CN107794762A - One kind processing tweed softening agent and preparation method thereof - Google Patents

One kind processing tweed softening agent and preparation method thereof Download PDF

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Publication number
CN107794762A
CN107794762A CN201711112931.0A CN201711112931A CN107794762A CN 107794762 A CN107794762 A CN 107794762A CN 201711112931 A CN201711112931 A CN 201711112931A CN 107794762 A CN107794762 A CN 107794762A
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parts
softening agent
sodium
tweed
polyvinyl alcohol
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汪卫芬
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Anhui Chuan Rong Garment Accessories Co Ltd
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Anhui Chuan Rong Garment Accessories Co Ltd
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
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    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
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    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
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    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

One kind processing tweed softening agent, is made up of following raw material：APES, octamethylcyclotetrasiloxane, APEO, odium stearate, sodium benzoate, HYDROXY PROPYL METHYLCELLULOSE, polyvinyl alcohol, enuatrol, sodium tripolyphosphate, lauryl sodium sulfate, citric acid, organosilicon, sulfonated castor oil, magnesium chloride, calcium monohydrogen phosphate, 2,3 dyhydrobutanedioic acids, triethanolamine, water；Its preparation method mainly above raw material is reacted successively according to certain order, finally give solution be mixed evenly produce it is described processing tweed softening agent.Beneficial effects of the present invention are：(1) finally caused bating effect is good for the invention, and the lint cloth handled by the softening agent is more soft and fluffy, and feel is good, and persistence is also grown；(2) preparation method of the softening agent is simple, and preparation cost is low, while the softening agent prepared is to environment and human body non-hazardous, environmental protection safe to use.

Description

One kind processing tweed softening agent and preparation method thereof
Technical field
The present invention relates to garment accessories field, and in particular to one kind processing tweed softening agent and preparation method thereof.
Background technology
Clothes are an engineerings, including design, are made, and wherein the various links of manufacturing process point, a most important link are exactly Material is selected, in material again facet material cloth and other auxiliary materials.We are referred to as garment accessories to this other auxiliary material, and it is in addition to fabric Decorate clothes and extend the essential element of clothing function.
Clothes are an engineerings, including make and design, and wherein many links of manufacturing process point, a most important link are exactly Material is selected, facet material cloth and other auxiliary materials again in material.We are referred to as garment accessories to other auxiliary materials said herein, and it is In addition to fabric, extension clothing function and the essential element for decorating clothes, including:Slide fastener, button, ribbon, shoulder pad, lace, Lining cloth, lining, clothes hanger, drop, ornaments, filler rod, tailor's chalk, fastener, fur, trade mark, cotton rope, filler, plastic fittings, metal are matched somebody with somebody Part, Packing chest bag, marking bar code and other correlations etc..
(suppor materials include garment accessories:Lining matrix liner material sewing wire material fastening material decoration material Expect slide fastener button ribbon shoulder pad lace lining cloth lining clothes hanger drop ornaments filler rod tailor's chalk fastener fur trade mark cotton rope filler plastics Accessory metal fittings Packing chest bag marking bar code and other correlations etc..
All these auxiliary materials, no matter the inherent quality pair with clothes, or external quality suffers from material impact.Such as: Lining, sewing thread are mainly the inherent quality for influenceing clothes, and affect clothes uses firmness, also functions to certain dress certainly Decorations act on.And wadding, lace etc. are primarily used to decorate clothes.
The quality of a set of dress designing, auxiliary material often play a significantly greater role, and work and have been even more than fabric in itself.It is auxiliary The appropriate mix of material, it can play a part of adding a crucial touch, get twice the result with half the effort, and conversely, can only draw a snake and add feet to it.
When forming clothes, all materials being used in addition to fabric on clothes are referred to as garment accessories.Existed according to auxiliary material Effect difference played in clothes can be classified as lining, wadding, filler, sewing thread, fastening material, ornament materials, mark Will material, packaging material etc..
When producing some lint clothes, the problems such as cloth feel is bad, not soft enough often occurs, then general meeting Use softening agent.Wherein, softening agent, also known as softening agent, the entitled Softener of English.For increasing textile, rubber, skin The material of the flexibility of leather, paper etc..Conventional after-treating auxiliary of the softening agent as fabric, application have generation more than half so far To record, development is very fast, and it develops into high molecular polymerization species softening agent from earliest surfactant-based softening agent, and from height Molecular polyethylene wax develops into organosilicon polymer, and develops into hydroxy-terminated polysiloxane breast from aqueous emulsion of dimethyl polysiloxane fluid Liquid, Hydrophilic Silicone Micro Emulsion, amino silicones emulsion, amino silicones micro emulsion, low-yellowing amino-modified silicone Softening agent, hydrophilic amino silicone softening agent and ultra-smooth amino modified polysiloxane etc..Cationic softener is to use Widest a kind of, it can divide quaternary, fatty acid ester type, right wax pattern, polyethylene, organic siliconresin type etc. again, wherein Quaternary softening agent occupies larger specific gravity in cationic softener, mainly there is monoalkyl quaternary ammonium salts, dialkyl quats salt, alkane Base acyl group quaternary ammonium salt, pyridine quaternary ammonium salt type and imidazole type softening agent etc., monoalkyl season in presently used quaternary softening agent Ammonium salt is gradually eliminated because toxicity is big, biological degradability is poor etc.；The toxicity of dialkyl quats salt and alkyl acyl quaternary ammonium salt Though lower than monoalkyl quaternary ammonium salts, its biological degradability is very poor, can kill biological bacteria and easily be absorbed in sewage disposal by sludge And polluted agricultural land, therefore stopped using in states such as Germany, Holland in the early 1990s in last century, European Union was 2002 year May 15 Double [hydrogenated tallow alkyl] alkyl dimethyl ammonium chloride, double [stearyl] diformazans are clearly prohibitted the use of in the Eco-Label of day issue Ammonium chloride and double [tallow alkyl] alkyl dimethyl ammonium chlorides and the preparation or formula that are made up of them；As for imidazole type (such as softness Agent IS) and the BOD of pyridine quaternary ammonium salt type (such as VelanPF) cationic softener it is small, with traditional biochemical process come handle drop Solve relatively difficult, although currently without disabling, by ecological requirements, their use is also problematic in that.
Wherein, cost is big, and preparation method is complicated, and bating effect is not sufficiently good, and persistence is shorter, and environment is produced simultaneously The factors such as negatively influencing, all it is the problem of will overcoming in the prior art.
The content of the invention
The invention aims to overcome deficiency of the prior art, there is provided one kind processing tweed softening agent and its Preparation method.
In order to solve the above technical problems, the technical scheme is that：
One kind processing tweed softening agent, is made up of following parts by weight raw material：25-35 part alkylphenol-polyethenoxies Ether, 10-20 part octamethylcyclotetrasiloxanes, 10-20 part APEOs, 4-8 part odium stearate, 7-9 part sodium benzoates, 3-5 parts HYDROXY PROPYL METHYLCELLULOSE, 8-10 part polyvinyl alcohol, 3-5 part enuatrols, 3-5 part sodium tripolyphosphates, 3-5 part dodecyl sulphur Sour sodium, 25-35 part citric acids, 10-14 part organosilicons, 4-8 part sulfonated castor oils, 3-5 part magnesium chlorides, 6-8 part calcium monohydrogen phosphates, 2- 4 parts of 2,3- dyhydrobutanedioic acids, 1-3 part triethanolamines, 60-80 part water.
Further, it is made up of following parts by weight raw material：25 parts of APESs, 10 parts of silica of prestox four Alkane, 10 parts of APEOs, 4 parts of odium stearate, 7 parts of sodium benzoates, 3 parts of HYDROXY PROPYL METHYLCELLULOSEs, 8 parts of polyvinyl alcohol, 3 Part enuatrol, 3 parts of sodium tripolyphosphates, 3 parts of lauryl sodium sulfate, 25 parts of citric acids, 10 parts of organosilicons, 4 portions of sulfonated castor oils, 3 parts of magnesium chlorides, 6 parts of calcium monohydrogen phosphates, 2 parts of 2,3- dyhydrobutanedioic acids, 1 part of triethanolamine, 60 parts of water.
Further, it is made up of following parts by weight raw material：35 parts of APESs, 20 parts of silica of prestox four Alkane, 20 parts of APEOs, 8 parts of odium stearate, 9 parts of sodium benzoates, 5 parts of HYDROXY PROPYL METHYLCELLULOSEs, 10 parts of polyvinyl alcohol, 5 parts of enuatrols, 5 parts of sodium tripolyphosphates, 5 parts of lauryl sodium sulfate, 35 parts of citric acids, 14 parts of organosilicons, 8 parts of sulfonation castor-oil plants Oil, 5 parts of magnesium chlorides, 8 parts of calcium monohydrogen phosphates, 4 parts of 2,3- dyhydrobutanedioic acids, 3 parts of triethanolamines, 80 parts of water.
Further, it is made up of following parts by weight raw material：30 parts of APESs, 15 parts of silica of prestox four Alkane, 15 parts of APEOs, 6 parts of odium stearate, 8 parts of sodium benzoates, 4 parts of HYDROXY PROPYL METHYLCELLULOSEs, 9 parts of polyvinyl alcohol, 4 Part enuatrol, 4 parts of sodium tripolyphosphates, 4 parts of lauryl sodium sulfate, 30 parts of citric acids, 12 parts of organosilicons, 6 portions of sulfonated castor oils, 4 parts of magnesium chlorides, 7 parts of calcium monohydrogen phosphates, 3 parts of 2,3- dyhydrobutanedioic acids, 2 parts of triethanolamines, 70 parts of water.
A kind of method for preparing above-mentioned processing tweed softening agent, comprises the following steps：By the alkane of above-mentioned parts by weight Base phenol polyethenoxy ether, APEO and water are under pH value 9-10 alkalescence condition, and temperature is 75-85 DEG C of reaction 6-8h, so It is gradually heating to 95-105 DEG C again afterwards to continue to react 6-8h, obtains mixed solution A；By the octamethylcyclotetrasiloxane of above-mentioned parts by weight With polyvinyl alcohol under pH value 8-9 alkalescence condition, temperature is 110-120 DEG C of reaction 4-6h, is then gradually cooled to 70-80 DEG C, above-mentioned citric acid is added dropwise it is neutralized, until when pH value is down to 6-7, obtain mixed solution B；By above-mentioned mixed solution A and For mixed solution B in the case where pH value is 8-9 alkalescence condition, temperature is 80-90 DEG C of reaction 3-4h, is down to room temperature；Obtained by upward step The odium stearate of above-mentioned parts by weight, sodium benzoate, HYDROXY PROPYL METHYLCELLULOSE, enuatrol, trimerization are sequentially added in solution Sodium phosphate, lauryl sodium sulfate, organosilicon, sulfonated castor oil, magnesium chloride, calcium monohydrogen phosphate, 2,3- dyhydrobutanedioic acids and three Monoethanolamine, stir and produce the processing tweed softening agent.
Beneficial effects of the present invention are：(1) finally caused bating effect is good for the invention, is handled by the softening agent Lint cloth is more soft and fluffy, and feel is good, and persistence is also grown；(2) preparation method of the softening agent is simple, prepares Cost is low, while the softening agent prepared is to environment and human body non-hazardous, environmental protection safe to use.
Embodiment
The effect of to make to architectural feature of the invention and being reached, has a better understanding and awareness, to preferable Embodiment coordinates detailed description, is described as follows：
Embodiment 1
One kind processing tweed softening agent, is made up of following parts by weight raw material：25 parts of APESs, 10 Part octamethylcyclotetrasiloxane, 10 parts of APEOs, 4 parts of odium stearate, 7 parts of sodium benzoates, 3 parts of hydroxypropyl methyl celluloses Element, 8 parts of polyvinyl alcohol, 3 parts of enuatrols, 3 parts of sodium tripolyphosphates, 3 parts of lauryl sodium sulfate, 25 parts of citric acids, 10 parts organic Silicon, 4 portions of sulfonated castor oils, 3 parts of magnesium chlorides, 6 parts of calcium monohydrogen phosphates, 2 parts of 2,3- dyhydrobutanedioic acids, 1 part of triethanolamine, 60 parts Water.
A kind of method for preparing above-mentioned processing tweed softening agent, comprises the following steps：By the alkane of above-mentioned parts by weight Under the alkalescence condition of pH value 9, temperature is 75 DEG C and reacts 6h, then gradual again for base phenol polyethenoxy ether, APEO and water It is warming up to 95 DEG C to continue to react 6h, obtains mixed solution A；By the octamethylcyclotetrasiloxane of above-mentioned parts by weight and polyvinyl alcohol in PH Under the alkalescence condition of value 8, temperature is 110 DEG C of reaction 4h, is then gradually cooled to 70 DEG C, above-mentioned citric acid is added dropwise it is neutralized, Until when pH value is down to 6, mixed solution B is obtained；By above-mentioned mixed solution A and mixed solution B in the alkalescence condition that pH value is 8 Under, temperature is 80 DEG C of reaction 3h, is down to room temperature；The stearic acid of above-mentioned parts by weight is sequentially added in upward step resulting solution Sodium, sodium benzoate, HYDROXY PROPYL METHYLCELLULOSE, enuatrol, sodium tripolyphosphate, lauryl sodium sulfate, organosilicon, sulfonation castor Sesame oil, magnesium chloride, calcium monohydrogen phosphate, 2,3- dyhydrobutanedioic acids and triethanolamine, stir and produce the processing lint Cloth softening agent.
Embodiment 2
One kind processing tweed softening agent, is made up of following parts by weight raw material：35 parts of APESs, 20 Part octamethylcyclotetrasiloxane, 20 parts of APEOs, 8 parts of odium stearate, 9 parts of sodium benzoates, 5 parts of hydroxypropyl methyl celluloses Element, 10 parts of polyvinyl alcohol, 5 parts of enuatrols, 5 parts of sodium tripolyphosphates, 5 parts of lauryl sodium sulfate, 35 parts of citric acids, 14 parts organic Silicon, 8 portions of sulfonated castor oils, 5 parts of magnesium chlorides, 8 parts of calcium monohydrogen phosphates, 4 parts of 2,3- dyhydrobutanedioic acids, 3 parts of triethanolamines, 80 parts Water.
A kind of method for preparing above-mentioned processing tweed softening agent, comprises the following steps：By the alkane of above-mentioned parts by weight Under the alkalescence condition of pH value 10, temperature is 85 DEG C and reacts 8h, then gradual again for base phenol polyethenoxy ether, APEO and water It is warming up to 105 DEG C to continue to react 8h, obtains mixed solution A；The octamethylcyclotetrasiloxane of above-mentioned parts by weight and polyvinyl alcohol are existed Under the alkalescence condition of pH value 9, temperature is 120 DEG C of reaction 6h, is then gradually cooled to 80 DEG C, above-mentioned citric acid is added dropwise to wherein With until pH value when being down to 7, obtains mixed solution B；By above-mentioned mixed solution A and mixed solution B in the alkalescence that pH value is 9 Under the conditions of, temperature is 90 DEG C of reaction 4h, is down to room temperature；The tristearin of above-mentioned parts by weight is sequentially added in upward step resulting solution Sour sodium, sodium benzoate, HYDROXY PROPYL METHYLCELLULOSE, enuatrol, sodium tripolyphosphate, lauryl sodium sulfate, organosilicon, sulfonation Castor oil, magnesium chloride, calcium monohydrogen phosphate, 2,3- dyhydrobutanedioic acids and triethanolamine, stir and produce the processing hair Flannelette softening agent.
Embodiment 3
One kind processing tweed softening agent, is made up of following parts by weight raw material：30 parts of APESs, 15 Part octamethylcyclotetrasiloxane, 15 parts of APEOs, 6 parts of odium stearate, 8 parts of sodium benzoates, 4 parts of hydroxypropyl methyl celluloses Element, 9 parts of polyvinyl alcohol, 4 parts of enuatrols, 4 parts of sodium tripolyphosphates, 4 parts of lauryl sodium sulfate, 30 parts of citric acids, 12 parts organic Silicon, 6 portions of sulfonated castor oils, 4 parts of magnesium chlorides, 7 parts of calcium monohydrogen phosphates, 3 parts of 2,3- dyhydrobutanedioic acids, 2 parts of triethanolamines, 70 parts Water.
A kind of method for preparing above-mentioned processing tweed softening agent, comprises the following steps：By the alkane of above-mentioned parts by weight Base phenol polyethenoxy ether, APEO and water under the alkalescence condition of pH value 9.5, temperature be 80 DEG C reaction 7h, then again by Gradually it is warming up to 100 DEG C to continue to react 7h, obtains mixed solution A；By the octamethylcyclotetrasiloxane and polyvinyl alcohol of above-mentioned parts by weight Under the alkalescence condition of pH value 8.5, temperature is 115 DEG C of reaction 5h, is then gradually cooled to 75 DEG C, above-mentioned citric acid is added dropwise to it Neutralize, until when pH value is down to 6.5, obtain mixed solution B；In pH value it is 8.5 by above-mentioned mixed solution A and mixed solution B Alkalescence condition under, temperature be 85 DEG C reaction 3.5h, be down to room temperature；Above-mentioned parts by weight are sequentially added in upward step resulting solution Several odium stearate, sodium benzoate, HYDROXY PROPYL METHYLCELLULOSE, enuatrol, sodium tripolyphosphate, lauryl sodium sulfate, have Machine silicon, sulfonated castor oil, magnesium chloride, calcium monohydrogen phosphate, 2,3- dyhydrobutanedioic acids and triethanolamine, stir and produce institute State processing tweed softening agent.
Beneficial effects of the present invention are：(1) finally caused bating effect is good for the invention, is handled by the softening agent Lint cloth is more soft and fluffy, and feel is good, and persistence is also grown；(2) preparation method of the softening agent is simple, prepares Cost is low, while the softening agent prepared is to environment and human body non-hazardous, environmental protection safe to use.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry For personnel it should be appreciated that the present invention is not limited to the above embodiments, that described in above-described embodiment and specification is the present invention Principle, various changes and modifications of the present invention are possible without departing from the spirit and scope of the present invention, these change and Improvement is both fallen within the range of claimed invention.The protection domain of application claims by appended claims and its Equivalent defines.

Claims (5)

1. one kind processing tweed softening agent, it is characterised in that：It is made up of following parts by weight raw material：25-35 part alkyl phenols APEO, 10-20 part octamethylcyclotetrasiloxanes, 10-20 part APEOs, 4-8 part odium stearate, 7-9 part benzoic acid Sodium, 3-5 part HYDROXY PROPYL METHYLCELLULOSEs, 8-10 part polyvinyl alcohol, 3-5 part enuatrols, 3-5 part sodium tripolyphosphates, 3-5 parts ten Sodium dialkyl sulfate, 25-35 part citric acids, 10-14 part organosilicons, 4-8 part sulfonated castor oils, 3-5 part magnesium chlorides, 6-8 part phosphorus Sour hydrogen calcium, 2-4 parts 2,3- dyhydrobutanedioic acids, 1-3 part triethanolamines, 60-80 part water.
A kind of 2. processing tweed softening agent according to claim 1, it is characterised in that：By following parts by weight raw material Composition：25 parts of APESs, 10 parts of octamethylcyclotetrasiloxanes, 10 parts of APEOs, 4 parts of odium stearate, 7 parts of benzene Sodium formate, 3 parts of HYDROXY PROPYL METHYLCELLULOSEs, 8 parts of polyvinyl alcohol, 3 parts of enuatrols, 3 parts of sodium tripolyphosphates, 3 parts of dodecyls Sodium sulphate, 25 parts of citric acids, 10 parts of organosilicons, 4 portions of sulfonated castor oils, 3 parts of magnesium chlorides, 6 parts of calcium monohydrogen phosphates, 2 parts of 2,3- dihydroxies Base succinic acid, 1 part of triethanolamine, 60 parts of water.
A kind of 3. processing tweed softening agent according to claim 1, it is characterised in that：By following parts by weight raw material Composition：35 parts of APESs, 20 parts of octamethylcyclotetrasiloxanes, 20 parts of APEOs, 8 parts of odium stearate, 9 parts of benzene Sodium formate, 5 parts of HYDROXY PROPYL METHYLCELLULOSEs, 10 parts of polyvinyl alcohol, 5 parts of enuatrols, 5 parts of sodium tripolyphosphates, 5 parts of dodecyls Sodium sulphate, 35 parts of citric acids, 14 parts of organosilicons, 8 portions of sulfonated castor oils, 5 parts of magnesium chlorides, 8 parts of calcium monohydrogen phosphates, 4 parts of 2,3- dihydroxies Base succinic acid, 3 parts of triethanolamines, 80 parts of water.
A kind of 4. processing tweed softening agent according to claim 1, it is characterised in that：By following parts by weight raw material Composition：30 parts of APESs, 15 parts of octamethylcyclotetrasiloxanes, 15 parts of APEOs, 6 parts of odium stearate, 8 parts of benzene Sodium formate, 4 parts of HYDROXY PROPYL METHYLCELLULOSEs, 9 parts of polyvinyl alcohol, 4 parts of enuatrols, 4 parts of sodium tripolyphosphates, 4 parts of dodecyls Sodium sulphate, 30 parts of citric acids, 12 parts of organosilicons, 6 portions of sulfonated castor oils, 4 parts of magnesium chlorides, 7 parts of calcium monohydrogen phosphates, 3 parts of 2,3- dihydroxies Base succinic acid, 2 parts of triethanolamines, 70 parts of water.
5. a kind of prepare the method that tweed softening agent is handled any one of claim 1-4, it is characterised in that：
Comprise the following steps：By the APES, APEO and water of above-mentioned parts by weight pH value 9-10's Under alkalescence condition, temperature is 75-85 DEG C of reaction 6-8h, is then gradually heating to 95-105 DEG C again and continues to react 6-8h, must mix Solution A；By the octamethylcyclotetrasiloxane of above-mentioned parts by weight and polyvinyl alcohol under pH value 8-9 alkalescence condition, temperature is 110-120 DEG C of reaction 4-6h, is then gradually cooled to 70-80 DEG C, above-mentioned citric acid is added dropwise it is neutralized, until pH value is down to 6- When 7, mixed solution B is obtained；By above-mentioned mixed solution A and mixed solution B in the case where pH value is 8-9 alkalescence condition, temperature is 80-90 DEG C of reaction 3-4h, is down to room temperature；Odium stearate, the benzene of above-mentioned parts by weight are sequentially added in upward step resulting solution Sodium formate, HYDROXY PROPYL METHYLCELLULOSE, enuatrol, sodium tripolyphosphate, lauryl sodium sulfate, organosilicon, sulfonated castor oil, Magnesium chloride, calcium monohydrogen phosphate, 2,3- dyhydrobutanedioic acids and triethanolamine, stir and produce the processing tweed with soft Agent.
CN201711112931.0A 2017-11-13 2017-11-13 One kind processing tweed softening agent and preparation method thereof Pending CN107794762A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111493473A (en) * 2020-06-15 2020-08-07 杭州天龙手袋股份有限公司 Waterproof antibacterial soft material handbag

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103850121A (en) * 2014-02-21 2014-06-11 朱文潮 Wool spinning softening agent
CN104313878A (en) * 2014-10-20 2015-01-28 江苏金牛华尔车服饰有限公司 Clothes softening agent
CN105442324A (en) * 2015-11-26 2016-03-30 常熟市淼泉盛达助剂厂 Softening agent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103850121A (en) * 2014-02-21 2014-06-11 朱文潮 Wool spinning softening agent
CN104313878A (en) * 2014-10-20 2015-01-28 江苏金牛华尔车服饰有限公司 Clothes softening agent
CN105442324A (en) * 2015-11-26 2016-03-30 常熟市淼泉盛达助剂厂 Softening agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111493473A (en) * 2020-06-15 2020-08-07 杭州天龙手袋股份有限公司 Waterproof antibacterial soft material handbag
CN111493473B (en) * 2020-06-15 2022-07-12 杭州天龙手袋股份有限公司 Waterproof antibacterial soft material handbag

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