CN107758061B - Communication intelligence optical maintenance tool box - Google Patents
Communication intelligence optical maintenance tool box Download PDFInfo
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- CN107758061B CN107758061B CN201711238683.4A CN201711238683A CN107758061B CN 107758061 B CN107758061 B CN 107758061B CN 201711238683 A CN201711238683 A CN 201711238683A CN 107758061 B CN107758061 B CN 107758061B
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- upper housing
- nano
- lower case
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
- B65D25/02—Internal fittings
- B65D25/04—Partitions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- G—PHYSICS
- G08—SIGNALLING
- G08B—SIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
- G08B21/00—Alarms responsive to a single specified undesired or abnormal condition and not otherwise provided for
- G08B21/02—Alarms for ensuring the safety of persons
-
- G—PHYSICS
- G08—SIGNALLING
- G08B—SIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
- G08B25/00—Alarm systems in which the location of the alarm condition is signalled to a central station, e.g. fire or police telegraphic systems
- G08B25/01—Alarm systems in which the location of the alarm condition is signalled to a central station, e.g. fire or police telegraphic systems characterised by the transmission medium
- G08B25/10—Alarm systems in which the location of the alarm condition is signalled to a central station, e.g. fire or police telegraphic systems characterised by the transmission medium using wireless transmission systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of communication intelligence optical maintenance tool boxes, including outer container, the outer container includes upper housing, the upper housing bottom is equipped with lower case, the upper housing is connected through hinge activity with lower case, solar panel is equipped at the top of the upper housing, battery is equipped with inside the upper housing, the battery side is equipped with converter, the converter side is equipped with GPS locator and bottom is equipped with programmable controller, the programmable controller is equipped with operating switch and cancel switch, the cancel switch is set at the top of operating switch, the programmable controller side is equipped with alarm, the present invention is by being equipped with GPS locator and signal conveyer, in order to which the staff of server internal can be unfolded to search and rescue by the position signal that GPS locator sends over to user, to improve user Safety, make present invention practicability with higher.
Description
Technical field
The present invention relates to technical field of electric power, in particular to a kind of communication intelligence optical maintenance tool box.
Background technique
Electric power overhaul is the work with higher risk, due to undermanned, many electric power overhaul persons
It needs to carry out service work alone, there are also being exactly because some electric power overhaul regions are more remote, which results in electric power
When carrying out service work if accident, which occurs, for maintenance person leads to stupor, it is unable to get effective rescue.
Therefore, it is necessary to solve the above problems to invent a kind of communication intelligence optical maintenance tool box.
Summary of the invention
The purpose of the present invention is to provide a kind of communication intelligence optical maintenance tool boxes, to solve to mention in above-mentioned background technique
Out the problem of, while cabinet satisfactory mechanical property of the invention, water-fast, high temperature resistant, corrosion-resistant, adhesive force is strong.
To achieve the above object, the invention provides the following technical scheme: a kind of communication intelligence optical maintenance tool box, including
Outer container, the outer container include upper housing, and it is living by hinge that the upper housing bottom is equipped with lower case, the upper housing and lower case
Dynamic connection, the upper housing top are equipped with solar panel, are equipped with battery, the battery side inside the upper housing
Equipped with converter, the converter side is equipped with GPS locator and bottom is equipped with programmable controller, the PLC technology
Device is equipped with operating switch and cancel switch, and the cancel switch is set at the top of operating switch, the programmable controller side
Equipped with alarm, the alarm side is equipped with signal conveyer, is equipped with communicator, the lower casing at the top of the signal conveyer
Internal portion is equipped with baffler, and the baffler two sides are equipped with well, is equipped with piston in the well, the piston into
Port is equipped with check valve, is equipped with the electric telescopic rod for pulling piston rod in the well, the electric telescopic rod and programmable
Controller connection.
Preferably, signal conveyer connecting pin is equipped with signal receiver, and the signal receiver is set in server
Portion.
Preferably, it is equipped with the first protective layer on the inside of the upper housing, is equipped with the second protective layer on the inside of the lower case.
Preferably, first protective layer, the second protective layer and baffler are made of sponge material.
Preferably, the battery, GPS locator, alarm, signal conveyer and communicator be and programmable controller
It is electrically connected.
Preferably, the outer container side is equipped with lock, is equipped with handle between the lock.
Preferably, the solar panel is electrically connected by converter and battery.
The outer surface of the upper housing and lower case is coated with abrasion-proof insulating layer, is made of following components and its content:
2-5 parts of epoxy resin 30-44 parts by weight, polymethyl acrylate, 5-10 parts of chloroform, coupling agent 3.8-5.5 parts by weight, nanometer
Oxide 12-17 parts by weight, polydiene base the third alkyl dimethyl ammonium chloride 4.5-5.6 parts by weight, tributyl phosphate 2.8-3.3 weight
Part, waterproofing agent 6.7-7.2 parts by weight, heat-resistant agent 5.8-6.3 parts by weight, corrosion-resistant agent 8.9-9.6 parts by weight, corrosion inhibiter 7.3-
8.8 parts by weight, acetone 20-26 parts by weight, water 46-55 parts by weight.
Further, the coupling agent is 3-aminopropyltriethoxysilane or 3- glycydoxy front three
Oxysilane.
Further, the nano-oxide is the mixing of nano magnesia, nano silica, nano-titanium dioxide
Object, weight ratio nano magnesia: nano silica: nano-titanium dioxide 4:3:3.
Further, the waterproofing agent is the mixture of sodium methyl silicate and calcium stearate, weight ratio sodium methyl silicate: hard
Resin acid calcium is 7:3.
Further, the corrosion-resistant agent is one of hexa, cinnamic acid, poly-aspartate or a variety of.
Further, the corrosion-resistant agent is hexa, cinnamic acid, poly-aspartate, weight ratio hexa-methylene
Tetramine: cinnamic acid: poly-aspartate 2:3:5.
Further, the corrosion inhibiter is sodium chromate or sodium nitrite.
Further, the heat-resistant agent is one of N-phenylmaleimide or Dacthal
Or two kinds.
Further, the heat-resistant agent is the mixing of N-phenylmaleimide and Dacthal
Object, weight ratio N-phenylmaleimide: Dacthal 4:6.
Further, the preparation method of the abrasion-proof insulating layer, comprises the following steps:
1) after the nano-oxide of 12-17 parts by weight being placed in 80 DEG C of vacuum ovens dry 13-14h, with 20-26 weight
The acetone mixing for measuring part, is added the coupling agent of 3.8-5.5 parts by weight, is placed in magnetic stirring apparatus and stirs, in 20 DEG C -25 DEG C of item
Under part, revolving speed 300-400r/min, mixing time 2-4h filter, 6-8h are dried in 75-80 DEG C of baking oven, grind, obtain
The modified nano-oxide powder in surface;
2) polymethyl acrylate of 2-5 parts by weight is added in the chloroform of 5-10 parts by weight and is mixed, be placed in magnetic force
In blender, under conditions of 20 DEG C -25 DEG C, revolving speed 200-300r/min, mixing time 40-45min obtain mixed liquor
One;
3) the modified nano oxidized powder in the surface that step 1) obtains is mixed with the mixed liquor one that step 2 obtains, and added
The tributyl phosphate of the water and 2.8-3.3 parts by weight that enter 46-55 parts by weight is placed in ball milling in ball mill, revolving speed 150-180r/
Min, time 10-12h obtain mixed liquor two;
4) be added into the mixed liquor two that step 3) obtains the epoxy resin of 30-44 parts by weight, 4.5-5.6 parts by weight it is poly-
The third alkyl dimethyl ammonium chloride of dialkylene, is placed in high-speed mixer, and adjusting revolving speed is 700-900r/min, mixing time 15-
30min, then be added the waterproofing agent of 6.7-7.2 parts by weight, the heat-resistant agent of 5.8-6.3 parts by weight, 8.9-9.6 parts by weight corrosion resistant
The corrosion inhibiter of agent, 7.3-8.8 parts by weight is lost, adjusting revolving speed is 400-500r/min, and mixing time is 5-8h to get target production
Object;
5) target product that step 4) obtains is shaken into 10-12h, amplitude 50mm, revolving speed 100- in bottle swingging machine
200r/min filters to get final product.
The beneficial effects of the present invention are: epoxy resin is as etch-proof material, not only water resistant, leakage resistance are good, intensity
It is higher, while adhesive force is strong, dielectric properties are good, and deformation retract rate is small, and the stability and flexibility of material can be improved.The present invention
The epoxy resin used has good mechanical performance for novolac epoxy resin, and heat resistance is more preferable.
Using coupling agent modified nano-oxide, the lipophilicity of nanoparticle is improved, is made it easier in organic solvent
Dispersion enhances the compatibility between molecule, shows good interfacial phenomenon, improve the mechanical property of material.Polydiene base third
Alkyl dimethyl ammonium chloride and nanometer oxide particle organically combine, improve the corrosion resistance of material, while reinforced epoxy is consolidated
Change effect.
Chloroform dissolves polymethyl acrylate as solvent.Polymethyl acrylate has anti-microbial property and ultraviolet screener
Performance improves the adhesive force of coating in conjunction with epoxy resin, acts synergistically with nano-oxide, extends the weatherability of material.Phosphorus
Sour tributyl reduces surface tension as defoaming agent, and foam is inhibited to generate, and improves chemical stability.
Waterproofing agent enhances hydrophobicity, improves the impervious moisture protection of material, and corrosion-resistant agent improves material acid-proof alkaline, increases
Extensive chemical stability extends the service life of material.Heat-resistant agent can be acceleratedCrystalline rate, increase crystal density and promote crystal grain ruler
Very little miniaturization significantly improves the heat distortion temperature of coating.Molecular orientation in corrosion inhibiter is arranged in metal surface, forms one layer and dredges
Moisture film, isolation hydrone are contacted with metal surface, to play inhibition, anti-rust action, acetone is organic solvent.
The present invention is modified nano-oxide, and nano-oxide has significant synergistic effect, and a variety of materials are organic
In conjunction with playing the synergistic effect of each component, abrasion-proof insulating layer obtained, mechanical performance and excellent insulating property, water-fast, resistance to height
Warm, resistant to chemical etching, adhesive force is strong, can keep stability for a long time in acid or alkali environment, can be in -50 DEG C to 100 DEG C of ring
It is used for a long time in border, excellent combination property.The coating can form one layer of fine and close protective film on an iron rake with three to six teeth surface, etch-proof same
When, the effect of antirust is played, the service life of electric power tower is extended.
Technical effect and advantage of the invention: the present invention is by being equipped with GPS locator and signal conveyer, in order to service
Staff inside device can be unfolded to search and rescue by the position signal that GPS locator sends over to user, to improve
The safety of user makes present invention practicability with higher, being equipped with the first protective layer made of sponge material, the
Two protective layers and baffler prevent the present invention in carrying or transportational process in order to the tool inside effective protection well,
The case where tool in well collides with outer container, and tool or the present invention is caused to damage, to improve use of the invention
Service life avoids the unnecessary economic loss of user.
Detailed description of the invention
Fig. 1 is overall structure diagram of the invention.
Fig. 2 is upper housing structural schematic diagram of the invention.
Fig. 3 is lower case structural schematic diagram of the invention.
Fig. 4 is programmable controller structural schematic diagram of the invention.
In figure: 1 outer container, 2 upper housings, 3 lower cases, 4 solar panels, 5 batteries, 6 converters, 7 GPS locators,
8 programmable controllers, 9 operating switches, 10 cancel switches, 11 alarms, 12 signal conveyers, 13 communicators, 14 bafflers, 15
Well, 16 first protective layers, 17 second protective layers, 18 locks, 19 handles.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
It is described outer the present invention provides a kind of communication intelligence optical maintenance tool box as shown in Figs 1-4, including outer container 1
Case 1 includes upper housing 2, and 2 bottom of upper housing is equipped with lower case 3, and the upper housing 2 is connected with lower case 3 by hinge activity
It connects, solar panel 4 is equipped at the top of the upper housing 2, is equipped with battery 5, the battery 5 one inside the upper housing 2
Side is equipped with converter 6, and 6 side of converter is equipped with GPS locator 7 and bottom is equipped with programmable controller 8, described to compile
Range controller 8 is equipped with operating switch 9 and cancel switch 10, and the cancel switch 10 is set to 9 top of operating switch, described to compile
8 side of range controller is equipped with alarm 11, and 11 side of alarm is equipped with signal conveyer 12, and the signal conveyer 12 pushes up
Portion is equipped with communicator 13, is equipped with baffler 14 inside the lower case 3, and 14 two sides of baffler are equipped with well 15, use
In being equipped with piston 22 in storage service kit, the well, the air inlet of the piston is equipped with check valve 23, the well
Interior to be equipped with the electric telescopic rod 21 for pulling piston rod, the electric telescopic rod is connect with programmable controller.After cabinet is closed,
The sealing ring being arranged between cabinet plays sealing function, and the longitudal section position taper of sealing ring, is controlled, can be compiled by Digiplex
Range controller controls electric telescopic rod and pulls piston rod, and by the intracorporal air sucker of case, the interior formation negative pressure of cabinet is annular
Height on the outside of sealing ring is higher than inside, and ring type seal is inwardly extruded between upper housing and lower case, suction function sealing
Effect is good, while the intracorporal air of case is absorbed piston by piston, contacts less air with valuable equipment, and equipment saves good
It is good.
12 connecting pin of signal conveyer is equipped with signal receiver, and the signal receiver is set to server internal, institute
It states and is equipped with the first protective layer 16 on the inside of upper housing 2, be equipped with the second protective layer 17, first protective layer on the inside of the lower case 3
16, the second protective layer 17 and baffler 14 are made of sponge material, in order to the tool inside effective protection well 15, prevent
Only in carrying or transportational process, the tool in well 15 collides the present invention with outer container 1, and tool or the present invention is caused to damage
The case where, to improve service life of the invention, avoid the unnecessary economic loss of user, the battery 5,
GPS locator 7, alarm 11, signal conveyer 12 and communicator 13 are electrically connected with programmable controller 8, the outer container 1
Side is equipped with lock 18, and handle 19 is equipped between the lock 18, and the solar panel 4 passes through converter 6 and battery 5
It is electrically connected, is stored in storage in order to which solar panel 4 absorbs solar energy and converts solar energy into electrical energy by converter 6
In battery 5.
This practical working principle: when user carries out service work, outer container 1 is opened, operating switch 9, GPS locator are pressed
7 start to work, and service work is carried out the tool that user takes out needs since well 15, when GPS locator 7 in real time to
Programmable controller 8 sends signal, and programmable controller 8 is sent out by signal conveyer 12 to the signal receiver of server internal
Position signal is sent, when programmable controller 8 detects that GPS locator 7 does not move within the set time, programmable controller 8
It controls alarm 11 and carries out sound-light alarm, user can press cancel switch 10 at this time, and programmable controller 8 controls alarm
11 stop alarming, and when not pressing cancel switch 10 in user's setting time, programmable controller 8 is conveyed by signal
Device 12 sends position signal to the signal receiver of server internal, to remind at the staff user of server internal
User, when can not contact, the work of server internal are contacted by communicator 13 in the staff of abnormality, server
The position signal expansion that personnel are sended over by GPS locator 7 is searched and rescued.
The abrasion-proof insulating layer is made of following components and its content: 30 parts by weight of epoxy resin, polymethyl acrylate 2
Part, 5 parts of chloroform, 3.8 parts by weight of 3-aminopropyltriethoxysilane, 12 parts by weight of nano-oxide, polydiene base third
4.5 parts by weight of alkyl dimethyl ammonium chloride, 2.8 parts by weight of tributyl phosphate, 6.7 parts by weight of waterproofing agent, N-phenylmaleimide 5.8
Parts by weight, 8.9 parts by weight of hexa, 7.3 parts by weight of sodium chromate, 20 parts by weight of acetone, 46 parts by weight of water.
The nano-oxide is the mixture of nano magnesia, nano silica, nano-titanium dioxide, and weight ratio is received
Rice magnesia: nano silica: nano-titanium dioxide 4:3:3.
The waterproofing agent is the mixture of sodium methyl silicate and calcium stearate, and weight ratio sodium methyl silicate: calcium stearate is
7:3。
The preparation method of the abrasion-proof insulating layer, comprises the following steps:
1) nano-oxide of 12 parts by weight is placed in third in 80 DEG C of vacuum ovens after drying 13h, with 20 parts by weight
Ketone mixing, is added the coupling agent of 3.8 parts by weight, is placed in magnetic stirring apparatus and stirs, under conditions of 20 DEG C -25 DEG C, revolving speed is
300r/min, mixing time 2h filter, dry 6h in 75 DEG C of baking ovens, grind, and obtain the modified nano-oxide powder in surface
End;
2) polymethyl acrylate of 2 parts by weight is added in the chloroform of 5 parts by weight and is mixed, be placed in magnetic stirring apparatus
In, under conditions of 20 DEG C -25 DEG C, revolving speed 200r/min, mixing time 40min obtain mixed liquor one;
3) the modified nano oxidized powder in the surface that step 1) obtains is mixed with the mixed liquor one that step 2 obtains, and added
The tributyl phosphate of the water and 2.8 parts by weight that enter 46 parts by weight is placed in ball milling in ball mill, revolving speed 150r/min, and the time is
10h obtains mixed liquor two;
4) epoxy resin of 30 parts by weight, the polydiene base of 4.5 parts by weight are added into the mixed liquor two that step 3) obtains
Third alkyl dimethyl ammonium chloride, is placed in high-speed mixer, and adjusting revolving speed is 700r/min, then mixing time 15min is added
The waterproofing agent of 6.7 parts by weight, the heat-resistant agent of 5.8 parts by weight, the corrosion-resistant agent of 8.9 parts by weight, 7.3 parts by weight corrosion inhibiter, adjust
Section revolving speed is 400r/min, and mixing time is 5h to get target product;
5) target product that step 4) obtains is shaken into 10h, amplitude 50mm, revolving speed 100r/min in bottle swingging machine,
It filters to get final product.
Embodiment two
A kind of abrasion-proof insulating layer, is made of following components and its content: 32 parts by weight of epoxy resin, polymethyl acrylate
2.5 parts, 6 parts of chloroform, 4 parts by weight of 3-aminopropyltriethoxysilane, 13 parts by weight of nano-oxide, polydiene base third
4.7 parts by weight of alkyl dimethyl ammonium chloride, 2.9 parts by weight of tributyl phosphate, 6.8 parts by weight of waterproofing agent, four chloro terephthalic acid (TPA)s two
5.9 parts by weight of methyl esters, 9 parts by weight of cinnamic acid, 7.5 parts by weight of sodium nitrite, 21 parts by weight of acetone, 48 parts by weight of water.
The nano-oxide is the mixture of nano magnesia, nano silica, nano-titanium dioxide, and weight ratio is received
Rice magnesia: nano silica: nano-titanium dioxide 4:3:3.
The waterproofing agent is the mixture of sodium methyl silicate and calcium stearate, and weight ratio sodium methyl silicate: calcium stearate is
7:3。
The preparation method of the abrasion-proof insulating layer, comprises the following steps:
1) after the nano-oxide of 13 parts by weight being placed in 80 DEG C of vacuum ovens dry 13.5h, with 21 parts by weight
Acetone mixing, is added the 3-aminopropyltriethoxysilane of 4 parts by weight, is placed in magnetic stirring apparatus and stirs, at 20 DEG C -25 DEG C
Under conditions of, revolving speed 300r/min, mixing time 2.5h filter, dry 6.5h in 75 DEG C of baking ovens, grind, obtain table
The modified nano-oxide powder in face;
2) polymethyl acrylate of 2.5 parts by weight is added in the chloroform of 6 parts by weight and is mixed, be placed in magnetic agitation
In device, under conditions of 20 DEG C -25 DEG C, revolving speed 200r/min, mixing time 42min obtain mixed liquor one;
3) the modified nano oxidized powder in the surface that step 1) obtains is mixed with the mixed liquor one that step 2 obtains, and added
The tributyl phosphate of the water and 2.9 parts by weight that enter 48 parts by weight is placed in ball milling in ball mill, revolving speed 160r/min, and the time is
10.5h obtains mixed liquor two;
4) epoxy resin of 32 parts by weight, the polydiene base of 4.7 parts by weight are added into the mixed liquor two that step 3) obtains
Third alkyl dimethyl ammonium chloride, is placed in high-speed mixer, and adjusting revolving speed is 750r/min, then mixing time 18min is added
The waterproofing agent of 6.8 parts by weight, the Dacthal of 5.9 parts by weight, the cinnamic acid of 9 parts by weight, 7.8 parts by weight
Sodium nitrite, adjusting revolving speed be 450r/min, mixing time be 5.5h to get target product;
5) target product that step 4) obtains is shaken into 10.5h, amplitude 50mm, revolving speed 120r/ in bottle swingging machine
Min filters to get final product.
Embodiment three
A kind of abrasion-proof insulating layer, is made of following components and its content: 35 parts by weight of epoxy resin, polymethyl acrylate 3
Part, 7 parts of chloroform, 4.4 parts by weight of 3- glycidyl ether oxypropyltrimethoxysilane, 14 parts by weight of nano-oxide,
4.8 parts by weight of the third alkyl dimethyl ammonium chloride of polydiene base, 3 parts by weight of tributyl phosphate, 6.9 parts by weight of waterproofing agent, N- phenyl Malaysia
6 parts by weight of acid imide, 9.2 parts by weight of poly-aspartate, 7.6 parts by weight of sodium chromate, 22 parts by weight of acetone, 49 parts by weight of water.
The nano-oxide is the mixture of nano magnesia, nano silica, nano-titanium dioxide, and weight ratio is received
Rice magnesia: nano silica: nano-titanium dioxide 4:3:3.
The waterproofing agent is the mixture of sodium methyl silicate and calcium stearate, and weight ratio sodium methyl silicate: calcium stearate is
7:3。
The preparation method of the abrasion-proof insulating layer, comprises the following steps:
1) nano-oxide of 14 parts by weight is placed in third in 80 DEG C of vacuum ovens after drying 14h, with 22 parts by weight
Ketone mixing, is added the 3- glycidyl ether oxypropyltrimethoxysilane of 4.4 parts by weight, is placed in magnetic stirring apparatus and stirs,
Under conditions of 20 DEG C -25 DEG C, revolving speed 350r/min, mixing time 3h filter, dry 7h in 80 DEG C of baking ovens, grind,
Obtain the modified nano-oxide powder in surface;
2) polymethyl acrylate of 3 parts by weight is added in the chloroform of 7 parts by weight and is mixed, be placed in magnetic stirring apparatus
In, under conditions of 20 DEG C -25 DEG C, revolving speed 300r/min, mixing time 45min obtain mixed liquor one;
3) the modified nano oxidized powder in the surface that step 1) obtains is mixed with the mixed liquor one that step 2 obtains, and added
The tributyl phosphate of the water and 3 parts by weight that enter 49 parts by weight is placed in ball milling in ball mill, revolving speed 160r/min, time 11h,
Obtain mixed liquor two;
4) epoxy resin of 35 parts by weight, the polydiene base of 4.8 parts by weight are added into the mixed liquor two that step 3) obtains
Third alkyl dimethyl ammonium chloride, is placed in high-speed mixer, and adjusting revolving speed is 800r/min, then mixing time 20min is added
The waterproofing agent of 6.9 parts by weight, the N-phenylmaleimide of 6 parts by weight, the poly-aspartate of 9.2 parts by weight, 7.6 parts by weight
Sodium chromate, adjusting revolving speed are 450r/min, and mixing time is 7h to get target product;
5) target product that step 4) obtains is shaken into 11h, amplitude 50mm, revolving speed 150r/min in bottle swingging machine,
It filters to get final product.
Example IV
A kind of abrasion-proof insulating layer, the component and its content for including are the same as embodiment three.
The preparation method of the abrasion-proof insulating layer, comprises the following steps:
1) nano-oxide of 14 parts by weight is placed in third in 80 DEG C of vacuum ovens after drying 14h, with 22 parts by weight
Ketone mixing, is added the 3- glycidyl ether oxypropyltrimethoxysilane of 4.4 parts by weight, is placed in magnetic stirring apparatus and stirs,
Under conditions of 20 DEG C -25 DEG C, revolving speed 400r/min, mixing time 4h filter, dry 8h in 80 DEG C of baking ovens, grind,
Obtain the modified nano-oxide powder in surface;
2) polymethyl acrylate of 3 parts by weight is added in the chloroform of 7 parts by weight and is mixed, be placed in magnetic stirring apparatus
In, under conditions of 20 DEG C -25 DEG C, revolving speed 300r/min, mixing time 45min obtain mixed liquor one;
3) the modified nano oxidized powder in the surface that step 1) obtains is mixed with the mixed liquor one that step 2 obtains, and added
The tributyl phosphate of the water and 3 parts by weight that enter 49 parts by weight is placed in ball milling in ball mill, revolving speed 180r/min, time 12h,
Obtain mixed liquor two;
4) epoxy resin of 35 parts by weight, the polydiene base of 4.8 parts by weight are added into the mixed liquor two that step 3) obtains
Third alkyl dimethyl ammonium chloride, is placed in high-speed mixer, and adjusting revolving speed is 900r/min, then mixing time 30min is added
The waterproofing agent of 6.9 parts by weight, the N-phenylmaleimide of 6 parts by weight, the poly-aspartate of 9.2 parts by weight, 7.6 parts by weight
Sodium chromate, adjusting revolving speed are 500r/min, and mixing time is 8h to get target product;
5) target product that step 4) obtains is shaken into 12h, amplitude 50mm, revolving speed 200r/min in bottle swingging machine,
It filters to get final product.
Embodiment five
A kind of abrasion-proof insulating layer, is made of following components and its content: 39 parts by weight of epoxy resin, polymethyl acrylate 4
Part, 8 parts of chloroform, 5 parts by weight of 3-aminopropyltriethoxysilane, 15 parts by weight of nano-oxide, polydiene base the third two
It is 5.2 parts by weight of ammonio methacrylate, 3.1 parts by weight of tributyl phosphate, 7 parts by weight of waterproofing agent, 6.1 parts by weight of heat-resistant agent, corrosion-resistant
9.3 parts by weight of agent, 8.3 parts by weight of sodium chromate, 24 parts by weight of acetone, 50 parts by weight of water.
The nano-oxide is the mixture of nano magnesia, nano silica, nano-titanium dioxide, and weight ratio is received
Rice magnesia: nano silica: nano-titanium dioxide 4:3:3.
The waterproofing agent is the mixture of sodium methyl silicate and calcium stearate, and weight ratio sodium methyl silicate: calcium stearate is
7:3。
The corrosion-resistant agent is hexa, cinnamic acid, poly-aspartate, weight ratio hexa: cortex cinnamomi
Aldehyde: poly-aspartate 2:3:5.
The heat-resistant agent is the mixture of N-phenylmaleimide and Dacthal, weight ratio N-
Phenyl maleimide: Dacthal 4:6.
The preparation method of the abrasion-proof insulating layer, comprises the following steps:
1) nano-oxide of 15 parts by weight is placed in third in 80 DEG C of vacuum ovens after drying 14h, with 24 parts by weight
Ketone mixing, is added the 3-aminopropyltriethoxysilane of 5 parts by weight, is placed in magnetic stirring apparatus and stirs, at 20 DEG C -25 DEG C
Under the conditions of, revolving speed 350r/min, mixing time 4h filter, dry 8h in 80 DEG C of baking ovens, grind, and it is modified to obtain surface
Nano-oxide powder;
2) polymethyl acrylate of 4 parts by weight is added in the chloroform of 8 parts by weight and is mixed, be placed in magnetic stirring apparatus
In, under conditions of 20 DEG C -25 DEG C, revolving speed 300r/min, mixing time 45min obtain mixed liquor one;
3) the modified nano oxidized powder in the surface that step 1) obtains is mixed with the mixed liquor one that step 2 obtains, and added
The tributyl phosphate of the water and 3.1 parts by weight that enter 50 parts by weight is placed in ball milling in ball mill, revolving speed 170r/min, and the time is
12h obtains mixed liquor two;
4) epoxy resin of 39 parts by weight, the polydiene base of 5.2 parts by weight are added into the mixed liquor two that step 3) obtains
Third alkyl dimethyl ammonium chloride, is placed in high-speed mixer, and adjusting revolving speed is 800r/min, then mixing time 30min is added 7
The waterproofing agent of parts by weight, the heat-resistant agent of 6.1 parts by weight, the corrosion-resistant agent of 9.3 parts by weight, 8.3 parts by weight sodium chromate, adjust turn
Speed is 450r/min, and mixing time is 7h to get target product;
5) target product that step 4) obtains is shaken into 12h, amplitude 50mm, revolving speed 180r/min in bottle swingging machine,
It filters to get final product.
Embodiment six
A kind of abrasion-proof insulating layer, including component and its content be with embodiment five, but from embodiment five unlike,
The corrosion-resistant agent that embodiment uses is hexa.
This is used for the preparation method of the erosion resisting insulation material of buried cable with embodiment five.
Embodiment seven
A kind of abrasion-proof insulating layer, is made of following components and its content: 42 parts by weight of epoxy resin, polymethyl acrylate
4.5 parts, 9 parts of chloroform, 5.2 parts by weight of 3-aminopropyltriethoxysilane, 16 parts by weight of nano-oxide, polydiene base
Third alkyl dimethyl ammonium chloride, 5.4 parts by weight, 3.2 parts by weight of tributyl phosphate, 7.1 parts by weight of waterproofing agent, four chloro terephthalic acid (TPA)s
6.2 parts by weight of dimethyl ester, 9.5 parts by weight of corrosion-resistant agent, 8.5 parts by weight of sodium chromate, 25 parts by weight of acetone, 52 parts by weight of water.
The nano-oxide is the mixture of nano magnesia, nano silica, nano-titanium dioxide, and weight ratio is received
Rice magnesia: nano silica: nano-titanium dioxide 4:3:3.
The waterproofing agent is the mixture of sodium methyl silicate and calcium stearate, and weight ratio sodium methyl silicate: calcium stearate is
7:3。
The corrosion-resistant agent is hexa, cinnamic acid, poly-aspartate, weight ratio hexa: cortex cinnamomi
Aldehyde: poly-aspartate 2:3:5.
The preparation method of the abrasion-proof insulating layer, comprises the following steps:
1) nano-oxide of 16 parts by weight is placed in third in 80 DEG C of vacuum ovens after drying 13h, with 25 parts by weight
Ketone mixing, is added the 3-aminopropyltriethoxysilane of 5.2 parts by weight, is placed in magnetic stirring apparatus and stirs, at 20 DEG C -25 DEG C
Under conditions of, revolving speed 300r/min, mixing time 2h filter, dry 6h in 75 DEG C of baking ovens, grind, obtain to surface and change
The nano-oxide powder of property;
2) polymethyl acrylate of 4.5 parts by weight is added in the chloroform of 9 parts by weight and is mixed, be placed in magnetic agitation
In device, under conditions of 20 DEG C -25 DEG C, revolving speed 200r/min, mixing time 40min obtain mixed liquor one;
3) the modified nano oxidized powder in the surface that step 1) obtains is mixed with the mixed liquor one that step 2 obtains, and added
The tributyl phosphate of the water and 3.2 parts by weight that enter 52 parts by weight is placed in ball milling in ball mill, revolving speed 150r/min, and the time is
10h obtains mixed liquor two;
4) epoxy resin of 42 parts by weight, the polydiene base of 5.4 parts by weight are added into the mixed liquor two that step 3) obtains
Third alkyl dimethyl ammonium chloride, is placed in high-speed mixer, and adjusting revolving speed is 700r/min, then mixing time 25min is added
The waterproofing agent of 7.1 parts by weight, the Dacthal of 6.2 parts by weight, the corrosion-resistant agent of 9.5 parts by weight, 8.5 weights
The sodium chromate of part is measured, adjusting revolving speed is 400r/min, and mixing time is 5h to get target product;
5) target product that step 4) obtains is shaken into 10h, amplitude 50mm, revolving speed 100r/min in bottle swingging machine,
It filters to get final product.
Embodiment eight
A kind of abrasion-proof insulating layer, is made of following components and its content: 44 parts by weight of epoxy resin, polymethyl acrylate 5
Part, 10 parts of chloroform, 5.5 parts by weight of 3- glycidyl ether oxypropyltrimethoxysilane, 17 parts by weight of nano-oxide,
5.6 parts by weight of the third alkyl dimethyl ammonium chloride of polydiene base, 3.3 parts by weight of tributyl phosphate, 7.2 parts by weight of waterproofing agent, heat-resistant agent 6.3
Parts by weight, 9.6 parts by weight of corrosion-resistant agent, 8.8 parts by weight of sodium nitrite, 26 parts by weight of acetone, 55 parts by weight of water.
The nano-oxide is the mixture of nano magnesia, nano silica, nano-titanium dioxide, and weight ratio is received
Rice magnesia: nano silica: nano-titanium dioxide 4:3:3.
The waterproofing agent is the mixture of sodium methyl silicate and calcium stearate, and weight ratio sodium methyl silicate: calcium stearate is
7:3。
The corrosion-resistant agent is hexa, cinnamic acid, poly-aspartate, weight ratio hexa: cortex cinnamomi
Aldehyde: poly-aspartate 2:3:5.
The heat-resistant agent is the mixture of N-phenylmaleimide and Dacthal, weight ratio N-
Phenyl maleimide: Dacthal 4:6.
The preparation method of the abrasion-proof insulating layer, comprises the following steps:
1) nano-oxide of 17 parts by weight is placed in third in 80 DEG C of vacuum ovens after drying 14h, with 26 parts by weight
Ketone mixing, is added the 3- glycidyl ether oxypropyltrimethoxysilane of 5.5 parts by weight, is placed in magnetic stirring apparatus and stirs,
Under conditions of 20 DEG C -25 DEG C, revolving speed 400r/min, mixing time 4h filter, dry 8h in 80 DEG C of baking ovens, grind,
Obtain the modified nano-oxide powder in surface;
2) polymethyl acrylate of 5 parts by weight is added in the chloroform of 10 parts by weight and is mixed, be placed in magnetic agitation
In device, under conditions of 20 DEG C -25 DEG C, revolving speed 300r/min, mixing time 45min obtain mixed liquor one;
3) the modified nano oxidized powder in the surface that step 1) obtains is mixed with the mixed liquor one that step 2 obtains, and added
The tributyl phosphate of the water and 3.3 parts by weight that enter 55 parts by weight is placed in ball milling in ball mill, revolving speed 180r/min, and the time is
12h obtains mixed liquor two;
4) epoxy resin of 44 parts by weight, the polydiene base of 5.6 parts by weight are added into the mixed liquor two that step 3) obtains
Third alkyl dimethyl ammonium chloride, is placed in high-speed mixer, and adjusting revolving speed is 900r/min, then mixing time 30min is added
The waterproofing agent of 7.2 parts by weight, the heat-resistant agent of 6.3 parts by weight, the corrosion-resistant agent of 9.6 parts by weight, 8.8 parts by weight sodium nitrite,
Adjusting revolving speed is 500r/min, and mixing time is 8h to get target product;
5) target product that step 4) obtains is shaken into 12h, amplitude 50mm, revolving speed 200r/min in bottle swingging machine,
It filters to get final product.
Comparative example one
A kind of abrasion-proof insulating layer, including component and its content with embodiment two, but unlike embodiment two, this is right
Ratio is not added with waterproofing agent and heat-resistant agent.
The abrasion-proof insulating layer, the step of including, is the same as embodiment two.
Comparative example two
A kind of abrasion-proof insulating layer, including component and its content with embodiment three, but unlike embodiment three, this is right
Ratio is not added with corrosion-resistant agent and corrosion inhibiter.
The abrasion-proof insulating layer, the step of including, is the same as embodiment three.
Comparative example three
A kind of abrasion-proof insulating layer, including component and its content with embodiment five.
This is used for the erosion resisting insulation material of buried cable, and the step of including is but different from embodiment five with embodiment five
, which lacks step 5), i.e., does not shake target product in bottle swingging machine.
Comparative example four
A kind of abrasion-proof insulating layer, including component and its content with embodiment seven, but unlike embodiment seven, this is right
Ratio lacks coupling agent.
The abrasion-proof insulating layer, the step of including, the comparative example lacked step with embodiment seven, but unlike embodiment three
It is rapid 1), i.e., not by nano-oxide with coupling agent modified.
Performance test:
1) measuring mechanical property
In actual application, the mechanical performance of coating is to measure the important performance assessment criteria of its durability.Coating is because matching
Square component ratio is different, and mechanical performance has certain difference.
It is poured into deployed mixed liquor into mold, obtains coating sample after solidifying at room temperature.Its specification are as follows: a length of 30
Mm, wide lO mm, with a thickness of 100 μm.Stress-strain test is carried out to paint layer using U.S.'s Mei Tesi CMT5305 universal testing machine,
Strain rate is 10mm/min.
Tensile strength is sample when being pulled off on puller system, and the load born on unit cross-sectional area uses N/mm2It indicates,
Calculation formula is as shown in 1-1:
P=F/S (1-1)
In formula:
The tensile strength of mono- sample of P, N/mm2;
Power suffered on rupture cross section, N when F- sample fracture;
The area in S- sample fracture face, mm2。
Wherein, 1MPa=1N/mm2
Elongation at break is the ratio of the elongation and raw footage when sample is pulled off, and is expressed as a percentage, and calculation formula is such as
Shown in 1-2:
E=(L1-L0)/L0 (1-2)
In formula:
Mono- elongation at break of E, %;
L0One sample raw footage, mm;
L1The length of part of the force, mm when-sample fracture.
2) water resistance test
It takes coating mixed liquor 30g in glass culture dish, spontaneously dries, film is made.Using water absorption rate characterization film
Film is cut into the square sample of 15mm × 15mm by water resistance, weighs sample mass (being accurate to 0.001g).It puts it into
In culture dish equipped with distilled water, distilled water did not had the upper surface of film, impregnates take out afterwards for 24 hours at room temperature.Gently with filter paper
The moisture of film surface is wiped out, and is weighed immediately.According to formula 2-1, the water absorption rate of film is calculated, each sample testing 3 times,
It is averaged.
W=(m1-m0)/m0× 100% (2-1)
In formula, the water absorption rate of W- film, %;
m0The initial mass of sample, g;
m1Quality after sample water suction, g.
3) corrosion-resistant test
Three clean beakers are taken, prepare the hydrochloric acid of 10% concentration, the NaOH solution of 10% concentration respectively, by coating sample point
The corrosion feelings of coating sample observation film surface Jin Ru not be taken out in two kinds of prepared solution, after being kept for sealed environment 45 days
Condition.
4) adhesive force is tested
Adhesive force test utilizes cross-hatching, is on galvanized sheet iron to ground according to ISO2409 and GB/19286-98 standard
The test coating that coating thickness is 121-250 μm carries out well stroke lattice to coating sample, gently sweeps off surface impurity later, with
It is placed in parallel among adhesive tape with scribing line lattice, checks cutting part shape then to open adhesive tape close to 60 ° of angles with hand levelling glue band
State.
5) long-term height temperature stability
The coating of 1000mg/L is respectively configured, respectively 200mL is taken to be respectively placed in ageing can, by its elder generation at -50 DEG C constant temperature
It places 90 days, then constant temperature is placed 90 days at 100 DEG C, measures its interfacial tension with surface tension instrument, and calculate interfacial tension
Growth rate investigates the height temperature stability of coating.
The Measurement results such as table 1 of embodiment one to eight and comparative example one to four:
The test result of table 1 embodiment and comparative example
Tensile strength MPa | Elongation at break % | Water resistance | Acid resistance | Alkali resistance | Adhesive force | Height temperature stability (%) | |
Embodiment one | 22.5 | 120.7 | 41 | Without elephant skin, bubble, peeling phenomenon | Without elephant skin, bubble, peeling phenomenon | Smooth, nothing falls off | 5.4 |
Embodiment two | 22.1 | 127.6 | 40 | Without elephant skin, bubble, peeling phenomenon | Without elephant skin, bubble, peeling phenomenon | Smooth, nothing falls off | 5.2 |
Embodiment three | 23.9 | 133.6 | 36 | Without elephant skin, bubble, peeling phenomenon | Without elephant skin, bubble, peeling phenomenon | Smooth, nothing falls off | 4.5 |
Example IV | 23.7 | 130.8 | 35 | Without elephant skin, bubble, peeling phenomenon | Without elephant skin, bubble, peeling phenomenon | Smooth, nothing falls off | 4.6 |
Embodiment five | 25.4 | 141.3 | 31 | Without elephant skin, bubble, peeling phenomenon | Without elephant skin, bubble, peeling phenomenon | Smooth, nothing falls off | 3.8 |
Embodiment six | 24.4 | 138.9 | 35 | Without elephant skin, bubble, peeling phenomenon | Without elephant skin, bubble, peeling phenomenon | Smooth, nothing falls off | 4.5 |
Embodiment seven | 24.2 | 136.7 | 35 | Without elephant skin, bubble, peeling phenomenon | Without elephant skin, bubble, peeling phenomenon | Smooth, nothing falls off | 4.4 |
Embodiment eight | 25.0 | 140.3 | 33 | Without elephant skin, bubble, peeling phenomenon | Without elephant skin, bubble, peeling phenomenon | Smooth, nothing falls off | 4.0 |
Comparative example one | 13.2 | 106.3 | 55 | A large amount of elephant skin, bubble, peeling phenomenons | A large amount of elephant skin, bubble, peeling phenomenons | A little Paint Falling | 12.6 |
Comparative example two | 13.3 | 105.5 | 46 | A large amount of elephant skin, bubble, peeling phenomenons | A large amount of elephant skin, bubble, peeling phenomenons | A little Paint Falling | 11 |
Comparative example three | 12.4 | 102.4 | 52 | A large amount of elephant skin, bubble, peeling phenomenons | A large amount of elephant skin, bubble, peeling phenomenons | Large area Paint Falling | 11.8 |
Comparative example four | 11.6 | 100.3 | 50 | A small amount of elephant skin, bubble, peeling phenomenon | A small amount of elephant skin, bubble, peeling phenomenon | Large area Paint Falling | 12.5 |
As can be seen from Table 1: 1) embodiment one to eight shows good comprehensive performance: having excellent mechanicalness
Can, tensile strength is in 22MPa or more, and elongation at break is 120% or more, and water-fast, resistant to chemical etching, adhesive force is strong, in high/low temperature
Under environment, performance is stablized.2) embodiment one to four is a kind of single substance, embodiment five using heat-resistant agent and corrosion-resistant agent
To eight, use heat-resistant agent and corrosion-resistant agent for the mixture of two or three of substance, the comprehensive performance of five to eight material of embodiment
It is better than embodiment one to four;For example IV compared with embodiment three, material composition is identical with content, the technical parameter of preparation method
The performance of difference, embodiment three is better than example IV.3) comparative example one lacks waterproofing agent and heat-resistant agent compared with embodiment two;
Comparative example two lacks corrosion-resistant agent and corrosion inhibiter compared with embodiment three;Comparative example three does not produce target compared with embodiment five
Object shakes in bottle swingging machine;Nano-oxide is not modified by comparative example four compared with embodiment seven;Comparative example one to four
The performance of material is poorer than embodiment one to eight.Illustrate to be complementary between each raw material, lacks any raw material, material
Performance will be decreased obviously, therefore use insulating layer material of the invention, use same power and Rubbing number in ground friction
Afterwards, service chamber of the invention abrasion is slight, using the material object serious wear of documents, while in transport and equal height
Fall rear cabinet of the invention substantially without damage, tool is normal in cabinet, broken using the insulating materials body structure of documents
It is bad, and tool damage in cabinet.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features,
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention
Within protection scope.
Claims (5)
1. a kind of communication intelligence optical maintenance tool box, including outer container (1), it is characterised in that: the outer container (1) includes upper housing
(2), upper housing (2) bottom is equipped with lower case (3), and the upper housing (2) is connected through hinge activity with lower case (3),
Solar panel (4) are equipped at the top of the upper housing (2), are equipped with battery (5) inside the upper housing (2), the electric power storage
Pond (5) side is equipped with converter (6), and converter (6) side is equipped with GPS locator (7) and bottom is equipped with programmable control
Device (8) processed, the programmable controller (8) are equipped with operating switch (9) and cancel switch (10), and the cancel switch (10) sets
At the top of operating switch (9), programmable controller (8) side is equipped with alarm (11), and alarm (11) side is set
Have signal conveyer (12), be equipped with communicator (13) at the top of the signal conveyer (12), resistance is equipped with inside the lower case (3)
Partition (14), baffler (14) two sides are equipped with well (15), and the outer surface of the upper housing and lower case is coated with
There is abrasion-proof insulating layer, piston is equipped in the well, the air inlet of the piston is equipped with check valve, is equipped in the well
The electric telescopic rod of piston rod is pulled, the electric telescopic rod is connect with programmable controller;The signal conveyer (12) is even
It connects end and is equipped with signal receiver, the signal receiver is set to server internal;The first protection is equipped on the inside of the upper housing (2)
Layer (16), lower case (3) inside are equipped with the second protective layer (17);The outer surface of the upper housing and lower case is coated with
Abrasion-proof insulating layer, is made of following components and its content: 2-5 parts of epoxy resin 30-44 parts by weight, polymethyl acrylate, trichlorine
5-10 parts of methane, coupling agent 3.8-5.5 parts by weight, nano-oxide 12-17 parts by weight, the third alkyl dimethyl ammonium chloride of polydiene base
4.5-5.6 parts by weight, tributyl phosphate 2.8-3.3 parts by weight, waterproofing agent 6.7-7.2 parts by weight, heat-resistant agent 5.8-6.3 weight
Part, corrosion-resistant agent 8.9-9.6 parts by weight, corrosion inhibiter 7.3-8.8 parts by weight, acetone 20-26 parts by weight, water 46-55 parts by weight.
2. a kind of communication intelligence optical maintenance tool box according to claim 1, it is characterised in that: first protective layer
(16), the second protective layer (17) and baffler (14) are made of sponge material.
3. a kind of communication intelligence optical maintenance tool box according to claim 1, it is characterised in that: the battery (5),
GPS locator (7), alarm (11), signal conveyer (12) and communicator (13) electrically connect with programmable controller (8)
It connects.
4. a kind of communication intelligence optical maintenance tool box according to claim 1, it is characterised in that: outer container (1) side
Face is equipped with lock (18), is equipped with handle (19) between the lock (18).
5. a kind of communication intelligence optical maintenance tool box according to claim 1, it is characterised in that: the solar battery
Plate (4) is electrically connected by converter (6) and battery (5).
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JP2006166831A (en) * | 2004-12-17 | 2006-06-29 | Matsushita Electric Ind Co Ltd | Oxygen concentration changeable storage |
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