CN108003814A - A kind of production technology of corrosion-resistant corrugated board glue - Google Patents
A kind of production technology of corrosion-resistant corrugated board glue Download PDFInfo
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- CN108003814A CN108003814A CN201711193567.5A CN201711193567A CN108003814A CN 108003814 A CN108003814 A CN 108003814A CN 201711193567 A CN201711193567 A CN 201711193567A CN 108003814 A CN108003814 A CN 108003814A
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- corrugated board
- corrosion
- board glue
- production technology
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of production technology of corrosion-resistant corrugated board glue, it is related to corrugated board glue technical field.The production technology of the corrosion-resistant corrugated board glue of the present invention, lye is prepared first, add other auxiliary agents such as cornstarch, bridging agent, stabilization agent, real-time monitoring viscosity is to determine mixing time, it is ensured that first bonding force of the cornstarch under low-temperature condition and moisture content when curing accelerate soon；It is aided with the auxiliary agents such as surfactant, defoamer, light filler again so that the corrugated board glue has good adhesion strength, corrosion resistance, improves the service life of corrugated board after bonding.
Description
Technical field：
The present invention relates to corrugated board glue technical field, and in particular to a kind of production work of corrosion-resistant corrugated board glue
Skill.
Background technology：
Corrugated board is also known as corrugated cardboard, is bonded by least one layer of corrugated paper and one layer of boxboard, has preferable
Elasticity and extensibility, mainly for the manufacture of carton, other sandwich and delicate articles packaging materials of carton.
At present, usually using starch as raw material, amylum adhesive is derived from a wealth of sources, contained the bond for corrugated board of China's production
Amount is abundant, nontoxic and pollution-free, cost is low, but is influenced by temperature, constituent very big, and performance is unstable, and is using process
Middle drying temperature is excessive, it is impossible to meet the needs of high-speed production, easily produce precipitation, poor permeability, cause productivity it is low, production
The problems such as of high cost, unstable product quality.And the use environment of corrugated board is changeable, when in the environment in seriously corroded
When, making glue, slowly burn into is mouldy, comes unglued, and causes the service life reduction of corrugated board, influence the safety of encapsulating products, it is necessary to
Inspect periodically and glue, add cost and manpower.Therefore, it is necessary to a kind of production technology of corrosion-resistant corrugated board glue to expire
Sufficient corrugated board storage and the demand used.
The content of the invention：
The technical problems to be solved by the invention are to provide a kind of production technology of corrosion-resistant corrugated board glue, technique
Simple controllable, glue has good adhesion strength, corrosion resistance, improves the service life of corrugated board after bonding.
The technical problems to be solved by the invention are realized using following technical solution：
A kind of production technology of corrosion-resistant corrugated board glue, comprises the following steps：
(1) water of 80~100 parts by weight and the caustic soda of 6~8 parts by weight, heating water bath to 30~35 are added in reaction kettle
DEG C, stirring is carried out at the same time, lye, stand for standby use are obtained after stirring 3~5min；
(2) 40~60 parts by weight of cornstarch are added in lye, after 5~10min of stirring at normal temperature, add bridging agent, stable
Agent, stirs simultaneously monitoring viscosity, when viscosity reaches 15~18s, adds borax, polyvinyl alcohol, dimethicone, ethylene glycol only son
Ether, stirs simultaneously monitoring viscosity, when viscosity reaches 13~15s, it is spare to obtain mixed serum；Wherein, the cornstarch, boron
Sand, polyvinyl alcohol, dimethicone, the mass ratio of ethylene glycol monobutyl ether are 40~60:1~3:3~5:1~2:0.2~0.5；
(3) dodecyl benzyl dimethyl ammonium chloride, defoamer, nano silicon dioxide, deionization are added in mixed serum
Water, is discharged after being stirred using dispersion machine with the rotating speed of 2000~3000r/min, and the corrugated board glue is made；Wherein, ten
Dialkyl dimethyl benzyl ammonium chloride, defoamer, nano silicon dioxide, the mass ratio of deionized water are 2~5:1~3:1~3:5
~10.
Preferably, after adding cornstarch in step (2) lye, 35~40 DEG C of heating water bath stirrings are warming up to.
Preferably, the stabilization agent is the one or more in barium stearate, calcium stearate, zinc stearate, magnesium stearate
Combination.
Preferably, the defoamer is one or more groups in DS-8800, DS-9000, DS-5080, DS-2001
Close.
Preferably, the mixed serum that prepared by the step (2) uses 320~360s of high speed shear, and the screw rod of dispersion machine turns
Speed is 1400~1600r/min.
The beneficial effects of the invention are as follows：1st, the production technology of corrugated board glue of the invention, technique is simply controllable, raw material
It is safe and non-toxic, lye is prepared first, adds other auxiliary agents such as cornstarch, bridging agent, stabilization agent, real-time monitoring viscosity is with true
Determine mixing time, it is ensured that moisture content when first bonding force of the cornstarch under low-temperature condition and curing accelerates soon；It is aided with table again
The auxiliary agents such as face activating agent, defoamer, light filler so that the corrugated board glue has good adhesion strength, corrosion resistance,
Improve the service life of corrugated board after bonding.
2nd, in additive of the invention, polyvinyl alcohol, can be fine with cornstarch as common emulsifying agent, adhesive
Ground is compatible, reduces its solidification temperature；Light filler nano silicon dioxide, surfactant sodium dodecyl base dimethyl benzyl ammonium chloride
The performance of corrosion resistance, water resistance and antibacterial and deodouring can be significantly improved.
Embodiment：
In order to make the technical means, the creative features, the aims and the efficiencies achieved by the present invention easy to understand, tie below
Specific embodiment is closed, the present invention is further explained.
Embodiment 1
A kind of production technology of corrosion-resistant corrugated board glue, comprises the following steps：
(1) water of 90kg and the caustic soda of 6.8kg are added in reaction kettle, heating water bath is carried out at the same time stirring to 30 DEG C, stirs
Lye, stand for standby use are obtained after 5min.
(2) bridging agent 1.5kg, stabilization agent stearic acid are added after addition cornstarch 52kg, stirring at normal temperature 8min in lye
Barium 4.0kg, stirs simultaneously monitoring viscosity, when viscosity reaches 16s, adds borax 2kg, polyvinyl alcohol 3.5kg, dimethicone
1.2kg, ethylene glycol monobutyl ether 0.3kg, stir simultaneously monitoring viscosity, when viscosity reaches 13s, it is spare to obtain mixed serum.
(3) dodecyl benzyl dimethyl ammonium chloride 3.5kg, defoamer DS-50801.8kg are added in mixed serum, is received
Rice silica 2.2kg, deionized water 8kg, are discharged after being stirred using dispersion machine with the rotating speed of 2600r/min, and being made should
Corrugated board glue.
Embodiment 2
A kind of production technology of corrosion-resistant corrugated board glue, comprises the following steps：
(1) water of 95kg and the caustic soda of 8kg are added in reaction kettle, heating water bath is carried out at the same time stirring to 35 DEG C, stirs
Lye, stand for standby use are obtained after 4min.
(2) it is stearic that bridging agent 2.2kg, stabilization agent are added after addition cornstarch 55kg, stirring at normal temperature 10min in lye
Sour magnesium 4.5kg, stirs simultaneously monitoring viscosity, when viscosity reaches 18s, adds borax 2.6kg, polyvinyl alcohol 4.3kg, dimethyl-silicon
Oily 1.5kg, ethylene glycol monobutyl ether 0.5kg, stir simultaneously monitoring viscosity, when viscosity reaches 15s, it is spare to obtain mixed serum.
(3) dodecyl benzyl dimethyl ammonium chloride 4.2kg, defoamer DS-88002.5kg are added in mixed serum, is received
Rice silica 2.2kg, deionized water 9.5kg, are discharged after being stirred using dispersion machine with the rotating speed of 2800r/min, are made
The corrugated board glue.
Embodiment 3
A kind of production technology of corrosion-resistant corrugated board glue, comprises the following steps：
(1) water of 100kg and the caustic soda of 7.5kg are added in reaction kettle, heating water bath is carried out at the same time stirring, stirs to 33 DEG C
Lye, stand for standby use are obtained after mixing 5min.
(2) bridging agent 3kg, stabilization agent stearic acid are added after addition cornstarch 60kg, stirring at normal temperature 10min in lye
Zinc 4.8kg, stirs simultaneously monitoring viscosity, when viscosity reaches 17s, adds borax 2.8kg, polyvinyl alcohol 4.5kg, dimethicone
2.0kg, ethylene glycol monobutyl ether 0.5kg, stir simultaneously monitoring viscosity, when viscosity reaches 15s, it is spare to obtain mixed serum.
(3) dodecyl benzyl dimethyl ammonium chloride 4.5kg, defoamer DS-90003.0kg are added in mixed serum, is received
Rice silica 1 .9kg, deionized water 10kg, are discharged after being stirred using dispersion machine with the rotating speed of 3000r/min, and being made should
Corrugated board glue.
Comparative example 1
A kind of production technology of corrosion-resistant corrugated board glue, comprises the following steps：
(1) water of 90kg and the caustic soda of 6.8kg are added in reaction kettle, heating water bath is carried out at the same time stirring to 30 DEG C, stirs
Lye, stand for standby use are obtained after 5min.
(2) bridging agent 1.5kg, stabilization agent stearic acid are added after addition cornstarch 52kg, stirring at normal temperature 8min in lye
Barium 4.0kg, stirs simultaneously monitoring viscosity, when viscosity reaches 16s, adds borax 2kg, polyvinyl alcohol 3.5kg, dimethicone
1.2kg, ethylene glycol monobutyl ether 0.3kg, stir simultaneously monitoring viscosity, when viscosity reaches 13s, it is spare to obtain mixed serum.
(3) defoamer DS-5080 1.8kg, nano silicon dioxide 2.2kg, deionized water 8kg are added in mixed serum, is made
Discharge after being stirred with dispersion machine with the rotating speed of 2600r/min, the corrugated board glue is made.
Comparative example 2
A kind of production technology of corrosion-resistant corrugated board glue, comprises the following steps：
(1) water of 90kg and the caustic soda of 6.8kg are added in reaction kettle, heating water bath is carried out at the same time stirring to 30 DEG C, stirs
Lye, stand for standby use are obtained after 5min.
(2) bridging agent 1.5kg, stabilization agent stearic acid are added after addition cornstarch 52kg, stirring at normal temperature 8min in lye
Barium 4.0kg, stirs simultaneously monitoring viscosity, when viscosity reaches 16s, adds borax 2kg, polyvinyl alcohol 3.5kg, dimethicone
1.2kg, ethylene glycol monobutyl ether 0.3kg, stir simultaneously monitoring viscosity, when viscosity reaches 13s, it is spare to obtain mixed serum.
(3) dodecyl benzyl dimethyl ammonium chloride 3.5kg, defoamer DS-50801.8kg are added in mixed serum, is gone
Ionized water 8kg, is discharged after being stirred using dispersion machine with the rotating speed of 2600r/min, and the corrugated board glue is made.
Corrosion resistance is tested：Corrugated board glue prepared by above-described embodiment, comparative example is used for conventional corrugated paper
After plate bonding, it is soaked in acid and alkalescence solution, tests the time that the corrugated board glue comes unglued completely, concrete outcome
It see the table below：
1. corrugated board glue corrosion resistance test result of table
As can be seen from the above table, the acid-alkali-corrosive-resisting ability of the corrugated board glue of the embodiment of the present invention is excellent, comparative example
Due to lacking surfactant sodium dodecyl base dimethyl benzyl ammonium chloride, light filler nano silicon dioxide so that its is corrosion-resistant
Property, the performance such as temperature tolerance reduce it is notable.
The basic principles, main features and the advantages of the invention have been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (5)
1. a kind of production technology of corrosion-resistant corrugated board glue, it is characterised in that comprise the following steps：
(1) water of 80~100 parts by weight and the caustic soda of 6~8 parts by weight are added in reaction kettle, heating water bath is to 30~35 DEG C, together
When be stirred, stir 3~5min after obtain lye, stand for standby use；
(2) 40~60 parts by weight of cornstarch are added in lye, after 5~10min of stirring at normal temperature, bridging agent, stabilization agent is added, stirs
Simultaneously monitoring viscosity is mixed, when viscosity reaches 15~18s, borax, polyvinyl alcohol, dimethicone, ethylene glycol monobutyl ether is added, stirs
Simultaneously monitoring viscosity is mixed, when viscosity reaches 13~15s, it is spare to obtain mixed serum；Wherein, the cornstarch, borax, poly- second
Enol, dimethicone, the mass ratio of ethylene glycol monobutyl ether are 40~60:1~3:3~5:1~2:0.2~0.5；
(3) dodecyl benzyl dimethyl ammonium chloride, defoamer, nano silicon dioxide, deionized water are added in mixed serum, is made
Discharge after being stirred with dispersion machine with the rotating speed of 2000~3000r/min, the corrugated board glue is made；Wherein, dodecane
Base dimethyl benzyl ammonium chloride, defoamer, nano silicon dioxide, the mass ratio of deionized water are 2~5:1~3:1~3:5~
10。
2. the production technology of corrosion-resistant corrugated board glue according to claim 1, it is characterised in that the step (2)
After adding cornstarch in lye, 35~40 DEG C of heating water bath stirrings are warming up to.
3. the production technology of corrosion-resistant corrugated board glue according to claim 1, it is characterised in that the stabilization agent is
One or more combinations in barium stearate, calcium stearate, zinc stearate, magnesium stearate.
4. the production technology of corrosion-resistant corrugated board glue according to claim 1, it is characterised in that the defoamer is
One or more combinations in DS-8800, DS-9000, DS-5080, DS-2001.
5. the production technology of corrosion-resistant corrugated board glue according to claim 1, it is characterised in that the step (2)
The mixed serum of preparation uses 320~360s of high speed shear, and the screw speed of dispersion machine is 1400~1600r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711193567.5A CN108003814A (en) | 2017-11-24 | 2017-11-24 | A kind of production technology of corrosion-resistant corrugated board glue |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711193567.5A CN108003814A (en) | 2017-11-24 | 2017-11-24 | A kind of production technology of corrosion-resistant corrugated board glue |
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| CN108003814A true CN108003814A (en) | 2018-05-08 |
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|---|---|---|---|
| CN201711193567.5A Pending CN108003814A (en) | 2017-11-24 | 2017-11-24 | A kind of production technology of corrosion-resistant corrugated board glue |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109334129A (en) * | 2018-10-23 | 2019-02-15 | 东莞市厚威包装科技股份有限公司 | A kind of corrugated paper bonded using low temperature corrugation paper-hanging |
| CN109777319A (en) * | 2018-12-20 | 2019-05-21 | 昆山美泰纸业有限公司 | A kind of preparation method and corrugation paper-hanging of corrugation paper-hanging |
| CN110511696A (en) * | 2019-08-20 | 2019-11-29 | 马鞍山市康辉纸箱纸品有限公司 | A kind of preparation method of the adhesive of corrugated paper production |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011160049A1 (en) * | 2010-06-18 | 2011-12-22 | Cargill, Incorporated | Reduced solids adhesive composition and related methods |
| CN104513636A (en) * | 2015-01-12 | 2015-04-15 | 西安长鸣包装有限责任公司 | Adhesive with anti-line-explosion function for corrugated paperboard production and preparation method of adhesive |
| CN104893614A (en) * | 2015-05-21 | 2015-09-09 | 芜湖蒲草电子商务有限公司 | High-strength waterproof binder for corrugated paper case |
| CN106700971A (en) * | 2017-01-20 | 2017-05-24 | 沈阳 | Quick-drying anticorrosive adhesive for corrugated paper and preparation method thereof |
-
2017
- 2017-11-24 CN CN201711193567.5A patent/CN108003814A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011160049A1 (en) * | 2010-06-18 | 2011-12-22 | Cargill, Incorporated | Reduced solids adhesive composition and related methods |
| CN104513636A (en) * | 2015-01-12 | 2015-04-15 | 西安长鸣包装有限责任公司 | Adhesive with anti-line-explosion function for corrugated paperboard production and preparation method of adhesive |
| CN104893614A (en) * | 2015-05-21 | 2015-09-09 | 芜湖蒲草电子商务有限公司 | High-strength waterproof binder for corrugated paper case |
| CN106700971A (en) * | 2017-01-20 | 2017-05-24 | 沈阳 | Quick-drying anticorrosive adhesive for corrugated paper and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109334129A (en) * | 2018-10-23 | 2019-02-15 | 东莞市厚威包装科技股份有限公司 | A kind of corrugated paper bonded using low temperature corrugation paper-hanging |
| CN109777319A (en) * | 2018-12-20 | 2019-05-21 | 昆山美泰纸业有限公司 | A kind of preparation method and corrugation paper-hanging of corrugation paper-hanging |
| CN109777319B (en) * | 2018-12-20 | 2020-08-07 | 昆山美泰纸业有限公司 | Preparation method of corrugated paper glue and corrugated paper glue |
| CN110511696A (en) * | 2019-08-20 | 2019-11-29 | 马鞍山市康辉纸箱纸品有限公司 | A kind of preparation method of the adhesive of corrugated paper production |
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Application publication date: 20180508 |