CN107778975A - A kind of ink printing connection material formula and preparation method thereof - Google Patents
A kind of ink printing connection material formula and preparation method thereof Download PDFInfo
- Publication number
- CN107778975A CN107778975A CN201610770388.2A CN201610770388A CN107778975A CN 107778975 A CN107778975 A CN 107778975A CN 201610770388 A CN201610770388 A CN 201610770388A CN 107778975 A CN107778975 A CN 107778975A
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- Prior art keywords
- auxiliary agent
- oil
- ink printing
- added
- temperature
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
- C08G8/12—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with monohydric phenols having only one hydrocarbon substituent ortho on para to the OH group, e.g. p-tert.-butyl phenol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates
- C08G8/34—Chemically modified polycondensates by natural resins or resin acids, e.g. rosin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
The present invention discloses a kind of ink printing and links material formula and preparation method thereof, belongs to ink-printing techniques field, each material composition and weight percentage are：Rosin 45-55, octyl phenol 10 12, nonyl phenol 20 25, paraformaldehyde 8-20, polyalcohol 56, vegetable oil 20 40, mineral oil 25 35, catalyst 0.5 1, antioxygen auxiliary agent 0.15 0.2, water resistant auxiliary agent 0.2 0.3.The beneficial effects of the invention are as follows use the printing-ink phenolic resin：By the usage amount of two kinds of alkyl phenols, the molecular weight of resin is improved, makes the high comprehensive performances such as the water resistant of binder；Using one of the component of vegetable oil as binder, do not pollute the environment, be advantageous to manufacture and the health of user.
Description
Technical field
The invention belongs to ink-printing techniques field, is printed more particularly, to a kind of ink with connection material formula and its preparation
Method.
Background technology
Binder is the core component for manufacturing single-sheet offset printing ink, and its dosage accounts for the ink quality percentage
80% or so, refine the binder system for being adapted to high-grade ink to use, it is necessary to have rational process route.
In the prior art, phenolic -modified abietic resin is made with formaldehyde reaction in a kind of alkyl phenol of generally use, the technique
The phenolic resin molecular weight of production is confined to 2-3 ten thousand, and mineral oil dissolubility and demulsification performance are all very poor, it is difficult to meets present
The requirement of print speed printing speed development.
Meanwhile manufactured in common ink containing a large amount of harmful volatile organic compound ingredients in ink
When printing, drying process or equipment cleaning and waste ink are handled, substantial amounts of organic principle volatilization not only seriously endangers production operation people
The health of member, and environment can be caused greatly to destroy, seriously endanger health.
The content of the invention
In order to overcome the above-mentioned deficiencies of the prior art, it is an object of the invention to disclose a kind of ink printing with binder to be matched somebody with somebody
Side and preparation method thereof, improves the molecular weight of resin, makes the high comprehensive performances such as the water resistant of binder, do not pollute the environment,
Be advantageous to manufacture and the health of user.
To achieve these goals, the present invention is realized using following technical scheme：
A kind of ink printing connection material formula, it is characterised in that：Each material composition and weight percentage are：Rosin
45-55, octyl phenol 10-12, nonyl phenol 20-25, paraformaldehyde 8-20, polyalcohol 5-6, vegetable oil 20-40, mineral oil 25-
35, catalyst 0.5-1, antioxygen auxiliary agent 0.15-0.2, water resistant auxiliary agent 0.2-0.3.
The vegetable oil includes soybean oil and linseed oil.
The catalyst is lithium hydroxide.
A kind of ink printing connection material formula, each material composition and weight percentage are：Rosin 45-55, octyl phenol
10-12, nonyl phenol 20-25, paraformaldehyde 8-20, polyalcohol 5-6, soybean oil 13-23, linseed oil 7-17, mineral oil 25-35,
Lithium hydroxide catalyst 0.5-1, antioxygen auxiliary agent 0.15-0.2, water resistant auxiliary agent 0.2-0.3.
A kind of preparation method of ink printing binder, it is characterised in that comprise the following steps：
1. reactant preheating is melted
Vegetable oil and catalyst are added in a kettle according to the formula described in claim 1, are 175- in heating-up temperature
At 185 DEG C, rosin and nonyl phenol are added, is stirred.
2. condensation reaction
Octyl phenol, paraformaldehyde, control temperature 110-180 are added in a kettle according to the formula described in claim 1
DEG C insulation 1-6 hours, carry out condensation reaction.
3. esterification reaction
When temperature is risen into 230-240 DEG C, polyalcohol is added in a kettle, 30 minutes is incubated, then by reactor liter
Temperature arrives 240-260 DEG C, and surface leads to nitrogen in temperature-rise period, is incubated 2 hours, and sampling detection color and luster, viscosity, release property, acid value are straight
It is extremely qualified.
Detect it is qualified after, add vegetable oil and mineral oil in a kettle according to the formula described in claim 1, stirring is simultaneously
It is warming up to 210-230 DEG C and is incubated 30 minutes, detects viscosity, until it is qualified, antioxygen auxiliary agent and water resistant auxiliary agent are added after viscosity is qualified,
Releasing filters and packages.
The present invention has the advantages and positive effects of：
1. by the usage amount of two kinds of alkyl phenols, the molecular weight of resin is improved, makes the combination properties such as the water resistant of binder
It is excellent.
2. using one of component as binder of vegetable oil, do not pollute the environment, be advantageous to being good for for manufacture and user
Health.
Embodiment
Explanation is further explained to the present invention with reference to specific embodiment.
The present invention discloses a kind of ink printing connection material formula, it is characterised in that：Each material composition and weight percent contain
Measure and be：Rosin 45-55, octyl phenol 10-12, nonyl phenol 20-25, paraformaldehyde 8-20, polyalcohol 5-6, vegetable oil 20-40,
Mineral oil 25-35, catalyst 0.5-1, antioxygen auxiliary agent 0.15-0.2, water resistant auxiliary agent 0.2-0.3.
The vegetable oil includes soybean oil and linseed oil.
The catalyst is lithium hydroxide.
A kind of ink printing connection material formula, each material composition and weight percentage are：Rosin 45-55, octyl phenol
10-12, nonyl phenol 20-25, paraformaldehyde 8-20, polyalcohol 5-6, soybean oil 13-23, linseed oil 7-17, mineral oil 25-35,
Lithium hydroxide catalyst 0.5-1, antioxygen auxiliary agent 0.15-0.2, water resistant auxiliary agent 0.2-0.3.
A kind of preparation method of ink printing binder, it is characterised in that comprise the following steps：
1. reactant preheating is melted
Vegetable oil and catalyst are added in a kettle according to the formula described in claim 1, are 175- in heating-up temperature
At 185 DEG C, rosin and nonyl phenol are added, is stirred.
2. condensation reaction
Octyl phenol, paraformaldehyde, control temperature 110-180 are added in a kettle according to the formula described in claim 1
DEG C insulation 1-6 hours, carry out condensation reaction.
3. esterification reaction
When temperature is risen into 230-240 DEG C, polyalcohol is added in a kettle, 30 minutes is incubated, then by reactor liter
Temperature arrives 240-260 DEG C, and surface leads to nitrogen in temperature-rise period, is incubated 2 hours, and sampling detection color and luster, viscosity, release property, acid value are straight
It is extremely qualified.
Detect it is qualified after, add vegetable oil and mineral oil in a kettle according to the formula described in claim 1, stirring is simultaneously
It is warming up to 210-230 DEG C and is incubated 30 minutes, detects viscosity, until it is qualified, antioxygen auxiliary agent and water resistant auxiliary agent are added after viscosity is qualified,
Releasing filters and packages.
Time for being fed during resinon is refined, order, the length of soaking time, the height of temperature are to resinon
Performance has a significant impact：
The addition sequence and addition of two kinds of alkyl phenols have a great impact for this programme, by lot of experiments table
It is bright, in this scheme, nonyl phenol 20-25 is first added, octyl phenol 10-12 is added, the molecular weight of resin can be brought up to most
Greatly, significantly improve the combination properties such as water resistant, the pigment wetting of binder.
Holding temperature is higher, the time is longer, and the gloss of resinon is better, but the set speed of post-production ink is slow；Instead
It, holding temperature is lower, the time is shorter, and the gloss of resinon is poorer, but the set speed of post-production ink is fast, by multiple
Experiment, rational process route is finally determined, strict 220-225 DEG C of refining temperature, is incubated 30 minutes, synthesis meets that production will
Ask.
It is determined that suitable vegetable oil proportioning is also the emphasis of the technical program, there to have in post-production ink formulations to be suitable
Vegetable oil ratio, it can be only achieved post-production ink property indices and print request can be met, properly increase vegetable oil, drop
Low mineral oil also complies with environmental protection concept, by the making experiment and performance test of vegetable oil for several times, is finally determined that vegetable oil is matched somebody with somebody
Than：Soybean oil 13-23, linseed oil 7-17, to reach the main technical requirements such as gloss, set.
Production method implements process：
Embodiment 1：
A kind of ink printing connection material formula, each material composition and weight percentage are：Rosin 45-55, octyl phenol
10-12, nonyl phenol 20-25, paraformaldehyde 8-20, polyalcohol 5-6, vegetable oil 20-40, mineral oil 25-35, catalyst 0.5-
1, antioxygen auxiliary agent 0.15-0.2, water resistant auxiliary agent 0.2-0.3.
Embodiment 2：
A kind of ink printing connection material formula, each material composition and weight percentage are：Rosin 45-55, octyl phenol
10-12, nonyl phenol 20-25, paraformaldehyde 8-20, polyalcohol 5-6, soybean oil 13-23, linseed oil 7-17, mineral oil 25-35,
Lithium hydroxide catalyst 0.5-1, antioxygen auxiliary agent 0.15-0.2, water resistant auxiliary agent 0.2-0.3.
Embodiment 3：
A kind of preparation method of ink printing binder, it is 1. that 180 kilograms of soybean oil, linseed oil 120 is public according to step
In jin addition reactor, 7 kilograms of lithium hydroxide is added, when heating-up temperature is 175-185 DEG C, adds 300 kilograms of rosin, nonyl
60 kilograms of base phenol, is stirred；
30 kilograms of octyl phenol is 2. added in a kettle according to step, 190-210 DEG C of control temperature is incubated 1-1.5 hours,
33 kilograms of paraformaldehyde, 15 kilograms of polyalcohol are added in a kettle, paraformaldehyde are resolved into the formaldehyde of monomer, and contracted
Reaction is closed, when temperature is 210-220 DEG C, insulation 2-4 hours, surface leads to argon gas in temperature-rise period.
Reactor is 3. warming up to 220-225 DEG C according to step, is incubated 30 minutes, sampling detection is until color and luster #≤14；
Sampling detection release property, detection in every 20 minutes is determined once according to the data of detection, until release property >=2.5ml/
2g；
After release property detection is qualified, by 250 kilograms of addition reactors of higher boiling mineral oil, stir 30 minutes, detection is viscous
Degree, until viscosity is 30000mpa.s/25 DEG C, 1.6 kilograms of antioxygen auxiliary agent is added after viscosity is qualified, 2.5 kilograms of water resistant auxiliary agent, is put
Go out to filter and package.
The example performance indications reach：Viscosity：30000mpa.s/25 DEG C, release property >=5ml/2g, acid number≤15mgKOH/
G, color and luster #≤14, it is qualified products.
3 embodiments of the present invention are described in detail above, but the content is only the preferable implementation of the present invention
Example, it is impossible to be considered as the practical range for limiting the present invention.All equivalent changes made according to the present patent application scope and improvement
Deng, all should still belong to the present invention patent covering scope within.
Claims (5)
- A kind of 1. ink printing connection material formula, it is characterised in that：Each material composition and weight percentage are：Rosin 45- 55th, octyl phenol 10-12, nonyl phenol 20-25, paraformaldehyde 8-20, polyalcohol 5-6, vegetable oil 20-40, mineral oil 25-35, are urged Agent 0.5-1, antioxygen auxiliary agent 0.15-0.2, water resistant auxiliary agent 0.2-0.3.
- 2. ink printing connection material formula according to claim 1, it is characterised in that：The vegetable oil includes soybean oil And linseed oil.
- 3. ink printing connection material formula according to claim 2, it is characterised in that：The catalyst is hydroxide Lithium.
- 4. the ink printing connection material formula according to claim 1-3 any one, it is characterised in that：Each material composition And weight percentage is：Rosin 45-55, octyl phenol 10-12, nonyl phenol 20-25, paraformaldehyde 8-20, polyalcohol 5-6, Soybean oil 13-23, linseed oil 7-17, mineral oil 25-35, lithium hydroxide catalyst 0.5-1, antioxygen auxiliary agent 0.15-0.2, water resistant Auxiliary agent 0.2-0.3.
- 5. a kind of preparation method of ink printing binder, it is characterised in that comprise the following steps：1. reactant preheating is meltedVegetable oil and catalyst are added in a kettle according to the formula described in claim 1, are 175-185 DEG C in heating-up temperature When, rosin and nonyl phenol are added, is stirred.2. condensation reactionOctyl phenol, paraformaldehyde, 110-180 DEG C of guarantor of control temperature are added in a kettle according to the formula described in claim 1 Temperature 1-6 hours, carry out condensation reaction.3. esterification reactionWhen temperature is risen into 230-240 DEG C, polyalcohol is added in a kettle, is incubated 30 minutes, is then warming up to reactor 240-260 DEG C, surface leads to nitrogen in temperature-rise period, is incubated 2 hours, and sampling detection color and luster, viscosity, release property, acid value are until close Lattice.Detect it is qualified after, add vegetable oil and mineral oil in a kettle according to the formula described in claim 1, stir and heat up 30 minutes are incubated to 210-230 DEG C, detects viscosity, until it is qualified, antioxygen auxiliary agent and water resistant auxiliary agent are added after viscosity is qualified, is released Filter and package.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610770388.2A CN107778975A (en) | 2016-08-30 | 2016-08-30 | A kind of ink printing connection material formula and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610770388.2A CN107778975A (en) | 2016-08-30 | 2016-08-30 | A kind of ink printing connection material formula and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107778975A true CN107778975A (en) | 2018-03-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610770388.2A Pending CN107778975A (en) | 2016-08-30 | 2016-08-30 | A kind of ink printing connection material formula and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102040716A (en) * | 2010-11-09 | 2011-05-04 | 天津天女化工集团股份有限公司 | Phenolic resin for printing ink and production method thereof |
| CN103554401A (en) * | 2013-11-22 | 2014-02-05 | 天津市天宁树脂有限公司 | Formula and production method of phenolic resin for printing ink |
| CN105367728A (en) * | 2015-11-30 | 2016-03-02 | 苏州市博来特油墨有限公司 | Rosin modified phenol-formaldehyde resin and preparation method therefor |
| CN105968945A (en) * | 2016-06-06 | 2016-09-28 | 宋入林 | Connecting material composition for ink printing and preparation method thereof |
-
2016
- 2016-08-30 CN CN201610770388.2A patent/CN107778975A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102040716A (en) * | 2010-11-09 | 2011-05-04 | 天津天女化工集团股份有限公司 | Phenolic resin for printing ink and production method thereof |
| CN103554401A (en) * | 2013-11-22 | 2014-02-05 | 天津市天宁树脂有限公司 | Formula and production method of phenolic resin for printing ink |
| CN105367728A (en) * | 2015-11-30 | 2016-03-02 | 苏州市博来特油墨有限公司 | Rosin modified phenol-formaldehyde resin and preparation method therefor |
| CN105968945A (en) * | 2016-06-06 | 2016-09-28 | 宋入林 | Connecting material composition for ink printing and preparation method thereof |
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Application publication date: 20180309 |