CN107793670A - A kind of smooth PVC film and its production method - Google Patents
A kind of smooth PVC film and its production method Download PDFInfo
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- CN107793670A CN107793670A CN201711048599.6A CN201711048599A CN107793670A CN 107793670 A CN107793670 A CN 107793670A CN 201711048599 A CN201711048599 A CN 201711048599A CN 107793670 A CN107793670 A CN 107793670A
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- pvc film
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- smooth pvc
- smooth
- polyvinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
Abstract
A kind of smooth PVC film and its production method of the present invention, its formula are：80 90 parts of polyvinyl chloride resin, 13 parts of epoxidized soybean oil, 35 45 parts of plasticizer DPHP, 13 parts of thermoplastic acrylic resin, 0.05 0.1 parts of pigment 0.1 0.2,0.001 0.002 parts of brightening agent and slipping agent, are acted on by each formula, make PVC film surface abrasion resistance, smooth, there is preferable corrosion resistance and tensile property.
Description
Technical field
The invention belongs to high-molecular compound technical field, and in particular to a kind of smooth PVC film and its production method.
Background technology
PVC film Main Ingredients and Appearance is polyvinyl chloride, separately has and adds other compositions to strengthen its heat resistance, toughness, ductility
Deng.PVC film be liked deeply in the world today, a kind of rather popular and synthetic material for being also widely used.PVC film
Global usage amount be in second in various synthetic materials.In the material that can produce three-dimensional table facial mask, PVC is most suitable
Material.
It is not corrosion-resistant but existing PVC film stretch-proof, anti-wear performance are poor, and surface is not smooth enough, greatly
The big use for limiting PVC film.
The content of the invention
Instant invention overcomes in the prior art the shortcomings that, there is provided a kind of smooth PVC film and its production method, it is wear-resisting,
With preferable corrosion resistance and tensile property.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions：
A kind of smooth PVC film, its formula are：Polyvinyl chloride resin 80-90 parts, epoxidized soybean oil 1-3 parts, plasticizer DPHP
35-45 parts, thermoplastic acrylic resin 1-3 parts, pigment 0.1-0.2, brightening agent 0.001-0.002 parts and slipping agent 0.05-0.1
Part.
Further, it is additionally added the Graphene powder of the polyvinyl chloride resin mass fraction 1-3%.
Further, it is additionally added the fullerene powder of the polyvinyl chloride resin mass fraction 2-5%.
Further, it is additionally added the graphite powder of the polyvinyl chloride resin mass fraction 4-6%.
Further, the pigment is 7078 and 087F.
Further, the brightening agent is CBS127.
Further, the slipping agent is talcum powder, diatomite or silica.
A kind of production method of smooth PVC film, comprises the following steps：
S1. each component raw material is put into progress high-speed stirred mixing in high-speed mixer in proportion, then controls mixer will
Material scattering is in granular form；
S2. the granular material in step S1 is filtered, thing is obtained to the preliminary melting mixing of the material after filtering
Expect A；
S3. the material A obtained in step S2 is cooled down under agitation, obtains compound, compound is discharged into close
In mill, banburying of pressurizeing, colloid material is obtained；Colloid material carries out rolling plasticizing, obtains colloid；
S4. colloid material is put into filter, filtering, obtains melting charge, afterwards melting charge carried out pre-crystallized and dried
Operate obtained material B；
S5. material B is rolled by calender, afterwards, by the wheel group embossing molding being made up of minute surface steel wheel and rubber wheel,
Obtain material C；
S6. by the material C of embossing shaping in step S2 after cooling, cutting edge, winding, a kind of cold-proof PVC film is obtained.
Compared with prior art, the beneficial effects of the invention are as follows：
A kind of smooth PVC film and its production method of the present invention, its formula are：Polyvinyl chloride resin 80-90 parts, epoxy are big
Soya-bean oil 1-3 parts, plasticizer DPHP 35-45 parts, thermoplastic acrylic resin 1-3 parts, pigment 0.1-0.2, brightening agent 0.001-
0.002 part and slipping agent 0.05-0.1 parts, are acted on by each formula, make PVC film surface abrasion resistance, smooth, have preferably resistance to
Corrosivity and tensile property.
Embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
A kind of smooth PVC film of the present invention, 85 parts of polyvinyl chloride resin, 2 parts of epoxidized soybean oil, 39 parts of plasticizer DPHP,
1.8 parts of thermoplastic acrylic resin, pigment are 7078 and 087F, and 7078 be 0.008 part, and 087F is 0.12 part, brightening agent 0.001
0.085 part of part and slipping agent.
The Graphene powder of polyvinyl chloride resin mass fraction 2% is additionally added, Graphene powder increases the wearability of PVC film, PVC trees
The fullerene powder of fat mass fraction 4%, the graphite powder of polyvinyl chloride resin mass fraction 5%, fullerene powder and graphite powder add PVC
The smoothness of film.
Brightening agent is CBS127, and slipping agent is talcum powder, diatomite or silica.
A kind of production method of smooth PVC film, comprises the following steps：
S1. each component raw material is put into progress high-speed stirred mixing in high-speed mixer in proportion, then controls mixer will
Material scattering is in granular form；
S2. the granular material in step S1 is filtered, thing is obtained to the preliminary melting mixing of the material after filtering
Expect A；
S3. the material A obtained in step S2 is cooled down under agitation, obtains compound, compound is discharged into close
In mill, banburying of pressurizeing, colloid material is obtained；Colloid material carries out rolling plasticizing, obtains colloid；
S4. colloid material is put into filter, filtering, obtains melting charge, afterwards melting charge carried out pre-crystallized and dried
Operate obtained material B；
S5. material B is rolled by calender, afterwards, by the wheel group embossing molding being made up of minute surface steel wheel and rubber wheel,
Obtain material C；
S6. by the material C of embossing shaping in step S2 after cooling, cutting edge, winding, a kind of cold-proof PVC film is obtained.
Indices such as following table：
Finally it should be noted that：The preferred embodiments of the present invention are these are only, are not intended to limit the invention, although
The present invention is described in detail with reference to embodiment, for those skilled in the art, it still can be to foregoing
Technical scheme described in each embodiment is modified, or to which part technical characteristic carry out equivalent substitution, but it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc., the protection of the present invention should be included in
Within the scope of.
Claims (8)
1. a kind of smooth PVC film, it is characterised in that its formula is：Polyvinyl chloride resin 80-90 parts, epoxidized soybean oil 1-3 parts, plasticising
Agent DPHP 35-45 parts, thermoplastic acrylic resin 1-3 parts, pigment 0.1-0.2, brightening agent 0.001-0.002 parts and slipping agent
0.05-0.1 parts.
2. a kind of smooth PVC film according to claim 1, it is characterised in that be additionally added the polyvinyl chloride resin mass fraction 1-
3% Graphene powder.
3. a kind of smooth PVC film according to claim 1, it is characterised in that be additionally added the polyvinyl chloride resin mass fraction 2-
5% fullerene powder.
4. a kind of smooth PVC film according to claim 1, it is characterised in that be additionally added the polyvinyl chloride resin mass fraction 4-
6% graphite powder.
5. a kind of smooth PVC film according to claim 1, it is characterised in that the pigment is 7078 and 087F.
6. a kind of smooth PVC film according to claim 1, it is characterised in that the brightening agent is CBS127.
A kind of 7. smooth PVC film according to claim 1, it is characterised in that the slipping agent be talcum powder, diatomite or
Silica.
8. according to a kind of any one of claim 1 to 7 production method of smooth PVC film, it is characterised in that：Including following
Step：
S1. each component raw material is put into progress high-speed stirred mixing in high-speed mixer in proportion, then controls mixer by material
Break up and be in granular form；
S2. the granular material in step S1 is filtered, material A is obtained to the preliminary melting mixing of the material after filtering；
S3. the material A obtained in step S2 is cooled down under agitation, obtains compound, compound is discharged into banbury
It is interior, banburying of pressurizeing, obtain colloid material；Colloid material carries out rolling plasticizing, obtains colloid；
S4. colloid material is put into filter, filtering, obtains melting charge, melting charge is subjected to pre-crystallized and drying process afterwards
Obtained material B；
S5. material B is rolled by calender, afterwards, by the wheel group embossing molding being made up of minute surface steel wheel and rubber wheel, is obtained
Material C；
S6. by the material C of embossing shaping in step S2 after cooling, cutting edge, winding, a kind of cold-proof PVC film is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711048599.6A CN107793670A (en) | 2017-10-31 | 2017-10-31 | A kind of smooth PVC film and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711048599.6A CN107793670A (en) | 2017-10-31 | 2017-10-31 | A kind of smooth PVC film and its production method |
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| Publication Number | Publication Date |
|---|---|
| CN107793670A true CN107793670A (en) | 2018-03-13 |
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ID=61548638
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711048599.6A Pending CN107793670A (en) | 2017-10-31 | 2017-10-31 | A kind of smooth PVC film and its production method |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109354804A (en) * | 2018-10-24 | 2019-02-19 | 江苏名阳高分子新材料有限公司 | A kind of PVC floor film of superpower wear-resistant and preparation method thereof |
| CN111073177A (en) * | 2019-12-30 | 2020-04-28 | 上海永利输送系统有限公司 | PVC conducting bar and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865197A (en) * | 2014-03-18 | 2014-06-18 | 山东企鹅塑胶集团有限公司 | Antistatic composite thin film based on polyvinyl chloride and graphene and preparation method thereof |
| CN104861364A (en) * | 2014-12-30 | 2015-08-26 | 殷培花 | High-slipping polyvinyl chloride film material and preparation method thereof |
| CN107057229A (en) * | 2017-05-12 | 2017-08-18 | 佛山市天进塑胶有限公司 | A kind of PVC film gloss application sheet |
-
2017
- 2017-10-31 CN CN201711048599.6A patent/CN107793670A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865197A (en) * | 2014-03-18 | 2014-06-18 | 山东企鹅塑胶集团有限公司 | Antistatic composite thin film based on polyvinyl chloride and graphene and preparation method thereof |
| CN104861364A (en) * | 2014-12-30 | 2015-08-26 | 殷培花 | High-slipping polyvinyl chloride film material and preparation method thereof |
| CN107057229A (en) * | 2017-05-12 | 2017-08-18 | 佛山市天进塑胶有限公司 | A kind of PVC film gloss application sheet |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109354804A (en) * | 2018-10-24 | 2019-02-19 | 江苏名阳高分子新材料有限公司 | A kind of PVC floor film of superpower wear-resistant and preparation method thereof |
| CN111073177A (en) * | 2019-12-30 | 2020-04-28 | 上海永利输送系统有限公司 | PVC conducting bar and preparation method thereof |
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Application publication date: 20180313 |
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