CN107793852A - It is a kind of using ceramic polished waste residue as environment-friendly type emulsion paint of regeneration filler and preparation method thereof - Google Patents

It is a kind of using ceramic polished waste residue as environment-friendly type emulsion paint of regeneration filler and preparation method thereof Download PDF

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Publication number
CN107793852A
CN107793852A CN201711171148.1A CN201711171148A CN107793852A CN 107793852 A CN107793852 A CN 107793852A CN 201711171148 A CN201711171148 A CN 201711171148A CN 107793852 A CN107793852 A CN 107793852A
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waste residue
ceramic polished
polished waste
emulsion paint
environment
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CN107793852B (en
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郭艳平
李保庆
王丽娜
赵由才
任杰
韩金岑
林锦军
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Guangdong Vocational College of Environmental Protection Engineering
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Guangdong Vocational College of Environmental Protection Engineering
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C09D5/024—Emulsion paints including aerosols characterised by the additives
    • C09D5/028—Pigments; Filters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/053—Polyhydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

Present invention offer is a kind of using ceramic polished waste residue as environment-friendly type emulsion paint of regeneration filler and preparation method thereof, is related to environmental technology field.A kind of environment-friendly type emulsion paint using ceramic polished waste residue as regeneration filler, by weight percentage, raw material includes：Ceramic polished waste residue 10~50%, emulsion 10~50%, color stuffing 0~28%, the water of additive 1~21.5% and surplus.The emulsion paint economizes on resources, and reduces cost, safety and environmental protection, has chemistry and the mechanical performance such as preferable acid-proof alkaline, resistance to scrub, wear-resisting, have a wide range of application, have preferable application prospect.A kind of preparation method using ceramic polished waste residue as the environment-friendly type emulsion paint of regeneration filler, including：After ceramic polished waste residue, color stuffing, additive and water are carried out into sand milling mashing, add emulsion and reconciled.This method preparation technology is simple, and controllability is strong, and preparation cost is low, is adapted to large-scale production.

Description

A kind of environment-friendly type emulsion paint and its preparation using ceramic polished waste residue as regeneration filler Method
Technical field
The present invention relates to environmental technology field, and more particularly to a kind of environment-friendly type using ceramic polished waste residue as regeneration filler Emulsion paint and preparation method thereof.
Background technology
In building coating field, emulsion paint is to add pigment, filler and various auxiliary agents as base-material using synthetic resin emulsion to match somebody with somebody A kind of water paint formed is made, preparation technology is simple, easy for construction, and environmental pollution is small, and its application is increasingly by city The favor of field.Extender pigment of the filler as emulsion paint, primarily serve skeleton structure, improve the effect of coating property, account for breast The 20~40% of shellac varnish composition.At present, the filler of the most of emulsion paint products of in the market is using powdered whiting, lightweight carbon The mineral matters such as sour calcium, talcum powder, wollastonite in powder, sericite in powder, silica flour.The exploitation and processing of these mineral raw materials are to environment And the destruction of natural resources is expendable.
During architectural pottery sanding and polishing, substantial amounts of ceramic polished waste residue can be produced.In terms of siccative, one is often produced Square metre polished bricks produce solid waste 2.1kg or so.China's ceramic polished brick annual production reaches more than several hundred million squares, causes The incredible amount of ceramic polished waste residue caused by annual.The problems such as being limited to due to production technology, this kind of waste residue are circulated on a large scale Utilization rate is very low, and about more than 90% waste residue is not yet efficiently utilized at present, more based on being filled after simple dehydration, to ring Border causes potential risks, and constrains the development of ceramic industry significantly.Ceramic fixed-end forces center such as somewhere will receive After the ceramic useless slurry dehydration of collection or simple process, then the alternative materials as production construction material carry out it is outer sell, including produce Grey brick, glazed tile, ceramic tile, porous brick, cement etc..But these approach are often low because of waste residue application percentage, and added value of product is low, make Overall waste residue utilization amount is little, enterprise profit is low, and processing production capacity is difficult to be lifted, and frequently results in the debris dump after a large amount of dehydrations Product, land occupation resource, has a strong impact on surrounding enviroment.Therefore, the diversification of the ceramic polished waste residue in China, scale resource comprehensive Utilizing question is in the urgent need to address.
The content of the invention
It is an object of the invention to provide a kind of environment-friendly type emulsion paint using ceramic polished waste residue as regeneration filler, the latex Paint economizes on resources, and reduces cost, safety and environmental protection, has chemistry and the mechanicalness such as preferable acid-proof alkaline, resistance to scrub, wear-resisting Can, have a wide range of application, there is preferable application prospect.
It is a kind of using ceramic polished waste residue as the environment-friendly type emulsion paint of regeneration filler another object of the present invention is to provide Preparation method, this method preparation technology is simple, and controllability is strong, and preparation cost is low, is adapted to large-scale production.
The present invention is solved its technical problem and realized using following technical scheme.
The present invention proposes a kind of environment-friendly type emulsion paint using ceramic polished waste residue as regeneration filler, by weight percentage, Preparing the raw material using ceramic polished waste residue as the environment-friendly type emulsion paint of regeneration filler includes：Ceramic polished waste residue 10~50%, breast Liquid 10~50%, color stuffing 0~28%, the water of additive 1~21.5% and surplus.
The present invention proposes a kind of preparation method using ceramic polished waste residue as the environment-friendly type emulsion paint of regeneration filler, including： After ceramic polished waste residue, color stuffing, additive and water are carried out into sand milling mashing, add emulsion and reconciled.
The embodiment of the present invention it is a kind of using ceramic polished waste residue as environment-friendly type emulsion paint of regeneration filler and preparation method thereof Beneficial effect be：
A kind of environment-friendly type emulsion paint using ceramic polished waste residue as regeneration filler provided by the invention, with ceramic polished waste residue Proxy mineral filler rationally using discarded object, economizes on resources as regenerative raw materials, reduces cost, environmental protection.It is ceramic polished useless Slag derives from the ceramic material containing crystalline phase after more than 1,000 degree high-temperature process in itself, has hardness height, intensity is big, physicochemical property is steady The features such as determining.After the sanding and polishing process of ceramic production technology, obtained polishing slag original grain diameter is small, and is irregular nothing Shape class laminated structure.After the sand milling technique prepared through emulsion paint, ceramic polished solid impurity particle, which easily further refines, is melted into surface The laminated structure of flat smooth, grain diameter decentralization reduce, contribute to emulsion paint film forming, are covered in acting surface, prevent latex Paint chap, postpones efflorescence, improves the intensity and hardness of emulsion paint, makes chemistry and the machinery such as its acid-proof alkaline, resistance to scrub, wear-resisting Performance is strengthened, and the environment-friendly type emulsion paint of production has preferable application prospect.
A kind of preparation method using ceramic polished waste residue as the environment-friendly type emulsion paint of regeneration filler, the letter of this method preparation process It is single, conventional emulsion paint production process equipment can be used, ceramic polished waste residue is added into a dustings such as color stuffing, additive first Mill mashing, the mediation such as emulsion is subsequently added into, preparation cost is low, is adapted to large-scale production.
Brief description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, below by embodiment it is required use it is attached Figure is briefly described.It should be appreciated that the following drawings illustrate only certain embodiments of the present invention, therefore it is not construed as pair The restriction of scope.For those of ordinary skill in the art, on the premise of not paying creative work, can also be according to this A little accompanying drawings obtain other related accompanying drawings.
Fig. 1 is the scanning electron microscope diagram of ceramic polished waste residue provided in an embodiment of the present invention；
Fig. 2 is the scanning electron microscope diagram of ceramic polished waste residue provided in an embodiment of the present invention；
Fig. 3 is scanning electron microscope diagram of the ceramic polished slag waste residue provided in an embodiment of the present invention after 20min is sanded.
Embodiment
, below will be in the embodiment of the present invention to make the purpose, technical scheme and advantage of the embodiment of the present invention clearer Technical scheme be clearly and completely described.Unreceipted actual conditions person, builds according to normal condition or manufacturer in embodiment The condition of view is carried out.Agents useful for same or the unreceipted production firm person of instrument, it is the conventional production that can be obtained by commercially available purchase Product.
Below to a kind of environment-friendly type emulsion paint and its system using ceramic polished waste residue as regeneration filler of the embodiment of the present invention Preparation Method is specifically described.
A kind of environment-friendly type emulsion paint using ceramic polished waste residue as regeneration filler provided in an embodiment of the present invention, by weight hundred Divide than meter, preparing the raw material of emulsion paint includes：Ceramic polished waste residue 10~50%, emulsion 10~50%, color stuffing 0~28%, The water of additive 1~21.5% and surplus.Ceramic polished waste residue can be 15%, 21%, 36%, 41%, and emulsion can be 35%th, 25%, 18%, 30%, color stuffing can be 4%, 27%, 26%, 3.5%, additive can be 6.6%, 2.1%, 1.9%th, 3.2%.
Further, in the preferred embodiment of the present invention, by weight percentage, raw material includes：Ceramic polished waste residue 20~40%, the water of emulsion 20~40%, color stuffing 5~25%, additive 5~17% and surplus.Preferably, it is ceramic polished Waste residue can be 24%, 27%, 31%, 36%, and emulsion can be 28%, 25%, 22%, 20%, and color stuffing can be 5.5%th, 8.5%, 10.5%, 14.2%, additive can be 8.6%, 12.2%, 8.7%, 5.5%.
The ceramic polished waste residue chemical composition (%) of table 1
The ceramic polished waste residue thing phase composition (sxemiquantitative %) of table 2
From table 1 and table 2, the chemical composition such as the main silicon oxide-containing of ceramic polished waste residue provided by the invention, aluminum oxide, Its principal crystalline phase material is quartz.Ceramic polished waste residue sheet as the ceramics containing crystalline phase after high-temperature process is spent 1,000 more Material, hardness is high, intensity is big, stable in physicochemical property.After the sanding and polishing process of ceramic production technology, obtained waste particle Particle diameter is small.According to grain size analysis statistical result, by volume percentage, 90% grain diameter is not more than in ceramic polished waste residue 50~120 microns, 50% grain diameter is not more than 30~50 microns, and 10% grain diameter is not more than 1~10 micron, averagely 10~50 microns of grain diameter.Specific surface area is more than 800m2/ kg, whiteness is between 80~92.
Added using ceramic polished waste residue as emulsion paint with filler, after the sand milling technique prepared through emulsion paint, polish slag Particle, which easily further refines, is melted into the smooth laminated structure of surfacing, and grain diameter decentralization reduces.Laminated structure helps In emulsion paint film forming, acting surface is covered in, prevents emulsion paint from chapping, postpones efflorescence, improves the intensity and hardness of emulsion paint, make it The chemistry such as acid-proof alkaline, resistance to scrub, wear-resisting and mechanical performance are strengthened.It is beneficial and ceramic polished waste residue is in itself in alkalescence In the stabilization of emulsion paint system, the emulsion paint product of production has preferable application prospect.
To ceramic polished waste residue provided by the invention and its serous granule progress microscopic appearance test is sanded.By Fig. 1 and Fig. 2 Understand, the ceramic polished waste residue of original provided by the invention is irregular amorphous-type laminated structure；From the figure 3, it may be seen that the present invention provides Ceramic polished waste residue after 20min is sanded, uniformly, its particle is the smooth laminated structure of surfacing.Compared to spherical, pin Shape structure, laminated structure are advantageous to emulsion paint film forming, are covered in acting surface, prevent emulsion paint from chapping, and postpone efflorescence, and help In the intensity and hardness that improve emulsion paint, performance is improved, expands application.
Emulsion has direct influence to the quality of emulsion paint quality.Emulsion plays increase coating intensity in emulsion paint, carried Height smears the effect of scrubbing resistance number.In the present invention, emulsion and the species of ceramic polished waste residue and each additive, proportioning are logical Experimental study is crossed, makes materials compatibility good, obtained emulsion paint performance is good.In embodiments of the present invention, mainly from phenylpropyl alcohol breast Liquid, pure-acrylic emulsion and silicone acrylic emulsion etc..
Color stuffing is the important component of emulsion paint.In order to meet the needs of different, emulsion paint has multiple color, needs By pigment addition in emulsion paint, different colors is assigned, plays a part of decorating and protects.In the present embodiment, pigment Including the general inorganics such as titanium dioxide, fluorescent whitening agent, ultramarine, phthalocyanine blue and zinc yellow or organic pigment, single use or multiple Close and use.
Filler is also known as extender pigment, it is possible to reduce the use of expensive pigment, reduces cost, while increases strength of coating, changes Kind coating property.Conventional emulsion paint filler is mainly powdered whiting, precipitated calcium carbonate, wollastonite in powder, sericite in powder, quartz The mineral fillers such as powder.Exploitation and processing meeting welding and natural resources due to mineral filler, therefore the present invention is thrown using ceramics Light waste residue alternative ore filler.When suitably reducing other conventional mineral fillers, when using ceramic polished waste residue replacement instead, can strengthen The performance of emulsion paint.In the present invention, mineral filler includes talcum powder, calcined kaolin, mica powder, powdered whiting and light Matter calcium carbonate etc., single use or compound use.
In the preparation process of emulsion paint, different additives is added according to being actually needed, to reach required performance. In the preferred embodiment of the present invention, additive includes thickener, dispersant, defoamer, Antisepticize and mildew preventive, coalescents, levelling Any one in agent, pH adjusting agent or at least two.
Thickener is mainly used in improving and increased the viscosity of emulsion paint, keep as additive important in emulsion paint Certain rheological characteristic, prevent sagging phenomenon occur in construction, while assign emulsion paint excellent mechanical performance and storage stability. In embodiments of the present invention, thickener selects polyurethanes thickener, alkali swelling type thickener and cellulose thickener etc., Single addition or compound addition.
Dispersant reduces the jitter time of raw material, stabilising dispersions, has and reduces flocculation phenomenon, strengthens stability, lifting Gloss, increase the effect of color developing.In an embodiment of the present invention, dispersant includes anionic dispersing agent, nonionic point Powder and hydrophobic type dispersant etc..
When emulsion paint is used in building etc. it is necessary to have the performance of anticorrosive mildewproof, avoid coating body by chemistry The corrosion of the corrosive substances such as material and the erosion of mould.In embodiments of the present invention, isothiazolone, benzene are also included in additive And Antisepticize and mildew preventive such as thiazolinone and its derivative etc. is to improve the performance of emulsion paint.
Coalescents make emulsion paint reach workability and quality of forming film as one of additive important in emulsion paint. The film forming procedure of emulsion paint is complex, makes scattered polymer beads to being mutually coalesced as entirety.Coalescents promote breast The Plastic Flow and elastic deformation of micelle, soften particle surface, promote the easy compressive deformation of polymer particle, merge film forming； Coalescents can reduce the MFT of emulsion and emulsion paint.In embodiments of the present invention, coalescents select alcohol ester Class film forming agent, alcohol ethers film forming agent, propane diols, ethylene glycol etc., single or compound use.
In work progress, emulsion paint flow leveling is bad, understands and occur brush mark, orange peel in brush/spraying, in drying process Occurs phenomena such as shrinkage cavity, pin hole, sagging together.The effective ways for overcoming this bad disadvantage of levelability are addition levelling agents. In the embodiment of the present invention, mainly from organic-silicon-modified levelling agent, acrylic compounds levelling agent and polyurethanes auxiliary rheological agents etc., Single or compound use.
PH adjusting agent is used for the pH value for adjusting emulsion paint, increases the stability of emulsion paint, while also have and soak, disperse Effect.In an embodiment of the present invention, pH adjusting agent includes organic amine conditioning agent, Amp-95pH conditioning agents etc..
In order that there is the emulsion paint that must be prepared preferably mechanical performance and chemical property, the experiment through the present inventor to grind Study carefully, color stuffing includes pigment 0~8%, at least one of mineral filler 0~20%, additive include thickener 0.2~ 3.2%th, dispersant 0.3~4%, defoamer 0.2~3%, Antisepticize and mildew preventive 0.1~3%, coalescents 0.1~6%, levelling Any one in agent 0.1~2% and pH adjusting agent 0~0.3% or at least two.
The embodiment of the present invention additionally provides a kind of preparation using ceramic polished waste residue as the environment-friendly type emulsion paint of regeneration filler Method, including：
Be pre-metered 1/2~4/5 water, part thickener, dispersant, 1/2~3/4 defoamer, anti-corrosion are prevented Mould dose is sufficiently mixed 0~20min of stirring under 500~800rpm stir speed (S.S.).
After stirring, ceramic polished waste residue, pigment are added.In an embodiment of the present invention, mineral can also be added to fill out Material, 0~40min is disperseed under 800~1500rpm stir speed (S.S.), obtains coarse dispersion.
Coarse dispersion is added 5~60min is ground in sand mill, grinding chamber motor speed is 1000~3000rpm.It is more excellent , in order to grind fully, the particle diameter of grinding bead is 0.3~3.0mm.Grinding bead particle diameter is smaller, and the particle diameter of grinding milk particle is got over It is small.Fineness is tested, preferably, fineness is less than 40 μm, produces finely dispersed color stuffing slurries.
Be slowly added in slurries metering emulsion, coalescents, remaining defoamer.In 300~800rpm condition Under, after stirring at low speed is uniform, remaining thickener, pH adjusting agent, the viscosity of remaining water regulation system are added, after stirring Produce emulsion paint sample.Preferably, a certain amount of levelling agent can be added, in the feed, the mass percent of levelling agent for 0.1~ 2%.
The feature and performance of the present invention are described in further detail with reference to embodiments.
Embodiment 1
A kind of environment-friendly type emulsion paint using ceramic polished waste residue as regeneration filler is present embodiments provided, by weight percentage Meter, including：
Ceramic polished waste residue 35%, styrene-acrylic emulsion 25%, rutile type titanium white 5%, fluorescent whitening agent 0.1%, the third two Alcohol 2.2%, alcohol ester film forming agent 1.3%, hydroxyethyl cellulose 0.1%, anionic dispersing agents 0.8%, organic-silicon-modified defoamer 0.7%th, isothiazole ketone Antisepticize and mildew preventive 0.2%, alkali swelling type thickener 0.5%, organic-silicon-modified levelling agent 0.4%, The water of Amp-95pH conditioning agents 0.2%, surplus.
Mainly it is made by the following method：
The raw material of above metering is weighed, by hydroxyethyl cellulose, anionic dispersing agents, isothiazole ketone preservative, the third two Alcohol and 1/2 organic-silicon-modified defoamer, 2/3 water is added, 5min is sufficiently mixed under 500rpm rotating speed.Then, add Ceramic polished waste residue, rutile type titanium white and the fluorescent whitening agent of metering above, the lower coarse dispersion 10min of 1200rpm high speeds.
Coarse dispersion is added in sand mill and grinds 20min, grinding bead 1mm, grinding chamber motor speed is 1500rpm, Test below 25 μm of fineness, finely dispersed color stuffing slurries are made.
The styrene-acrylic emulsion, alcohol ester film forming agent, surplus defoamer of above metering are slowly added in slurries, with the low of 500rpm After speed stirs, add more than metering alkali swelling type thickener, with organic-silicon-modified levelling agent, Amp-95pH conditioning agents, Paint sample is made to 85KU in the water regulation system viscosity of surplus.
Embodiment 2
A kind of environment-friendly type emulsion paint using ceramic polished waste residue as regeneration filler is present embodiments provided, by weight percentage Meter, including：
Ceramic polished waste residue 20%, styrene-acrylic emulsion 30%, titanium dioxide 3%, ultramarine 0.1%, talcum powder 5%, calcining kaolinite Soil 5%, propane diols 2.5%, alcohol ester film forming agent 1.5%, modified hydroxyethylcellulosadsorbing 0.1%, non-ionic dispersing agent 0.7%, have Machine silicon defoaming agent 0.6%, isothiazole ketone Antisepticize and mildew preventive 0.2%, polyurethane thickener 0.5%, organic amine pH adjusting agent 0.2%th, the water of surplus.
Mainly it is made by the following method：
Weigh the modified hydroxyethylcellulosadsorbing of above metering, non-ionic dispersing agent, isothiazole ketone Antisepticize and mildew preventive, the third two Alcohol and 3/4 organic silicon defoamer, 4/5 water is added, 10min is sufficiently mixed under 400rpm speed.Then, more than addition The ceramic polished waste residue of metering, talcum powder, calcined kaolin, titanium dioxide, ultramarine, the coarse dispersion under 1200rpm high speed 15min。
Coarse dispersion is added in sand mill and grinds 10min, grinding bead 1mm, grinding chamber motor speed is 1800rpm, Test below 30 μm of fineness, finely dispersed color stuffing slurries are made.
The styrene-acrylic emulsion, alcohol ester film forming agent, surplus defoamer of above metering are slowly added in slurries, 450rpm low speed stirs Mix uniformly after, add more than metering polyurethane thickener, with organic amine pH adjusting agent, surplus water regulation system viscosity extremely 90KU, paint sample is made.
Embodiment 3
A kind of environment-friendly type emulsion paint using ceramic polished waste residue as regeneration filler is present embodiments provided, by weight percentage Meter, including：
Ceramic polished waste residue 35%, pure-acrylic emulsion 25%, phthalocyanine blue 2%, mica powder 5%, ethylene glycol 2.0%, alcohol ether into Film 1.3%, association type alkali swollen thickener 0.6%, hydrophobic additives 0.7%, organic-silicon-modified defoamer 0.6%, benzene And thiazolinone 0.3%, Amp-95pH conditioning agents 0.1%, the water of surplus.
Mainly it is made by the following method：
Weigh hydrophobic additives, benzothiazolinone, ethylene glycol and the 3/5 organic-silicon-modified defoaming of above metering Agent, 1/2 association type alkali swelling type thickener, 3/4 water is added, 5min is sufficiently mixed under 300rpm rotating speed.Then, add Enter ceramic polished waste residue, mica powder and the phthalocyanine blue of above metering, the coarse dispersion 15min under 1500rpm high speed.
Coarse dispersion is added in sand mill and grinds 15min, grinding bead 1.5mm, grinding chamber motor speed is 2000rpm, test below 35 μm of fineness, finely dispersed color stuffing slurries are made.
The pure-acrylic emulsion, alcohol ether film forming agent, surplus defoamer of above metering are slowly added in slurries, 350rpm low speed stirs Mix uniformly after, add more than metering remaining thickener, with Amp-95pH conditioning agents, surplus water regulation system viscosity extremely 85KU, paint sample is made.
Embodiment 4
A kind of environment-friendly type emulsion paint using ceramic polished waste residue as regeneration filler is present embodiments provided, by weight percentage Meter, including：
Ceramic polished waste residue 30%, silicone acrylic emulsion 20%, zinc yellow 4%, powdered whiting 5%, talcum powder 5%, the third two Alcohol 1.8%, alcohol ester film forming agent 1.2%, hydroxymethyl cellulose 0.1, polyurethane thickener 0.5%, non-ionic dispersing agent 0.9%, Organic silicon defoamer 0.7%, benzothiazoline ketone derivatives 0.3%, Amp-95pH conditioning agents 0.1%, the water of surplus.
Mainly it is made by the following method：
Weigh non-ionic dispersing agent, benzothiazoline ketone derivatives, propane diols and the defoaming of 3/4 organosilicon of above metering Agent, hydroxymethyl cellulose, 3/5 water is added, 5min is sufficiently mixed under 500rpm middling speed.Then, metering more than adding Ceramic polished waste residue, powdered whiting, talcum powder and zinc yellow, the coarse dispersion 20min under 1000rpm high speed.
Coarse dispersion is added in sand mill and grinds 20min, grinding bead 1.5mm, grinding chamber motor speed is 1600rpm, test below 35 μm of fineness, finely dispersed color stuffing slurries are made.
The silicone acrylic emulsion, alcohol ester film forming agent, surplus defoamer of above metering are slowly added in slurries, in 400rpm bar Under part, after stirring at low speed is uniform, the polyurethane thickener of metering above is added, is adjusted with the water of Amp-95pH conditioning agents, surplus Paint sample is made to 95KU in system viscosity.
Test example
The environment-friendly type emulsion paint using ceramic polished waste residue as regeneration filler prepared by embodiment 1~4 is chosen, carries out performance inspection Survey, it is as a result as follows：
The performance test results of table 3
As shown in Table 3, the environment-friendly type emulsion paint using ceramic polished waste residue as regeneration filler that embodiment 1~4 provides has There are preferable stability, brushing resistance, acid resistance, alkali resistance and water resistance, have good workability, drying time is short, and outward appearance is preferable. Wherein, ceramic polished waste residue instead of most mineral filler by embodiment 2, embodiment 3 and embodiment 4, and embodiment 1 is with pottery Porcelain polishing slag instead of whole mineral fillers, according to test result, emulsion paint product made from embodiment 1 and embodiment 3 Brushing resistance is stronger, and more than 2000 times, drying time is less than two hours, has more excellent performance.
In summary, a kind of environment-friendly type emulsion paint using ceramic polished waste residue as regeneration filler provided by the invention, with pottery Porcelain polishing slag proxy mineral filler rationally using discarded object, economizes on resources as raw material, reduces cost, environmental protection.Ceramics Polishing slag derives from the ceramic material containing crystalline phase after more than 1,000 degree high-temperature process in itself, with hardness is high, intensity is big, physics and chemistry The features such as property is stable.After the sanding and polishing process of ceramic production technology, obtained polishing slag original grain diameter is small, and for not Regular amorphous-type laminated structure.After the sand milling technique prepared through emulsion paint, easily further refinement is homogenized ceramic polished solid impurity particle The laminated structure smooth into surfacing, grain diameter decentralization reduce, contribute to emulsion paint film forming, are covered in acting surface, prevent Only emulsion paint is chapped, and postpones efflorescence, improves the intensity and hardness of emulsion paint, makes the chemistry such as its acid-proof alkaline, resistance to scrub, wear-resisting Strengthened with mechanical performance, the environment-friendly type emulsion paint of production has preferable application prospect.
Embodiments described above is part of the embodiment of the present invention, rather than whole embodiments.The reality of the present invention The detailed description for applying example is not intended to limit the scope of claimed invention, but is merely representative of the selected implementation of the present invention Example.Based on the embodiment in the present invention, what those of ordinary skill in the art were obtained under the premise of creative work is not made Every other embodiment, belongs to the scope of protection of the invention.

Claims (10)

  1. A kind of 1. environment-friendly type emulsion paint using ceramic polished waste residue as regeneration filler, it is characterised in that by weight percentage, system The standby raw material using ceramic polished waste residue as the environment-friendly type emulsion paint of regeneration filler includes：Ceramic polished waste residue 10~50%, Emulsion 10~50%, color stuffing 0~28%, the water of additive 1~21.5% and surplus.
  2. 2. the environment-friendly type emulsion paint according to claim 1 using ceramic polished waste residue as regeneration filler, it is characterised in that press Percentage by weight meter, the raw material include：The ceramic polished waste residue 20~40%, the emulsion 20~40%, the face are filled out The water of material 5~25%, the additive 5~17% and surplus.
  3. 3. the environment-friendly type emulsion paint according to claim 1 using ceramic polished waste residue as regeneration filler, it is characterised in that institute Stating color stuffing includes at least one of pigment, mineral filler, and the additive includes thickener, dispersant, defoamer, anti-corrosion Any one in mould inhibitor, coalescents, levelling agent and pH adjusting agent or at least two.
  4. 4. the environment-friendly type emulsion paint according to claim 3 using ceramic polished waste residue as regeneration filler, it is characterised in that press Percentage by weight meter, the color stuffing include at least one of the pigment 0~8%, described mineral filler 0~20%, institute Stating additive includes the thickener 0.2~3.2%, dispersant 0.3~4%, the defoamer 0.2~3%, described anti- Rotten mould inhibitor 0.1~3%, the coalescents 0.1~6%, the levelling agent 0.1~2% and the pH adjusting agent 0~ Any one in 0.3% or at least two.
  5. 5. the environment-friendly type emulsion paint according to claim 1 using ceramic polished waste residue as regeneration filler, it is characterised in that press Volume percentage, the ceramic polished waste residue include：Particle diameter is less than 50~120 microns of particle 90~100%, it is preferable that Particle diameter is less than 30~50 microns of particle 50%, it is highly preferred that particle diameter is less than 1~10 micron of particle 10%.
  6. 6. the environment-friendly type emulsion paint according to claim 5 using ceramic polished waste residue as regeneration filler, it is characterised in that institute The average particle size for stating ceramic polished waste residue is 10~50 microns.
  7. 7. it is a kind of as described in any one of claim 1 to 6 using ceramic polished waste residue as the environment-friendly type emulsion paint of regeneration filler Preparation method, it is characterised in that including：The ceramic polished waste residue, the color stuffing, the additive and the water are entered After mashing is sanded in row, adds the emulsion and reconciled.
  8. 8. the preparation method according to claim 7 using ceramic polished waste residue as the environment-friendly type emulsion paint of regeneration filler, its It is characterised by, including：The additive include thickener, dispersant, defoamer, Antisepticize and mildew preventive, coalescents, levelling agent with And pH adjusting agent, by least one of water, at least one of thickener, the dispersant, at least a portion The defoamer, the Antisepticize and mildew preventive mixing, mix with the ceramic polished waste residue, the color stuffing progress coarse dispersion Afterwards, mashing is sanded；Slurries and the emulsion, the coalescents, the remaining defoamer, the remaining thickener, institute Levelling agent, the pH adjusting agent and the remaining water is stated to reconcile.
  9. 9. the preparation method according to claim 8 using ceramic polished waste residue as the environment-friendly type emulsion paint of regeneration filler, its It is characterised by, the jitter time of coarse dispersion mixture is 0~40min, and it is 800~1500rpm to disperse rotating speed.
  10. 10. the preparation method according to claim 8 using ceramic polished waste residue as the environment-friendly type emulsion paint of regeneration filler, its It is characterised by, the milling time that mashing is sanded in coarse dispersion is 5~60min, grinds 1000~3000rpm of rotating speed, grinding bead Particle diameter is 0.3~3.0mm, and the mixing speed of mediation is 300~800rpm.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109135353A (en) * 2018-06-19 2019-01-04 同济大学 The method that high washability water paint is prepared using regenerated building micro mist
CN110408244A (en) * 2019-08-23 2019-11-05 佛山市顺德区数码彩涂料有限公司 A kind of environmentally friendly liquid Tao Jing exterior coating and preparation method thereof of high intensity
CN112358761A (en) * 2020-10-20 2021-02-12 广东环境保护工程职业学院 Modified nano ceramic slurry, water-based paint, and preparation method and application thereof

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CN104176977A (en) * 2013-05-21 2014-12-03 辽宁明上建材工业有限公司 Stone like coating prepared by using waste ceramic, and its preparation method
CN104946059A (en) * 2014-11-18 2015-09-30 湖南瑞石科技发展有限公司 Anticorrosive paint composition comprising modified ceramic waste and preparation method thereof
CN105439548A (en) * 2014-08-07 2016-03-30 辽宁利永盛新材料有限公司 Ceramic-polishing-waste-containing breathing brick and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN104176977A (en) * 2013-05-21 2014-12-03 辽宁明上建材工业有限公司 Stone like coating prepared by using waste ceramic, and its preparation method
CN105439548A (en) * 2014-08-07 2016-03-30 辽宁利永盛新材料有限公司 Ceramic-polishing-waste-containing breathing brick and preparation method thereof
CN104946059A (en) * 2014-11-18 2015-09-30 湖南瑞石科技发展有限公司 Anticorrosive paint composition comprising modified ceramic waste and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109135353A (en) * 2018-06-19 2019-01-04 同济大学 The method that high washability water paint is prepared using regenerated building micro mist
CN110408244A (en) * 2019-08-23 2019-11-05 佛山市顺德区数码彩涂料有限公司 A kind of environmentally friendly liquid Tao Jing exterior coating and preparation method thereof of high intensity
CN112358761A (en) * 2020-10-20 2021-02-12 广东环境保护工程职业学院 Modified nano ceramic slurry, water-based paint, and preparation method and application thereof
CN112358761B (en) * 2020-10-20 2023-08-11 广东环境保护工程职业学院 Modified nano ceramic slurry, water-based paint, and preparation method and application thereof

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