CN107793916A - A kind of preparation method of the coating of ventilative Wind-proof, moisture-permeability - Google Patents

A kind of preparation method of the coating of ventilative Wind-proof, moisture-permeability Download PDF

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Publication number
CN107793916A
CN107793916A CN201711208356.4A CN201711208356A CN107793916A CN 107793916 A CN107793916 A CN 107793916A CN 201711208356 A CN201711208356 A CN 201711208356A CN 107793916 A CN107793916 A CN 107793916A
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coating
preparation
component
thermal expansion
nano silicon
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宣乐
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of preparation method of ventilative wind-proof coating, the preparation of the coating includes following two key steps：Vinyl polysiloxane, nano silicon, silazane and ethanol in proportion is mixed 1 2h by 1 in a high shear mixer, and being cooled to room temperature after being handled under 200 DEG C of vacuum obtains a homogeneous mixture.Thermal expansion microcapsules and catalyst chloroplatinic acid are added, is then filtrated to get component A；2 add the lignocellulosic of aforementioned proportion in reactor, then add barium sulfate powder and diatomite is uniformly mixed, and ball milling disperses after first ultrasonic disperse, the other remaining constitutive materials then added outside component A, are uniformly mixing to obtain component B；A, B component are mixed again moistureproof anti-aging type coating is made by ultrasonic disperse and ball milling are scattered.Fabric and polyurethane composite membrane are not stratified when coating fabric face using the coating, and polyurethane film layer has excellent windproof air-moisture-permeable effect, while fabric feeling is good.

Description

A kind of preparation method of the coating of ventilative Wind-proof, moisture-permeability
Technical field
The invention belongs to laminate fabric manufacturing field, and in particular to a kind of preparation method of the coating of windproof air-moisture-permeable.
Background technology
The windproof air-moisture-permeable laminated fabric of polytetrafluoroethylmicroporous microporous membrane through biaxial tension be the windproof ventilative, moisture-inhibiting of collection, The high-tech products of function such as windproof and chemical defence, the laminated fabric are widely used in outdoor sports coat, easy dress, windproof The fields such as gas moisture permeable shoes.The micro-structural of film is made up of " fibril-node ", and film thickness is 5~80 microns, aperture 0.1~5 Micron, per square inch on there are about 9,000,000,000 micropores, percent opening is up to more than 80%.Due to the ratio surface of polytetrafluoroethylene film Product is big, and the material such as salinity, grease and cosmetics in easy adsorption of dust, human sweat, detergent is also easily remained in hole, causes Decline windproof gas permeability.Therefore, polyurethane of the coating with moisture permeability is standby multiple on polytetrafluoroethylene film It is the current main path for solving problem above to close film.Have been disclosed for a variety of preparing polytetrafluoroethylene (PTFE) and polyurethane is compound at present The method of film.
Patent of invention ZL03100830.5 and Z1200510061827.4 disclose a kind of using hot melt sheet extrusion thermoplastic Property polyurethane, be cast on PTFE base band, finally carry out the method that co-stretched and solidification prepares composite membrane.Patent of invention ZL03100829.1 discloses a kind of compound membrane preparation method, and polyurethane solutions are coated in release liners, then will be through two-way drawing The polytetrafluoroethylmicroporous microporous membrane stretched is bonded with the release liners coated with polyurethane solutions, is dried after being pressurizeed using press device, Release liners and polytetrafluoroethylmicroporous microporous membrane are peeled off after drying, obtain polyurethane and polytetrafluoroethylene (PTFE) bidirectional elastic film.
But the surface tension of polytetrafluoroethylene (PTFE) is low, it is difficult to and other materials is preferably combined together, and causes polytetrafluoroethyl-ne Easily it is layered in use between alkene film and polyurethane.The polytetrafluoroethylene film and polyurethane prepared using the above method Be difficult to merge between two kinds of different materials, between peel strength it is relatively low, easily layering.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of preparation method of the coating of windproof air-moisture-permeable, utilizes this Fabric and polyurethane composite membrane are not stratified when coating coats fabric face, and polyurethane film layer has excellent windproof air-moisture-permeable Effect, while fabric feeling is good.
The technical solution adopted for the present invention to solve the technical problems is：A kind of preparation method of windproof vapor-permeable type coating, The parts by weight of its main constitutive material are：Polyether-type hydrolysis resistant polyurethane resin 30-40, vinyl polysiloxane 30- 45th, containing hydrogen silicone oil 10-14, expanded vermiculite 5-8, thermal expansion microcapsules 1-10, catalyst chloroplatinic acid 0.5-1, silazane 0.4- 0.5th, lauryl sodium sulfate 1.5-1.6, natural plant gum 1-2, anti-wear agent 0.5-0.8, barium sulfate powder 43-45, lignocellulosic It is 6-8, silane coupler 3.5-4.5, diatomite 1-3, inhibitor 10-12, nano silicon 3-5, titanium dioxide 5-7, ultraviolet Light stabilizer 3-10 and ethanol 25-30；The thermal expansion microcapsules are to contain a kind of volatility thing in the spherical shell of thermoplastic resin Matter heating expansion obtains；Wherein, the composition of the spherical shell includes polyethylene, polystyrene, polybutadiene, polyvinyl acetate One or more in the copolymer of ester, neoprene and other vinyl oligomeric compounds, volatilize in the thermal expansion microcapsules Property material include one or more in butane, iso-butane, propane, dichloroethanes etc.；The preparation of the coating includes following two Key step：
（1）Vinyl polysiloxane, nano silicon, silazane and ethanol are mixed into 1- in a high shear mixer 2h, it is cooled to room temperature after handling under 200 DEG C of vacuum and obtains a homogeneous mixture.Thermal expansion microcapsules and catalyst chloroplatinic acid are added, Then it is filtrated to get component A;
（2）Lignocellulosic is added in reactor, then barium sulfate powder is added and diatomite is uniformly mixed, first ultrasound Ball milling disperses 15-20h after scattered 15-20min, the other remaining constitutive materials then added outside component A, stirs To component B；A, B component are mixed again and disperse the obtained vapor-permeable type coating of 4-6h by ultrasonic disperse 25-35min and ball milling.
Further, it is micro- in 20-50 after expansion before the thermal expansion microcapsule diameter expansion in 5.0-15 micrometer ranges Rice scope.
Further, the specific surface area of the nano silicon at least wants 200m2/g。
The beneficial effect that the present invention obtains
Composite coating disclosed by the invention can take knife to scrape the production technology of coating, and the positive and negative of textile cloth is coated in by scraper On face, obtained windproof cloth material of good performance, apply in the manufacture of windproof articles for use and light screening material field.It is disclosed by the invention Composite coating is furnished with good adhesive force to PET, PE textile, while has with the PET textiles cloth of this composite coating coating There is good water resistance, water pressure resistance can be up to 7000~9000mm water columns.Thermal expansion microcapsules and expanded vermiculite in formula have The windproof ventilative, anti-leakage of the raising coating of effect, reduce hollowing cracking；And the present invention is by liquid polysiloxane It is modified, the windproof gas permeability of coating can be improved, the usability of strengthening slurry, is easy to coated on fabric.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, but scope of the present invention is simultaneously It is not limited to the described scope of embodiment.
Embodiment 1
A kind of preparation method of windproof vapor-permeable type coating, the parts by weight of its main constitutive material are：Polyether-type hydrolysis resistant polyurethane Resin 30, vinyl polysiloxane 30, containing hydrogen silicone oil 10, expanded vermiculite 5, thermal expansion microcapsules 1, catalyst chlorine platinum Acid 0.5, silazane 0.4, lauryl sodium sulfate 1.5, natural plant gum 1, anti-wear agent 0.5, barium sulfate powder 43, lignocellulosic 6, Silane coupler 3.5, diatomite 1, inhibitor 10, nano silicon 3, titanium dioxide 5, UV light stabilizing agent 3 and ethanol 25；The thermal expansion microcapsules are that the heating expansion containing a kind of volatile materials obtains in the spherical shell of thermoplastic resin, wherein, The composition of the spherical shell includes polyethylene, polystyrene, polybutadiene, polyvinyl acetate, neoprene and other vinyl One or more in the copolymer of low polymer, volatile materials includes butane, iso-butane, third in the thermal expansion microcapsules One or more in alkane, dichloroethanes etc.；The preparation of the coating includes following two key steps：
（1）By vinyl polysiloxane, nano silicon, silazane and the ethanol of aforementioned proportion in high shear mixer Middle mixing 1-2h, it is cooled to room temperature after handling under 200 DEG C of vacuum and obtains a homogeneous mixture.Add thermal expansion microcapsules and catalyst Chloroplatinic acid, then it is filtrated to get component A.
（2）The lignocellulosic of aforementioned proportion is added in reactor, then adds barium sulfate powder and diatomite stirring Well mixed, ball milling disperses 15-20h after first ultrasonic disperse 15-20min, the other remaining compositions then added outside component A Raw material, it is uniformly mixing to obtain component B；A, B component are mixed again and are made by ultrasonic disperse 25-35min and the scattered 4-6h of ball milling Moistureproof anti-aging type coating.It is micro- in 20-50 after expansion before the thermal expansion microcapsule diameter expansion in 5.0-15 micrometer ranges Rice scope.The specific surface area of the nano silicon at least wants 200m2/g。
Embodiment 2
A kind of preparation method of windproof vapor-permeable type coating, the parts by weight of its main constitutive material are：Polyether-type hydrolysis resistant polyurethane Resin 40, vinyl polysiloxane 45, containing hydrogen silicone oil 14, expanded vermiculite 8, thermal expansion microcapsules 10, catalyst chlorine Platinic acid 1, silazane 0.5, lauryl sodium sulfate 1.6, natural plant gum 2, anti-wear agent 0.8, barium sulfate powder 45, lignocellulosic 8, Silane coupler 4.5, diatomite 3, inhibitor 12, nano silicon 5, titanium dioxide 7, UV light stabilizing agent 10 and ethanol 30；The thermal expansion microcapsules are that the heating expansion containing a kind of volatile materials obtains in the spherical shell of thermoplastic resin, wherein, The composition of the spherical shell includes polyethylene, polystyrene, polybutadiene, polyvinyl acetate, neoprene and other vinyl One or more in the copolymer of low polymer, volatile materials includes butane, iso-butane, third in the thermal expansion microcapsules One or more in alkane, dichloroethanes etc.；The preparation of the coating includes following two key steps：
（1）By vinyl polysiloxane, nano silicon, silazane and the ethanol of aforementioned proportion in high shear mixer Middle mixing 1-2h, it is cooled to room temperature after handling under 200 DEG C of vacuum and obtains a homogeneous mixture.Add thermal expansion microcapsules and catalyst Chloroplatinic acid, then it is filtrated to get component A.
（2）The lignocellulosic of aforementioned proportion is added in reactor, then adds barium sulfate powder and diatomite stirring Well mixed, ball milling disperses 15-20h after first ultrasonic disperse 15-20min, the other remaining compositions then added outside component A Raw material, it is uniformly mixing to obtain component B；A, B component are mixed again and are made by ultrasonic disperse 25-35min and the scattered 4-6h of ball milling Moistureproof anti-aging type coating.It is micro- in 20-50 after expansion before the thermal expansion microcapsule diameter expansion in 5.0-15 micrometer ranges Rice scope.The specific surface area of the nano silicon at least wants 200m2/g。
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any Those skilled in the art disclosed herein technical scope in, can without the change that creative work is expected or Replace, should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be limited with claims Fixed protection domain is defined.

Claims (4)

1. a kind of preparation method of ventilative wind-proof coating, it is characterised in that the parts by weight of constitutive material are：Polyether-type hydrolysis Polyurethane resin 30, vinyl polysiloxane 30, containing hydrogen silicone oil 10, expanded vermiculite 5, thermal expansion microcapsules 1, catalysis Agent chloroplatinic acid 0.5, silazane 0.4, lauryl sodium sulfate 1.5, natural plant gum 1, anti-wear agent 0.5, barium sulfate powder 43, wooden fibre Dimension element 6, silane coupler 3.5, diatomite 1, inhibitor 10, nano silicon 3, titanium dioxide 5, the and of UV light stabilizing agent 3 Ethanol 25；The thermal expansion microcapsules are that the heating expansion containing a kind of volatile materials obtains in the spherical shell of thermoplastic resin, Wherein, the composition of the spherical shell includes polyethylene, polystyrene, polybutadiene, polyvinyl acetate, neoprene and other second One or more in the copolymer of alkenyl low polymer, volatile materials includes butane, isobutyl in the thermal expansion microcapsules One or more in alkane, propane, dichloroethanes etc.；The preparation of the coating includes following two key steps：
（1）By vinyl polysiloxane, nano silicon, silazane and the ethanol of aforementioned proportion in high shear mixer Middle mixing 1-2h, it is cooled to room temperature after handling under 200 DEG C of vacuum and obtains a homogeneous mixture.
2. adding thermal expansion microcapsules and catalyst chloroplatinic acid, component A is then filtrated to get；
（2）The lignocellulosic of aforementioned proportion is added in reactor, then barium sulfate powder is added and diatomite is stirred Uniformly, ball milling disperses 15-20h after first ultrasonic disperse 15-20min, and the other remaining compositions then added outside component A are former Material, is uniformly mixing to obtain component B；A, B component are mixed again and are made anti-by ultrasonic disperse 25-35min and the scattered 4-6h of ball milling The anti-aging type coating of tide.
3. preparation method according to claim 1, it is characterised in that about before the thermal expansion microcapsule diameter expansion In 5.0-15 micrometer ranges, in about 20-50 micrometer ranges after expansion.
4. preparation method according to claim 1 or 2, it is characterised in that the specific surface area of the nano silicon is extremely 200m is wanted less2/g。
CN201711208356.4A 2015-06-29 2015-06-29 A kind of preparation method of the coating of ventilative Wind-proof, moisture-permeability Pending CN107793916A (en)

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CN201510365383.7A CN104894874B (en) 2015-06-29 2015-06-29 A kind of preparation method of the coating of windproof air-moisture-permeable
CN201711208356.4A CN107793916A (en) 2015-06-29 2015-06-29 A kind of preparation method of the coating of ventilative Wind-proof, moisture-permeability

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Application publication date: 20180313