CN107777765A - In nuclear power station acidic and alkaline waste water and discharge method and system - Google Patents

In nuclear power station acidic and alkaline waste water and discharge method and system Download PDF

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Publication number
CN107777765A
CN107777765A CN201610728137.8A CN201610728137A CN107777765A CN 107777765 A CN107777765 A CN 107777765A CN 201610728137 A CN201610728137 A CN 201610728137A CN 107777765 A CN107777765 A CN 107777765A
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CN
China
Prior art keywords
waste water
acidic
alkaline waste
alkaline
soda acid
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CN201610728137.8A
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Chinese (zh)
Inventor
梁桥洪
王志明
吴襄竹
熊京川
杨光文
詹媛
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China General Nuclear Power Corp
China Nuclear Power Engineering Co Ltd
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China General Nuclear Power Corp
China Nuclear Power Engineering Co Ltd
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Priority to CN201610728137.8A priority Critical patent/CN107777765A/en
Publication of CN107777765A publication Critical patent/CN107777765A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The invention discloses in a kind of acidic and alkaline waste water and discharge method, including:Record the parameter of the sum in and in container of the acidic and alkaline waste water under different operating modes;Physical dimension according to container is neutralized determines to neutralize the liquid level of container and the functional relation of volume;Acidic and alkaline waste water is mixed in and in container and gathers its liquid level and pH value data;According to the parameter of record, the functional relation determined, the data of collection, optimal soda acid chemical feeding quantity is calculated with mathematical modeling;Medicine is launched according to optimal soda acid chemical feeding quantity, waste water is completed and neutralizes.Compared with prior art, the present invention can realize waste water full automatic neutralization and qualified discharge under various operating modes, operated without manpower intervention, and its wastewater treatment time, dosing are optimal, reduce manpower, time, the reagent cost of waste water neutralisation treatment, be obviously improved the treatment effeciency of waste water neutralization.In addition, the invention also discloses in a kind of acidic and alkaline waste water and exhaust system.

Description

In nuclear power station acidic and alkaline waste water and discharge method and system
Technical field
The invention belongs to Treatment of Industrial Water field, it is more particularly related to which a kind of nuclear power station acidic and alkaline waste water neutralizes Discharge method and system.
Background technology
In the industries such as thermoelectricity, nuclear power, semiconductor, chemical industry, demineralized water production and condensation Water warfare are handed over using ion mostly Method is changed, the trace impurity that spent ion exchange resin is gone in water removal, prepares the demineralized water or condensed water for reaching system process requirement.From In sub- exchange process, during cationic, anionic exchange resin operational failure, excessive acid regeneration failure cationic ion-exchange resin, mistake are added The alkali regeneration failure anion exchange resin of amount, therefore produce positive and negative resin regeneration waste water.PH value after waste water neutralizes meets GB8978《Integrated wastewater discharge standard》, i.e. pH value control, could outer row in the range of 6-9.
Generally, in waste water and when, first by positive resin regenerate discharge acid waste water and negative resin regenerate discharge Alkaline waste water is collected to neutralization pond, is thoroughly mixed, self-neutralization, then measures the pH value of waste water in neutralization pond, operations staff's root Determine to add acid or alkali into neutralization pond according to pH value, be then stirred, survey pH value, by offeing medicine, stirring repeatedly, when pH value control When system is in 6-9, start discharge of wastewater pump waste discharge.
In waste water N-process, soda acid dosage, mixing time etc. are all by operations staff according to measurement pH value and experience It is determined that this generates problems with:
(1) according only to PH meter measured value, when adding soda acid by theoretical calculation, in by waste water and when pH value it is non-thread Property, being mixed evenly property, instrument measurement accuracy and hysteresis quality, the factor such as resiliency of waste water influence, calculated value is not Actual conditions must be adapted to;In addition, in disparity items, the physical dimension of acidic and alkaline waste water neutralization pond, agitating device configuration, soda acid dosing The position of point etc. is different, necessarily causes stirring to reach well mixed time difference, along with pH value is in 6-9, adds A small amount of soda acid, pH value have very macromutation, such as neutralize and only lean on one factor controlling of PH measured values with soda acid dosage, it is difficult to automatically Neutralization reaches discharge standard, and majority of case is required for manual intervention, adds operations staff's workload.
(2) soda acid dosing is easily excessive, causes soda acid to neutralize repeatedly, increases chemical consumption.
(3) mixing time randomness is larger, when mixing time is long, loses time, electric energy;Mixing time deficiency, then give up Water mixing is uneven, and soda acid does not neutralize fully, causes soda acid to add deficiency or excessive.
(4) discharge of wastewater is not up to standard, not only pollutes environment, can also corrode discharge of wastewater pipeline, irrigation canals and ditches produce potential safety hazard.
(5) partial deionization system includes multiple row equipment, and when regeneration frequency is high, each regenerative wastewater neutralizes, discharge is completed to need To complete within a certain period of time, as neutralization pond waste water can not in limiting time in and qualified discharge, then occur below fail Equipment can not be timely completed regeneration, desalting system is not run continuously, influence reliability of water supply.
In view of this, it is necessory to provide in a kind of nuclear power station acidic and alkaline waste water that can solve the problem that above mentioned problem and discharge method And system.
The content of the invention
It is an object of the invention to:A kind of overcome the deficiencies in the prior art, there is provided in nuclear power station acidic and alkaline waste water and discharge side Method and system.
In order to realize foregoing invention purpose, the invention provides in a kind of acidic and alkaline waste water and discharge method, including:
Record the parameter of the sum in and in container of the acidic and alkaline waste water under different operating modes:Optimal soda acid dosing number, most preferably stir Mix time, pH value measurement time delay;
Physical dimension according to container is neutralized determines to neutralize the liquid level of container and the functional relation of volume;
Acidic and alkaline waste water is mixed in and in container and gathers its liquid level and pH value data;
According to the parameter of the record, the functional relation determined, the data of collection, it is calculated most preferably with mathematical modeling Soda acid chemical feeding quantity;
Medicine is launched according to the optimal soda acid chemical feeding quantity, waste water is completed and neutralizes.
Improved as in acidic and alkaline waste water of the present invention with a kind of of discharge method, the completion waste water also includes after neutralizing: Whether the waste water after detection neutralizes reaches standard, if not up to standard, corrects the parameter of the record.
Improved as in acidic and alkaline waste water of the present invention with a kind of of discharge method, the parameter of the amendment record includes:Intervene The waste water of standard is not up to after neutralization, standard is reached, according to the parameter of intervention amendment record.
Improved as in acidic and alkaline waste water of the present invention with a kind of of discharge method, whether the waste water after the detection neutralizes reaches Further comprise after standard:If reaching standard, the data of the collection are recorded, and waste water is discharged.
Improved as in acidic and alkaline waste water of the present invention with a kind of of discharge method, the different works that the record acidic and alkaline waste water neutralizes Parameter under condition is specially:Artificial neutralization test is carried out in and in container to the acidic and alkaline waste water under different operating modes, and records examination Optimal soda acid dosing number, optimal mixing time, the pH value measurement delay time parameter tested.
Improved as in acidic and alkaline waste water of the present invention with a kind of of discharge method, it is described according to recording parameters, functional relation, adopt Collection data calculate optimal soda acid chemical feeding quantity:Recording parameters, functional relation are stored into database, by computer according to number According to storehouse information, gathered data, optimal soda acid chemical feeding quantity is calculated with mathematical modeling.
Improved as in acidic and alkaline waste water of the present invention with a kind of of discharge method, the intervention is not up to the useless of standard after neutralizing Water is specially:By manually launch medicine intervention neutralize after not up to standard waste water.
Improved as in acidic and alkaline waste water of the present invention with a kind of of discharge method, the optimal soda acid chemical feeding quantity of basis launches medicine Product are specially:Medicine is launched by measuring pump or batch meter according to optimal soda acid chemical feeding quantity.
Improved as in acidic and alkaline waste water of the present invention with a kind of of discharge method, the completion waste water, which neutralizes, is specially:Using Compressed air or waste drains pump stirring waste water are neutralized with completing waste water.
Improved as in acidic and alkaline waste water of the present invention with a kind of of discharge method, it is described waste water is reached further after standard Including:Waste water is discharged.
In order to realize foregoing invention purpose, the present invention also provides in a kind of acidic and alkaline waste water and exhaust system, including neutralization pond, Fluid level measuring gauge, PH meters, sour throwing mechanism, alkali throwing mechanism, rabbling mechanism and control system;
Neutralization pond accommodates acidic and alkaline waste water;
Control system controls the liquid level and pH value data of acidic and alkaline waste water in fluid level measuring gauge and PH meters collection neutralization pond, And according to the functional relation of the data collected, the liquid level determined by neutralization pool size prestored and volume, and difference The neutralization parameter information of acidic and alkaline waste water under operating mode, calculates optimal soda acid chemical feeding quantity, and control soda acid measuring pump launches medicine, control Rabbling mechanism stirs acidic and alkaline waste water.
Improved as in acidic and alkaline waste water of the present invention with a kind of of exhaust system, the neutralization parameter information includes:Optimal acid Alkali dosing number, optimal mixing time, pH value measurement time delay.
Improved as in acidic and alkaline waste water of the present invention with a kind of of exhaust system, the sour throwing mechanism is sour measuring pump or acid Batch meter, the alkali throwing mechanism are alkali measuring pump or alkali batch meter.
Improved as in acidic and alkaline waste water of the present invention with a kind of of exhaust system, the rabbling mechanism be compressed air piping or Waste drains pump.
Improve with a kind of of exhaust system as in acidic and alkaline waste water of the present invention, also wrapped with exhaust system in the acidic and alkaline waste water Discharge of wastewater automatic valve and return of waste water automatic valve are included, if the pH value data of PH meter collections reach standard, control system control is useless Water discharge automatic valve discharges waste water, if the pH value data of PH meter collections are not up to standard, control system control return of waste water is certainly Dynamic valve makes return of waste water enter neutralization pond.
Improved as in acidic and alkaline waste water of the present invention with a kind of of exhaust system, institute in the acidic and alkaline waste water and in exhaust system Have and handled with the equipment of waste water and pipeline by acid/alkali-corrosion-resistant.
Compared with prior art, at least there is technology beneficial below with discharge method and system in acidic and alkaline waste water of the present invention Effect:
(1) manpower, time, the reagent cost of waste water neutralisation treatment are reduced, is obviously improved the treatment effeciency of waste water neutralization;
(2) complete in waste water and discharge in the shortest time, prevent desalting system from stopping because waste water can not neutralize discharge on time Fortune, improve the reliability of desalting system water supply;
(3) ensure acidic and alkaline waste water qualified discharge, prevent ecological environment from being destroyed, water source is contaminated, guarantee resident's safety;
(4) effectively reduce staff operating experience requirement, reduce operations staff's labor intensity, reduce operations staff with Hazardous chemicals touch opportunity, shorten working time of the operations staff under high noisy, acid mist environment, safeguard work personnel people Body health and safety.
Brief description of the drawings
With reference to the accompanying drawings and detailed description, in acidic and alkaline waste water of the present invention and discharge method, system and its beneficial Technique effect is described in detail.
Fig. 1 is in acidic and alkaline waste water of the present invention and the structural representation of exhaust system.
Fig. 2 is in acidic and alkaline waste water of the present invention and the flow chart of discharge method.
Embodiment
In order that the purpose of the present invention, technical scheme and advantageous effects become apparent from understanding, below in conjunction with accompanying drawing and Embodiment, the present invention will be described in further detail.It should be appreciated that the specific implementation described in this specification Mode is not intended to limit the present invention just for the sake of explaining the present invention.
Referring to Fig. 1, include in acidic and alkaline waste water of the present invention with exhaust system:Neutralization pond 10, fluid level measuring gauge 12, PH measurements Meter 14, sour throwing mechanism, alkali throwing mechanism, rabbling mechanism and control system 20;
Neutralization pond 10 accommodates acidic and alkaline waste water;
Control system 20 control fluid level measuring gauge 12 and PH meters 14 gather in neutralization pond 10 liquid level of acidic and alkaline waste water and PH value data, and closed according to the function of the data collected, the liquid level determined by the size of neutralization pond 10 prestored and volume System, and the neutralization parameter information of the acidic and alkaline waste water under different operating modes, calculate optimal soda acid chemical feeding quantity, and control soda acid measuring pump is thrown Put medicine, control rabbling mechanism stirring acidic and alkaline waste water.
Referring to Fig. 2, include in acidic and alkaline waste water of the present invention with discharge method:
Step 101, the parameter of the sum in and in container of the acidic and alkaline waste water under different operating modes is recorded:Optimal soda acid dosing time Several, optimal mixing time, pH value measurement time delay;
Step 103, determined to neutralize the liquid level of container and the functional relation of volume according to the physical dimension for neutralizing container;
Step 105, mixed by acidic and alkaline waste water in and in container and gather its liquid level and pH value data;
Step 107, according to the parameter of the record, the functional relation determined, the data of collection, calculated with mathematical modeling Obtain optimal soda acid chemical feeding quantity;
Step 109, medicine is launched according to the optimal soda acid chemical feeding quantity, completes waste water and neutralize.
It is one embodiment with exhaust system and method in acidic and alkaline waste water of the present invention below.
Fig. 1 and Fig. 2 are referred to, acidic and alkaline waste water caused by industrial production is contained in neutralization pond 10.The survey of fluid level measuring gauge 12 Neutralization pond 10 is stretched at amount end, dispensing end, the dispensing end of alkali measuring pump 18 of sour measuring pump 16.One end of compressed air piping 22 leads to Overcompression air stirring automatic valve 24 stretches into neutralization pond 10, and the other end is used to input compressed air.One end of waste drains pump 26 is stretched into Neutralization pond 10, other end connection PH meters 14, discharge of wastewater automatic valve 28 and return of waste water automatic valve 30.Fluid level measuring gauge 12nd, sour measuring pump 16, alkali measuring pump 18, compressed air stir automatic valve 24, waste drains pump 26, PH meters 14, discharge of wastewater certainly Move valve 28 and return of waste water automatic valve 30 is connected with control system 20 and controlled system 20 controls.Control system 20, which has, deposits The database and logic judgment of storage, operation processing function.It is all to pass through with the equipment of waste water and pipeline at anticorrosion Reason, is resistant to the corrosion of soda acid.
It should be noted that in other embodiments, sour measuring pump 16 can be substituted using acid batch meter, alkali measuring pump 18 It can be substituted using alkali batch meter.
In project debugging and initial operating stage stage, carried out in multiple acidic and alkaline waste water and tried in neutralization pond 10 by manual type Test, record in the acidic and alkaline waste water of different operating modes and when optimal soda acid dosing number, optimal mixing time, pH value measurement delay when Between etc. parameter, by the database of these substantial amounts of test parameters information input control systems 20.
The liquid level of neutralization pond 10 and the functional relation of volume are determined by the physical dimension of neutralization pond 10, functional relation is stored in Control system.
In the project commencement of commercial operation stage, control system 20 controls first opens compressed air stirring automatic valve 24 or/and waste liquid Pump 26, acidic and alkaline waste water is well mixed by compressed air stirring or/and circulation stirring, makes acid waste water and alkaline waste water in With.
After the completion of self-neutralization, control system 20 controls fluid level measuring gauge 12 to gather the liquid level of acidic and alkaline waste water in neutralization pond, control PH meters 14 processed gather pH value data, according to the functional relation of data, the liquid level of neutralization pond 10 and the volume collected, with data The parameter information of library storage calculates optimal soda acid chemical feeding quantity compared to mathematical modeling.
Control system 20 controls sour measuring pump 16 or alkali measuring pump 18 according to result of calculation by certain operation cloth sequence With corresponding medicine is launched in pond 10, and control and open compressed air stirring automatic valve 24 or/and waste drains pump 26, pass through compress it is empty Medicine is well mixed by gas agitating or/and circulation stirring with waste water.
Control system 20 collects the pH value data of PH meters 14 again.
If pH value is not up to discharge standard, the control of control system 20 opens return of waste water automatic valve 30, closes waste water row Automatic valve 28 is put, makes below standard return of waste water to neutralization pond 10, and by manually launching medicine or manually manipulating sour measuring pump 16th, alkali measuring pump 18 intervenes the waste water that discharge standard is not up in neutralization pond 10, until waste water reaches standard.Control system 20 is controlled System opens discharge of wastewater automatic valve 28, closes return of waste water automatic valve 30, discharges waste water, meanwhile, control system 20 is according to artificial The parameter information stored in the process amendment of intervention and supplementary data storehouse.Information in the database of control system 20 and other Associated control parameters rule of thumb can also be modified and be supplemented by debugging, operations staff.
If pH value reaches discharge standard, the control of control system 20 opens discharge of wastewater automatic valve 28, closes return of waste water Automatic valve 30, discharge waste water.Meanwhile the gathered data and the key parameter of correlation that this is neutralized are recorded supplement by control system 20 Into database, make database constantly improve.Information and other associated control parameters in the database of control system 20 Rule of thumb it can be modified and supplemented by debugging, operations staff.
Can be seen that with reference to above detailed description of the present invention in the acidic and alkaline waste water of the present invention has certainly with exhaust system Learning functionality, with the increase in project waste water with number of run, accumulated through service data after a while, control system 20 Database information constantly improve, may finally realize that waste water full automatic under various operating modes neutralizes and qualified discharge, without Manpower intervention operates.In addition, longer with exhaust system run time in acidic and alkaline waste water, the data of accumulation are more, then acidic and alkaline waste water It is more accurate to neutralize dosage, the neutralization time is shorter, and it is lower to neutralize soda acid drug consumption.
Relative to prior art, include but not with the advantageous effects of discharge method and system in acidic and alkaline waste water of the present invention It is limited to:
(1) manpower, time, the reagent cost of waste water neutralisation treatment are reduced, is obviously improved the treatment effeciency of waste water neutralization;
(2) complete in waste water and discharge in the shortest time, prevent desalting system from stopping because waste water can not neutralize discharge on time Fortune, improve the reliability of desalting system water supply;
(3) ensure acidic and alkaline waste water qualified discharge, prevent ecological environment from being destroyed, water source is contaminated, guarantee resident's safety;
(4) effectively reduce staff operating experience requirement, reduce operations staff's labor intensity, reduce operations staff with Hazardous chemicals touch opportunity, shorten working time of the operations staff under high noisy, acid mist environment, safeguard work personnel people Body health and safety.
According to above-mentioned principle, the present invention can also carry out appropriate change and modification to above-mentioned embodiment.Therefore, this hair It is bright to be not limited to embodiment disclosed and described above, some modifications and changes of the present invention should also be as falling into this In the scope of the claims of invention.In addition, although used some specific terms in this specification, but these terms Merely for convenience of description, any restrictions are not formed to the present invention.

Claims (16)

1. in a kind of acidic and alkaline waste water and discharge method, it is characterised in that the described method comprises the following steps:
Record the parameter of the sum in and in container of the acidic and alkaline waste water under different operating modes:Optimal soda acid dosing number, when most preferably stirring Between, pH value measurement time delay;
Physical dimension according to container is neutralized determines to neutralize the liquid level of container and the functional relation of volume;
Acidic and alkaline waste water is mixed in and in container and gathers its liquid level and pH value data;
According to the parameter of the record, the functional relation determined, the data of collection, optimal soda acid is calculated with mathematical modeling Chemical feeding quantity;
Medicine is launched according to the optimal soda acid chemical feeding quantity, waste water is completed and neutralizes.
2. in acidic and alkaline waste water according to claim 1 and discharge method, it is characterised in that after the completion waste water neutralizes Also include:Whether the waste water after detection neutralizes reaches standard, if not up to standard, corrects the parameter of the record.
3. in acidic and alkaline waste water according to claim 2 and discharge method, it is characterised in that the parameter bag of the amendment record Include:Intervene the waste water that standard is not up to after neutralizing, standard is reached, according to the parameter of intervention amendment record.
4. in acidic and alkaline waste water according to claim 2 and discharge method, it is characterised in that the detection neutralize after waste water Whether reach standard afterwards to further comprise:If reaching standard, the data of the collection are recorded, and waste water is discharged.
5. in acidic and alkaline waste water according to claim 1 and discharge method, it is characterised in that the record acidic and alkaline waste water neutralizes Different operating modes under parameter be specially:Artificial neutralization test is carried out in and in container to the acidic and alkaline waste water under different operating modes, And record optimal soda acid dosing number, optimal mixing time, the pH value measurement delay time parameter of experiment.
6. in acidic and alkaline waste water according to claim 1 and discharge method, it is characterised in that described according to recording parameters, letter Number relation, gathered data calculate optimal soda acid chemical feeding quantity and are specially:Recording parameters, functional relation are stored into database, by counting Optimal soda acid chemical feeding quantity is calculated with mathematical modeling according to database information, gathered data in calculation machine.
7. in acidic and alkaline waste water according to claim 3 and discharge method, it is characterised in that it is described intervene neutralize after not up to The waste water of standard is specially:By manually launch medicine intervention neutralize after not up to standard waste water.
8. in acidic and alkaline waste water according to claim 1 and discharge method, it is characterised in that the optimal soda acid dosing of basis Amount launches medicine:Medicine is launched by measuring pump or batch meter according to optimal soda acid chemical feeding quantity.
9. in acidic and alkaline waste water according to claim 1 and discharge method, it is characterised in that in the completion waste water and specific For:Compressed air or waste drains pump is used to stir waste water to complete waste water neutralization.
10. in acidic and alkaline waste water according to claim 3 and discharge method, it is characterised in that described waste water is reached standard Further comprise afterwards:Waste water is discharged.
11. in a kind of acidic and alkaline waste water and exhaust system, including neutralization pond, fluid level measuring gauge, PH meters, sour throwing mechanism, alkali Throwing mechanism, rabbling mechanism and control system;
Neutralization pond accommodates acidic and alkaline waste water;
Control system controls the liquid level and pH value data of acidic and alkaline waste water in fluid level measuring gauge and PH meters collection neutralization pond, and root According to the functional relation of the data collected, the liquid level determined by neutralization pool size prestored and volume, and different operating modes Under acidic and alkaline waste water neutralization parameter information, calculate optimal soda acid chemical feeding quantity, control soda acid measuring pump launches medicine, control stirring Agitated vessel acidic and alkaline waste water.
12. in acidic and alkaline waste water according to claim 11 and exhaust system, it is characterised in that the neutralization parameter information bag Include:Optimal soda acid dosing number, optimal mixing time, pH value measurement time delay.
13. in acidic and alkaline waste water according to claim 11 and exhaust system, it is characterised in that the sour throwing mechanism is acid Measuring pump or acid batch meter, the alkali throwing mechanism are alkali measuring pump or alkali batch meter.
14. in acidic and alkaline waste water according to claim 11 and exhaust system, it is characterised in that the rabbling mechanism is compression Air duct or waste drains pump.
15. according in the acidic and alkaline waste water described in claim 11 and exhaust system, it is characterised in that in the acidic and alkaline waste water and discharge System also includes discharge of wastewater automatic valve and return of waste water automatic valve, if the pH value data of PH meter collections reach standard, control system System control discharge of wastewater automatic valve discharges waste water, if the pH value data of PH meter collections are not up to standard, control system control is useless Water backflow automatic valve makes return of waste water enter neutralization pond.
16. according in the acidic and alkaline waste water described in claim 11 and exhaust system, it is characterised in that in the acidic and alkaline waste water and discharge It is all in system to be handled with the equipment of waste water and pipeline by acid/alkali-corrosion-resistant.
CN201610728137.8A 2016-08-26 2016-08-26 In nuclear power station acidic and alkaline waste water and discharge method and system Pending CN107777765A (en)

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CN110240305A (en) * 2019-05-20 2019-09-17 南京金陵化工厂有限责任公司 A kind of production wastewater treatment pond of stabilizer for plastics and its processing method
CN112723613A (en) * 2021-04-01 2021-04-30 南京国睿智能装备有限公司 Intelligent remote supervision method and terminal for sewage treatment station
CN115611400A (en) * 2022-11-11 2023-01-17 华能山东石岛湾核电有限公司 High-temperature gas cooled reactor wastewater discharge device and method

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN110240305A (en) * 2019-05-20 2019-09-17 南京金陵化工厂有限责任公司 A kind of production wastewater treatment pond of stabilizer for plastics and its processing method
CN112723613A (en) * 2021-04-01 2021-04-30 南京国睿智能装备有限公司 Intelligent remote supervision method and terminal for sewage treatment station
CN112723613B (en) * 2021-04-01 2021-06-22 南京国睿智能装备有限公司 Intelligent remote supervision method and terminal for sewage treatment station
CN115611400A (en) * 2022-11-11 2023-01-17 华能山东石岛湾核电有限公司 High-temperature gas cooled reactor wastewater discharge device and method

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