CN107797339A - A kind of quantum dot film with interior journey of adding lustre to - Google Patents

A kind of quantum dot film with interior journey of adding lustre to Download PDF

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Publication number
CN107797339A
CN107797339A CN201711308354.2A CN201711308354A CN107797339A CN 107797339 A CN107797339 A CN 107797339A CN 201711308354 A CN201711308354 A CN 201711308354A CN 107797339 A CN107797339 A CN 107797339A
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CN
China
Prior art keywords
polymer
layer
quantum dot
glue
microprism
Prior art date
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Pending
Application number
CN201711308354.2A
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Chinese (zh)
Inventor
王新辉
邱晓华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Wei Erison Mstar Technology Ltd
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Nantong Wei Erison Mstar Technology Ltd
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Priority to CN201711308354.2A priority Critical patent/CN107797339A/en
Publication of CN107797339A publication Critical patent/CN107797339A/en
Pending legal-status Critical Current

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/1336Illuminating devices
    • G02F1/133602Direct backlight
    • G02F1/133606Direct backlight including a specially adapted diffusing, scattering or light controlling members
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/1336Illuminating devices
    • G02F1/133602Direct backlight
    • G02F1/133603Direct backlight with LEDs
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/1336Illuminating devices
    • G02F1/133602Direct backlight
    • G02F1/133606Direct backlight including a specially adapted diffusing, scattering or light controlling members
    • G02F1/133607Direct backlight including a specially adapted diffusing, scattering or light controlling members the light controlling member including light directing or refracting elements, e.g. prisms or lenses
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/1336Illuminating devices
    • G02F1/133614Illuminating devices using photoluminescence, e.g. phosphors illuminated by UV or blue light

Abstract

The present invention relates to a kind of quantum dot film with interior journey of adding lustre to, it includes two layers of polymer membrane;The polymer membrane includes macromolecule basement membrane, and the side surface of basement membrane one is provided with diffusion particle coating or Microstructure Optics diffusion structure layer, and another side surface of basement membrane is provided with barrier layer, and microprism lattice layer is provided with barrier layer;It is bonded face-to-face by third polymer glue polymerizing curable between the microprism lattice layer of two layers of polymer membrane.Advantage is reasonable in design, and simple in construction, beneficial to effective solidification with quanta point material polymer latex, and solidification energy is relatively low, and process is easily controlled;Chance of the light with quantum dot collision excitation in quantum dot layer is added, effectively reduces the dosage of quanta point material, and the overall thickness of quantum dot layer can be lowered, beneficial to the slim and extra-thin quantum dot film of manufacture.

Description

A kind of quantum dot film with interior journey of adding lustre to
Technical field
The present invention relates to optical sheet field, and in particular to has the quantum dot film of interior journey of adding lustre to.
Background technology
In the flat display equipment of liquid crystal, the white light that backlight needs is that have the blue-ray LED coated with fluorescer to produce.Pass through With the reasonably combined backlight realized needed for LCD panel of light guide plate and blooming piece.The blue-ray LED collocation of generally use Yellow fluorescent powder, the white light finally sent have that color is partially blue, and colour purity is not high, and color saturation is too low and color gamut value mistake It is low.With the development of media, image technique, flat panel display requirement of the people to high colour gamut, high color saturation, energy-conservation is got over Come higher.
The quanta point material of Nano grade can be excited by blue violet light, convert glow color, bring display and more more force Genuine color scene, greatly extend the existing ability in color surface of traditional LCD displays.
The quantum dot optical thin film made using quanta point material is applied in liquid crystal flat-panel display device, is placed directly within the back of the body Optical mode group, excited by blue-ray LED light, produce R, G spectral line of optimization, in the case where not making very big change to original device, pole The color capabilities of big change display device, it is a kind of extremely promising and technology of development prospect.
The content of the invention
To solve the above problems, the present invention proposes a kind of quantum dot film with interior journey of adding lustre to, reasonable in design, structure letter Single, beneficial to effective solidification with quanta point material polymer latex, and solidification energy is relatively low, and process is easily controlled;Add Chance of the light in quantum dot layer with quantum dot collision excitation, effectively reduces the dosage of quanta point material, and can lower The overall thickness of quantum dot layer, thickness evenness is excellent, while beneficial to the slim and extra-thin quantum dot film of manufacture.
Technical solution of the present invention:
A kind of quantum dot film with interior journey of adding lustre to, it includes two layers of polymer membrane;The polymer membrane Including macromolecule basement membrane, one layer of side surface of polymer membrane basement membrane one is provided with diffusion particle coating or Microstructure Optics Diffusion structure layer, another side surface of basement membrane is provided with barrier layer, and microprism lattice layer is provided with barrier layer, another floor height The side surface of Molecularly Imprinted Polymer film basement membrane one is not provided with either being provided with diffusion particle coating or Microstructure Optics diffusion structure layer, Another side surface of basement membrane is provided with barrier layer, and microprism lattice layer is provided with barrier layer;Two layers of high molecular polymerization It is bonded face-to-face by third polymer glue polymerizing curable between the microprism lattice layer of thing film.
The barrier layer is that either Vacuum Deposition forms on basement membrane or is a floor height molecular optics film for barrier material coating Layer.
The optical film uses the single layer structure with barrier or the multi-layer compound structure with barrier.
The barrier material includes high barrier material, earth silicon material, alumina material.
The basement membrane, optical film use high polymer material, high polymer material be polyethylene terephthalate or Person's polyimides.
The microprism lattice layer is made using lattice material by ultraviolet forming technology, and lattice material is the first polymerization Thing glue or second polymer glue, microprism lattice layer microprism height is in 3um-100um, 45-130 ° of corner angle, and two layers Microprism lattice layer is parallel or differs an angle.
The first polymer glue is the polymer latex with quanta point material, refractive index n1;Second polymer glue is Polymer latex with quanta point material, refractive index n2;Third polymer glue is the polymer latex with quanta point material, folding It is n3 to penetrate rate.
The polymer latex with quanta point material is that acrylate polymer, epoxide resin polymer and solidification trigger Agent.
The Microstructure Optics diffusion structure layer irradiates polymerization or heat cure mode by ultraviolet shaping glue by ultraviolet It is made, ultraviolet shaping glue is made up of series of acrylate polymer and light trigger.
The third polymer glue connects two layers of polyphosphazene polymer by ultraviolet light polymerizing curable or heat cure mode Compound film.
The method have the advantages that it is reasonable in design, it is simple in construction, using elder generation respectively in two layers of polymer membrane side table Face is passed through by first polymer glue or second polymer glue ultra-violet curing microprism lattice layer again between microprism lattice layer Third polymer glue carries out ultra-violet curing, is so solidified step by step, glue-line is relatively thin, beneficial to quanta point material polymer latex Effective solidification, and solidification energy is relatively low, and process is easily controlled;Utilize the microprism lattice layer for being arranged on the side surface of basement membrane one Play a part of increasing light propagation path in quantum dot layer, add light in quantum dot layer and quantum dot collision excitation Chance, effectively reduce the dosage of quanta point material, and the overall thickness of quantum dot layer can be lowered, beneficial to manufacture it is slim and Extra-thin quantum dot film, the uniform type of quantum dot film product thickness are excellent.
Brief description of the drawings
Fig. 1 is polymer membrane structural representation of the present invention.
Fig. 2 is schematic structural view of the invention(1).
Fig. 3 is schematic structural view of the invention(2).
Fig. 4 is Making programme figure of the present invention.
Embodiment
Referring to the drawings 1-4, a kind of quantum dot film with interior journey of adding lustre to, it includes two layers of polymer membrane;Institute Stating polymer membrane includes macromolecule basement membrane 01, and one layer of side surface of polymer membrane basement membrane 01 1 is provided with diffusion grain Sub- coating or Microstructure Optics diffusion structure layer 02,01 another side surface of basement membrane are provided with barrier layer 03, and in barrier layer 03 On be provided with microprism lattice layer, another layer of side surface of polymer membrane basement membrane 01 1 is not provided with or is provided with diffusion grain Sub- coating or Microstructure Optics diffusion structure layer 02,01 another side surface of basement membrane are provided with barrier layer 03, and in barrier layer 03 On be provided with microprism lattice layer;Pass through the 3rd face-to-face between the microprism lattice layer 04 of two layers of polymer membrane The polymerizing curable of polymer latex 05 is bonded.
The barrier layer 03 is that either Vacuum Deposition forms on basement membrane or is a floor height molecular optics for barrier material coating Film layer.
The optical film uses the single layer structure with barrier or the multi-layer compound structure with barrier.
The barrier material includes high barrier material, earth silicon material, alumina material.
The basement membrane 01, optical film use high polymer material, and high polymer material is polyethylene terephthalate Or polyimides.
The microprism lattice layer 04 is made using lattice material by ultraviolet forming technology, and lattice material is first poly- Compound glue or second polymer glue, the microprism of microprism lattice layer 04 height is in 3um-100um, 45-130 ° of corner angle, and Two layers of microprism lattice layer 04 is parallel or differs an angle.
The first polymer glue is the polymer latex with quanta point material, refractive index n1;Second polymer glue is Polymer latex with quanta point material, refractive index n2;Third polymer glue 05 is the polymer latex with quanta point material, Refractive index is n3.
The polymer latex with quanta point material is that acrylate polymer, epoxide resin polymer and solidification trigger Agent.
The Microstructure Optics diffusion structure layer 02 irradiates polymerization or heat cure side by ultraviolet shaping glue by ultraviolet Formula is made, and ultraviolet shaping glue is made up of series of acrylate polymer and light trigger.
The third polymer glue 05 connects two layers of polymer membrane by ultraviolet light polymerizing curable.
Making programme of the present invention, first make Microstructure Optics diffusion structure in the side surface of polymer membrane basement membrane 01 1 Layer 02 or coating diffusion particle coating, make barrier layer 03 in 01 another side surface of polymer membrane basement membrane, are obstructing Layer 03 makes microprism lattice layer 04, two layers of polymer membrane microprism with first polymer glue or second polymer glue Ultra-violet curing is carried out by third polymer glue 05 between lattice layer 04 and synthesizes quantum dot film product.
The method have the advantages that it is reasonable in design, it is simple in construction, using elder generation respectively in two layers of polymer membrane side table Face is by first polymer glue or second polymer glue ultra-violet curing microprism lattice layer 04, between microprism lattice layer 04 again Ultra-violet curing is carried out by third polymer glue 05, such branch is solidified, and glue-line is relatively thin, gathers beneficial to quanta point material Effective solidification of compound glue, and solidification energy is relatively low, and process is easily controlled;Utilize the micro- rib for being arranged on the side surface of basement membrane 01 1 Mirror lattice layer 04 plays a part of increasing light propagation path in quantum dot layer, adds light in quantum dot layer and quantum The chance of point collision excitation, effectively reduces the dosage of quanta point material, and can lower the overall thickness of quantum dot layer, is beneficial to Manufacture slim and extra-thin quantum dot film.

Claims (10)

1. a kind of quantum dot film with interior journey of adding lustre to, it is characterised in that it includes two layers of polymer membrane;The height Molecularly Imprinted Polymer film includes macromolecule basement membrane, one layer of side surface of polymer membrane basement membrane one be provided with diffusion particle coating or Person's Microstructure Optics diffusion structure layer, another side surface of basement membrane are provided with barrier layer, and microprism point is provided with barrier layer Battle array layer, another layer of side surface of polymer membrane basement membrane one is not provided with either being provided with diffusion particle coating or micro-structural light Diffusion structure layer is learned, another side surface of basement membrane is provided with barrier layer, and microprism lattice layer is provided with barrier layer;Described two It is bonded face-to-face by third polymer glue polymerizing curable between the microprism lattice layer of layer polymer membrane.
A kind of 2. quantum dot film with interior journey of adding lustre to according to claim 1, it is characterized in that the barrier layer is resistance Either Vacuum Deposition forms on basement membrane or is a floor height molecular optics film layer for barrier material coating.
A kind of 3. quantum dot film with interior journey of adding lustre to according to claim 2, it is characterized in that the optical film is adopted With the single layer structure with barrier or the multi-layer compound structure with barrier.
A kind of 4. quantum dot film with interior journey of adding lustre to according to claim 2, it is characterized in that the barrier material bag Include high barrier material, earth silicon material, alumina material.
A kind of 5. quantum dot film with interior journey of adding lustre to according to claim 1, it is characterized in that the basement membrane, optical film Layer uses high polymer material, and high polymer material is polyethylene terephthalate or polyimides.
A kind of 6. quantum dot film with interior journey of adding lustre to according to claim 1, it is characterized in that the microprism dot matrix Layer is made using lattice material by ultraviolet forming technology, and lattice material is first polymer glue or second polymer glue, Microprism lattice layer microprism height 3um-100um, 45-130 ° of corner angle, and two layers of microprism lattice layer it is parallel or Differ an angle.
A kind of 7. quantum dot film with interior journey of adding lustre to according to claim 6, it is characterized in that the first polymer Glue is the polymer latex with quanta point material, refractive index n1;Second polymer glue is the polymer with quanta point material Glue, refractive index n2;Third polymer glue is the polymer latex with quanta point material, refractive index n3.
A kind of 8. quantum dot film with interior journey of adding lustre to according to claim 7, it is characterized in that described have quantum dot The polymer latex of material is acrylate polymer, epoxide resin polymer and curing initiator.
A kind of 9. quantum dot film with interior journey of adding lustre to according to claim 1, it is characterized in that the Microstructure Optics Diffusion structure layer irradiates polymerization by ultraviolet by ultraviolet shaping glue or heat cure mode is made, and ultraviolet shaping glue is by acrylic acid Ester series polymer and light trigger composition.
A kind of 10. quantum dot film with interior journey of adding lustre to according to claim 1, it is characterized in that the third polymer Glue connects two layers of polymer membrane by ultraviolet light polymerizing curable or heat cure mode.
CN201711308354.2A 2017-12-11 2017-12-11 A kind of quantum dot film with interior journey of adding lustre to Pending CN107797339A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107718819A (en) * 2017-12-11 2018-02-23 南通惟怡新材料科技有限公司 One kind has lattice structure lenticule multi-layer quantum point film
CN113777681A (en) * 2021-09-09 2021-12-10 东莞市锦富丽新材料科技有限公司 Brightness enhancement film and manufacturing method thereof

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Publication number Priority date Publication date Assignee Title
CN103487857A (en) * 2013-10-11 2014-01-01 张家港康得新光电材料有限公司 Quantum dot film and backlight module
KR20160089695A (en) * 2015-01-20 2016-07-28 (주)이노큐디 Composite Quantum Dot Prism Sheet with coating layer with air gap
CN105891922A (en) * 2016-06-08 2016-08-24 汕头万顺包装材料股份有限公司 Quantum dot film product and producing method thereof
TW201634954A (en) * 2015-03-31 2016-10-01 華宏新技股份有限公司 Multi-function optical film
CN106903945A (en) * 2016-08-05 2017-06-30 宁波长阳科技股份有限公司 A kind of quantum dot film of wide colour gamut and preparation method thereof
CN107057679A (en) * 2017-05-10 2017-08-18 南通天鸿镭射科技有限公司 A kind of quantum dot membrane product and preparation method thereof
CN207882624U (en) * 2017-12-11 2018-09-18 南通惟怡新材料科技有限公司 A kind of quantum dot film with interior journey of adding lustre to

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103487857A (en) * 2013-10-11 2014-01-01 张家港康得新光电材料有限公司 Quantum dot film and backlight module
KR20160089695A (en) * 2015-01-20 2016-07-28 (주)이노큐디 Composite Quantum Dot Prism Sheet with coating layer with air gap
TW201634954A (en) * 2015-03-31 2016-10-01 華宏新技股份有限公司 Multi-function optical film
CN105891922A (en) * 2016-06-08 2016-08-24 汕头万顺包装材料股份有限公司 Quantum dot film product and producing method thereof
CN106903945A (en) * 2016-08-05 2017-06-30 宁波长阳科技股份有限公司 A kind of quantum dot film of wide colour gamut and preparation method thereof
CN107057679A (en) * 2017-05-10 2017-08-18 南通天鸿镭射科技有限公司 A kind of quantum dot membrane product and preparation method thereof
CN207882624U (en) * 2017-12-11 2018-09-18 南通惟怡新材料科技有限公司 A kind of quantum dot film with interior journey of adding lustre to

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107718819A (en) * 2017-12-11 2018-02-23 南通惟怡新材料科技有限公司 One kind has lattice structure lenticule multi-layer quantum point film
CN113777681A (en) * 2021-09-09 2021-12-10 东莞市锦富丽新材料科技有限公司 Brightness enhancement film and manufacturing method thereof

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