CN107793876A - The method for preparing external wall reflective heat-insulation paint - Google Patents

The method for preparing external wall reflective heat-insulation paint Download PDF

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Publication number
CN107793876A
CN107793876A CN201711193167.4A CN201711193167A CN107793876A CN 107793876 A CN107793876 A CN 107793876A CN 201711193167 A CN201711193167 A CN 201711193167A CN 107793876 A CN107793876 A CN 107793876A
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parts
external wall
insulation paint
component
reflective heat
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黄涌芮
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a kind of method for preparing external wall reflective heat-insulation paint, comprise the following steps successively:(1)Water-based acrylic resin, aqueous elastic resin, deionized water are mixed, obtain component A material;(2)Component A material is put into container, adds following raw material while stirring:Titanium dioxide, far infrared nano powder, sepiolite powder, hollow beads, closed-cell expanded perlite, nanometer calcium silicates, fire retardant, dispersant, defoamer, preservative, stir, and obtain B component material;(3)Following raw material is added in B component material:Thickener, coalescents, stir, you can.Coating producing process of the present invention is simple, production cost is low, the raw material added is free of harmful substance, it is environmentally safe, wherein adding the raw material coating such as far infrared nano powder, hollow beads, closed-cell expanded perlite, fire retardant by rational proportion not only has good reflective thermal-insulating heat-blocking action, while also has good fire resistance.

Description

The method for preparing external wall reflective heat-insulation paint
Technical field
The invention belongs to building coating technical field, and in particular to a kind of side for preparing external wall reflective heat-insulation paint Method.
Background technology
There is building coating decoration functions, defencive function and livability to improve function.Proportion shared by various functions is because making It is not quite similar with purpose difference.Decoration functions are to improve the function of its appearance value by the beautification of building.Mainly Design design and the design of three-dimensional pattern design in terms of including plane color, pattern and gloss.But will be with building in itself The size and shape of moulding and base material in itself is engaged, and just can fully play out.Defencive function refers to protect building not Function that is protected from environmental and destroying.Different types of content for being required by protective defencive function is also different.Such as It is indoor just very big with index difference that is reaching required by outdoor application.Some buildings are to mould proof, fire prevention, insulation, corrosion resistant Erosion etc. has particular/special requirement.Livability improves function mainly for indoor application, just contributes to improve the work(of living environment Can, such as sound-proofing, the effect of sound absorption properties coating and its classification, anti-condensation.
With the deep propulsion being becoming tight the day of the energy with country in terms of energy-conserving and environment-protective and sustainable development, reflective insulation The application of coating is more and more extensive.Reflective heat-insulation paint is a kind of new energy-saving material developed in recent years, by effective Ground reflection, barrier, the energy of radiation sunshine, can substantially reduce skin, roof and indoor temperature, so as to effectively reduce The energy consumption of refrigeration plant such as air-conditioning under the high temperature conditions.Therefore, reflective heat-insulation paint can improve working environment, save again The substantial amounts of energy.But though the reflective heat-insulation paint produced in the market does not have with certain reflective insulation effect There is fire resistance, limit its application.
The content of the invention
For deficiency of the prior art, the invention provides a kind of method for preparing external wall reflective heat-insulation paint.
Specifically, the method for the present invention for preparing external wall reflective heat-insulation paint, by the component of following parts by weight It is prepared:Water-based acrylic resin 200-300 parts, aqueous elastic resin 50-100 parts, deionized water 300-400 parts, titanium white Powder 80-120 parts, far infrared nano powder 30-50 parts, sepiolite powder 30-50 parts, hollow beads 30-50 parts, closed-cell expanded perlite 30-50 parts, nanometer calcium silicates 30-50 parts, fire retardant 3-5 parts, thickener 10-50 parts, dispersant 1-3 parts, defoamer 1-3 parts, Preservative 0.5-1 parts, coalescents 0.1-1 parts;Specifically, comprise the following steps successively:
(1)Water-based acrylic resin 200-300 parts, aqueous elastic resin 50-100 parts, deionized water 300-400 parts are mixed, Obtain component A material;
(2)Component A material is put into container, adds the raw material of following parts by weight while stirring:Titanium dioxide 80-120 parts, far infrared Nano powder 30-50 parts, sepiolite powder 30-50 parts, hollow beads 30-50 parts, closed-cell expanded perlite 30-50 parts, nanometer silicic acid Calcium 30-50 parts, fire retardant 3-5 parts, dispersant 1-3 parts, defoamer 1-3 parts, preservative 0.5-1 parts, stir, obtain B component Material;
(3)The raw material of following parts by weight is added in B component material:Thickener 10-50 parts, coalescents 0.1-1 parts, stirring are equal It is even, you can.
Water-based acrylic resin includes emulsion acrylic resin, aqueous acrylic resin dispersion(Also known as water-dilutable propylene Acid)And acrylic resin aqueous solution.Emulsion is mainly emulsified in water by oiliness vinyl monomer draws in water-based free radical initiator Synthesis is given, and resin water dispersion is synthesized by the different technique of free radical solution polymerization or progressively polymerisation in solution etc. 's.Water soluble acrylic resin belongs to anionic more, in the monomer of copolymer resins from appropriate unsaturated carboxylic acid such as acrylic acid, Methacrylic acid, maleic anhydride, methylene-succinic acid etc., make to carry carboxyl on side chain, then neutralized with organic amine or ammoniacal liquor Water solubility is obtained into salt.In addition can also be by introducing-OH hydroxyls ,-CONH2 acyls from appropriate monomer on resin side chain The hydrophilic radical such as amino or-O- ehter bonds and increase the water solubility of resin.Water, but its water can be dissolved in by neutralizing into the acrylic resin of salt Dissolubility is simultaneously not bery strong, the liquid of milkiness shape or the solution that viscosity is very high is frequently formed, so must add in water-soluble resin Enter a certain proportion of hydrophilic cosolvent to increase the water solubility of resin.
Nano inorganic far-infrared powder is with the refined compound far infrared health care of novel nano formed of special nanometer composite technology Functional material.Detected through China National Measuring Science Research Inst., the infrared emittance under normal temperature in the μ m of wavelength 2-18 is up to 92%.Japan is in the leading level in the world in the research and development of normal temperature far-infrared technique, and according to Japan Patent introduction, far infrared is spun The ceramic powder normal temperature radiance that fabric is selected is generally higher than 0.65, and preferably more than 0.75, best is more than 0.90.Now, far The particle diameter of infrared nanometer powder can produce -80 nanometers of 1250 mesh.Nano composite inorganic far infrared health care material has and human body radiation The farsighted infrared emittance of respective wavelength is absorbed, is good body-care far-infrared radiation material, there is uvioresistant, kill Bacterium eliminates peculiar smell, the function such as prevent and cure diseases, and can effectively improve microcirculation in human body, promotes normal microcirculation blood flow increase by 2 ~ 3 Times, tissue oxygen supply is improved, improves metabolism, strengthen immunity.
Sepiolite has extremely strong absorption, decolourizes and the performance such as scattered, also there is a high heat endurance, and heat-resisting quantity is reachable 1500 ~ 1700 DEG C, formative nature, insulating properties, salt resistance degree are all very good.
The water-based acrylic resin selects anion-type water-thinned acrylic resin.
The aqueous elastic resin selects ultraviolet light self-crosslinking elastic pure acrylic acid resin.
The hollow beads are made up of glass hollow microballon and ceramic hollow microballon, and glass hollow microballon and ceramic hollow are micro- The mass ratio of pearl is 3:1.
The particle diameter of the closed-cell expanded perlite is 1-1.5mm.
The fire retardant selects Firebrake ZB or aluminium hydroxide.
The thickener selects polyurethane thickener.
The dispersant selects inorganic silicic acid salt dispersant.
The defoamer is from this DF-7010 type defoamer of hamming.
The preservative selects isothiazoline -3- ketone preservatives.
The coalescents select the coalescents of alcohol ester 12.
External wall reflective heat-insulation paint simple production process of the present invention, production cost is low, and the raw material added does not contain Evil material, it is environmentally safe, wherein by rational proportion add far infrared nano powder, hollow beads, closed-cell expanded perlite, The raw materials such as fire retardant cause coating not only to have good reflective thermal-insulating heat-blocking action, while also have good fire resistance.
Embodiment
The present invention is described in further detail below in conjunction with specific embodiment, the present embodiment is only more clear to present invention work The explanation of Chu, rather than limitation of the present invention, made under other any Spirit Essences and principle without departing from the present invention Change, modify, substitute, combine, simplify, should be equivalent substitute mode, be included within protection scope of the present invention.
Embodiment 1
The method for preparing external wall reflective heat-insulation paint, comprises the following steps successively:
(1)By anion-type water-thinned acrylic resin 200kg, ultraviolet light self-crosslinking elastic pure acrylic acid resin 80kg, deionization Water 350kg is mixed, and obtains component A material;
(2)Component A material is put into container, adds the raw material of following weight while stirring:The kg of titanium dioxide 100, far infrared nano Powder 30kg, sepiolite powder 40kg, hollow beads(It is made up of glass hollow microballon and ceramic hollow microballon, wherein glass hollow is micro- The mass ratio of pearl and ceramic hollow microballon is 3:1)40kg, closed-cell expanded perlite(Particle diameter is 1-1.5mm)50 kg, nano-silicon The sour kg of calcium 35, the kg of aluminium hydroxide fire retardant 4, the kg of inorganic silicic acid salt dispersant 2, hamming this DF-7010 types defoamer 3 Kg, isothiazoline -3- ketone preservative 0.5kg, stir, obtain B component material;
(3)The raw material of following weight is added in B component material:The kg of polyurethane thickener 35, the coalescents 0.5kg of alcohol ester 12, Stir, you can.
Embodiment 2
The method for preparing external wall reflective heat-insulation paint, comprises the following steps successively:
(1)By anion-type water-thinned acrylic resin 250kg, ultraviolet light self-crosslinking elastic pure acrylic acid resin 100kg, deionization Water 400kg is mixed, and obtains component A material;
(2)Component A material is put into container, adds the raw material of following weight while stirring:The kg of titanium dioxide 80, far infrared nano The kg of powder 50, the kg of sepiolite powder 30, hollow beads(It is made up of glass hollow microballon and ceramic hollow microballon, wherein glass hollow The mass ratio of microballon and ceramic hollow microballon is 3:1)50 kg, closed-cell expanded perlite(Particle diameter is 1-1.5mm)40 kg, nanometer The kg of calcium silicates 40, the kg of zinc borate flame retardant 3, the kg of inorganic silicic acid salt dispersant 3, hamming this DF-7010 types defoamer 1 Kg, the kg of isothiazoline -3- ketones preservative 1, stir, obtain B component material;
(3)The raw material of following weight is added in B component material:The kg of polyurethane thickener 15, the coalescents 0.5 of alcohol ester 12 Kg, stir, you can.
Embodiment 3
The method for preparing external wall reflective heat-insulation paint, comprises the following steps successively:
(1)By anion-type water-thinned acrylic resin 300kg, ultraviolet light self-crosslinking elastic pure acrylic acid resin 80kg, deionization Water 300kg is mixed, and obtains component A material;
(2)Component A material is put into container, adds the raw material of following weight while stirring:The kg of titanium dioxide 120, far infrared nano The kg of powder 40, the kg of sepiolite powder 50, hollow beads(It is made up of glass hollow microballon and ceramic hollow microballon, wherein glass hollow The mass ratio of microballon and ceramic hollow microballon is 3:1)40 kg, closed-cell expanded perlite(Particle diameter is 1-1.5mm)50 kg, nanometer The kg of calcium silicates 40, aluminium hydroxide fire retardant 3kg, the kg of inorganic silicic acid salt dispersant 3, hamming this DF-7010 types defoamer 2 Kg, the kg of isothiazoline -3- ketones preservative 1, stir, obtain B component material;
(3)The raw material of following weight is added in B component material:The kg of polyurethane thickener 40, the coalescents 0.2 of alcohol ester 12 Kg, stir, you can.
Embodiment 4
The method for preparing external wall reflective heat-insulation paint, comprises the following steps successively:
(1)By anion-type water-thinned acrylic resin 240kg, ultraviolet light self-crosslinking elastic pure acrylic acid resin 100kg, deionization Water 350kg is mixed, and obtains component A material;
(2)Component A material is put into container, adds the raw material of following weight while stirring:The kg of titanium dioxide 100, far infrared nano The kg of powder 40, sepiolite powder 35kg, hollow beads(It is made up of glass hollow microballon and ceramic hollow microballon, wherein glass hollow is micro- The mass ratio of pearl and ceramic hollow microballon is 3:1)35 kg, closed-cell expanded perlite(Particle diameter is 1-1.5mm)35 kg, nano-silicon Sour calcium 40kg, zinc borate flame retardant 5kg, the kg of inorganic silicic acid salt dispersant 1, this DF-7010 type defoamer of hamming 2kg, different thiophene The kg of oxazoline -3- ketones preservative 0.8, stirs, obtains B component material;
(3)The raw material of following weight is added in B component material:The kg of polyurethane thickener 15, the coalescents 0.3kg of alcohol ester 12, Stir, you can.
Embodiment 5
The method for preparing external wall reflective heat-insulation paint, comprises the following steps successively:
(1)By anion-type water-thinned acrylic resin 260kg, ultraviolet light self-crosslinking elastic pure acrylic acid resin 110kg, deionization Water 320kg is mixed, and obtains component A material;
(2)Component A material is put into container, adds the raw material of following weight while stirring:The kg of titanium dioxide 80, far infrared nano The kg of powder 35, sepiolite powder 40kg, hollow beads(It is made up of glass hollow microballon and ceramic hollow microballon, wherein glass hollow is micro- The mass ratio of pearl and ceramic hollow microballon is 3:1)20kg, closed-cell expanded perlite(Particle diameter is 1-1.5mm)30kg, nanometer silicic acid Calcium 25kg, zinc borate flame retardant 10kg, the kg of inorganic silicic acid salt dispersant 5, this DF-7010 type defoamer of hamming 3kg, different thiophene Oxazoline -3- ketone preservative 1kg, stir, obtain B component material;
(3)The raw material of following weight is added in B component material:The kg of polyurethane thickener 20, the coalescents 0.8kg of alcohol ester 12, Stir, you can.

Claims (8)

1. prepare the method for external wall reflective heat-insulation paint, it is characterised in that be prepared by the component of following parts by weight: Water-based acrylic resin 200-300 parts, aqueous elastic resin 50-100 parts, deionized water 300-400 parts, titanium dioxide 80-120 Part, far infrared nano powder 30-50 parts, sepiolite powder 30-50 parts, hollow beads 30-50 parts, closed-cell expanded perlite 30-50 parts, Nanometer calcium silicates 30-50 parts, fire retardant 3-5 parts, thickener 10-50 parts, dispersant 1-3 parts, defoamer 1-3 parts, preservative 0.5-1 parts, coalescents 0.1-1 parts;
Specifically, comprise the following steps successively:
(1)Water-based acrylic resin 200-300 parts, aqueous elastic resin 50-100 parts, deionized water 300-400 parts are mixed, Obtain component A material;
(2)Component A material is put into container, adds the raw material of following parts by weight while stirring:Titanium dioxide 80-120 parts, far infrared Nano powder 30-50 parts, sepiolite powder 30-50 parts, hollow beads 30-50 parts, closed-cell expanded perlite 30-50 parts, nanometer silicic acid Calcium 30-50 parts, fire retardant 3-5 parts, dispersant 1-3 parts, defoamer 1-3 parts, preservative 0.5-1 parts, stir, obtain B component Material;
(3)The raw material of following parts by weight is added in B component material:Thickener 10-50 parts, coalescents 0.1-1 parts, stirring are equal It is even, you can.
2. the method for external wall reflective heat-insulation paint is prepared according to claim 1, it is characterised in that the aqueous acrylamide Acid resin selects anion-type water-thinned acrylic resin.
3. the method for external wall reflective heat-insulation paint is prepared according to claim 1, it is characterised in that the aqueous elastic Resin selects ultraviolet light self-crosslinking elastic pure acrylic acid resin.
4. the method for external wall reflective heat-insulation paint is prepared according to claim 1, it is characterised in that the hollow beads It is made up of glass hollow microballon and ceramic hollow microballon, the mass ratio of glass hollow microballon and ceramic hollow microballon is 3:1.
5. the method for external wall reflective heat-insulation paint is prepared according to claim 1, it is characterised in that described closed-cell expanded The particle diameter of perlite is 1-1.5mm.
6. the method for external wall reflective heat-insulation paint is prepared according to claim 1, it is characterised in that the fire retardant choosing With Firebrake ZB or aluminium hydroxide;The thickener selects polyurethane thickener.
7. the method for external wall reflective heat-insulation paint is prepared according to claim 1, it is characterised in that the dispersant choosing With inorganic silicic acid salt dispersant;The defoamer is from this DF-7010 type defoamer of hamming.
8. the method for external wall reflective heat-insulation paint is prepared according to claim 1, it is characterised in that the preservative choosing With isothiazoline -3- ketone preservatives;The coalescents select the coalescents of alcohol ester 12.
CN201711193167.4A 2017-11-24 2017-11-24 The method for preparing external wall reflective heat-insulation paint Withdrawn CN107793876A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109181190A (en) * 2018-11-14 2019-01-11 江苏贝尔诺新能源科技有限公司 A kind of thermosetting composite polystyrene foam heat-insulating board water-proof emulsion preparation method
CN111073454A (en) * 2019-12-25 2020-04-28 辽宁圣图新材料科技有限公司 Novel water-based heat-insulating environment-friendly coating
CN113980548A (en) * 2021-12-03 2022-01-28 佛山市惟欣科技有限公司 Multifunctional building coating and preparation process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101565581A (en) * 2009-06-02 2009-10-28 富思特制漆(北京)有限公司 Reflective heat-insulation coating and preparation method thereof
CN104610829A (en) * 2014-12-30 2015-05-13 北京鹏创伟业科技有限公司 Reflective and heat-insulation coating for buildings and preparation method thereof
CN106700789A (en) * 2015-07-16 2017-05-24 沈阳化工研究院有限公司 Waterborne energy-saving building coating and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101565581A (en) * 2009-06-02 2009-10-28 富思特制漆(北京)有限公司 Reflective heat-insulation coating and preparation method thereof
CN104610829A (en) * 2014-12-30 2015-05-13 北京鹏创伟业科技有限公司 Reflective and heat-insulation coating for buildings and preparation method thereof
CN106700789A (en) * 2015-07-16 2017-05-24 沈阳化工研究院有限公司 Waterborne energy-saving building coating and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109181190A (en) * 2018-11-14 2019-01-11 江苏贝尔诺新能源科技有限公司 A kind of thermosetting composite polystyrene foam heat-insulating board water-proof emulsion preparation method
CN111073454A (en) * 2019-12-25 2020-04-28 辽宁圣图新材料科技有限公司 Novel water-based heat-insulating environment-friendly coating
CN113980548A (en) * 2021-12-03 2022-01-28 佛山市惟欣科技有限公司 Multifunctional building coating and preparation process thereof

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