CN107759840A - A kind of complex biological matter resin - Google Patents
A kind of complex biological matter resin Download PDFInfo
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- CN107759840A CN107759840A CN201711181654.9A CN201711181654A CN107759840A CN 107759840 A CN107759840 A CN 107759840A CN 201711181654 A CN201711181654 A CN 201711181654A CN 107759840 A CN107759840 A CN 107759840A
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- weight
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- resin
- complex biological
- biological matter
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The present invention relates to a kind of complex biological matter resin, is made up of following component by weight：The parts by weight of compound stabilizer 5 12, modified plant fibers plain 12 27 parts by weight, the parts by weight of plant amylum 25 50, the parts by weight of plant protein powder 4 10, the parts by weight of resol resin 48, the parts by weight of resin additive 10 15, the parts by weight of urea resin 25 and the parts by weight of preservative 2~5.The complex biological matter resin of the present invention, as product that is structurally-modified to natural macromolecular and recombinating, the chemical structure characteristic of natural biological macromolecular has been held comprehensively, effective transformation of molecular function on the premise of covalent bond, is being realized not inside saboteur.On the basis of the purpose of specific function is reached, the energy expended in production process is greatly lowered than the method that degradable biomass macromolecular is crosslinked again again, realizes making full use of for resource and the energy, production process is environment friendly and pollution-free.The application, storage and transport of basic biomass synthetic resin are simplified, has expanded application space.
Description
Technical field
The invention belongs to biomass energy technology field, more particularly to a kind of complex biological matter resin.
Background technology
Biomass synthetic resin refers to a kind of mainly using physically or chemically means to natural macromolecular such as protein, starch
Or carbohydrate carries out appropriateness and is modified, and is allowed to some characteristics for possessing synthetic resin, can substitute in certain application field
Traditional synthetic resin, while there is the novel biomass synthetic material of complete nuisanceless degraded feature again.
The composition principle of biomass synthetic resin mainly uses gentle chemistry in using water as the reaction system of solvent
The natural macromolecular conformation transition of complexity is simple chain structure by reagent or enzyme preparation, makes to be hidden in originally intramolecular
Chemical functional group is exposed, and participates in intermolecular chemical reaction under certain condition, generates the polymer of body formula resin structure.
The application field of biomass synthetic resin mainly has biomass adhesive, coating etc..Biomass adhesive has
There is degradable, free of contamination advantage, since last century the '30s, in wood processing field, people make great efforts to take respectively always
Kind method makes biomass adhesive enter scale industrial production.In early stage, the biomass adhesive one using rubber made from soybean cake as representative
Degree occupies the 85% of U.S. glued board market.But after World War II, with the development of petroleum industry, with oil
Derivative gradually instead of soybean adhesive for the adhesive of base-material.Synthetic adhesive is more cheap, has and is preferably bonded by force
Degree and water-resistance.Leading position is occupy with " three-aldehyde glue " for a long time for the synthetic adhesive of representative in wood-based plate field.Although various countries
Scientist takes various methods to be modified biological material, but up to the present, biomass adhesive is upper with closing in application
Resin adhesive still suffers from larger gap.
The content of the invention
The technical problems to be solved by the invention are in view of the shortcomings of the prior art, there is provided a kind of complex biological matter tree
Fat, to solve at least one of above-mentioned technical problem.
The technical scheme that the present invention solves above-mentioned technical problem is as follows：A kind of complex biological matter resin, by below by weight
Measure the component composition of part meter：Compound stabilizer 5-12 parts by weight, modified plant fibers element 12-27 parts by weight, plant amylum 25-50
Parts by weight, plant protein powder 4-10 parts by weight, resol resin 4-8 parts by weight, resin additive 10-15 parts by weight, urea
Resin 2-5 parts by weight and the parts by weight of preservative 2~5.
The beneficial effects of the invention are as follows：The complex biological matter resin of the present invention, as structurally-modified to natural macromolecular
And the product recombinated, the chemical structure characteristic of natural biological macromolecular has been held comprehensively, in not covalent bond inside saboteur
Under the premise of, realize effective transformation of molecular function.On the basis of the purpose of specific function is reached, the energy that is expended in production process
Source is greatly lowered than the method that degradable biomass macromolecular is crosslinked again again, realizes making full use of for resource and the energy,
Production process is environment friendly and pollution-free.The application, storage and transport of basic biomass synthetic resin are simplified, has expanded application space.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, it is made up of following component by weight：The parts by weight of compound stabilizer 6, modified plant fibers element 21
Parts by weight, the parts by weight of plant amylum 42, the parts by weight of plant protein powder 5, the parts by weight of resol resin 4, the weight of resin additive 14
Measure part, the parts by weight of urea resin 3 and the parts by weight of preservative 3.
Further, the compound stabilizer is trisodium citrate, sodium metasilicate, ferrous sulfate, sodium dihydrogen phosphate, potassium tartrate
At least one of sodium, algin, polyethylene glycol oxide, polyvinyl alcohol, polyethylene glycol and polyacrylamide.
Further, the plant amylum is in cornstarch, wheaten starch, potato starch, chestnut starch and starch from sweet potato
At least one.
Further, the modified plant fibers element powder is that Semen Tritici aestivi fiber powder, zein fiber powder, cotton fibre powder and flax are fine
Tie up at least one of powder.
Further, the protein content in the plant protein powder is not less than 50wt%.
Further, the resin additive includes water-soluble cationic resins, mutual solvent and pH value additive.
Embodiment
The principles and features of the present invention are described below, and the given examples are served only to explain the present invention, is not intended to limit
Determine the scope of the present invention.
A kind of complex biological matter resin, it is made up of following component by weight：Compound stabilizer 5-12 parts by weight,
Modified plant fibers element 12-27 parts by weight, plant amylum 25-50 parts by weight, plant protein powder 4-10 parts by weight, soluble phenolic aldehyde
Resin 4-8 parts by weight, resin additive 10-15 parts by weight, urea resin 2-5 parts by weight and the parts by weight of preservative 2~5.It is described multiple
Conjunction stabilizer be trisodium citrate, sodium metasilicate, ferrous sulfate, sodium dihydrogen phosphate, sodium potassium tartrate tetrahydrate, algin, polyethylene glycol oxide,
At least one of polyvinyl alcohol, polyethylene glycol and polyacrylamide.The plant amylum is cornstarch, wheaten starch, soil
At least one of beans starch, chestnut starch and starch from sweet potato.The modified plant fibers element powder is Semen Tritici aestivi fiber powder, corn fibre
Tie up at least one of powder, cotton fibre powder and flax fiber powder.Protein content in the plant protein powder is not less than
50wt%.The resin additive includes water-soluble cationic resins, mutual solvent and pH value additive.
The complex biological matter resin of the present invention, as product that is structurally-modified to natural macromolecular and recombinating, comprehensively handle
The chemical structure characteristic of natural biological macromolecular has been held, on the premise of covalent bond, molecule work(is being realized not inside saboteur
Effective transformation of energy.On the basis of the purpose of specific function is reached, the energy expended in production process is than degradable biomass
The method that macromolecular is crosslinked again again is greatly lowered, and realizes making full use of for resource and the energy, production process is environment friendly and pollution-free.
The application, storage and transport of basic biomass synthetic resin are simplified, has expanded application space.
It is introduced below by specific embodiment.
Embodiment 1
A kind of complex biological matter resin, it is made up of following component by weight：The parts by weight of compound stabilizer 6, change
Property plant cellulose 21 parts by weight, the parts by weight of plant amylum 42, plant protein powder 4-10 parts by weight, the weight of resol resin 4
Measure part, the parts by weight of resin additive 14, the parts by weight of urea resin 3 and the parts by weight of preservative 3.
Embodiment 2
A kind of complex biological matter resin, it is made up of following component by weight：The parts by weight of compound stabilizer 5, change
Property plant cellulose 18 parts by weight, the parts by weight of plant amylum 40, the parts by weight of plant protein powder 5, the weight of resol resin 4
Part, the parts by weight of resin additive 14, the parts by weight of urea resin 3 and the parts by weight of preservative 3.
Embodiment 3
A kind of complex biological matter resin, it is made up of following component by weight：The parts by weight of compound stabilizer 8, change
Property plant cellulose 25 parts by weight, the parts by weight of plant amylum 33, the parts by weight of plant protein powder 5, the weight of resol resin 4
Part, the parts by weight of resin additive 12, the parts by weight of urea resin 3 and the parts by weight of preservative 3.
Comparative example 1
A kind of complex biological matter resin, it is made up of following component by weight：Modified plant fibers 21 weight of element
Part, the parts by weight of plant amylum 42, the parts by weight of plant protein powder 5, the parts by weight of resol resin 4, the parts by weight of resin additive 14,
The parts by weight of urea resin 3 and the parts by weight of preservative 3.
Comparative example 2
A kind of complex biological matter resin, it is made up of following component by weight：The parts by weight of compound stabilizer 6, change
Property plant cellulose 21 parts by weight, the parts by weight of plant amylum 42, plant protein powder 4-10 parts by weight, the weight of resol resin 4
Measure part, the parts by weight of urea resin 3 and the parts by weight of preservative 3.
Comparative example 3
A kind of complex biological matter resin, it is made up of following component by weight：The parts by weight of compound stabilizer 6, change
Property plant cellulose 15 parts by weight, the parts by weight of plant amylum 50, the parts by weight of plant protein powder 5, the weight of resol resin 4
Part, the parts by weight of resin additive 5 and the parts by weight of preservative 3.
Comparative example 4
A kind of complex biological matter resin, it is made up of following component by weight：The parts by weight of compound stabilizer 6, change
Property plant cellulose 21 parts by weight, the parts by weight of plant amylum 42, the parts by weight of resol resin 4, the parts by weight of resin additive 14,
The parts by weight of urea resin 3 and the parts by weight of preservative 3.
Measure of merit
In above-described embodiment and the ratio of comparative example, compound stabilizer is added to the water and is configured to the aqueous solution；It is molten in gained
Plant protein powder, regulation pH value to 7 are added in liquid；The resol resin weighed is added in the solution, under the conditions of 40 DEG C
React 200min；When system viscosity reaches 800~1200mPa.s, 75 DEG C are warming up to, is incubated 18min；Added in reaction solution
The plant amylum weighed and modified plant fibers element powder, are cooled to 40 DEG C；The resin weighed is added into reaction system successively to help
Agent, urea resin and preservative, continue polymerisation 20min, product biomass synthetic resin is obtained after reaction.It is glued to test it
Viscosity.
Test result is as shown in table 1.
Table 1
Data in table 1 can be seen that the complex biological matter resin of the present invention under equal conditions, viscous reducing
It is more preferable in terms of degree, it is with a wide range of applications.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.
Claims (7)
1. a kind of complex biological matter resin, it is characterised in that be made up of following component by weight：Compound stabilizer 5-
12 parts by weight, modified plant fibers element 12-27 parts by weight, plant amylum 25-50 parts by weight, plant protein powder 4-10 parts by weight,
Resol resin 4-8 parts by weight, resin additive 10-15 parts by weight, urea resin 2-5 parts by weight and the weight of preservative 2~5
Part.
2. a kind of complex biological matter resin according to claim 1, it is characterised in that by following component by weight
Composition：Plain 21 parts by weight of the parts by weight of compound stabilizer 6, modified plant fibers, the parts by weight of plant amylum 42, the weight of plant protein powder 5
Measure part, the parts by weight of resol resin 4, the parts by weight of resin additive 14, the parts by weight of urea resin 3 and the parts by weight of preservative 3.
3. a kind of complex biological matter resin according to claim 1, it is characterised in that the compound stabilizer is citric acid
Trisodium, sodium metasilicate, ferrous sulfate, sodium dihydrogen phosphate, sodium potassium tartrate tetrahydrate, algin, polyethylene glycol oxide, polyvinyl alcohol, poly- second two
At least one of alcohol and polyacrylamide.
4. a kind of complex biological matter resin according to claim 1, it is characterised in that the plant amylum forms sediment for corn
At least one of powder, wheaten starch, potato starch, chestnut starch and starch from sweet potato.
5. a kind of complex biological matter resin according to claim 1, it is characterised in that the modified plant fibers element powder is
At least one of Semen Tritici aestivi fiber powder, zein fiber powder, cotton fibre powder and flax fiber powder.
A kind of 6. complex biological matter resin according to claim 1, it is characterised in that the albumen in the plant protein powder
Matter content is not less than 50wt%.
7. a kind of complex biological matter resin according to claim 1, it is characterised in that the resin additive includes water solubility
Resin cation, mutual solvent and pH value additive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711181654.9A CN107759840A (en) | 2017-11-23 | 2017-11-23 | A kind of complex biological matter resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711181654.9A CN107759840A (en) | 2017-11-23 | 2017-11-23 | A kind of complex biological matter resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107759840A true CN107759840A (en) | 2018-03-06 |
Family
ID=61278763
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711181654.9A Withdrawn CN107759840A (en) | 2017-11-23 | 2017-11-23 | A kind of complex biological matter resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107759840A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101629019A (en) * | 2009-01-21 | 2010-01-20 | 郑州佰沃生物质材料有限公司 | Basic biomass synthetic resin and preparation method and application thereof |
| CN105368071A (en) * | 2015-12-12 | 2016-03-02 | 郑州佰沃生物质材料有限公司 | Biomass resin and preparation method of fibre oriented shaving composite board |
-
2017
- 2017-11-23 CN CN201711181654.9A patent/CN107759840A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101629019A (en) * | 2009-01-21 | 2010-01-20 | 郑州佰沃生物质材料有限公司 | Basic biomass synthetic resin and preparation method and application thereof |
| CN105368071A (en) * | 2015-12-12 | 2016-03-02 | 郑州佰沃生物质材料有限公司 | Biomass resin and preparation method of fibre oriented shaving composite board |
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180306 |
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| WW01 | Invention patent application withdrawn after publication |