CN107760229A - A kind of Beer rubberizing and preparation method thereof - Google Patents
A kind of Beer rubberizing and preparation method thereof Download PDFInfo
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- CN107760229A CN107760229A CN201711042183.3A CN201711042183A CN107760229A CN 107760229 A CN107760229 A CN 107760229A CN 201711042183 A CN201711042183 A CN 201711042183A CN 107760229 A CN107760229 A CN 107760229A
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- parts
- beer
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- retort
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J127/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers
- C09J127/02—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J127/04—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09J127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/164—Aluminum halide, e.g. aluminium chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
A kind of Beer rubberizing, including the raw material by following parts by weight：40 50 parts of crystal aluminum chloride, 15 25 parts of starch, 5 15 parts of basic species, 5 10 parts of defoamer, 1.6 4 parts of casein, 150 parts of PVC130,130 150 parts of urea, 1.6 4 parts of filler, appropriate deionized water.
Description
Technical field
The present invention relates to a kind of Beer rubberizing and preparation method thereof.
Background technology
With the fast development of beer industry, beer housing material labels the continuous improvement of throughput rate, it is desirable to labels
It is strong, solid fast that glue possesses initial bonding strength（It can prevent from producing displacement when moment from labelling, fall phenomena such as glue）, and soaked in label in water
Without obscission after bubble 72h.At present, starch, modified starch, PVA formals etc. label used by the industry of China's Beer Brewage
Adhesive, although cheap, simple production process, middle low speed labelling machine is simply possible to use in, and rate of drying is slow, resistance to
Water-based difference, it is impossible to meet requirement and seriously polluted.
The content of the invention
The present invention is directed to problem above, there is provided a kind of environment friendly and pollution-free Beer rubberizing and preparation method thereof.
The goal of the invention of the present invention is realized by following scheme：A kind of Beer rubberizing, including the original by following parts by weight
Material：Crystal aluminum chloride 40-50 parts, starch 15-25 parts, basic species 5-15 parts, defoamer 5-10 parts, casein 1.6-4 parts,
PVC130-150 parts, urea 130-150 parts, filler 1.6-4 parts, appropriate deionized water.
A kind of preparation method of Beer rubberizing, comprises the following steps：（1）Deionized water and crystal aluminum chloride are added to
In retort, stir to crystal aluminum chloride and be completely dissolved；Then basic species are added, it is alkalescence to adjust the pH value inside retort,
Stir half an hour；
（2）Defoamer, casein, urea, starch, heating stirring are added in retort；When being warming up to 70 degrees Celsius, filling is added
Agent is stirred until homogeneous；
（3）After glue is completely dissolved in retort, then pH value is adjusted, and be heated to 85 degrees Celsius of reactions；
（4）Then after being progressively cooled to 65 degrees Celsius, then pH value is adjusted, then keeps constant temperature in tank to continue stirring to glue point
From.
Further, pH value is adjusted in step 3 again to alkalescence.
Further, pH value is adjusted in step 4 again to alkalescence.
The beneficial effects of the present invention are：The glue is green glue, has good water resistance, and rate of drying is fast, is glued
Angle value is high；Modification under used raw material high temperature, add water resistance and the rapid draing of glue；Glue can also be increased
Mechanical property and water-fast, heat-resisting, acid-proof alkaline.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described：
Embodiment one, the present invention：A kind of Beer rubberizing, including the raw material by following parts by weight：Crystal aluminum chloride 40-50 parts,
Starch 15-25 parts, basic species 5-15 parts, defoamer 5-10 parts, casein 1.6-4 parts, PVC130-150 parts, urea 130-150
Part, filler 1.6-4 parts, deionized water 500-1000 parts.
A kind of preparation method of Beer rubberizing, comprises the following steps：（1）Deionized water and crystal aluminum chloride are added to
In retort, stir to crystal aluminum chloride and be completely dissolved；Then basic species are added, it is alkalescence to adjust the pH value inside retort,
Stir half an hour；
（2）Defoamer, casein, urea, starch, heating stirring are added in retort；When being warming up to 70 degrees Celsius, filling is added
Agent is stirred until homogeneous；
（3）After glue is completely dissolved in retort, then pH value is adjusted, and be heated to 85 degrees Celsius of reactions；
（4）Then after being progressively cooled to 65 degrees Celsius, then pH value is adjusted, then keeps constant temperature in tank to continue stirring to glue point
From.
A kind of preparation method of Beer rubberizing, pH value is adjusted again to alkalescence in step 3.
A kind of preparation method of Beer rubberizing, pH value is adjusted again to alkalescence in step 4.
Embodiment two, the present invention：A kind of Beer rubberizing, including the raw material by following parts by weight：45 parts of crystal aluminum chloride,
20 parts of starch, 10 parts of basic species, 8 parts of defoamer, 3 parts of casein, PVC120 parts, 120 parts of urea, 3 parts of filler, deionized water
800 parts.
A kind of preparation method of Beer rubberizing, comprises the following steps：（1）Deionized water and crystal aluminum chloride are added to
In retort, stir to crystal aluminum chloride and be completely dissolved；Then basic species are added, it is alkalescence to adjust the pH value inside retort,
Stir half an hour；
（2）Defoamer, casein, urea, starch, heating stirring are added in retort；When being warming up to 70 degrees Celsius, filling is added
Agent is stirred until homogeneous；
（3）After glue is completely dissolved in retort, then pH value is adjusted, and be heated to 85 degrees Celsius of reactions；
（4）Then after being progressively cooled to 65 degrees Celsius, then pH value is adjusted, then keeps constant temperature in tank to continue stirring to glue point
From.
A kind of preparation method of Beer rubberizing, pH value is adjusted again to alkalescence in step 3.
A kind of preparation method of Beer rubberizing, pH value is adjusted again to alkalescence in step 4.
Embodiment three, the present invention：A kind of Beer rubberizing, including the raw material by following parts by weight：40 parts of crystal aluminum chloride,
15 parts of starch, 5 parts of basic species, 5 parts of defoamer, 1.6 parts of casein, PVC130 parts, 130 parts of urea, 1.6 parts of filler, go from
Sub- 500 parts of water.
A kind of preparation method of Beer rubberizing, comprises the following steps：（1）Deionized water and crystal aluminum chloride are added to
In retort, stir to crystal aluminum chloride and be completely dissolved；Then basic species are added, it is alkalescence to adjust the pH value inside retort,
Stir half an hour；
（2）Defoamer, casein, urea, starch, heating stirring are added in retort；When being warming up to 70 degrees Celsius, filling is added
Agent is stirred until homogeneous；
（3）After glue is completely dissolved in retort, then pH value is adjusted, and be heated to 85 degrees Celsius of reactions；
（4）Then after being progressively cooled to 65 degrees Celsius, then pH value is adjusted, then keeps constant temperature in tank to continue stirring to glue point
From.
A kind of preparation method of Beer rubberizing, pH value is adjusted again to alkalescence in step 3.
A kind of preparation method of Beer rubberizing, pH value is adjusted again to alkalescence in step 4.
Example IV, the present invention：A kind of Beer rubberizing, including the raw material by following parts by weight：50 parts of crystal aluminum chloride,
25 parts of starch, 15 parts of basic species, 10 parts of defoamer, 4 parts of casein, PVC150 parts, 150 parts of urea, 4 parts of filler, deionization
1000 parts of water.
A kind of preparation method of Beer rubberizing, comprises the following steps：（1）Deionized water and crystal aluminum chloride are added to
In retort, stir to crystal aluminum chloride and be completely dissolved；Then basic species are added, it is alkalescence to adjust the pH value inside retort,
Stir half an hour；
（2）Defoamer, casein, urea, starch, heating stirring are added in retort；When being warming up to 70 degrees Celsius, filling is added
Agent is stirred until homogeneous；
（3）After glue is completely dissolved in retort, then pH value is adjusted, and be heated to 85 degrees Celsius of reactions；
（4）Then after being progressively cooled to 65 degrees Celsius, then pH value is adjusted, then keeps constant temperature in tank to continue stirring to glue point
From.
A kind of preparation method of Beer rubberizing, pH value is adjusted again to alkalescence in step 3.
A kind of preparation method of Beer rubberizing, pH value is adjusted again to alkalescence in step 4.
1-4 of embodiment of the present invention Labeling Adhesive with Super is measured, embodiment 1, embodiment 2, embodiment 3, the patch of embodiment 1
Mark glue respectively in 15 DEG C of water soak 88H do not fall off, viscosity respectively reach 10.2*104mPa.s, 12.2*104mPa.s,
10.4*104mPa.s、10.8*104mPa.s。
1-4 of embodiment of the present invention Labeling Adhesive with Super is measured, embodiment 1, embodiment 2, embodiment 3, the patch of embodiment 4
Mark the release of the equal contamination-free of glue.
Although the present invention is described by reference to preferred embodiment, those of ordinary skill in the art should
Work as understanding, the description of above-described embodiment can be not limited to, in the range of claims, can make each in form and details
Kind change.
Claims (4)
1. a kind of Beer rubberizing, it is characterised in that including the raw material by following parts by weight：Crystal aluminum chloride 40-50 parts, starch
15-25 parts, basic species 5-15 parts, defoamer 5-10 parts, casein 1.6-4 parts, PVC130-150 parts, urea 130-150 parts, fill out
Fill agent 1.6-4 parts, appropriate deionized water.
2. a kind of preparation method of beer Labeling Adhesive with Super as claimed in claim 1, it is characterised in that comprise the following steps：（1）Will
Deionized water and crystal aluminum chloride are added in retort, are stirred to crystal aluminum chloride and are completely dissolved；Then basic species are added, are adjusted
The pH value saved inside retort is alkalescence, stirs half an hour；
（2）Defoamer, casein, urea, starch, heating stirring are added in retort；When being warming up to 70 degrees Celsius, filling is added
Agent is stirred until homogeneous；
（3）After glue is completely dissolved in retort, then pH value is adjusted, and be heated to 85 degrees Celsius of reactions；
（4）Then after being progressively cooled to 65 degrees Celsius, then pH value is adjusted, then keeps constant temperature in tank to continue stirring to glue point
From.
3. the preparation method of beer Labeling Adhesive with Super according to claim 2, it is characterised in that：PH value is adjusted again extremely in step 3
Alkalescence.
4. the preparation method of beer Labeling Adhesive with Super according to claim 2, it is characterised in that：PH value is adjusted again extremely in step 4
Alkalescence.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711042183.3A CN107760229A (en) | 2017-10-31 | 2017-10-31 | A kind of Beer rubberizing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711042183.3A CN107760229A (en) | 2017-10-31 | 2017-10-31 | A kind of Beer rubberizing and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107760229A true CN107760229A (en) | 2018-03-06 |
Family
ID=61270945
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711042183.3A Withdrawn CN107760229A (en) | 2017-10-31 | 2017-10-31 | A kind of Beer rubberizing and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107760229A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1212985A (en) * | 1997-09-29 | 1999-04-07 | 中国科学院福建物质结构研究所 | Water-resistant adhesive for label |
-
2017
- 2017-10-31 CN CN201711042183.3A patent/CN107760229A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1212985A (en) * | 1997-09-29 | 1999-04-07 | 中国科学院福建物质结构研究所 | Water-resistant adhesive for label |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| WW01 | Invention patent application withdrawn after publication | ||
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Application publication date: 20180306 |