CN107779914B - Cathode of starting sheet - Google Patents

Cathode of starting sheet Download PDF

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Publication number
CN107779914B
CN107779914B CN201610743824.7A CN201610743824A CN107779914B CN 107779914 B CN107779914 B CN 107779914B CN 201610743824 A CN201610743824 A CN 201610743824A CN 107779914 B CN107779914 B CN 107779914B
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China
Prior art keywords
conductive
starting sheet
rod
clamping piece
self
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CN201610743824.7A
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CN107779914A (en
Inventor
邓爱民
邵晓光
汪佳良
刘文彬
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Jiangxi Nerin Equipment Co Ltd
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Jiangxi Nerin Equipment Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/02Electrodes; Connections thereof
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/06Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
    • C25C1/08Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of nickel or cobalt
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Prevention Of Electric Corrosion (AREA)

Abstract

The invention discloses a cathode of a starting sheet. The starting sheet cathode includes: a conductive rod; a starting sheet; and the conductive clamp is sleeved on the conductive rod and clamps the starting sheet. The starting sheet is directly connected with the conductive rod through the clamping of the conductive clamp, pretreatment such as embossing correction is not needed for the starting sheet, and the shape of an electrolytic or electrodeposited finished product is guaranteed to be perfect, so that the finished product is not required to be transferred to finished product processing equipment, lifting lug shearing and packing operations are performed, the electric efficiency is obviously increased, the operation procedures are simplified, the equipment is reduced, the labor is saved, the energy is saved, the consumption is reduced, and the production cost is greatly reduced.

Description

Cathode of starting sheet
Technical Field
The invention relates to the field of chemical industry, in particular to a cathode of a starting sheet.
Background
The traditional electric nickel production needs to make nickel negative plate, and nickel negative plate comprises conducting rod, lug and starting sheet, and the lug needs dedicated lug cutter to make, and the starting sheet needs the embossing to correct, and the lug of making is bent the back and is passed the conducting rod to rivet on the starting sheet. Because the lifting lug on the electric nickel finished product can influence the sales of electric nickel, the electric nickel finished product needs to be transported to finished product processing equipment to perform operations such as lifting lug shearing and packing, but the sales price of the lifting lug sheared off can be lower than that of electric nickel. Because the conductive rod is repeatedly used, the part contacted with the lifting lug is required to be cleaned and polished regularly, and the electrolysis efficiency is not influenced; meanwhile, the resistance of the copper lifting lug is smaller than that of the nickel lifting lug. Therefore, the use of the traditional cathode requires more supporting equipment, more operators, more process transportation, low electrical efficiency and high cost.
Thus, the existing starting sheet cathode is to be improved.
Disclosure of Invention
The present invention aims to solve at least one of the technical problems existing in the prior art. Therefore, one purpose of the invention is to provide a cathode of a starting sheet, wherein the starting sheet is clamped and fixed on a conductive rod through a conductive clamp, the starting sheet does not need to be pretreated, the shape of an electrolytic or electrodeposited finished product is ensured to be intact, the electrolytic or electrodeposited finished product does not need to be transferred to a finished product processing device, and operations such as lifting lug shearing, packaging and the like are performed, so that the electric efficiency is high and the cost is low.
Thus, according to one aspect of the present invention, there is provided a starting sheet cathode. According to an embodiment of the present invention, the starting sheet cathode includes: a conductive rod; a starting sheet; and the conductive clamp is sleeved on the conductive rod and clamps the starting sheet.
According to the cathode of the starting sheet, the starting sheet is clamped and fixed on the conductive rod through the conductive clamp, pretreatment such as embossing correction is not needed for the starting sheet, and the shape of an electrolytic or electrodeposited finished product is guaranteed to be intact, so that the electrolytic or electrodeposited finished product is not needed to be transferred to a finished product processing device for operations such as lifting lug shearing and packaging, the electric efficiency is obviously high, the operation procedures are simplified, the devices are reduced, the manpower is saved, the energy is saved, the consumption is reduced, and the production cost is greatly reduced.
In addition, the cathode for a starting sheet according to the above embodiment of the present invention may have the following additional technical features:
according to an embodiment of the present invention, the conductive jig includes: the upper end of the conductive clamping piece is in a shape corresponding to the conductive rod and is in contact with the conductive rod; the deflector rod is arranged opposite to the conductive clamping piece; the self-locking pressing block is rotatably arranged at the lower end of the deflector rod, and the self-locking pressing block is matched with the conductive clamping piece to clamp the starting sheet.
According to an embodiment of the present invention, the conductive jig further includes: and a rotation shaft about which the lever rotates.
According to an embodiment of the present invention, the conductive jig further includes: the first shell is arranged outside the conductive clamping piece, a first clamping piece is arranged in the first shell, and the first clamping piece is sleeved on the conductive rod; the second shell is arranged outside the deflector rod, a second clamping piece is arranged in the second shell, and the second clamping piece is sleeved on the conductive rod.
According to an embodiment of the invention, the self-locking compact has a serrated face.
According to an embodiment of the invention, the first housing and the second housing are connected by bolts and the conductive clip is fixed on the conductive rod.
According to the embodiment of the invention, the self-locking pressing block is hinged with the lower end of the deflector rod.
According to an embodiment of the present invention, the conductive jigs are plural.
According to an embodiment of the present invention, at least one of the lever, the first housing and the second housing is formed of a corrosion resistant material.
According to an embodiment of the invention, the conductive clip, the rotating shaft and the self-locking press block are all formed of pure copper.
Additional aspects and advantages of the invention will be set forth in part in the description which follows, and in part will be obvious from the description, or may be learned by practice of the invention.
Drawings
The foregoing and/or additional aspects and advantages of the invention will become apparent and may be better understood from the following description of embodiments taken in conjunction with the accompanying drawings in which:
FIG. 1 shows a schematic structure of a cathode of a starting sheet according to an embodiment of the present invention;
FIG. 2 shows a schematic longitudinal section of a conductive clip according to one embodiment of the invention;
fig. 3 shows a schematic partial structure of a cathode of a starting sheet according to the present invention.
Detailed Description
Embodiments of the present invention are described in detail below, examples of which are illustrated in the accompanying drawings, wherein like or similar reference numerals refer to like or similar elements or elements having like or similar functions throughout. The embodiments described below by referring to the drawings are illustrative only and are not to be construed as limiting the invention.
In the description of the present invention, the terms "longitudinal", "transverse", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", etc. refer to the orientation or positional relationship based on that shown in the drawings, merely for convenience of description of the present invention and do not require that the present invention must be constructed and operated in a specific orientation, and thus should not be construed as limiting the present invention.
It should be noted that the terms "first," "second," and "second" are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or implying a number of technical features being indicated. Thus, a feature defining "a first" or "a second" may explicitly or implicitly include one or more such feature. Further, in the description of the present invention, unless otherwise indicated, the meaning of "a plurality" is two or more.
According to one aspect of the invention, a starting sheet cathode is provided. Referring to fig. 1, the starting sheet cathode according to an embodiment of the present invention includes: the device comprises a conductive rod 1, a starting sheet 2 and a conductive clamp 3, wherein the conductive clamp 3 is sleeved on the conductive rod 1 and clamps the starting sheet 2.
The cross-sectional shape of the conductive rod is not particularly limited, and may be adjusted according to the production requirements. According to some embodiments of the invention, the cross-section of the conductive rod may be circular and square.
In addition, the material of the starting sheet is not particularly limited as long as electrolysis and electrodeposition can be performed, and can be adjusted according to the kind of metal cations in the electrolyte, and the starting sheet material includes, but is not limited to, copper, lead, zinc, nickel and stainless steel.
Referring to fig. 2, fig. 2 is a schematic view of a conductive clip along section C-C, according to an embodiment of the present invention, the conductive clip 3 may include: the upper end of the conductive clamping piece 3.4 is in a shape corresponding to the conductive rod 1 and is in contact with the conductive rod 1, so that the upper end of the conductive clamping piece is attached and fixed on the conductive rod 1, and the conduction of current between the conductive rod and the starting sheet is ensured; the deflector rod 3.6 is arranged opposite to the conductive clamping piece 3.4, so that the starting sheet is conveniently clamped by utilizing the interaction force between the self-locking pressing block at the lower end of the deflector rod and the conductive clamping piece; the self-locking pressing block 3.5 is rotatably arranged at the lower end of the deflector rod 3.6, and the self-locking pressing block 3.5 is matched with the conductive clamping piece 3.4 to clamp the starting sheet 2. When the starting sheet 2 is placed in the self-locking pressing block 3.5 and the conductive clamping sheet 3.4, the stirring rod 3.6 is used for stirring the stirring rod 3.6 to turn the self-locking pressing block 3.5 to the upper side, so that the protrusion is upwards oriented, the starting sheet 2 is convenient to put in, when the starting sheet 2 is placed in the self-locking pressing block 3.5 and the conductive clamping sheet 3.4, the stirring rod 3.6 is used for stirring the self-locking pressing block 3.5 to turn downwards, the self-locking pressing block 3.5 has a trend of continuing to turn downwards due to the action of gravity, the protrusion end and the conductive clamping sheet 3.4 mutually squeeze and clamp the starting sheet 2, and the conductive clamping sheet 3.4 is contacted with the starting sheet 2 for direct current conduction between the conductive rod and the starting sheet in the electrolysis process.
According to an embodiment of the present invention, the conductive jig 3 further includes: the rotation shaft 3.3 and the shift lever 3.6 rotate around the rotation shaft 3.3. Therefore, the rotation shaft is utilized to realize the movement of the deflector rod, the lower part of the deflector rod is further stirred to drive the self-locking pressing block to press the starting sheet, one side of the starting sheet is extruded by the self-locking pressing block, and the other side of the starting sheet is tightly attached to the conductive clamping piece.
Wherein the rotation shaft 3.3 can be fixed to the second housing 3.2 by means of a hinge as shown in fig. 3, ensuring that the lever is rotatable around the rotation shaft in the second housing 3.2.
Referring to fig. 3, according to an embodiment of the present invention, the conductive jig 3 further includes: the first shell 3.1 and the second shell 3.2, wherein the first shell 3.1 is arranged outside the conductive clamping piece 3.4, a first clamping piece 3.7 is arranged in the first shell 3.1, and the first clamping piece 3.7 is sleeved on the conductive rod 1, so that the first shell is fixed on the conductive rod through the first clamping piece; the second casing 3.2 is arranged outside the deflector rod 3.6, and a second clamping piece 3.8 is arranged in the second casing 3.2, and the second clamping piece 3.8 is sleeved on the conductive rod, so that the second casing is fixed on the conductive rod through the second clamping piece.
According to an embodiment of the invention, the self-locking compact 3.5 has serrated surfaces. Therefore, the friction force between the self-locking pressing block and the starting sheet is increased by the serrated surface, so that the starting sheet is fixed more firmly.
Referring to fig. 3, according to an embodiment of the present invention, the first housing 3.1 and the second housing 3.2 are connected by bolts and the conductive clip 3.4 is fixed to the conductive rod 1. Therefore, the fixing method is simple, and the conductive clamping piece is convenient to clamp between the first shell and the second shell, so that the conductive clamping piece is fixed on the conductive rod.
According to the embodiment of the invention, the self-locking pressing block 3.5 is hinged with the lower end of the deflector rod 3.6. Therefore, the self-locking pressing block is convenient to rotate under the drive of the deflector rod.
According to an embodiment of the invention, the conductive clamp is a plurality of. Thus, the starting sheet is fixed more firmly.
According to an embodiment of the present invention, at least one of the lever 3.6, the first housing 3.1 and the second housing 3.2 is formed of a corrosion resistant material. Therefore, the conductive clamp has good corrosion resistance and long service life.
According to an embodiment of the invention, the conductive clip is formed of pure copper. Therefore, the conductive effect is good, and the conduction of current in the electrolysis process is facilitated.
In order to facilitate understanding of the starting sheet cathode according to the embodiment of the present invention, the following explains the working principle of the starting sheet cathode: when the novel self-locking device is in operation, the upper part of the poking rod 3.6 is poked to drive the self-locking pressing block 3.5 to be opened upwards, namely the lower end of the self-locking pressing block is separated from the conductive clamping piece 3.4 in the shell 3.1 by a certain distance, then the starting sheet 2 is inserted into a gap between the first shell 3.1 and the second shell 3.2 by a certain depth along the vertical direction, and the upper part of the poking rod is poked in the opposite direction, so that the poking rod drives the self-locking pressing block to move inwards to press the starting sheet on the conductive clamping piece 3.4 in the first shell 3.1. At this time, the gravity center of the self-locking pressing block 3.5 is positioned at the inner side of the self-rotation hinge point, and the self-locking pressing block 3.5 has a tendency of rotating and tilting towards the side of the starting sheet 2, so that a certain extrusion force is generated on the starting sheet 2 by the gravity of the self-locking pressing block 3.5, and self-locking is formed. After the starting sheet is fixed in the conductive clamp 3, a complete cathode for electrolysis and electrodeposition is formed, and finally, the transfer equipment hooks or grabs the conductive rod 1 to transfer the cathode into the electrolysis or electrodeposition tank, and the self-locking pressing block 3.5 forms self-locking on the starting sheet 2 in the transfer process, so that the tendency that the starting sheet 2 slips off the conductive clamp 3 is avoided. After the electrolysis or the electrodeposition is finished, the starting sheet 2 is changed into an electrolysis sheet or an electrodeposition sheet finished product is transported out, after the electrolysis sheet or the electrodeposition sheet finished product is transported to related equipment, the stirring rod 3.6 drives the self-locking pressing block 3.5 to leave the starting sheet 2 through the reverse operation, then the electrolysis or the electrodeposition product formed by the starting sheet 2 falls on subsequent output equipment, and the conductive rod 1 and the conductive clamp continuously clamp the new starting sheet to work.
Compared with the existing cathode of the starting sheet for electrolysis and electrodeposition, the cathode of the starting sheet provided by the embodiment of the invention has at least the following advantages:
(1) The lifting lug shearing machine, the finished nickel shearing equipment and the starting sheet embossing machine which are needed in the existing preparation process of the cathode of the starting sheet for electrolysis and electrodeposition are omitted, pretreatment of the starting sheet is not needed, the process is simplified, and equipment is saved;
(2) The middle part of the conductive rod does not need polishing and cleaning, so that the equipment investment is reduced;
(3) The equipment is reduced, so that the transfer of materials among the equipment is reduced;
(4) The reduction of equipment effectively simplifies workshop construction and reduces initial investment cost;
(5) The full-automatic work reduces operators;
(6) The production and use cost is low, and vulnerable parts used for punching lugs, lifting lug shearing, starting sheet riveting and the like, such as cutters, punches and the like, are not required;
(7) Compared with a nickel lifting lug which is used conventionally, the conductive efficiency of the conductive clamp is improved by more than 5 times, the voltage of the electrolytic tank is effectively reduced, the installed power of the equipment is lower, and the electricity consumption cost in production is effectively reduced;
(8) The lifting lug of the starting sheet is eliminated, and the price of the electrolytic or electrodeposited finished product is improved;
(9) Saving electricity and water, and being environment-friendly.
The invention will now be described with reference to specific examples, which are intended to be illustrative only and are not to be construed as limiting the invention.
Example 1
In this embodiment, the cathode structure of the starting sheet is shown in fig. 1-3, and includes a conductive rod 1, a starting sheet 2 and a conductive fixture 3, where the conductive fixture includes a first housing 3.1, a second housing 3.2, a rotating shaft 3.3, a conductive clamping piece 3.4, a self-locking pressing block 3.5 and a deflector rod 3.6. One end of a conductive clamp is fixedly connected with a conductive rod 1, and the other end of the conductive clamp is in clamping connection with the top of a starting sheet 2 through a self-locking clamp 3. The conductive rod 1 is made of pure copper, two conductive clamps 3 are symmetrically arranged on the conductive rod 1, and the cross section of the conductive rod 1 is circular as shown in fig. 2. The clamping piece 3.7 on the first shell 3.1 and the clamping piece 3.8 on the second shell 3.2 of stainless steel are of semicircular clamp structures and are respectively clamped at two sides of the conductive rod 1, wherein a conductive pure copper plate 3.4 is sleeved between the clamp of the first shell 3.1 and the conductive rod 1, the clamp is fastened through a fastening piece such as a bolt, so that the conductive pure copper plate 3.4 is tightly attached to the conductive rod 1, and the conductive clamp 3 is also tightly fixed on the conductive rod 1.
The inner side of the first shell is embedded with a pure copper conductive clamping piece 3.4, current is conducted between the conductive rod 1 and the starting sheet 2 during electrolysis, a self-locking pressing block 3.5 made of stainless steel materials, a rotating shaft 3.3 made of tetrafluoro materials and a deflector rod 3.6 are installed in the second shell 3.2, the lower end of the self-locking pressing block 3.5 is hinged and assembled on the second shell 3.2, the upper end of the self-locking pressing block is hinged and connected with the deflector rod 3.6, the middle part of the deflector rod 3.6 can rotate around the rotating shaft 3.3, the upper end of the deflector rod 3.6 is exposed out of the second shell 3.2, during operation, the exposed part of the deflector rod 3.6 is stirred to control the self-locking pressing block 3.5 to press or loosen the nickel starting sheet 2, and the two ends of the rotating shaft 3.3 are hinged with the second shell 3.2, so that the rotating shaft 3.3 can rotate in the second shell 3.2.
In the description of the present specification, a description referring to terms "one embodiment," "some embodiments," "examples," "specific examples," or "some examples," etc., means that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the present invention. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiments or examples. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
While embodiments of the present invention have been shown and described, it will be understood by those of ordinary skill in the art that: many changes, modifications, substitutions and variations may be made to the embodiments without departing from the spirit and principles of the invention, the scope of which is defined by the claims and their equivalents.

Claims (6)

1. A starting sheet cathode, comprising:
a conductive rod;
a starting sheet; and
the conductive clamp is sleeved on the conductive rod and clamps the starting sheet;
the conductive clip includes: the upper end of the conductive clamping piece is in a shape corresponding to the conductive rod and is in contact with the conductive rod; the deflector rod is arranged opposite to the conductive clamping piece; the self-locking pressing block is rotatably arranged at the lower end of the deflector rod, and the self-locking pressing block and the conductive clamping piece are matched to clamp the starting sheet;
the conductive clip further comprises: a rotation shaft about which the lever rotates;
the conductive clip further comprises: the first shell is arranged outside the conductive clamping piece, a first clamping piece is arranged in the first shell, and the first clamping piece is sleeved on the conductive rod; the second shell is arranged outside the deflector rod, a second clamping piece is arranged in the second shell, and the second clamping piece is sleeved on the conductive rod;
the first shell is connected with the second shell through bolts, and the conductive clamping piece is fixed on the conductive rod.
2. The starting sheet cathode of claim 1 wherein the self-locking compact has a serrated face.
3. The starting sheet cathode of claim 1, wherein the self-locking pressure block is hinged to the lower end of the deflector rod.
4. The starting sheet cathode of claim 1 wherein the conductive clip is a plurality.
5. The starting sheet cathode of claim 1, wherein at least one of the lever, the first housing, and the second housing is formed of a corrosion resistant material.
6. The starting sheet cathode of claim 1, wherein the conductive clip is formed of pure copper.
CN201610743824.7A 2016-08-26 2016-08-26 Cathode of starting sheet Active CN107779914B (en)

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CN107779914B true CN107779914B (en) 2023-07-18

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109763144B (en) * 2019-01-28 2020-09-08 中国铝业股份有限公司 Aluminum electrolysis device and method based on continuous anode
CN115044942B (en) * 2022-06-30 2024-06-21 金川集团镍钴有限公司 Starting sheet cathode and application method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4085997A (en) * 1977-03-30 1978-04-25 The Boeing Company Anodize clamp
JPH01172587A (en) * 1987-12-26 1989-07-07 Sumitomo Metal Mining Co Ltd Mother board for producing starting sheet
CN1500913A (en) * 2002-09-30 2004-06-02 日矿金属株式会社 Correction device for platy parts
CN2883404Y (en) * 2006-03-17 2007-03-28 金川集团有限公司 Electrode plate retainer for electrolytic mfg. powder
JP2008303426A (en) * 2007-06-07 2008-12-18 Mitsubishi Materials Corp Starting sheet for copper and production method therefor
CN201534879U (en) * 2009-09-11 2010-07-28 江西瑞林装备技术有限公司 Telescopic symmetric clamping device for copper anode plates

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4085997A (en) * 1977-03-30 1978-04-25 The Boeing Company Anodize clamp
JPH01172587A (en) * 1987-12-26 1989-07-07 Sumitomo Metal Mining Co Ltd Mother board for producing starting sheet
CN1500913A (en) * 2002-09-30 2004-06-02 日矿金属株式会社 Correction device for platy parts
CN2883404Y (en) * 2006-03-17 2007-03-28 金川集团有限公司 Electrode plate retainer for electrolytic mfg. powder
JP2008303426A (en) * 2007-06-07 2008-12-18 Mitsubishi Materials Corp Starting sheet for copper and production method therefor
CN201534879U (en) * 2009-09-11 2010-07-28 江西瑞林装备技术有限公司 Telescopic symmetric clamping device for copper anode plates

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