CN107785245A - One kind improves conversion efficiency of solar cell diffusion method - Google Patents

One kind improves conversion efficiency of solar cell diffusion method Download PDF

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Publication number
CN107785245A
CN107785245A CN201610760645.4A CN201610760645A CN107785245A CN 107785245 A CN107785245 A CN 107785245A CN 201610760645 A CN201610760645 A CN 201610760645A CN 107785245 A CN107785245 A CN 107785245A
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flow
passed
nitrogen
oxygen
furnace temperature
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颜冬
初仁龙
董杰
李省
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TAIZHOU ET SOLAR CO Ltd
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TAIZHOU ET SOLAR CO Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/22Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities
    • H01L21/223Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities using diffusion into or out of a solid from or into a gaseous phase
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02107Forming insulating materials on a substrate
    • H01L21/02109Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
    • H01L21/02112Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
    • H01L21/02123Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
    • H01L21/02164Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material being a silicon oxide, e.g. SiO2
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02107Forming insulating materials on a substrate
    • H01L21/02225Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
    • H01L21/02227Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process
    • H01L21/0223Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by oxidation, e.g. oxidation of the substrate
    • H01L21/02233Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by oxidation, e.g. oxidation of the substrate of the semiconductor substrate or a semiconductor layer
    • H01L21/02236Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by oxidation, e.g. oxidation of the substrate of the semiconductor substrate or a semiconductor layer group IV semiconductor
    • H01L21/02238Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by oxidation, e.g. oxidation of the substrate of the semiconductor substrate or a semiconductor layer group IV semiconductor silicon in uncombined form, i.e. pure silicon

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Formation Of Insulating Films (AREA)

Abstract

The present invention relates to one kind to improve conversion efficiency of solar cell diffusion method, belongs to area of solar cell.It has quartzy stove preheating, pre-oxidation treatment, prediffusion processing, continue DIFFUSION TREATMENT, whole DIFFUSION TREATMENT and rear oxidation handle 6 steps, wherein prediffusion processing, the intake for continuing small nitrogen in DIFFUSION TREATMENT and whole DIFFUSION TREATMENT taper off trend.The present invention is advantageous in that:It is a kind of with TongYuan's degression type and constant temperature incrementally compound diffusion technique, under the premise of suitable Ohmic contact is ensured, surface recombination can be reduced, improve internal doping concentration, space-charge region performance is improved, reaches good Ohmic contact and recombination-rate surface, so as to improve battery conversion efficiency.

Description

One kind improves conversion efficiency of solar cell diffusion method
Technical field:
The present invention relates to one kind to improve conversion efficiency of solar cell diffusion method, belongs to area of solar cell.
Background technology:
Diffusing procedure is the core process of solar cell manufacturing process, and it to diffusion Quartz stove tube mainly by leading to POCL3 And oxygen, after pyrolytic, P2O5 and SI is produced, under p-type substrate, PN is formd by the diffusional deposition process of phosphorus atoms Knot, that is, the cardiac component of solar cell, traditional diffusion technique are mainly that constant temperature Heng Yuan spreads, basic diffusing step Or pass through:Oxidation, pre-deposition, deposition, diffusion etc..Although so sheet resistance has relatively stable, its surface recombination is dense Spend higher, increase its recombination-rate surface(SRV), in addition, junction depth also can be partially deep, may can have been helped for open-circuit voltage Voc Help, but can be poor for short-wave band response, influence its short circuit current(Isc), finally influence battery conversion efficiency(Eff).
The content of the invention:
For above technical problem, it is of the present invention it is a kind of improve conversion efficiency of solar cell diffusion method, have with Lower step:
Step 1, the preheating of quartzy stove
Silicon chip is put into quartzy stove, is passed through big nitrogen, the flow of big nitrogen is 15500-16500sccm, then by the stove of quartzy stove Temperature rise keeps 650-750s to 800-820 DEG C;
Step 2, pre-oxidation treatment
Oxygen and big nitrogen are passed through quartzy stove, wherein oxygen flow is 1800-2100sccm, and big nitrogen flow is 14700- 15000sccm, it is passed through time control and is maintained at 800-820 DEG C in 450-500s, furnace temperature, complete the pre-oxidation to silicon chip;
Step 3, prediffusion processing
The mixed gas of the small nitrogen for taking POCl3, big nitrogen and oxygen composition, the flow of its medium and small nitrogen are passed through into quartzy stove For 850-950sccm, the flow of big nitrogen is 14000-14500sccm, and the flow of oxygen is 700-800sccm, is passed through the time and is 550-650s, furnace temperature are maintained at 800-820 DEG C, complete prediffusion processing;
Step 4, continue DIFFUSION TREATMENT
Big nitrogen is passed through flow 15500-16500sccm, while furnace temperature is gradually increased into 810-830 DEG C, keeps 300-400s, then The mixed gas that the small nitrogen, big nitrogen and oxygen of taking POCl3 form is passed through quartzy stove, the flow of wherein its medium and small nitrogen is 750-850sccm, the flow of big nitrogen is 14500-15000sccm, and the flow of oxygen is 600-700sccm, is passed through the time and is 450-500s, furnace temperature are maintained at 810-830 DEG C, complete to continue DIFFUSION TREATMENT;
Step 5, whole DIFFUSION TREATMENT
Big nitrogen is passed through flow 15500-16500sccm, while furnace temperature is gradually increased into 817-837 DEG C, keeps 300-400s, then The mixed gas that the small nitrogen, big nitrogen and oxygen of taking POCl3 form is passed through quartzy stove, the flow of wherein its medium and small nitrogen is 650-750sccm, the flow of big nitrogen is 14600-15100sccm, and the flow of oxygen is 500-600sccm, is passed through the time and is 350-400s, furnace temperature are maintained at 817-837 DEG C, complete to continue DIFFUSION TREATMENT;
Step 6, rear oxidation is handled
To treat that furnace temperature is down at 700-750 DEG C, oxygen and big nitrogen are passed through quartzy stove, wherein oxygen flow is 800-1500sccm, Big nitrogen flow is 14800-15200sccm, is passed through time control in 350-400s, completes the pre-oxidation to silicon chip.
Preferably, the intake of small nitrogen tapers off in the prediffusion processing, continuation DIFFUSION TREATMENT and whole DIFFUSION TREATMENT Trend.
Compared with prior art, usefulness of the present invention is;It is a kind of incrementally compound with constant temperature with TongYuan's degression type Diffusion technique, under the premise of suitable Ohmic contact is ensured, surface recombination can be reduced, improve internal doping concentration, improve space Charged region performance, reach good Ohmic contact and recombination-rate surface, so as to improve battery conversion efficiency.
Embodiment:
A kind of raising conversion efficiency of solar cell diffusion method of the present invention, has steps of:
Step 1, the preheating of quartzy stove
Silicon chip is put into quartzy stove, is passed through big nitrogen, the flow of big nitrogen is 15500-16500sccm, then by the stove of quartzy stove Temperature rise keeps 650-750s to 800-820 DEG C;
Step 2, pre-oxidation treatment
Oxygen and big nitrogen are passed through quartzy stove, wherein oxygen flow is 1800-2100sccm, and big nitrogen flow is 14700- 15000sccm, it is passed through time control and is maintained at 800-820 DEG C in 450-500s, furnace temperature, complete the pre-oxidation to silicon chip;
Step 3, prediffusion processing
The mixed gas of the small nitrogen for taking POCl3, big nitrogen and oxygen composition, the flow of its medium and small nitrogen are passed through into quartzy stove For 850-950sccm, the flow of big nitrogen is 14000-14500sccm, and the flow of oxygen is 700-800sccm, is passed through the time and is 550-650s, furnace temperature are maintained at 800-820 DEG C, complete prediffusion processing;
Step 4, continue DIFFUSION TREATMENT
Big nitrogen is passed through flow 15500-16500sccm, while furnace temperature is gradually increased into 810-830 DEG C, keeps 300-400s, then The mixed gas that the small nitrogen, big nitrogen and oxygen of taking POCl3 form is passed through quartzy stove, the flow of wherein its medium and small nitrogen is 750-850sccm, the flow of big nitrogen is 14500-15000sccm, and the flow of oxygen is 600-700sccm, is passed through the time and is 450-500s, furnace temperature are maintained at 810-830 DEG C, complete to continue DIFFUSION TREATMENT;
Step 5, whole DIFFUSION TREATMENT
Big nitrogen is passed through flow 15500-16500sccm, while furnace temperature is gradually increased into 817-837 DEG C, keeps 300-400s, then The mixed gas that the small nitrogen, big nitrogen and oxygen of taking POCl3 form is passed through quartzy stove, the flow of wherein its medium and small nitrogen is 650-750sccm, the flow of big nitrogen is 14600-15100sccm, and the flow of oxygen is 500-600sccm, is passed through the time and is 350-400s, furnace temperature are maintained at 817-837 DEG C, complete to continue DIFFUSION TREATMENT;
Step 6, rear oxidation is handled
To treat that furnace temperature is down at 700-750 DEG C, oxygen and big nitrogen are passed through quartzy stove, wherein oxygen flow is 800-1500sccm, Big nitrogen flow is 14800-15200sccm, is passed through time control in 350-400s, completes the rear oxidation to silicon chip.
In order to further show the Spirit Essence of the present invention, it is described further with reference to embodiment:
Using raw material, thickness is 200 ± 20um, resistivity 0.5-6W.cm, by surface clean for P type monocrystalline silicon pieces With the processing of, surface-texturing, 1-3nm positive pyramid matte is formed on surface, silicon chip is put into and expanded in quartzy stove.
Step 1, the preheating of quartzy stove
Silicon chip is put into quartzy stove, is passed through big nitrogen, the flow of big nitrogen is 16000sccm, then rises to the furnace temperature of quartzy stove 800 DEG C, keep 705s;
Step 2, pre-oxidation treatment
Oxygen and big nitrogen are passed through quartzy stove, wherein oxygen flow is 2000sccm, and big nitrogen flow is 14800sccm, when being passed through Between control in 480s, furnace temperature is maintained at 800 DEG C, completes the pre-oxidation to silicon chip;
Step 3, prediffusion processing
The mixed gas of the small nitrogen for taking POCl3, big nitrogen and oxygen composition, the flow of its medium and small nitrogen are passed through into quartzy stove For 900sccm, the flow of big nitrogen is 14350sccm, and the flow of oxygen is 750sccm, and it is 600s to be passed through the time, and furnace temperature is maintained at 800 DEG C, complete prediffusion processing;
Step 4, continue DIFFUSION TREATMENT
Big nitrogen is passed through flow 16000sccm, while furnace temperature is gradually increased into 820 DEG C, keeps 360s, then will take POCl3 The mixed gas of small nitrogen, big nitrogen and oxygen composition is passed through quartzy stove, and the wherein flow of its medium and small nitrogen is 800sccm, big nitrogen Flow is 14550sccm, and the flow of oxygen is 650sccm, and it is 480s to be passed through the time, and furnace temperature is maintained at 820 DEG C, and completion continues to expand Dissipate processing;
Step 5, whole DIFFUSION TREATMENT
Big nitrogen is passed through flow 16000sccm, while furnace temperature is gradually increased into 827 DEG C, keeps 360s, then will take POCl3 The mixed gas of small nitrogen, big nitrogen and oxygen composition is passed through quartzy stove, and the wherein flow of its medium and small nitrogen is 700sccm, big nitrogen Flow is 14750sccm, and the flow of oxygen is 550sccm, and it is 360s to be passed through the time, and furnace temperature is maintained at 827 DEG C, and completion continues to expand Dissipate processing;
Step 6, rear oxidation is handled
Treat that furnace temperature is down at 720 DEG C, oxygen and big nitrogen are passed through quartzy stove, wherein oxygen flow is 1000sccm, big nitrogen flow For 15000sccm, time control is passed through in 360s, completes the rear oxidation to silicon chip.
Conventional method compares such as following table with the parameter of solar cell made of the inventive method:
Experiment condition Open-circuit voltage (U) Short circuit current (Isc) Fill factor, curve factor (FF) Series resistance (Rs) Parallel resistance (Rsh) Battery conversion efficiency (EFF) Reverse current (Irev2)
Gradient method diffusion technique 0.635 8.9 79.31 0.0022 95 18.41% 0.251
Normal diffusion technique 0.635 8.83 79.53 0.0021 130.2 18.26% 0.156
Need to be stressed that:It the above is only the introduction and description of the occupation mode of the present invention, not make any shape to the present invention Limitation in formula, any simple modification that every technical spirit according to the present invention is made to above example, equivalent variations with Modification, in the range of still falling within technical solution of the present invention.

Claims (3)

1. one kind improves conversion efficiency of solar cell diffusion method, it is characterised in that has steps of:
Step 1, the preheating of quartzy stove
Silicon chip is put into quartzy stove, is passed through big nitrogen, the flow of big nitrogen is 15500-16500sccm, then by the stove of quartzy stove Temperature rise keeps 650-750s to 800-820 DEG C;
Step 2, pre-oxidation treatment
Oxygen and big nitrogen are passed through quartzy stove, wherein oxygen flow is 1800-2100sccm, and big nitrogen flow is 14700- 15000sccm, it is passed through time control and is maintained at 800-820 DEG C in 450-500s, furnace temperature, complete the pre-oxidation to silicon chip;
Step 3, prediffusion processing
The mixed gas of the small nitrogen for taking POCl3, big nitrogen and oxygen composition, the flow of its medium and small nitrogen are passed through into quartzy stove For 850-950sccm, the flow of big nitrogen is 14000-14500sccm, and the flow of oxygen is 700-800sccm, is passed through the time and is 550-650s, furnace temperature are maintained at 800-820 DEG C, complete prediffusion processing;
Step 4, continue DIFFUSION TREATMENT
Big nitrogen is passed through flow 15500-16500sccm, while furnace temperature is gradually increased into 810-830 DEG C, keeps 300-400s, then The mixed gas that the small nitrogen, big nitrogen and oxygen of taking POCl3 form is passed through quartzy stove, the flow of wherein its medium and small nitrogen is 750-850sccm, the flow of big nitrogen is 14500-15000sccm, and the flow of oxygen is 600-700sccm, is passed through the time and is 450-500s, furnace temperature are maintained at 810-830 DEG C, complete to continue DIFFUSION TREATMENT;
Step 5, whole DIFFUSION TREATMENT
Big nitrogen is passed through flow 15500-16500sccm, while furnace temperature is gradually increased into 817-837 DEG C, keeps 300-400s, then The mixed gas that the small nitrogen, big nitrogen and oxygen of taking POCl3 form is passed through quartzy stove, the flow of wherein its medium and small nitrogen is 650-750sccm, the flow of big nitrogen is 14600-15100sccm, and the flow of oxygen is 500-600sccm, is passed through the time and is 350-400s, furnace temperature are maintained at 817-837 DEG C, complete to continue DIFFUSION TREATMENT;
Step 6, rear oxidation is handled
To treat that furnace temperature is down at 700-750 DEG C, oxygen and big nitrogen are passed through quartzy stove, wherein oxygen flow is 800-1500sccm, Big nitrogen flow is 14800-15200sccm, is passed through time control in 350-400s, completes the pre-oxidation to silicon chip.
A kind of 2. raising conversion efficiency of solar cell diffusion method according to claim 1, it is characterised in that:It is described Prediffusion processing, the intake for continuing small nitrogen in DIFFUSION TREATMENT and whole DIFFUSION TREATMENT taper off trend.
3. a kind of raising conversion efficiency of solar cell diffusion method according to claim 1, it is characterised in that each The technological parameter of step is as follows:
Step 1, the preheating of quartzy stove
The flow of big nitrogen is 16000sccm, and the furnace temperature of quartzy stove then is risen into 800 DEG C, keeps 705s;
Step 2, pre-oxidation treatment
Oxygen flow is 2000sccm, and big nitrogen flow is 14800sccm, is passed through time control and is maintained at 800 in 480s, furnace temperature ℃;
Step 3, prediffusion processing
The flow of small nitrogen is 900sccm, and the flow of big nitrogen is 14350sccm, and the flow of oxygen is 750sccm, is passed through the time and is 600s, furnace temperature are maintained at 800-820 DEG C;
Step 4, continue DIFFUSION TREATMENT
Furnace temperature ascent stage, big nitrogen is passed through flow 16000sccm, while furnace temperature is gradually increased into 820 DEG C, keeps 360s, diffusion In the stage, the flow of small nitrogen is 800sccm, and the flow of big nitrogen is 14550sccm, and the flow of oxygen is 650sccm, is passed through the time and is 480s, furnace temperature are maintained at 820 DEG C;
Step 5, whole DIFFUSION TREATMENT
Furnace temperature ascent stage, big nitrogen is passed through flow 16000sccm, while furnace temperature is gradually increased into 827 DEG C, keeps 360s, diffusion In the stage, the flow of small nitrogen is 700sccm, and the flow of big nitrogen is 14750sccm, and the flow of oxygen is 550sccm, is passed through the time and is 360s, furnace temperature are maintained at 827 DEG C;
Step 6, rear oxidation is handled
Oxygen flow is 1000sccm, and big nitrogen flow is 15000sccm, is passed through time control in 360s.
CN201610760645.4A 2016-08-31 2016-08-31 One kind improves conversion efficiency of solar cell diffusion method Pending CN107785245A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102723266A (en) * 2012-06-19 2012-10-10 江苏泓源光电科技有限公司 Solar battery diffusion method
CN104716232A (en) * 2015-03-13 2015-06-17 中节能太阳能科技(镇江)有限公司 Solar cell emitter doping distribution method
CN105280755A (en) * 2015-09-17 2016-01-27 江西展宇新能源股份有限公司 Thrice continuous deposition and heating diffusion technology

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102723266A (en) * 2012-06-19 2012-10-10 江苏泓源光电科技有限公司 Solar battery diffusion method
CN104716232A (en) * 2015-03-13 2015-06-17 中节能太阳能科技(镇江)有限公司 Solar cell emitter doping distribution method
CN105280755A (en) * 2015-09-17 2016-01-27 江西展宇新能源股份有限公司 Thrice continuous deposition and heating diffusion technology

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Application publication date: 20180309