced with into coloured composition 2, in addition, operates, is distilled similarly to Example 6 Property evaluation.Show the result in table 12.

Embodiment 8

Coloured composition 1 is replaced with into coloured composition 3, in addition, operates, is distilled similarly to Example 6 Property evaluation.Show the result in table 12.

Embodiment 9

Coloured composition 1 is replaced with into coloured composition 4, in addition, operates, is distilled similarly to Example 6 Property evaluation.Show the result in table 12.

Comparative example 2

Coloured composition 1 is replaced with into coloured composition 5, in addition, operates, is distilled similarly to Example 6 Property evaluation.Show the result in table 12.

[table 12]

	Thickness (μm)	Sublimability
			Embodiment 6	1.7	○
Embodiment 7	3.0	○
			Embodiment 8	2.5	○
Embodiment 9	2.2	○
			Comparative example 2	1.9	×

From above-mentioned result, for the coloured composition of the compound comprising the present invention, reduce colouring agent Distillation.

Embodiment 10

Following substances are mixed,

Colouring agent (A)：100 parts of the compound that formula (I-14) represents,

Dispersant (BYK-LPN21324；BYK-Chemie Japan (strain) make) 130 parts,

Resin (B)：170 parts of 4 solution of resin B, and

Solvent (E)：610 parts of propylene glycol monomethyl ether

Following substances are mixed,

380 parts of the coloured composition prepared through the above way,

Colouring agent (A)：C.I. 18 parts of pigment yellow 13 8 (pigment),

7.6 parts of dispersant,

7.6 parts of resin, and

Solvent (E)：120 parts of propylene glycol monomethyl ether

Using ball mill, pigment is disperseed, so as to prepare dispersible pigment dispersion,

Following substances are mixed, so as to obtain cured composition for color 1,

The whole amount of the dispersible pigment dispersion；

Colouring agent (A)：The compound that following formula represents (passes through the method described in Japanese Unexamined Patent Publication 2013-235257 publications And manufacture.) 4.2 parts；

Resin (B)：21 parts of 3 solution of resin B；

Polymerizable compound (C)：Polymerizable compound (A9550；Xin Zhong villages chemical industry (strain) is made)

25 parts；

Polymerization initiator (D)：The compound (Changzhou Tronly New Electronic Materials Co., Ltd.'s system) that following formula represents

6.6 part；

Solvent (E)：170 parts of 4- hydroxy-4-methyl-2-pentanones；

Solvent (E)：250 parts of propylene glycol monomethyl ether；And

Surfactant：Polyether modified silicon oil (Toray Silicone SH8400；Dow Corning Toray Co., Ltd. make) 0.075 part.

[making of colored pattern]

In glass substrate (the EAGLE XG of 2 inch squares；Corning company systems) on, it is solid using spin-coating method coating coloring The property changed composition 1, then carries out 3 minutes prebake conditions in 100 DEG C, forms cured composition for color layer.After cooling, make formed with The substrate of cured composition for color layer, at intervals of 200 μm, uses exposure machine (TME- with quartz glass photomask 150RSK；Topcon Corporation systems), under air atmosphere, with 80mJ/cm²Light exposure enter (on the basis of 365nm) Row exposure.It should be noted that as photomask, the line formed with 100 μm and intermittent pattern (line-and-space are used Pattern photomask).The cured composition for color layer after exposure is being contained into nonionic surfactants in 25 DEG C 0.12% and potassium hydroxide 0.04% the aqueous solution in impregnate 70 seconds and developed, washed.By the coloring coated film in 230 DEG C carry out 30 minutes after toast, thus, obtain colored pattern.

[sublimability evaluation]

In glass substrate (the EAGLE XG of 2 inch squares；Corning company systems) on, it is solid using spin-coating method coating coloring The property changed composition 1, then carries out 3 minutes prebake conditions in 100 DEG C, forms cured composition for color layer.After cooling, exposure is used Machine (TME-150RSK；Topcon Corporation systems), under air atmosphere, with 80mJ/cm²Light exposure (using 365nm as Benchmark) substrate formed with cured composition for color layer is exposed.The colored curable after exposure is combined in 25 DEG C Nitride layer impregnates 70 seconds and shown in the aqueous solution containing nonionic surfactants 0.12% and potassium hydroxide 0.04% Shadow, washed.

Use Japanese vacuum technique (strain) DEKTAK3 measure thickness processed.

The coloring coated film is set to test use with the sublimability obtained through the above way to separate the state at 70 μm of interval Resin coated film (SJSM) relatively, is toasted after being carried out 40 minutes in 220 DEG C.

Use colour examining machine (OSP-SP-200；OLYMPUS company systems) measure sublimability experiment use resin coated film (SJSM) Heating before and after aberration (Δ Eab*).If aberration (Δ Eab*) is more than 5.0, then it represents that colouring agent has sublimability.Will knot Fruit is shown in table 13.In table 13, zero expression colouring agent does not have sublimability, × represent that colouring agent has sublimability.

Embodiment 11

Following substances are mixed,

Colouring agent (A)：100 parts of the compound that formula (I-14) represents,

Dispersant (BYK-LPN21324；BYK-Chemie Japan (strain) make)

130 parts,

Resin (B)：170 parts of 4 solution of resin B, and

Solvent (E)：610 parts of propylene glycol monomethyl ether

Following substances are mixed,

340 parts of the coloured composition prepared through the above way,

Colouring agent (A)：C.I. 18 parts of pigment yellow 13 8 (pigment),

7.6 parts of dispersant,

7.6 parts of resin, and

Solvent (E)：120 parts of propylene glycol monomethyl ether

Following substances are mixed, so as to obtain cured composition for color 2,

The whole amount of the dispersible pigment dispersion；

Colouring agent (A)：The compound that following formula represents (passes through the method described in Japanese Unexamined Patent Publication 2013-235257 publications And manufacture.) 7.8 parts；

Resin (B)：27 parts of 3 solution of resin B；

26 parts；

6.8 part；

Solvent (E)：170 parts of 4- hydroxy-4-methyl-2-pentanones；

Solvent (E)：270 parts of propylene glycol monomethyl ether；And

Surfactant：Polyether modified silicon oil (Toray Silicone SH8400；Dow Corning Toray Co., Ltd. make) 0.075 part

Cured composition for color 1 is replaced with into cured composition for color 2, in addition, similarly to Example 10 Implement operation, carry out the making and sublimability evaluation of colored pattern.Sublimability evaluation result is shown in table 13.

Embodiment 12

Following substances are mixed,

Colouring agent (A)：100 parts of the compound that formula (I-14) represents,

Dispersant (BYK-LPN21324；BYK-Chemie Japan (strain) make) 130 parts,

Resin (B)：170 parts of 4 solution of resin B, and

Solvent (E)：610 parts of propylene glycol monomethyl ether

Following substances are mixed,

290 parts of the coloured composition prepared through the above way,

Colouring agent (A)：C.I. 23 parts of pigment yellow 13 8 (pigment),

9.6 parts of dispersant,

9.6 parts of resin, and

Solvent (E)：150 parts of propylene glycol monomethyl ether

Following substances are mixed, so as to obtain cured composition for color 3,

The whole amount of the dispersible pigment dispersion；

Colouring agent (A)：The compound that following formula represents (passes through the method described in Japanese Unexamined Patent Publication 2013-235257 publications And manufacture.) 5.1 parts；

Resin (B)：31 parts of 3 solution of resin B；

27 parts；

7.2 part；

Solvent (E)：170 parts of 4- hydroxy-4-methyl-2-pentanones；

Solvent (E)：280 parts of propylene glycol monomethyl ether；And

Cured composition for color 1 is replaced with into cured composition for color 3, in addition, similarly to Example 10 Implement operation, carry out the making and sublimability evaluation of colored pattern.Sublimability evaluation result is shown in table 13.

Embodiment 13

Following substances are mixed,

Colouring agent (A)：100 parts of the compound that formula (I-14) represents,

Dispersant (BYK-LPN21324；BYK-Chemie Japan (strain) make) 130 parts,

Resin (B)：170 parts of 4 solution of resin B, and

Solvent (E)：610 parts of propylene glycol monomethyl ether

Following substances are mixed,

270 parts of the coloured composition prepared through the above way,

Colouring agent (A)：C.I. 23 parts of pigment yellow 13 8 (pigment),

9.6 parts of dispersant,

9.6 parts of resin, and

Solvent (E)：150 parts of propylene glycol monomethyl ether

Following substances are mixed, so as to obtain cured composition for color 4,

The whole amount of the dispersible pigment dispersion；

Colouring agent (A)：The compound that following formula represents (passes through the method described in Japanese Unexamined Patent Publication 2013-235257 publications And manufacture.) 7.4 parts；

Resin (B)：35 parts of 3 solution of resin B；

27 parts；

7.3 part；

Solvent (E)：170 parts of 4- hydroxy-4-methyl-2-pentanones；

Solvent (E)：290 parts of propylene glycol monomethyl ether；And

Cured composition for color 1 is replaced with into cured composition for color 4, in addition, similarly to Example 10 Implement operation, carry out the making and sublimability evaluation of colored pattern.Sublimability evaluation result is shown in table 13.

Embodiment 14

The compound that formula (I-14) represents is replaced with to the compound of formula (I-2) expression, it is in addition, same with embodiment 10 Implement to operate sample, obtain cured composition for color 5, carry out the making and sublimability evaluation of colored pattern.Sublimability is commented Valency result is shown in table 13.

Embodiment 15

The compound that formula (I-14) represents is replaced with to the compound of formula (I-2) expression, it is in addition, same with embodiment 13 Implement to operate sample, obtain cured composition for color 6, carry out the making and sublimability evaluation of colored pattern.Sublimability is commented Valency result is shown in table 13.

Comparative example 3

The compound that formula (I-14) represents is replaced with into coumarin 6, in addition, implements behaviour similarly to Example 10 Make, obtain cured composition for color 7, carry out the making and sublimability evaluation of colored pattern.Sublimability evaluation result is shown in Table 13.

Comparative example 4

The compound that formula (I-14) represents is replaced with into coumarin 6, in addition, implements behaviour similarly to Example 13 Make, obtain cured composition for color 8, carry out the making and sublimability evaluation of colored pattern.Sublimability evaluation result is shown in Table 13.

[table 13]

	Thickness (μm)	Sublimability
			Embodiment 10	2.5	○
Embodiment 11	2.5	○
			Embodiment 12	2.5	○
Embodiment 13	2.5	○
			Embodiment 14	2.5	○
Embodiment 15	2.5	○
			Comparative example 3	2.5	×
Comparative example 4	2.5	×

From above-mentioned result, for the cured composition for color of the compound comprising the present invention, reduce The distillation of colouring agent.

Industrial applicability

Coloured composition, the cured composition for color of the present invention can reduce the sublimability of colouring agent, can suitably use In display devices such as colour filter, liquid crystal display devices.

Claims

1. coloured composition, it includes compound and the resin that formula (I) represents,

In formula (I),

R^N1And R^N2Represent there can be the aliphatic alkyl that the carbon number of substituent is 1~40 independently of each other；

R^N3Represent can the carbon number with substituent for 1~40 alkyl or can the heterocyclic radical with substituent；

R¹~R⁸Hydrogen atom ,-CO-R are represented independently of each other¹⁰²、-COO-R¹⁰¹、-OCO-R¹⁰²、-COCO-R¹⁰²、-O-R¹⁰²、- SO₂-R¹⁰¹、-SO₂N(R¹⁰²)₂、-CON(R¹⁰²)₂、-N(R¹⁰²)₂、-NHCO-R¹⁰²、-NHCO-N(R¹⁰²)₂、-NHCOOR¹⁰²、-OCON (R¹⁰²)₂, halogen atom, cyano group, nitro ,-SO₃M、-CO₂M, can have substituent carbon number be 1~40 alkyl or There can be the heterocyclic radical of substituent；

R¹⁰¹Represent can the carbon number with substituent for 1~40 alkyl or can the heterocyclic radical with substituent；R¹⁰² Represent hydrogen atom, can the carbon number with substituent for 1~40 alkyl or can the heterocyclic radical with substituent；M tables Show hydrogen atom or alkali metal atom；

R¹⁰¹、R¹⁰²And M exist it is multiple in the case of, they can be the same or different；

A^g-Represent the anion of g valencys；G represents 1~14 integer.

2. coloured composition as claimed in claim 1, wherein, A^g-For containing in the group being made up of tungsten, molybdenum, silicon and phosphorus The anion or fluo anion of at least one kind of element and oxygen as indispensable element.

3. coloured composition as claimed in claim 1 or 2, wherein, A^g-For containing in the group being made up of tungsten and phosphorus extremely The few anion or fluo anion of a kind of element and oxygen as indispensable element.

4. such as coloured composition according to any one of claims 1 to 3, wherein, A^g-Containing selected from being made up of tungsten and phosphorus The anion of at least one kind of element and oxygen as indispensable element in group.

5. such as coloured composition according to any one of claims 1 to 4, wherein, R^N1And R^N2Can independently of one another have The carbon number of substituent is 1~10 alkyl.

6. such as coloured composition according to any one of claims 1 to 5, the coloured composition also includes solvent.

7. such as coloured composition according to any one of claims 1 to 6, the coloured composition also comprising yellow colorants, Orange colorant or red stain.

8. cured composition for color, it includes coloured composition according to any one of claims 1 to 7 and polymerism Compound.

9. cured composition for color as claimed in claim 8, the cured composition for color also includes polymerization initiator.

10. colour filter, it is as described in coloured composition according to any one of claims 1 to 7 or claim 8 or 9 Cured composition for color formed.

11. liquid crystal display device, it includes the colour filter described in claim 10.

12. the compound that formula (I-B) represents,

In formula (I-B),

R¹⁰¹Represent can the carbon number with substituent for 1~40 alkyl or can the heterocyclic radical with substituent；

R¹⁰²Represent hydrogen atom, can the carbon number with substituent for 1~40 alkyl or can the heterocycle with substituent Base；

M represents hydrogen atom or alkali metal atom；

B^h-Expression contains the h valencys of at least one kind of element and oxygen as indispensable element in the group being made up of tungsten, molybdenum, silicon and phosphorus Anion；

H represents 1~14 integer.

13. compound as claimed in claim 12, wherein, B^h-For containing at least one kind of in the group being made up of tungsten and phosphorus The anion of element and oxygen as indispensable element.

14. the compound as described in claim 12 or 13, wherein, R^N1And R^N2Can independently of one another have the carbon of substituent Atomicity is 1~10 alkyl.