CN107779010A - Automobile generating cover plate catalysis oxidation paint vehicle - Google Patents

Automobile generating cover plate catalysis oxidation paint vehicle Download PDF

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Publication number
CN107779010A
CN107779010A CN201711065073.9A CN201711065073A CN107779010A CN 107779010 A CN107779010 A CN 107779010A CN 201711065073 A CN201711065073 A CN 201711065073A CN 107779010 A CN107779010 A CN 107779010A
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CN
China
Prior art keywords
parts
powder
paint vehicle
cover plate
catalysis oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711065073.9A
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Chinese (zh)
Inventor
李建国
黄秀云
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI BAODAO NEW ENERGY DEVELOPMENT Co Ltd
Original Assignee
ANHUI BAODAO NEW ENERGY DEVELOPMENT Co Ltd
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Filing date
Publication date
Application filed by ANHUI BAODAO NEW ENERGY DEVELOPMENT Co Ltd filed Critical ANHUI BAODAO NEW ENERGY DEVELOPMENT Co Ltd
Priority to CN201711065073.9A priority Critical patent/CN107779010A/en
Publication of CN107779010A publication Critical patent/CN107779010A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065After-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of automobile generating cover plate catalysis oxidation paint vehicle, the paint vehicle is made up of following raw material:22 parts of nanomaterial grade organosilicon-modified styrene-acrylic olefin(e) acid emulsion, 15 parts of urethane acrylate, 1,000 20 parts of mesh calcium carbonate, 1500 8 parts of mesh talcum powder, 18 parts of rutile titanium white powder, 5 parts of BMI, 5 parts of neopentyl glycol, 15 parts of hydroxyethyl cellulose, 8 parts of methyl-silicone oil, 5 parts of titanium dioxide, 3 parts of carboxylic acid, 14 parts of purified water, mixed type is without 3 parts of nonex powder, 6 parts of adhesion promoter, 4.8 parts of organic silicon modified polyurethane, hud typed micro- 5 parts of magnesium fluoride.The film of coating of the present invention is fine and close in neat formation, not bleeding, do not ftracture, do not rise it is swollen, and under intensive ultraviolet will not peeling, drying time is short, coordinates ultra violet lamp in spraying, can be so that coating is more preferable to cover plate adhesive force.

Description

Automobile generating cover plate catalysis oxidation paint vehicle
Technical field
The present invention relates to electric vehicle engineering field, more particularly to a kind of automobile generating cover plate catalysis oxidation paint vehicle.
Background technology
With the development of society, global energy crisis constantly aggravates, petroleum resources exhaustion, atmosphere pollution and global gas increasingly Temperature is warmed getting worse, and automobile is gone on a journey the indispensable vehicles as people, is usually relied on oil firing driving, can be aggravated energy Source and environmental crisis.On the other hand, automobile industry is proposed New-energy electric vehicle, oil firing can be avoided or reduced, may advantageously facilitate ring The short crisis of traditional energy is protected and alleviated in border, has wide market development prospect.
With the propulsion of China's energy-saving and emission-reduction policy, new energy vehicle is widely applied, particularly electric vehicle, is adopted With driven by power, exhaust emission is not produced, is the vital measure for realizing communications and transportation aspect energy-saving and emission-reduction.
In recent years, shared electric automobile engenders, due to its character of use, causes its frequency of use very high, during operation Between it is long, therefore higher is required to the coating quality on its surface, common coating can not meet indices, and common coating has following lack Point:
(1) common coating poor insulativity, using having potential safety hazard on electric automobile;
(2) common coating non-refractory, for a long time in the case where burning sun is exposed to the sun, it may occur that ftracture, bubble, come off;
(3) common coating water-proof is poor, easily by rain penetration, causes inside to be corroded;
(4) common coating wears no resistance intolerant to colliding with, poor adhesive force, after accidentally scratching, it may appear that depainting phenomenon, enter And easily it is corroded.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of automobile generating cover plate catalysis oxidation paint vehicle.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of automobile generating cover plate catalysis oxidation paint vehicle, the paint vehicle are made up of following raw material:Nanomaterial grade 22 parts of organosilicon-modified styrene-acrylic olefin(e) acid emulsion, 15 parts of urethane acrylate, 1,000 20 parts of mesh calcium carbonate, 1500 mesh talcum powder 8 Part, 18 parts of rutile titanium white powder, 5 parts of BMI, 5 parts of neopentyl glycol, 15 parts of hydroxyethyl cellulose, methyl-silicone oil 8 Part, 5 parts of titanium dioxide, 3 parts of carboxylic acid, 14 parts of purified water, mixed type is without 3 parts of nonex powder, 6 parts of adhesion promoter, organosilicon 4.8 parts of modified polyurethane, hud typed micro- 5 parts of magnesium fluoride.
Further, the mixed type includes fusing point at 750 degree without nonex powder and fusing point without nonex powder At 680 degree without nonex powder, and the fusing point at 750 degree without nonex powder and nothing of the fusing point at 680 degree The part by weight of nonex powder is 2: 3.
Further, the particle diameter of the hud typed magnesium fluoride microballoon is 4-150nm.
Further, the organic silicon modified polyurethane is block copolymer or one kind in graft copolymers or all two kinds Mixture.
Beneficial effects of the present invention:The film of coating of the present invention is fine and close in neat formation, not bleeding, does not ftracture, does not play swollen, Er Qie Under intensive ultraviolet will not peeling, drying time is short, spraying when coordinate ultra violet lamp, can so that coating to cover plate adhesive force more It is good.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of automobile generating cover plate catalysis oxidation paint vehicle, the paint vehicle are made up of following raw material:Nanomaterial grade 22 parts of organosilicon-modified styrene-acrylic olefin(e) acid emulsion, 15 parts of urethane acrylate, 1,000 20 parts of mesh calcium carbonate, 1500 mesh talcum powder 8 Part, 18 parts of rutile titanium white powder, 5 parts of BMI, 5 parts of neopentyl glycol, 15 parts of hydroxyethyl cellulose, methyl-silicone oil 8 Part, 5 parts of titanium dioxide, 3 parts of carboxylic acid, 14 parts of purified water, mixed type is without 3 parts of nonex powder, 6 parts of adhesion promoter, organosilicon 4.8 parts of modified polyurethane, hud typed micro- 5 parts of magnesium fluoride.
It is unleaded at 680 degree without nonex powder and fusing point at 750 degree that mixed type without nonex powder includes fusing point Boron glass powder, and the fusing point at 750 degree without nonex powder and weight without nonex powder of the fusing point at 680 degree Amount ratio is 2: 3.
The particle diameter of hud typed magnesium fluoride microballoon is 4-150nm.
Organic silicon modified polyurethane is block copolymer or one kind or all two kinds of mixture in graft copolymers.
Embodiment 2
A kind of automobile generating cover plate catalysis oxidation paint vehicle, the paint vehicle are made up of following raw material:Nanomaterial grade 22 parts of organosilicon-modified styrene-acrylic olefin(e) acid emulsion, 15 parts of urethane acrylate, 1,000 20 parts of mesh calcium carbonate, 1500 mesh talcum powder 8 Part, 18 parts of rutile titanium white powder, 5 parts of BMI, 5 parts of neopentyl glycol, 15 parts of hydroxyethyl cellulose, methyl-silicone oil 8 Part, 5 parts of titanium dioxide, 3 parts of carboxylic acid, 14 parts of purified water, mixed type is without 3 parts of nonex powder, 6 parts of adhesion promoter, organosilicon 4.8 parts of modified polyurethane, hud typed micro- 5 parts of magnesium fluoride.
It is unleaded at 680 degree without nonex powder and fusing point at 750 degree that mixed type without nonex powder includes fusing point Boron glass powder, and the fusing point at 750 degree without nonex powder and weight without nonex powder of the fusing point at 680 degree Amount ratio is 2: 3.
The particle diameter of hud typed magnesium fluoride microballoon is 4-150nm.
Organic silicon modified polyurethane is block copolymer or one kind or all two kinds of mixture in graft copolymers.
Catalysis oxidation paint vehicle lacquer spraying technique, comprises the following steps:
(1) preparation:Metal plate surface derusting is cleared up, and is derusted using sand paper;After derusting, with glacial acetic acid solution by base Face cleans up, and must smear greasy position wiped clean with staple etc., dry 6 minutes, one layer of latex is smeared on metal plate, waits metal plate On latex done after need to scrape powder of lacquer putty for use on the position painted in metal plate, polished after drying;
(2) paint:Not so block what need not be painted, metal plate is painted with the mode of spray painting, dry, spray painting When be irradiated with uviol lamp;
(3) dry:During more than 20 DEG C of atmospheric temperature, spontaneously dry, drying time is no less than 20 minutes;Atmospheric temperature is less than 20℃;
(4) polish:The metal plate for having sprayed finish paint is polished, labeling will processing;
(5) examine:Lacquered surface requirement is without slide mark, smooth, smooth.
Metal plate carries out Quenching Treatment before spray painting, and hardening heat is 150~200 DEG C, and the cool time is 5~10 seconds, is ensured The temperature of metal plate is 55 DEG C during spray painting.
The glacial acetic acid concentration is 4.3%.
Embodiment 3
A kind of automobile generating cover plate catalysis oxidation paint vehicle, the paint vehicle are made up of following raw material:Nanomaterial grade 22 parts of organosilicon-modified styrene-acrylic olefin(e) acid emulsion, 15 parts of urethane acrylate, 1,000 20 parts of mesh calcium carbonate, 1500 mesh talcum powder 8 Part, 18 parts of rutile titanium white powder, 5 parts of BMI, 5 parts of neopentyl glycol, 15 parts of hydroxyethyl cellulose, methyl-silicone oil 8 Part, 5 parts of titanium dioxide, 3 parts of carboxylic acid, 14 parts of purified water, mixed type is without 3 parts of nonex powder, 6 parts of adhesion promoter, organosilicon 4.8 parts of modified polyurethane, hud typed micro- 5 parts of magnesium fluoride.
It is unleaded at 680 degree without nonex powder and fusing point at 750 degree that mixed type without nonex powder includes fusing point Boron glass powder, and the fusing point at 750 degree without nonex powder and weight without nonex powder of the fusing point at 680 degree Amount ratio is 2: 3.
The particle diameter of hud typed magnesium fluoride microballoon is 4-150nm.
Organic silicon modified polyurethane is block copolymer or one kind or all two kinds of mixture in graft copolymers.
Catalysis oxidation paint vehicle lacquer spraying technique, comprises the following steps:
(1) preparation:Metal plate surface derusting is cleared up, and is derusted using sand paper;After derusting, with glacial acetic acid solution by base Face cleans up, and must smear greasy position wiped clean with staple etc., dry 6 minutes, one layer of latex is smeared on metal plate, waits metal plate On latex done after need to scrape powder of lacquer putty for use on the position painted in metal plate, polished after drying;
(2) paint:Not so block what need not be painted, metal plate is painted with the mode of spray painting, dry, spray painting When be irradiated with uviol lamp;
(3) dry:During more than 20 DEG C of atmospheric temperature, spontaneously dry, drying time is no less than 20 minutes;Atmospheric temperature is less than 20℃;
(4) polish:The metal plate for having sprayed finish paint is polished, labeling will processing;
(5) examine:Lacquered surface requirement is without slide mark, smooth, smooth.
Metal plate carries out Quenching Treatment before spray painting, and hardening heat is 150~200 DEG C, and the cool time is 5~10 seconds, then - 20 DEG C are cooled to metal plate again, then Quenching Treatment, hardening heat are 150~200 DEG C again, and the cool time is 5~10 seconds, is quenched Fire sprays tartaric acid solution to metal plate surface simultaneously.The temperature for ensureing metal plate during spray painting is 55 DEG C.
The glacial acetic acid concentration is 4.3%.
Performance measurement is carried out to the coating of embodiment 1,2,3, obtains following table:
The general principle and principal character of the present invention has been shown and described above.It should be understood by those skilled in the art that The present invention is not limited to the above embodiments, merely illustrating the principles of the invention described in above-described embodiment and specification, Without departing from the spirit and scope, various changes and modifications of the present invention are possible, and these changes and improvements all fall Enter in scope of the claimed invention.The scope of the present invention is defined by the appended claims and its equivalents.

Claims (4)

1. a kind of automobile generating cover plate catalysis oxidation paint vehicle, it is characterised in that the paint vehicle is by following raw material system Into:22 parts of nanomaterial grade organosilicon-modified styrene-acrylic olefin(e) acid emulsion, 15 parts of urethane acrylate, 1,000 20 parts of mesh calcium carbonate, 1500 8 parts of mesh talcum powder, 18 parts of rutile titanium white powder, 5 parts of BMI, 5 parts of neopentyl glycol, 15 parts of hydroxyethyl cellulose, first 8 parts of base silicone oil, 5 parts of titanium dioxide, 3 parts of carboxylic acid, 14 parts of purified water, mixed type is without 3 parts of nonex powder, 6 parts of adhesion promoter, 4.8 parts of organic silicon modified polyurethane, hud typed micro- 5 parts of magnesium fluoride.
2. automobile generating cover plate catalysis oxidation paint vehicle according to claim 1, it is characterised in that the mixed type without Nonex powder include fusing point 750 degree without nonex powder and fusing point at 680 degree without nonex powder, it is and described Fusing point is 2: 3 in 680 degree of the part by weight without nonex powder without nonex powder and the fusing point at 750 degree.
3. automobile generating cover plate catalysis oxidation paint vehicle according to claim 1, it is characterised in that the hud typed fluorine The particle diameter for changing magnesium microballoon is 4-150nm.
4. automobile generating cover plate catalysis oxidation paint vehicle according to claim 1, it is characterised in that the organosilicon changes Property polyurethane is block copolymer or one kind or all two kinds of mixture in graft copolymers.
CN201711065073.9A 2017-11-02 2017-11-02 Automobile generating cover plate catalysis oxidation paint vehicle Pending CN107779010A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711065073.9A CN107779010A (en) 2017-11-02 2017-11-02 Automobile generating cover plate catalysis oxidation paint vehicle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711065073.9A CN107779010A (en) 2017-11-02 2017-11-02 Automobile generating cover plate catalysis oxidation paint vehicle

Publications (1)

Publication Number Publication Date
CN107779010A true CN107779010A (en) 2018-03-09

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Country Status (1)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102558920A (en) * 2010-12-07 2012-07-11 比亚迪股份有限公司 Coating and light transmission material
CN102719193A (en) * 2012-06-27 2012-10-10 广州豪之晟化工有限公司 High-temperature resistant coating
CN103525294A (en) * 2013-09-28 2014-01-22 芜湖中集瑞江汽车有限公司 Rusted antirust paint and preparation method thereof
CN107177258A (en) * 2017-07-06 2017-09-19 安徽三环水泵有限责任公司 A kind of water pump antirust paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102558920A (en) * 2010-12-07 2012-07-11 比亚迪股份有限公司 Coating and light transmission material
CN102719193A (en) * 2012-06-27 2012-10-10 广州豪之晟化工有限公司 High-temperature resistant coating
CN103525294A (en) * 2013-09-28 2014-01-22 芜湖中集瑞江汽车有限公司 Rusted antirust paint and preparation method thereof
CN107177258A (en) * 2017-07-06 2017-09-19 安徽三环水泵有限责任公司 A kind of water pump antirust paint

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Application publication date: 20180309

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